434 7 PDF

Risk Assessment Data Directory
Report No. 434 7

March 2010
I n t e r n a t i o n a l A s s o c i a t i o n o f O i l & G a s P r o d u c e r s
Consequence
modelling
P
ublications
Global experience
Te International Association of Oil & Gas Producers has access to a wealth of technical
knowledge and experience with its members operating around the world in many diferent
terrains. We collate and distil this valuable knowledge for the industry to use as guidelines
for good practice by individual members.
Consistent high quality database and guidelines
Our overall aim is to ensure a consistent approach to training, management and best prac-
tice throughout the world.
Te oil and gas exploration and production industry recognises the need to develop consist-
ent databases and records in certain felds. Te OGPs members are encouraged to use the
guidelines as a starting point for their operations or to supplement their own policies and
regulations which may apply locally.
Internationally recognised source of industry information
Many of our guidelines have been recognised and used by international authorities and
safety and environmental bodies. Requests come from governments and non-government
organisations around the world as well as from non-member companies.
Disclaimer
Whilst every efort has been made to ensure the accuracy of the information contained in this publication,
neither the OGP nor any of its members past present or future warrants its accuracy or will, regardless
of its or their negligence, assume liability for any foreseeable or unforeseeable use made thereof, which
liability is hereby excluded. Consequently, such use is at the recipients own risk on the basis that any use
by the recipient constitutes agreement to the terms of this disclaimer. Te recipient is obliged to inform
any subsequent recipient of such terms.
Tis document may provide guidance supplemental to the requirements of local legislation. Nothing
herein, however, is intended to replace, amend, supersede or otherwise depart fom such requirements. In
the event of any confict or contradiction between the provisions of this document and local legislation,
applicable laws shall prevail.
Copyright notice
Te contents of these pages are Te International Association of Oil and Gas Producers. Permission
is given to reproduce this report in whole or in part provided (i) that the copyright of OGP and (ii)
the source are acknowledged. All other rights are reserved. Any other use requires the prior written
permission of the OGP.
Tese Terms and Conditions shall be governed by and construed in accordance with the laws of Eng-
land and Wales. Disputes arising here fom shall be exclusively subject to the jurisdiction of the courts of
England and Wales.
RADD Consequence modelling
OGP

contents

1.0 Scope and Definitions ........................................................... 1
2.0 Summary of Recommended Approaches ................................ 1
2.1 Release modelling .......................................................................................... 3
2.1.1 Simple approaches to release modelling................................................................. 4
2.1.2 Software for release modelling................................................................................. 6
2.1.3 Modelling Releases from Buried Pipelines.............................................................. 7
2.2 Dispersion and ventilation modelling........................................................... 7
2.2.1 Simple approaches to dispersion modelling........................................................... 9
2.2.2 Software for dispersion modelling ......................................................................... 11
2.2.3 CFD for ventilation and dispersion modelling....................................................... 12
2.3 Fire and thermal radiation modelling.......................................................... 13
2.3.1 Simple approaches to fire and thermal radiation modelling................................ 14
2.3.2 Software for fire and thermal radiation modelling ................................................ 20
2.3.3 CFD for fire and thermal radiation modelling........................................................ 20
2.4 Explosion modelling..................................................................................... 22
2.4.1 Simple approaches to explosion modelling .......................................................... 23
2.4.2 Software for explosion modelling........................................................................... 23
2.4.3 CFD for explosion modelling .................................................................................. 24
2.5 Smoke and gas ingress modelling.............................................................. 24
2.5.1 Simple approaches to smoke and gas ingress modelling ................................... 25
2.5.2 Software for smoke and gas ingress modelling.................................................... 26
2.5.3 CFD for smoke and gas ingress modelling ........................................................... 27
2.6 Toxicity modelling ........................................................................................ 27
2.6.1 Simple approaches to toxicity modelling .............................................................. 29
2.6.2 Software for toxicity modelling............................................................................... 29
2.6.3 CFD for toxicity modelling....................................................................................... 29
3.0 Guidance on use of approaches........................................... 29
3.1 General validity ............................................................................................. 29
3.2 Uncertainties ................................................................................................. 30
3.3 Choosing the right approach for consequence modelling....................... 30
3.4 Geometry modelling for CFD....................................................................... 31
4.0 Review of data sources ....................................................... 32
5.0 Recommended data sources for further information ............ 32
6.0 References .......................................................................... 32
6.1 References for Sections !2.0 to !4.0 .............................................................. 32
6.2 References for other data sources.............................................................. 34

OGP

Abbreviations:

BLEVE Boiling Liquid Expanding Vapour Explosion
CFD Computational Fluid Dynamics
CHRIS Chemical Hazards Reference Information System
CSTR Continuous Stirred Tank Reactor
CV Control Volume
DAL Design Accidental Load
DNV Det Norske Veritas
EU European Union
FV Finite Volume
HSE (UK) Health and Safety Executive
HVAC Heating, Ventilation and Air Conditioning
IDLH Immediate Danger to Life and Health
JIP Joint Industry Project
LD
x
Lethal Dose resulting in fatalities to x% of population
LFL Lower Flammable Limit (also known as Lower Explosive Limit, LEL)
LPG Liquefied Petroleum Gas
MSDS Material Safety Data Sheet
PDR Porosity, Distributed Resistance
QRA Quantitative Risk Assessment (sometimes Analysis)
SLOD Significant Likelihood of Death
SLOT Specified Level Of Toxicity
SVP Saturated Vapour Pressure
TNO Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk
Onderzoek
(Netherlands Organization for Applied Scientific Research)
TR Temporary Refuge
UVCE Unconfined Vapour Cloud Explosion
VCE Vapour Cloud Explosion

OGP

1
1.0 Scope and Definitions
Consequence modelling refers to the calculation or estimation of numerical values (or
graphical representations of these) that describe the credible physical outcomes of loss
of containment scenarios involving flammable, explosive and toxic materials with
respect to their potential impact on people, assets, or safety functions.
This datasheet presents (Section 2.0) recommended approaches to consequence
modelling for accidental releases of hazardous materials, with the potential to cause
harm to people, damage to assets and impairment of safety functions, from offshore
and onshore installations.
Consideration of environmental impacts is excluded, although the recommended
approaches to release modelling (in particular for liquids) may be applied to estimate
potential quantities of hydrocarbon spilt.
This datasheet is not intended to be a textbook of consequence modelling theory but
rather to indicate the consequence phenomena that need to be considered and to
provide guidance on modelling that is fit for purpose.

2.0 Summary of Recommended Approaches
This section addresses the following consequences of a loss of containment incident:
1. Release (discharge)
2. Dispersion in air and water
3. Fire and thermal radiation
4. Explosion
5. Smoke and gas ingress
6. Toxicity

Figure 2.1 illustrates and develops the relationship between many of these.
For each topic, guidance is given on some or all of the following possible approaches:
Simple correlations or formulae
General purpose consequence modelling software (see below)
CFD (Computational Fluid Dynamics see below)

Whichever approach is adopted, it should be used with an understanding of its range of
validity, its limitations, the input data required, the valid results that can be obtained, the
results sensitivity to the different input data, and how the results can be verified.
OGP

2
Fi gure 2. 1 Consequence Phenomena and thei r I nterrel ati onshi p

General Purpose Consequence Model l i ng Software
The main commercial general purpose consequence modelling packages are:
CANARY, from Quest (http://www.questconsult.com/canary.html)
EFFECTS, from TNO
(www.tno.nl/content.cfm?context=markten&content=product&laag1=186&laag2=267
&item_id=739)
PHAST, from DNV
(http://www.dnv.com/services/software/products/safeti/SafetiHazardAnalysis/index.a
sp)
TRACE, from Safer Systems (www.safersystem.com)

These model most of the consequences set out above apart from smoke. However, they
are designed for onshore studies and not all of the models included will be appropriate
for offshore use, in particular in enclosed modules. The sections below give guidance
on the appropriate use of these models.
In addition, there are freeware packages that can be downloaded for the internet but
these do not come with any training or support, or with any guarantee of code quality;
OGP

3
the commercial packages listed above do include these and come from reputable
organizations with quality management systems.
In addition, freeware calculators may be found for specific consequences (e.g.
BLEVE) but these suffer the same disadvantages listed above for general consequence
modelling.

