Professional Documents
Culture Documents
Product identity :
5625110000
Product type :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
yacht.
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
17 May 2013
22 January 2013.
Mixture
R10
Xn; R20/21
Xi; R38
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Warning
Hazard statements :
Precautionary statements :
General :
Read label before use. Keep out of reach of children. If medical advice is needed, have product
container or label at hand.
Prevention :
Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks, open flames and
hot surfaces. - No smoking. Use explosion-proof electrical, ventilating, lighting and all materialhandling equipment.
Response :
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF
ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
Storage :
Keep cool.
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5625110000
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients :
xylene
Contains methyl methacrylate and n-butyl methacrylate. May produce an allergic reaction.
Not applicable.
Yes, applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
xylene
R10
Xn; R20/21
Xi; R38
methyl methacrylate
EC: 201-297-1
CAS: 80-62-6
Index: 607-035-00-6
<1
F; R11
Xi; R37/38
R43
n-butyl methacrylate
EC: 202-615-1
CAS: 97-88-1
Index: 607-033-00-5
<1
R10
Xi; R36/37/38
R43
toluene
ethylbenzene
Classification
Regulation (EC) No.
1272/2008 [CLP]
F; R11
Xn; R20
Xn; R20, R65
Xi; R36/37/38
N; R51/53
F; R11
Repr. Cat. 3; R63
Xn; R48/20, R65
Xi; R38
R67
See Section 16 for the
full text of the R-phrases
declared above.
Type
[1] [2]
[1] [2]
[1] [2]
[1] [2]
[1]
[1] [2]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
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5625110000
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact :
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Harmful if inhaled. Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
No specific data.
Skin contact :
Ingestion :
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments :
No specific treatment.
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
Decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide/
oxides
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5625110000
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5625110000
ethylbenzene
methyl methacrylate
toluene
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
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5625110000
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
Not recommended: nitrile rubber, neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl
chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified
respirator or equivalent.
Liquid.
Odor :
Solvent-like
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
1 - 7 vol %
Vapor density :
Relative density :
1.295 g/cm
Solubility(ies) :
Very slightly soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Explosive properties :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Weighted average: 36 %
Water % by weight :
Weighted average: 0 %
VOC content :
471.8 g/l
TOC Content :
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5625110000
ethylbenzene
solvent naphtha (petroleum), light
arom.
methyl methacrylate
n-butyl methacrylate
toluene
Result
Species
Dose
Exposure
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Rat
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
>5000 mg/kg
3500 mg/kg
>5 mg/l
4 hours
4 hours
4 hours
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Oral
Rabbit
Rat
Rat
Rabbit
Rat
Rat
Rabbit
Rat
Rat
Rat
>2000 mg/kg
8400 mg/kg
78000 mg/m
>5 g/kg
7872 mg/kg
4910 ppm
11300 uL/kg
16 g/kg
49 g/m
636 mg/kg
4 hours
4 hours
4 hours
-
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5625110000
ATE value
Dermal
Inhalation (gases)
Inhalation (vapors)
3857.5 mg/kg
17534 ppm
140.9 mg/l
Irritation/Corrosion
Product/ingredient name
xylene
ethylbenzene
solvent naphtha (petroleum), light
arom.
n-butyl methacrylate
toluene
Result
Species
Score
Exposure
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 15 milligrams
24 hours 100 microliters
Rabbit
Rabbit
Rabbit
500 microliters
0.5 minutes 100 milligrams
24 hours 20 milligrams
Category
Category 3
Category 3
Category 3
Route of exposure
Target organs
Not applicable.
Not applicable.
Not applicable.
Category
toluene
Category 2
Route of exposure
Target organs
Not determined
Not determined
Aspiration hazard
Product/ingredient name
Result
Carcinogenic effects
Mutagenic effects
Developmental effects
Fertility effects
toluene
Repr. 2, H361d
Sensitization :
Other information :
Result
Acute LC50 8500 g/l Marine water
Acute LC50 13.5 mg/l
Acute EC50 4600 g/l Fresh water
Acute EC50 6530 - 9460 g/l Fresh water
Acute EC50 1.8 mg/l
Chronic NOEC <1000 g/l Fresh water
Acute EC50 19 mg/l
Acute EC50 6.14 mg/l
Acute LC50 9.22 mg/l
methyl methacrylate
n-butyl methacrylate
toluene
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Species
Crustaceans - Palaemonetes pugio
Fish
Algae - Pseudokirchneriella subcapitata
Crustaceans - Artemia sp. - Nauplii
Daphnia
Algae - Pseudokirchneriella subcapitata
Algae - Pseudokirchneriella subcapitata
(green algae)
Daphnia - Daphnia magna
Fish - Oncorhynchus mykiss (rainbow
trout)
Fish - Pimephales promelas - Adult
Daphnia - Daphnia magna - Neonate
Algae - Pseudokirchneriella subcapitata
Exposure
48 hours
96 hours
72 hours
48 hours
48 hours
96 hours
96 hours
48 hours
96 hours
96 hours
21 days
72 hours
5625110000
Crustaceans - Gammarus
pseudolimnaeus - Adult
Daphnia - Daphnia magna - Juvenile
(Fledgling, Hatchling, Weanling)
Fish - Oncorhynchus kisutch - Fry
Algae - Pseudokirchneriella subcapitata
Daphnia - Daphnia magna
48 hours
48 hours
96 hours
96 hours
21 days
Test
-
Product/ingredient name
xylene
ethylbenzene
solvent naphtha (petroleum), light
arom.
Result
Dose
Photolysis
Inoculum
-
Biodegradability
Readily
Readily
Readily
LogPow
xylene
ethylbenzene
methyl methacrylate
n-butyl methacrylate
toluene
3.16
3.1
1.38
2.88
2.69
BCF
6 - 23.4
8.3
Potential
low
low
low
low
low
Mobility :
Not applicable.
vPvB :
Not applicable.
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5625110000
ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
UN1263
PAINT
14.3
Transport hazard class(es)
3
14.4
PG*
14.5
Env* Additional information
III
No.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
PAINT
III
No.
Emergency schedules
(EmS)
F-E, S-E
IATA
Class
UN1263
PAINT
III
No.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
C6: Flammable (R10)
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5625110000
F - Highly flammable
Repr. Cat. 3 - Toxic to reproduction category 3
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
H225
H226
H304
H312
H315
H317
H319
H332
H335
H336
H361d
H373
H411
Justification
On basis of test data
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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