Computati onal Fl ui d Dynami cs
Computational Fluid Dynamics (CFD) can be used to obtain numerical solutions for
ventilation, dispersion and explosion problems for both offshore platforms and onshore
plants. CFD simulations are becoming increasingly common as the computing power of
standard desktop computers grows. The NORSOK standard Z-013 [21] specifies use of
CFD in its probabilistic approach to explosion risk assessment. The objective of the
probabilistic assessment is to generate realistic (representative) overpressures for an
area based on probabilistic arguments. Ventilation, gas leaks, dispersion as well as gas
explosions are considered by establishing probable explosion scenarios, performing
explosion simulations and establishing probability of exceedance curves.
The application of CFD for gas explosion studies is common for offshore platforms and
is increasingly used onshore in cases where the explosion risk is significant and a
better description of the physics is required in order to give a more robust estimate of
the risk.
CFD simulations essentially solve the conservation equations for mass, momentum and
enthalpy in addition to the equations for concentration and flammable gas effects. The
equations are generally closed using the !"# turbulence model. Most of the
commercially available CFD packages (see below) are based on the Finite Volume (FV)
method which uses an integral form of the conservation equations. Essentially, the
solution domain is subdivided into a number of control volumes (CV) at the centroid of
which lies a computational node where the variable values are calculated. The
conservation equations are applied to each CV and interpolation is used to express
variable values at the CV surface in terms of the centre values.
The most widely used commercially available CFD packages are:
AutoReaGas, from Century Dynamics
(http://www.ansys.com/Products/autoreagas.asp)
CFX, from ANSYS, Inc. (http://www.ansys.com/products/cfx.asp)
FLUENT, now also from ANSYS, Inc. (http://www.fluent.com/)
EXSIM, from EXSIM Consultants AS (http://www.exsim-consultants.com/)
FLACS, from GexCon (http://www.gexcon.com/index.php?src=flacs/overview.html)
Kameleon FireEx, from ComputIT (http://www.computit.no/)

2.1 Release modelling
Release modelling also called discharge or source term modelling is mainly used to
determine the rate at which a fluid is released to the environment in a loss of
containment incident, together with the associated physical properties (e.g.
temperature, momentum).
A simple approach is to calculate the initial rate and to assume that this is constant over
time. This is often used for studies of onshore facilities, especially where the offsite
risk is the motivation for the study.
OGP

4
A more sophisticated approach is to model the time dependence of the release rate.
This is often used for studies of offshore facilities, where the time dependence has a
significant impact on the likelihood, in particular, of the initial event escalating. The
modelling required is more complex but avoids certain issues that arise when initial rate
modelling is used:
Initial rate modelling can lead to over-prediction of the flammable/explosive mass in
a vapour cloud
Initial rate modelling can lead to over-prediction of the size of a jet fire over time but
under-predict its duration or the time for which it exceeds a critical length (e.g. to
other equipment)
Initial rate modelling can lead to over-prediction of the impact of toxic gas or smoke
effects

In general, time dependence should be explicitly modelled in offshore studies, where
the impacts over relatively short distances (tens of metres) and over time periods up to
the required endurance times of the TR (Temporary Refuge) and other safety functions,
which may be of the order of 1 hour, are of concern. Time dependence is less often
modelled in onshore studies, where the impacts over relatively long distances
(hundreds of metres to a few kilometres) and over time periods up to that required for
effective emergency action to commence. An exception to this is the modelling of
cross-country pipeline ruptures, for which time dependence may be important.

2.1.1 Simple approaches to release modelling
Where gas or non-flashing liquid would be released from an orifice, simple formulae
exist to calculate the initial rate, in particular Bernoullis equation for liquids (strictly,
incompressible fluids).
Some example release rates are shown in Figure 2.2, Figure 2.3 and Figure 2.4 for
selected representative materials. These were obtained using DNVs PHAST software.
Equations for modelling time-varying releases of gas, including blowdown, are given in
the CMPT Guide to quantitative risk assessment for offshore installations [1]. This also
includes a simple method for calculating the flash fraction of a liquid such as
unstabilized crude.
Modelling releases from ruptured pipelines is rather more complex as the pipeline
pressure decreases away from the release point over time and so the flow rate
decreases with time, especially for gases. It is therefore normal to use software tools
for discharge modelling.

OGP

5
Fi gure 2. 2 Rel ease Rates for Natural Gas at 20C

Fi gure 2. 3 Rel ease Rates for Propane at 20C

Note: at 1 barg and 5 barg the releases are vapour; at higher pressures they are two-phase.
OGP

6
Fi gure 2. 4 Rel ease Rates for Kerosene-type Li qui d at 20C (densi ty = 714
kg/ m
3
)

2.1.2 Software for release modelling
There is a range of software tools available that include release modelling. As with all
software, its range of validity and limitations need to be understood. For example, the
thermodynamics of mixtures may be modelled by an average equivalent pure
component. However, as computer power increases, this limitation is increasingly
being eliminated in favour of full multicomponent thermodynamics.
Software can model some or all of the following:
Time-dependent releases, including inflow, isolation and blowdown
Flashing liquid releases
" Releases that flash in the atmosphere as they are released
" Releases from vessels containing liquid that flashes as the pressure decreases
Releases from vessels of different shapes and orientations
Releases from long pipelines
These models are generally appropriate for use onshore and offshore.
When the fluid after release is two-phase, the modelling needs to predict the liquid
droplet size so that the amount of liquid that rains out (falls to the ground or water
surface) can be calculated as part of the dispersion modelling (Section 2.2).
SPT Groups OLGA software (http://www.sptgroup.com/products/olga) can be used to
model time dependent releases from pipeline networks and includes multiphase flow
capability.
It should be noted that a release from a high pressure reservoir will normally be quite
complex with sonic flow, expansion and compression shocks. In safety studies, this
OGP

7
complex outflow is often not calculated and the boundary conditions for the jet are
given at surrounding pressure. Both the specified momentum and the temperature
(density) of this jet may be important for the dispersion simulation and thereby the
resulting gas cloud size. Often this boundary condition is specified as pure gas at sonic
velocity at surrounding pressure or lower. This is not conserving momentum and
should not be used when momentum is important for dispersion.

2.1.3 Modelling Releases from Buried Pipelines
Following a full bore rupture there will be flow from both sides of the break. The
consequences of a full bore rupture of a buried pipeline can be modelled as follows:
1. Initial high flow rate: consider immediate ignition as a fireball, using mass released
up to the time when this mass equals the fireball mass giving the same fireball
duration.
2. Ensuing lower flow rate(s): model dispersion and delayed ignition with low
momentum (velocity) as the flows from both sides of the break are likely to interact.

The following figure illustrates a possible simplification into quadrants of release
directions for a leak from a buried pipeline. The text beside suggests an approach to
modelling these for medium and large leaks, based on these having sufficient force to
throw out the overburden (and even concrete slabs, if placed on top).
1. Vertical release. Model as vertical release
(upwards) without modification of normal discharge
modelling output, i.e. full discharge velocity.
2, 3. Horizontal release. Model at angle of 45
upwards with velocity of 70 m/s.
4. Downward release. Model as vertical release
(upwards) with low (e.g. 5 m/s) velocity to reflect loss of
momentum on impact with ground beneath.

For small horizontal or downward leaks, the force exerted by the flow is unlikely to
throw out the overburden, hence the flow will only slowly percolate to the surface. The
following approach is suggested for all release directions:
Calculate discharge rate as normal.
Remodel release with a very low pipeline pressure (1 barg for operating pressure
>10 barg, 0.1 barg for operating pressure < 10 barg), to simulate diffusion through
the soil, with the hole size modified to obtain the same discharge rate as above.

2.2 Dispersion and ventilation modelling
Dispersion modelling is used to determine how the fluid released spreads in the
environment: usually air but also water
1
.
Onshore, dispersion is usually modelled for releases into the open air
Offshore, modelling dispersion within an enclosed module is usually required;
modelling underwater releases (e.g. pipeline and flowline failures) is often also
needed.

1
Dispersion in soil is considered in environmental rather than safety risk studies and is outside
the scope of this datasheet.
OGP

8
When a release is in the open air, several mechanisms may cause it to disperse. These
are illustrated in Figure 2.5. Not all releases go through all phases. A gas release on an
offshore platform may go directly from turbulent jet to passvie dispersion. A release
from a stack may be passive from the stack tip. The vapour in a release of refrigerated
LPG will be dense from the start.

Fi gure 2. 5 Mechani sms of Atmospheri c Di spersi on of Vapour

A vapour release inside an enclosed volume (a module of an offshore installation or a
building onshore) will mix with the air flowing through the volume. On offshore facilities
with enclosed modules, what is required for fire and explosion calculations is first of all
the size of the flammable/explosive cloud within the module. Onshore, the vapour cloud
may emerge from a vent or stack, already partially diluted, and then disperse in the
environment.
When the release is wholly or partially liquid, typically this will fall onto a solid surface
or through a grated deck to the sea below; on a solid surface it will spread out to form a
pool. At the same time, some of this liquid may vaporize, adding to any vapour in the
initial release, and will disperse in the atmosphere, as illustrated in Figure 2.6.
Dispersion modelling thus frequently has to be able to model all of these phenomena, in
addition to addressing the different mechanisms of atmospheric dispersion. The
OGP

9
relationship between many of these phenomena and mechanisms is illustrated in Figure
2.1.

Fi gure 2. 6 Pool Vapori sati on

2.2.1 Simple approaches to dispersion modelling
Very little dispersion modelling can validly be done using simple formulae. That which
can is as follows:
1. Passive (Gaussian) dispersion
2. Gas build-up in enclosed volumes
" Using a Continuous Stirred Tank Reactor (CSTR) model, when it is acceptable to
assume a uniform concentration throughout the volume (e.g. as source term for a
release from a vent or stack, or calculating toxic impact for people indoors)
" To calculate the quantity of flammable gas, for explosion modelling (see Section
2.4)
3. Oil pool spreading
4. Gas releases subsea.
The equations for passive dispersion, 1, can be found in standard texts on atmospheric
dispersion. The equations for 2 (CSTR model) and 3 are given in [1].
Two simplified methods have been developed to calculate the quantity of flammable gas
in an enclosed volume such as an offshore module (2). Section 4.2.3.1 of [2] presents a
simple equation valid when the ventilation flow field is close to uniform. A workbook
approach to estimating the flammable volume produced by a gas release [3, 4] has been
developed as part of the JIP on Gas Build Up from High Pressure Natural Gas Releases in
Naturally Ventilated Offshore Modules, sponsored by 10 operators and the UK HSE.
For gas releases subsea (4), a common assumption is that the diameter of the plume at
the sea surface is 20% of the water depth at the release point, regardless of the gas flow
OGP

10
rate. This diameter together with the gas flow rate can then be used as input to a
Gaussian plume model.
Some example dispersion modelling results (distances to LFL) are given in Figure 2.7
and Figure 2.8. These were obtained using DNVs PHAST software.

Fi gure 2. 7 Di spersi on Di stances to LFL for Vapour Rel eases at 20C

Note: F1.5 refers to F stability, 1.5 m/s wind speed; D5 refers to D stability, 5 m/s
wind speed.
OGP

11
Fi gure 2. 8 Di spersi on Di stances to LFL for Two-Phase Propane Rel eases at
20C

Note: F1.5 refers to F stability, 1.5 m/s wind speed; D5 refers to D stability, 5 m/s
wind speed.

2.2.2 Software for dispersion modelling
Atmospheric dispersion modelling software mainly divides into:
Box models, which calculate vapour cloud dimensions and concentrations from
bulk properties.
CFD models, which divide the computational domain representing the space
through which the fluid disperses, into small volume elements where physical
properties are calculated explicitly.
In general, plume models do not allow for the influence of terrain, assuming a flat,
unobstructed surface. Plume models cannot model well the near field characteristics of
dispersion within a congested or confined area such as an offshore module or the
middle of a process unit. However, for far field (i.e. in open areas) dispersion and
when numerous release cases need to be run, plume models are ideal.
The software used needs to be selected with an understanding of the phenomena
(identified in Section 2.2) likely to occur for the cases being modelled, to ensure that the
software can adequately model them. For example:
A Gaussian plume model would not be appropriate for a gas release under pressure,
which will initially disperse as a turbulent jet (see Figure 2.5)
For releases of pressurised LPG, rain-out and re-evaporation may need to be
modelled.
The results from dispersion modelling need to be examined to ensure they are sensible,
i.e. that they match expectations about their behaviour.
OGP

12
FLOWSTAR, a model developed by CERC (www.cerc.co.uk/software/flowstar.htm) for
calculating profiles of the mean airflow and turbulence in the atmospheric boundary
layer, can calculate plume trajectory and spread in complex terrain and over variable
surface roughness. It is limited to passive dispersion (i.e. it cannot be used when fluid
momentum or density is significant) but its ability to model air flow over hilly terrain
may be useful. It is part of the widely accepted ADMS (Atmospheric Dispersion
Modelling System) suite of programs for air pollution modelling.
Other software packages such as CALPUFF and INPUFF are available, which are
especially suitable for mid- and far-field applications and for long (> 1 hour duration)
releases, however potential users should be aware of their limitations. HGSYSTEM
(www.hgsystem.com) is also well known as a freely available set of DOS-based
dispersion models.

2.2.3 CFD for ventilation and dispersion modelling
CFDs main application in dispersion modelling for QRA is in explosion analysis, of
which ventilation and dispersion simulations are an important part.
In explosion analysis for offshore installations, the objective of the ventilation
simulations is to generate a ventilation distribution in terms of rate, direction and
probability. Based on this information, representative wind conditions are selected for
the dispersion simulations. The NORSOK Z-013 standard [21] recommends that at least
8 wind directions are considered for the ventilation simulations. Only one wind speed is
necessary as it is generally assumed that the ventilation rate for a wind direction is
proportional to the wind speed so that ventilation rates can be linearly scaled with wind
speeds. Also, the number of simulations may be reduced from symmetry
considerations.
The objective of the dispersion simulations in explosion analysis is to identify credible
size, concentration and location of gas clouds and establish how the flammable gas
clouds varies with the hazardous leak location, external wind speed and direction and
leak direction. Those representative gas clouds are subsequently used in the explosion
studies.
Generally, the number of parameters that can be varied is high (leak
locations/rates/directions, wind conditions) and it is unrealistic to simulate all possible
combinations so that a selection must be made. The NORSOK probabilistic approach
[21] recommends that at least 3 leak points with 6 jet directions and 1 diffuse leak
should be evaluated. At least one of the scenarios needs to consider leak orientation
against prevailing ventilation direction. It is, however, possible to reduce the number of
dispersion simulations based on symmetry considerations and the physics of the
problem.
Additionally, not all the identified scenarios (after consideration of symmetry and
engineering judgement) need to be simulated. The frozen cloud concept can be used to
estimate the results of the scenarios not simulated. This is an assumption that gas
concentration scales with the leak rate and the inverse of the ventilation. The results
from the scenarios not simulated can then be obtained by altering the gas concentration
field in all control volumes by a constant factor. It is expected [26] that this assumption
will be reasonable in a ventilation dominated region (as opposed to a fuel dominated
region).
OGP

13
Although the NORSOK approach is for offshore installations, a similar approach can be
applied to explosion analysis for onshore installations. CFD modelling of ventilation
and dispersion is also useful for evaluating optimal geometry layout and location of gas
detectors [22,23]. CFD has also found some application in modelling dispersion in
complex topography (e.g. along a pipeline route), although it is not cost-effective to use
it routinely to model explicitly all scenarios typically represented in a QRA.

2.3 Fire and thermal radiation modelling
Fire modelling is typically used to calculate the flame dimensions for 2 purposes:
As input to a thermal radiation model
To determine whether a flame can reach a target for escalation (e.g. other
equipment)
It is important to understand the type of fire that can occur:
Fl ash fi re an ignited vapour plume, whose dimensions are typically determined
directly from the dispersion modelling as the distance to LFL
Jet fi re an intense, highly directional fire resulting from ignition of a vapour or
two-phase release with significant momentum
Pool fi re from an ignited liquid pool
2
or sea surface gas pool resulting from a
subsea gas release (e.g. from a pipeline or wellhead)
Offshore installations often have grated decks, so a liquid spill will fall through the
grating onto the sea surface. If ignited, the resulting sea fire may engulf one or more
legs of the installation as well as risers and conductors.
Boi l over when a full surface fire occurs in an oil storage tank, heat will slowly
conduct downwards to any layer of water in the bottom of the tank; this will then
vaporise and the resulting expansion will hurl boiling oil upwards out of the tank.
Fi rebal l / BLEVE
Strictly, a BLEVE (Boiling Liquid Expanding Vapour Explosion) is simply explosively
expanding vapour or two-phase fluid. A BLEVE results from a hot rupture of a
vessel typically containing hydrocarbons such as LPG
3
, stored and maintained as a
liquid under pressure, due to an impinging or engulfing fire. A flammable material
will be ignited immediately upon rupture by the impinging/engulfing fire and will
burn as a fireball.
A fireball would also result from immediate ignition of a release resulting from cold
catastrophic rupture of a pressurised vessel.
The initial phase of a gas pipeline rupture should also be modelled as a fireball.
Crater Fi re from ignition of a release from a buried pipeline. For vertical and
horizontal releases (see Section 2.1.3), the corresponding jet fire can be modelled.
For downward releases, the hole size corresponding to the low release velocity can
be taken as the diameter of a gas pool burning as a pool fire.

2
Note that it is not the liquid that burns but rather the vapour above it. The heat of the flame
vaporises the liquid beneath to provide the fuel supply.
3
BLEVEs of hydrocarbons up to butane or perhaps pentane are credible. A BLEVE of a vessel
containing a toxic material such as chlorine stored as a liquid under pressure is also credible
and should be considered if relevant. BLEVEs of heavier hydrocarbons such as crude oil or
petroleum do not occur.
OGP

14
An appropriate model for the type of fire that could result from ignition of the release
being considered can be selected. This will also depend on the time/location of ignition:
for example, for a high momentum vapour release, ignition close to the source will
result in a jet fire; ignition at a point away from the source will result in a flash fire or
explosion (see Section 2.4), which may also burn back to a jet fire.
Whatever model is selected, the following parameters of the flame have to be
calculated:
Flame dimensions
Surface emissive power (not for a flash fire)
Fireball only: duration (and possibly lift-off)

2.3.1 Simple approaches to fire and thermal radiation modelling
Some simple models for calculating flame dimensions are given in the sub-sections
below. Calculation of thermal radiation received by a target (e.g. a person) is not
straightforward, although an approximation can be used for a fireball due to its
spherical symmetry (see Section 0), and is best done using software. The simple flame
size models below are therefore best used either when only the flame dimensions are
required or to provide direct input to a flame radiation model.

2.3.1.1 Jet Fire
A simple correlation for the length L (m) of a jet flame due to Wertenbach [5]:
L = 18.5 Q
0.41
[Q = mass release rate (kg/s)]
A generalised formula for different fuel types is [6]:
L = 0.00326 (Q H
c
)
0.478
[H
c
= heat of combustion (J/kg)]
Based on calculations using the Chamberlain model [7], the following rough
relationships for distance along the flame axis to various thermal radiation levels have
been calculated:
37.5 kW/m
2
: 13.37 Q
0.447

12.5 kW/m
2
: 16.15 Q
0.447

5.0 kW/m
2
: 19.50 Q
0.447

Some example jet fire thermal radiation results for horizontal releases are presented in
Figure 2.9 and Figure 2.10. These were obtained using DNVs PHAST software, which
used the Chamberlain model [7].

OGP

15
Fi gure 2. 9 Jet Fi re Thermal Radi ati on Di stances at Ground Level for
Propane Rel eases at 1 m El evati on

Fi gure 2. 10 Jet Fi re Thermal Radi ati on Di stances at Ground Level for
Rel eases at 10 m El evati on

OGP

16
2.3.1.2 Pool Fire
The diameter of an equilibrium pool fire (i.e. where all the fuel is being consumed as it is
released) is easily calculated by equating the mass release rate over the pool surface
with the burning rate. Burning rates for typical materials are given in Table 2.1.
The pool diameter D (m) is given by:

(assuming constant thickness of the pool)

Tabl e 2. 1 Mass Burni ng Rates for Sel ected Materi al s (29] unl ess i ndi cated)
Materi al Mass Burni ng
Rate (kg/ m
2
s)
Burni ng vel oci ty
(mm/ s)
Gasoline 0.05 0.07
Kerosene 0.06 0.07
Crude oil 0.05 0.07
Hexane
1
0.08 0.11
Butane 0.08 0.13
LNG 0.14 on land [30]
0.24 on water [30]
0.24
2
0.42
2
LPG 0.11 on land
0.22 on water
0.21
0.42
Notes
1. Condensate may be taken as similar to hexane.
2. Calculated from mass burning rate using typical density of 450 kg/m
3

Note that a pool fires size may be constrained by a bund (dike) or drainage, and also
that process areas are often constructed with the floor sloping towards a drain. In both
cases, the resulting pool will not be circular. For modelling thermal radiation from the
fire, most models assume the pool is circular with the diameter of the fire corresponding
to the surface area of the pool.
The flame length and tilt angle of a pool fire can be simply calculated using the Thomas
correlation [8]. Other models are referred to in [1].
Some example pool fire thermal radiation results are presented in Figure 2.11 and
Figure 2.12. These were obtained using DNVs PHAST software.

OGP

17
Fi gure 2. 11 Li qui d Propane Pool Fi re Thermal Radi ati on Di stances at
Ground Level

Fi gure 2. 12 Kerosene-type Li qui d Pool Fi re Thermal Radi ati on Di stances at
Ground Level

Note: The shape of the curves for 12.5 kW/m
2
is explained by the decreasing flame surface
emissive power with increasing pool diameter.
OGP

18
2.3.1.3 Boilover
Boilover can be modelled as a pool fire with:
Diameter equal to the tank diameter
A height of 5 times the tank diameter
Flame thermal emissive power = 150 kW/m
2

However, a boilover also results in considerable rainout of burning hydrocarbon liquid
over a wide area, posing additional risk to people; this may also ignite hydrocarbon
vapours above neighbouring tanks.

2.3.1.4 Compartment Fire
For a fire inside an enclosed volume such as an offshore module, the fire size and
properties (in particular, smoke toxicity) depend on two factors:
Whether the fire is large enough to impinge on a wall or ceiling
Whether the fire is fuel- or ventilation-controlled
4
.
Figure 2.13 shows a procedure to determine the model required for a gas or 2-phase
release. A similar approach can be taken for a liquid release.
Lees [9, pp16/286ff] suggests possible approaches and other models for compartment
fires. Although written as applying to fires inside buildings, the text can also be applied
offshore.

4
In the former case there is an adequate supply of air to ensure complete combustion of the fuel;
in the latter case the ventilation is limited and the fuel is not fully combusted.
OGP

19
Fi gure 2. 13 Procedure for Fi re Model Sel ecti on (Gas or 2-phase Rel ease)

Note: in a highly confined volume with limited ventilation (e.g. a platform leg), even a small fire
may be ventilation controlled.

2.3.1.5 Fireball/BLEVE
Several models for fireball duration and diameter have been developed. Most are simple
correlations between these quantities and fireball mass
5
. One model is due to Prugh
[10]:

Diameter, D (m): D = 6.48 M
0.325
[M = fireball mass (kg)]
Duration, t
d
(s): t
d
= 0.825 M
0.26

Height of fireball centre, h (m): h = 0.75 D
Surface emissive power, q (kW/m
2
):
[P < 6 MPa; P is vapour pressure (MPa) at which failure occurs.]

5
When the release is two-phase, the fireball may not consume all the liquid. One possible
assumption is that the fireball mass is calculated assuming 3 ! the adiabatic flash fraction at the
burst pressure, constraining this to be " 1.0.
OGP

20
Radiation received, I (kW/m
2
): I = q F #
F = view factor: [x = distance (m) along ground]

" = transmissivity:

2.3.2 Software for fire and thermal radiation modelling
The software packages listed in Section 2.0 model the fire types listed in Section 2.3,
apart from compartment fires. They will model the flame dimensions and orientation,
and thence the thermal radiation received.
For a compartment fire, if the fire inside the module is a diffusive fire smaller in volume
than the module, it can be modelled as a pool fire with the dimensions suggested in
Section 2.3.1.4; the surface emissive power can be taken to be the same as that of the
unimpinged jet fire.

2.3.3 CFD for fire and thermal radiation modelling
CFD models can be used to determine the fire loading on critical areas on both offshore
structures and onshore plants. The Oil and Gas UK guidance [24] provides a state-of-
the-art review of CFD fire modelling. In particular, it is stated that although CFD models
provide a more realistic representation of the flow physics, there are uncertainties
associated with modelling turbulent flow and combustion as well as in definition of fire
source and ambient conditions. Commonly used software for fire modelling include
Kameleon FireEx and CFX. Kameleon FireEx is typically used for fire modelling on
offshore platforms and onshore plants; CFX is more commonly for low geometry
scenarios, e.g. fire and smoke modelling in tunnels.
For CFD fire modelling, it may be best to reduce the size of the problem by modelling
only a subset of the installation. Otherwise, the run times for the analyses would be very
long. The procedure for running the fire analyses can be summarised in the following
steps:
1. Define leak size and select realistic leak locations;
2. Select leak directions. Typically, the analyses are run for up to 6 leak directions;
3. Run the fire simulations for different leak rates for each leak location and direction
until steady state conditions are reached.
Huser [25] describes a probabilistic procedure for the design of process against fires
using CFD modelling. The probabilistic assessment provides a Dimensioning Accidental
Load (DAL) fire that is used for design of the structure and allows for the development
of a consistent methodology (similar to explosion approach) for calculating fire loads.
The methodology is illustrated in Figure 2.14.

OGP

21
Fi gure 2. 14 Probabi l i sti c Procedure for Establ i shi ng Di mensi oni ng
Acci dental Load (DAL) Fi re and Mi ti gati ng Measures (from [25])

[25] has shown that for CFD simulations of jet fires the following parameters are
important (i.e. resulting in more than 20% variation in the heat loads when all other
parameters are kept constant):
Initial leak rate and leak profile
Leak and fire location
OGP

22
Jet direction
Dynamic development of fire
Geometry layout and
Deluge
The probabilistic approach can be used to generate a fire exceedance curve from which
the DAL fire can be obtained.

2.4 Explosion modelling
For QRA and associated studies, explosions are usually taken to mean vapour cloud
explosions (VCEs). However, other types of explosion are possible (see Figure 2.1):
Condensed phase explosions
Dust explosions
Runaway reactions
In addition, BLEVEs and vessel bursts generate overpressures that may be significant.
However, this section focuses on VCEs.
Huge advances in understanding and modelling of VCEs have been made in the last
decade since the Spadeadam tests. For offshore, the NORSOK standard Z-013 [11] has
established a comprehensive but computationally demanding approach to explosion
modelling, requiring use of an advanced CFD tool. Whilst originally developed
specifically for platforms in Norwegian waters, this approach is being adopted in other
areas of the North Sea. Although CFD models cannot yet be incorporated directly within
(offshore) QRAs, output from QRA is increasingly expected to be used in them.
Onshore, CFD is less well established in QRA whilst the application of simpler models
available in general purpose software is becoming more sophisticated and considered
fit for purpose. However, where design or layout decisions may critically depend on
explosion risks, use of CFD for specific scenarios would give additional robustness to,
and confidence in, the results. Another issue where CFD would assist is where terrain
effects are important, for example if a facility is built on a slope or at the foot of a hill: in
this case dispersion would be significantly modified compared with that which would
result over flat ground.
The recent advances in understand of explosions referred to above mean that the
previous classification of VCEs as unconfined, semi-confined or confined can now be
considered over-simplistic. It would be better to talk about degrees of confinement and
congestion
6
. TNOs Multi-Energy model [12], discussed further in Section 2.4.2, allows
for 10 levels of confinement/congestion, ranging from the equivalent of a UVCE
(Unconfined Vapour Cloud Explosion) through to highly confined/ congested volumes
such as can be found in a densely packed process area of an onshore plant. In this and
similar models, some assessment or assumption needs to be made outside of the
model as to the maximum overpressure. In CFD modelling, the distinction between
levels of confinement/ congestion disappears since the geometry is defined and the
software itself calculates the maximum overpressure.

6
Confinement should be thought of as a solid barrier preventing flame acceleration in a certain
direction; congestion as a porous barrier, or set of discrete obstructions, inducing turbulence in
the flow and modifying (increasing) flame acceleration in a certain direction.
OGP

23
2.4.1 Simple approaches to explosion modelling
Historically, simple TNT equivalence models have been used for modelling explosion
overpressures from unconfined VCEs (UVCE) onshore. However, these require the
explosive mass to be calculated: as this is an output from dispersion modelling, manual
calculation of explosion overpressures is not likely to be undertaken.
Another old approach for onshore QRA [13] calculates the distance to specified levels
of damage directly from the explosion energy by a simple correlation. Again, this
requires the explosive mass to be calculated.

2.4.2 Software for explosion modelling
2.4.2.1 Onshore explosions
General purpose consequence modelling software (see list in Section 2.0) includes
either of both of two well established explosion models: the TNO Multi Energy model
[12] and the Baker Strehlow or Baker Strehlow Tang model [14].
In the Mul ti Energy model , a vapour cloud is divided into the regions of congestion,
or blast sources, they may enter and fill (or partially fill). Each of these blast sources
is treated independently of the others. The material and the volume of the cloud within
the blast source are used to calculate the explosion energy. A confined explosion
strength is assigned to the blast source by the analyst: this strength corresponds one
of 10 lines on a graph of peak side-on overpressure vs. scaled distance from the source.
The 10 lines represent a range of maximum overpressures (at the source) ranging from
0.01 to 13 bar. Selecting the correct confined explosion strength for a given situation
(e.g. a specific process unit on a refinery) is far from straightforward, although generally
no. 7 or 8 is used for process units. Guidance [15] has been developed to assist this,
although even with this it is strongly recommended to call upon experienced personnel
to make the assessment.
In the Baker Strehl ow Tang model the analyst selects instead the material reactivity
(high, medium, or low), flame expansion (number of directions in which the flame can
expand), obstacle density (high, medium, or low), and ground reflection factor (1 for air
burst, 2 for ground burst and hence ground reflection). This has two advantages over
the Multi Energy model:
Materials of different reactivities can be adequately represented
Selection of flame expansion and obstacle density is simpler
As in the Multi Energy model, the overpressure vs. scaled distance is a set of curves (in
this case 11) that span the range of input selections.
These models are appropriate for use in studies of onshore facilities including marine
terminals.

2.4.2.2 Offshore explosions
For offshore installations, non-CFD software has been used to estimate maximum
overpressures in modules using relatively simplified methods that nevertheless take
account of the broad features of module geometry. For example, DNV have used their
programs COMEX and NVBANG in numerous studies, however these programs are not
available commercially and are not recommended for non-specialists in explosion
modelling.
However, in offshore applications the maximum overpressure itself is usually not used
directly in the risk calculations. Rather, it represents the worst case combination of
module fill, release location and ignition location. In a real situation, this combination is
OGP

24
unlikely to be achieved and a lower overpressure will be reached. Of direct concern is
the likelihood of an explosion that will result in equipment escalation or breaching of the
TR wall, for example. This requires a probabilistic approach to estimate the likelihood
of any given explosion overpressure being exceeded at a specific location. This is the
approach set out in the NORSOK standard Z-013 [11]. CFD modelling is used to model
explosion overpressures for a number of scenarios. The results are then combined with
leak frequencies, ignition data and wind probabilities in another software package (e.g.
DNVs EXPRESS) to develop overpressure exceedence probability curves for use in the
QRA. The same approach can be used for more specific design problems, for example
designing an ESD or deluge system to withstand the drag forces likely to result from an
explosion.
This approach requires considerable investment of effort to obtain useful and robust
results. Previous, more simplified methods have the appearance of being less costly to
achieve the same end. However, the initially more costly NORSOK approach [11] can be
used to cost-optimise the design of a module for explosions, eliminating the need for
excessive and hence costly conservatism (i.e. over-engineering).

2.4.3 CFD for explosion modelling
The representative gas clouds from the CFD dispersion analysis (see Section 2.2.3) can
be ignited and explosion analysis carried out. The Oil and Gas UK guidance [24] reports
that it is not recommended to use dispersed non-homogeneous and turbulent gas
clouds in CFD explosion simulations due to the lack of testing/validation for this
application. Instead, an equivalent quiescent stoichiometric gas cloud, that gives similar
overpressures to the non-homogeneous and turbulent clouds, has to be calculated.
As an example of how this can be done, the FLACS software automatically calculates a
parameter (referred to as Q5) that converts the non-homogeneous cloud into an
equivalent quiescent gas cloud. It should be noted that the duration of the equivalent
gas cloud may be shorter than the non-homogeneous one resulting in a difference in
the structural response.
The explosion simulations should be carried out for various gas cloud sizes and
shapes, gas cloud locations and ignition locations. For each gas cloud size, the gas
cloud location and ignition location should be varied. In particular, it is important to
locate the clouds close to critical and congested areas of equipment and piping.
The ignition location will also have a strong impact on the explosion loads. Generally,
the CFD analyses are run with two different locations namely ignition location at centre
of cloud and at edge of cloud. Depending on the geometry and layout, edge ignition will
sometimes produce the higher (than central ignition) explosion overpressures due to
the increased flame distance.
Results in terms of explosion overpressures can be output at monitor points at pre-
defined locations and drag forces can be obtained for design of critical equipment and
piping.
2.5 Smoke and gas ingress modelling
Modelling of smoke and gas ingress to the TR or living quarters usually forms part of an
offshore QRA and could also be used in onshore studies. More generally, modelling of
smoke generation and dispersion can be useful to determine the likelihood of escape
routes being impaired or of people out-of-doors being overcome by smoke.
Smoke and gas ingress modelling has up to 4 stages:
Source Term $ Dispersion $ Ingress $ Effects
OGP

25
The source term comes from the release rate modelling (Section 2.1): directly for gas
and from suitable ratios of (mass of smoke) / (mass of hydrocarbon released).
Dispersion can be modelled as suggested in Section 2.2. Since smokes largest
constituent is nitrogen (i.e. the unburnt part of the air involved in combustion), one
approach used has been to model the smoke as hot, dense nitrogen, giving it a
molecular weight and temperature equal to those estimated for the combustion gases.
However, the high temperature invariably results in a rapidly rising smoke plume that
doesnt match experience. For example, photographs of smoke from the Piper Alpha
disaster show the plume travelling almost horizontally. One possible reason is that the
soot particles in the smoke increase the plumes density. Hence this approach is not
recommended for 3D results. However, it may be used to determine the smoke
concentration at a given distance horizontally from the release point, assuming as a
worst case that this is the centreline concentration.

2.5.1 Simple approaches to smoke and gas ingress modelling
The CMPT Guide to quantitative risk assessment for offshore installations [1] provides data
and references on smoke generation, composition, dispersion, visibility reduction,
ingress to TR and impact.
A series of linked models has been used in offshore QRAs for BP and other operators:
Smoke generation:
" Composition from [16]: see Table 2.2
" Depends on fuel (light = gas, heavy = condensate/oil)
" Depends on whether fire is fuel-controlled, ventilation-controlled or in between
these.

Tabl e 2. 2 Smoke Composi ti on Data
Fuel Type*

Fi re Area Type Component
Li ght Heavy
a) Fuel Controlled Carbon Monoxide (ppm)
Carbon Dioxide (%)
Oxygen (%)
Smoke Temperature (C)
Particulates (dB/m)
400
10.9
0
1,000
15
800
11.8
0
1,000
47
b) Ventilation Controlled Carbon Monoxide (ppm)
Carbon Dioxide (%)
Oxygen (%)
Smoke Temperature (C)
Particulates (dB/m)
30,000
8.2
0
600
29
31,000
9.2
0
600
70
* The light composition is used for gas jet fires. The heavy composition is used for
condensate fires.

Dispersion: based on a dilution factor, which is a function of fuel burn rate and of
distance from source (does not take into account wind speed or the presence of
barriers).
Figure 2.15 shows dilution factors, based on calculations using FLACS [17], for
different release rates.
Smoke Ingress:
OGP

26
" CO and CO
2
build-up in the module are calculated using a CSTR model, taking as
input the smoke concentration immediately outside the TR and the TRs
ventilation rate
" The CO
2
concentration calculation also includes exhaled CO
2
from personnel
inside
" The internal temperature is also calculated based on heat generated by TR
occupants

Fi gure 2. 15 Smoke Di l uti on Factors

Smoke effects/toxicity
" Based on dose relationships given in [18]
" Considers toxicity of CO; effects of CO
2
, lack of oxygen and high air temperature;
visibility reduction

For gas ingress a set of dilution factors is used, equivalent to but different from those
used for smoke. A CSTR model is used for gas ingress, and fatalities in the TR are
assumed to occur if the gas concentration exceeds 60% of LFL.

2.5.2 Software for smoke and gas ingress modelling
For smoke dispersion in the open, general purpose consequence modelling software
such as the packages listed in Section 2.0 is sometimes used. However, the validity of
this approach and its superiority to the simple approach described in Section 2.5.1 are
uncertain.
For smoke and gas build-up within modules, multizone models such as COMIS can be
used. Multizone modelling involves solving mass balance equations for the flow
between different zones, thus allowing for partitioning due to smoke barriers, walls
between rooms, etc. Multizone models were developed primarily to predict airflow in
buildings, but they are also capable of predicting the transient transport of
OGP

27
contaminants such as smoke. The method is applied by considering a building as being
divided into a number of zones (typically rooms) that are physically separated from one
another. As with the CSTR model, each zone is treated as fully mixed. The rate at which
air flows between zones is governed by the pressure difference and the modelled
connection (i.e. doors, ducts etc.) between the rooms. Multizone models have some of
the characteristics of both CFD and the CSTR model; conceptually the approach lies
between the two in terms of resolution and complexity.
2.5.3 CFD for smoke and gas ingress modelling
CFD modelling can be used to provide a detailed prediction of the smoke distribution in
TR or living quarters. The effect of heat sources due to people and computing
equipment can be included in the analysis. However, smoke modelling using CFD can
be quite difficult due to the variability and uncertainty in the boundary conditions [26]. A
recent article by ODonnell et. al. [27] provides a comparison of different approaches to
smoke modelling namely the CSTR model, a multizone model and a CFD model. CFX
and Kameleon FireEx can be used to carry out detailed CFD smoke modelling.
The smoke and gas dilution factors used in the models described in Section 2.5.1 were
determined using FLACS, a CFD package. This or another CFD package could be used
directly to model smoke dispersion from a source in the same way as described in
Section 2.2.3 for gas dispersion modelling in general. However, the approach described
in Section 2.5.1 has generally been accepted as fit for purpose in QRAs.
CFD is more likely to be useful in design, for example in locating HVAC air intakes to
minimise the likelihood of smoke ingress. Although best practice is to place them on
the TR face away from potential smoke sources (i.e. fires), flow around bluff bodies
results in zones of recirculation and hence of enhanced smoke concentration.

2.6 Toxicity modelling
The toxic effects of a material may be acute (resulting from accidental exposure to a
high concentration over a short period of time) or chronic (resulting from continuous
exposure to a lower concentration over a long period of time, as a result of routine
emissions or a small, undetected leak). Different toxic materials have different
physiological effects: they may inhibit respiration (causing asphyxiation) through
inhalation, they may affect the central nervous system, they may be ingested or
absorbed through the skin. For the purposes of this datasheet, the discussion is limited
to acute effects and it is not necessary to consider the nature of the physiological
effects. The discussion addresses toxicity on the basis of dose-response relationships
(see below).
Offshore, besides smoke (as discussed in Section 2.5), toxic modelling is usually limited
to the effects of sour gas, i.e. H
2
S.
Onshore, besides H
2
S (in onshore hydrocarbon production, transport and processing),
other toxic materials are potentially of concern. Toxic consequences are invariably
bound up with toxic effects: that is, a model for toxicity is a model for lethality or lesser
effects.
Toxicity data is typically encountered in two forms when required for QRA: specified
concentrations such as the IDLH (Immediate Danger to Life and Health), or
concentration-lethality levels for different species such as rats. Such data can be found
in Material Safety Data Sheets (MSDS) or online reference sources such as CHRIS
www.chrismanual.com.
OGP

28
For QRA, a dose-response relationship is often used that relates the lethality to the dose
received at a point. At its simplest, the dose is given by (concentration ! time),
assuming the concentration remains constant over time. However, for many materials,
the effect of concentration is magnified and, for concentration C and exposure time t,
the relevant dose A is given by:

Note that the exponent n is not necessarily an integer.
In its regulatory work the UK HSE (e.g. 19] uses two values of A:
SLOT (Specified Level Of Toxicity) Dangerous Toxic Load: the dose that results in
highly susceptible people being killed and a substantial portion of the exposed
population requiring medical attention and severe distress to the remainder
exposed. It represents the dose that will result in the onset of fatality for an
exposed population (commonly referred to as LD
1
or LD
1-5
)
SLOD (Significant Likelihood Of Death): is defined as the dose to typically result in
50% fatality (LD
50
) of an exposed population and is the value typically used for
group risk of death calculation onshore.
Values of the SLOT and SLOD for selected materials are given in Table 2.3. As can be
seen in the final column, values of n for these materials range from 1 to 4.

Tabl e 2. 3 SLOT & SLOD Val ues for Sel ected Materi al s
Substance SLOT SLOD n
Ammonia 3.78 ! 10
8
1.09 ! 10
9
2
Carbon monoxide 40125 57000 1
Chlorine 1.08 ! 10
5
4.84 ! 10
5
2
Hydrogen sulphide 2.0 ! 10
12
1.5 ! 10
13
4
Sulphur dioxide 4.66 ! 10
6
7.45 ! 10
7
2
Hydrogen fluoride 12000

41000 1
Oxides of nitrogen 96000 6.24 ! 10
5
2
Note: these values are based on concentration in ppm, time in minutes.

As stated above, the LD
50
is often used in risk calculations. The HSEs approach allows
for calculation of the LD
50
for any exposure duration.
The most sophisticated approach to determining toxicity adopts the same approach to
calculating the dose but allows the lethality to be calculated for any given concentration
and duration of exposure. This is the probit. A probit value Pr is calculated (for a
constant release rate and hence concentration
7
) as:

where a, b and n are all material specific constants (n is the same as above).
These constants have been published for many commonly encountered materials in a
number of sources [e.g. 9,20]. A table relating lethalities to probits can be found in
many places e.g. [9].

7
For a time varying release rate and hence concentration, the (C
n
t) can be replaced by an integral
over time.
OGP

29
2.6.1 Simple approaches to toxicity modelling
The toxic dose should always be calculated using the relationship discussed in
the text preceding this sub-section. It therefore requires results from dispersion
modelling (Section 2.2) together with the exposure time. Calculation of the LD
50
using
the HSE approach described in the text preceding this sub-section is recommended as
the best simple approach and will be sufficient for many purposes.

2.6.2 Software for toxicity modelling
The software listed in Section 2.0 will calculate probits for toxic materials and thence
the lethality level as a function of distance from the release point or as contours of
different lethalities overlaid on a plan or map. In this way the lethality at any point can
be determined for a given wind direction.

2.6.3 CFD for toxicity modelling
CFD will provide as output the concentration at any point. This could be used together
with a SLOT/SLOD value or probit to calculate lethality at that point. Contour plots of
toxic lethality are not available from CFD software but could probably be generated from
tabular output.

3.0 Guidance on use of approaches
3.1 General validity
The approaches described in Section 2.0 are based on published sources that are
widely known and accepted.
All modelling of physical phenomena is imperfect. Any use of software must be within
the limitations set out for the software, and even then the analyst must carry out a
reality check on the results. For example: a jet fire model applied to a large, high
pressure gas release will predict a jet flame several hundreds of metres long; the
analyst must consider whether this is credible, or whether the flame will impinge on an
obstruction within this distance.
Depending on the application, a simple model may be fit for purpose, or detailed
modelling (e.g. using CFD) may be required. Whilst it may be considered desirable to
use CFD as much as possible, the resources (time, trained personnel, and budget)
required to use it effectively are rarely available; hence it is usually used to address
specific problems or to provide results for a limited set of scenarios that can be applied
or extrapolated to all the scenarios being modelled in a QRA.
In the early stages of design, the detailed design information required for CFD to give
accurate predictions of overpressures is not available and hence decisions based on
CFD results may result in under-design for the potential overpressures.

OGP

30
3.2 Uncertainties
All modelling suffers from uncertainties. For a given set of input (initial) conditions, it is
unlikely exactly to match the physical outcome that would result in reality from the
same initial conditions. Indeed, numerous physical realisations of the same release
would give different results, whereas consequence modelling software gives the same
result each time
8
. Sources of uncertainty in consequence modelling for QRA include
the following:
A QRA only models a limited range of cases, so the conditions of an actual release
are unlikely to match exactly any of the cases modelled in a QRA
Ambient conditions (wind speed, wind direction) do not stay constant over the
duration of a release as is modelled
Box models for dispersion, and models of equivalent complexity for other
phenomena, cannot deal with solid or porous barriers (buildings, process units,
bund walls, etc.)
CFD cannot model sub grid scale turbulence (see Section 0)

3.3 Choosing the right approach for consequence modelling
As set out in Section 2.0, whilst simple models are available for some consequences,
and a range of numerical results for some consequences are given there, some
consequence modelling requires the use of either general purpose or CFD software. To
decide which is the best approach it is necessary to decide:
What is the scope of the study?
What is the required depth of the study?
How many release scenarios will be modelled?
Who will carry out the study?
Will the analysis need to be updated in the future, or the results interrogated? If so,
who will do this?
If the scope is a full, detailed QRA, then most or all of the 6 steps described in Section
2.0 will need to be undertaken. This means that the output from one step of the analysis
will become the input to the next step, and it is important to make the links between the
steps as straightforward and robust as possible. This in turn suggests that general
purpose consequence modelling software where the transitions from one model to the
next are automated is preferable to using a mixture of models from different sources
(perhaps with some implemented in spreadsheets, others coded). However, in this case
the automated transitions may be black box-like and so the analyst needs to
understand fully how these work to ensure that the results represent physical reality.
(For example, that a modelled jet fire is a credible outcome.)
If a coarse QRA of a simple installation is to be undertaken, a simpler approach may be
acceptable. This could use the correlations given or referred to in Section 2.0, or the
consequence results presented in that section.

8
Monte Carlo modelling could be used to vary slightly the input parameters but this does not
appear to be done routinely. Another type of dispersion modelling, random walk modelling,
likewise does not appear to be used for QRA.
OGP

31
For a QRA of an offshore installation with enclosed modules, use of CFD for explosion
modelling is now routinely used. For a new installation, it will almost certainly have to
be used in order to design for explosions. For an existing installation, explosion
modelling predating the Blast and Fire Engineering for Topside Structures JIP will probably
have been revised using CFD. Thus it is likely that the necessary CFD modelling will
have been done, or at least that the geometry model has been built and it will be
relatively straightforward to obtain any additional results required.
For QRAs of onshore installations, use of the TNO Multi Energy Model or the Baker
Strehlow Tang model (see Section 2.4.2.1) is strongly recommended over use of earlier
VCE models.
For problems of a more limited nature, in particular decisions about significant
investment in relation to fire or explosion and especially in relation to offshore
structures, it is advisable to use CFD in order to maximise the robustness of the
analysis and the confidence in the results.
CFD modelling requires considerable experience and expertise to use effectively. It is
rare for a risk analyst skilled in all aspects of QRA to possess the required degree of
specialist expertise. CFD analysis should therefore be assigned or contracted to
personnel with the required expertise.

3.4 Geometry modelling for CFD
Generally, the numerical grid in CFD models is not fine enough to resolve the smaller
items of equipment and pipe work which are responsible for a large part of the
turbulence generated during an explosion. Most of the software (FLACS, EXSIM,
AutoReaGas) uses a so-called distributed porosity concept (Porosity, Distributed
Resistance (PDR) model) to account for the objects which cannot be represented by the
grid. The porosity model is used to calculate the turbulence source terms due to those
small items and the flame speed enhancement arising from flame folding in the sub grid
wake.
Explosion relief panels and yielding walls can also be represented by modifying the
porosity in the region where they occur.
It is important that all the geometric details are properly represented in a CFD model due
to their importance in pressure build-up. The particular areas where gas explosion
analyses are carried out must be modelled with a high degree of accuracy. In the early
design stages, no detailed description of the geometry exists and this may pose a
problem with regard overpressure prediction. There are two ways in which this problem
can be circumvented namely by applying a factor for equipment growth to account and
by adding anticipated congestion to obtain final expected object density and
distribution.
The Oil and Gas UK guidance [24] reports on a detailed investigation of a typical North
Sea integrated deck platform which showed that, for good prediction of overpressures,
definition of all major equipment, boundaries (decks, TR), all piping with diameters >
0.2 m, and primary/ secondary structures with cross-section dimensions > 0.13 m is
required.
In addition, it is important to define the CFD grid to extend quite a large distance from
the area of interest to avoid too strong influence from open boundaries.

OGP

32
4.0 Review of data sources
Key general sources for suitable consequence modelling methods are the Guide to
quantitative risk assessment for offshore installations [1] and Lees Loss Prevention in the
Process Industries [9]. These have been supplemented by more specific published
papers and books as listed in Section 6.1: all of these are believed to have found wide
acceptance in the QRA community including with regulatory authorities.
The general purpose software packages listed in Section 2.0 are all commercially
available. Validation data for them, if required, should be sought from the software
providers. The EU SMEDIS project [28] in particular has compared the leading
dispersion models with results from experimental measurements.
The basis of the suggested approach to modelling releases from buried pipelines
(Section 2.1.3) is confidential work carried out by DNV on behalf of clients (personal
communication). No published methodology has been found.
The basis of the suggested approach to modelling boilover (Section 2.3.1.3) is the Dyfed
Fire Brigade video of the Amoco Milford Haven refinery tank fire. The flames from the
boilover reached a height of 3000 feet, or about 10 times the tank diameter; however,
they were not continuous or constant to this height over a typical period of interest, and
were partly obscured by smoke. Hence a height of 5 times tank diameter appears
reasonable.
For explosion modelling, FLACS and AutoReaGas have been extensively validated
against experimental data, in particular from the Phase 2 and Phase 3 JIP Blast and Fire
Engineering for Topside Structures experiments carried out at Spadeadam and elsewhere.
FLACS is also currently being validated for hydrogen as part of the EU HySafe
programme. Details of FLACS and AutoReaGas validation are available on their
respective websites (see Section 2.0).

5.0 Recommended data sources for further information
For further information, the data sources referenced in Sections 2.0 to 4.0 should be
consulted. Some additional references are given in Section 6.2.
On the subject of subsea releases, two major reports 32], [33] were published in 2007
and 2008 and should be consulted if detailed information is required (i.e. if subsea
releases appear to pose a significant risk).

6.0 References
6.1 References for Sections 2.0 to 4.0
1. Spouge, J, 1999. A guide to quantitative risk assessment for offshore installations, CMPT
publication no. 99/100, ISBN 978-1-870553-36-0 / 1 870553 36 5. Now available from
the Energy Institute www.energyinst.org.uk.
2. Czujko, J (ed.), 2001. Design of Offshore Facilities to Resist Gas Explosion Hazard
Engineering Handbook, Sandvika: CorrOcean ASA.
3. BP Amoco, CERC and BG Technology, 2000. Workbook on Gas Accumulation in a
Confined and Congested Area, Joint Industry Project Gas Build Up from High Pressure
Natural Gas Releases in Naturally Ventilated Offshore Modules. [Believed to be
available only to sponsors but summarised in the following reference.]
4. Cleaver, R P and Britter, R E, 2001. A Workbook Approach to Estimating the Flammable
Volume Produced by a Gas Cloud, Paper R416, FABIG Newsletter: Issue 30, 5-7.
OGP

33
5. Wertenbach, H G, 1971. Spread of Flames on Cylindrical Tanks for Hydrocarbon Fluids,
Gas and Erdgas 112.
6. API, 1982. Guide for Pressure Relieving and Depressuring Systems, American
Petroleum Institute, Recommended Practice RP 521, 2
nd
ed.
7. Chamberlain, G A, 1987. Developments in Design Methods for Predicting Thermal
Radiation from Flares, Chem Eng Res Des 65.
8. Thomas, P H, 1963. The Size of Flames from Natural Fires, 9th Intl. Combustion
Symposium, Combs Inst. Pittsburgh, PA, pp.844-859.
9. 2005. Lees Loss Prevention in the Process Industries, 3
rd
. ed., Mannan, S, ed., Oxford:
Elsevier Butterworth Heinemann.
10. Prugh, R W, 1994. Quantitative evaluation of fireball hazards, Process Safety Progress
13(2), 83-91.
11. Procedure for probabilistic explosion simulation, NORSOK Standard Z-013 Rev.2
Annex G.
12. TNO 1997. Methods for the calculation of physical effects due to releases of hazardous
materials (liquids and gases) [the Yellow Book], eds: van den Bosch, C J H and
Weterings, R A P M, Chapter 5: Vapor Cloud Explosions, Mercx, W P M and van den
Berg, A C.
13. TNO 1979. Methods for the Calculation of the Physical Effects of the Escape of
Dangerous Material, [the Yellow Book], Chapter 4: Vapour Cloud Explosions,
Wiekema, B J.
14. Tang, M J, and Baker, Q A, 1999. A New Set of Blast Curves from Vapour Cloud
Explosion, Proc. Safety Progress 18(4), 235-240.
15. Mercx, W P M et al., 1998. Application of correlations to quantify the source strength of
vapour cloud explosions in realistic situations. Final report for the project: GAMES, HSE
and TNO, http://www.hse.gov.uk/research/crr_pdf/2001/crr01318.pdf.
16. SINTEF 1992. Handbook for Fire Calculations and Fire Risk Assessment in the Process
Industry.
17. FLACS, V8 (version 8), 2003, see www.gexcon.com.
18. Purser, D, 1992. Toxic Effects of Fire Cases, Conf. on Offshore Fire and Smoke
Hazards, Aberdeen.
19. HSE 2006. Indicative Human Vulnerability to the Hazardous Agents Present Offshore for
Application in Risk Assessment Of Major Accidents, SPC/Tech/OSD/30.
http://www.hse.gov.uk/foi/internalops/hid/spc/spctosd30.pdf.
20. CPD 1992. Methods for the determination of possible damage to people and objects
resulting from releases of hazardous materials [theGreen Book], Committee for the
Prevention of Disasters caused by Dangerous Substances / TNO, The Hague:
Directorate-General of Labour of the Ministry of Social Affairs and Employment.
21. Norwegian Technology Centre, 2001. Risk and Emergency preparedness analysis,
NORSOK Z-013, http://www.standard.no/imaker.exe?id=1503.#
22. Huser, A., Oliveira, L F, Rasmussen, O, and Dries, J V D, 2002. Explosion risks in
large and widespread process areas, ERA Conference, November.
23. Huser, A, Oliveira, L F, and Dalheim, J, 2004. Cost optimisations of gas detector
systems, Proc. OMAE04, 23
rd
International Conference on Offshore Mechanics and Arctic
Engineering, June.
OGP

34
24. Oil and Gas UK & HSE, 2007. Fire and Explosion Guidance, publication no. EHS24.
Available from Oil and Gas UK http://www.ukooa.co.uk/ukooa/.
25. Huser, A, 2006. Probabilistic procedure for design of process areas against fires,
FABIG Newsletter 44. Available from FABIG www.fabig.com.
26. Talberg, O, Hansen, O R, Bakke, J R, and Wingerden, K. Application of a CFD-based
probabilistic explosion risk assessment to a gas-handling plant, conference paper
available from CMR-Gexcon http://www.gexcon.com/download/ERA_00-Paper.pdf.
27. ODonnell, K, Deevy, M, and Garrard, A, 2007. Assessment of mathematical models
for prediction of smoke ingress and movement in offshore installations, FABIG
Newsletter 48. Available from FABIG www.fabig.com.
28. Daish, N C, Britter, R E, Linden, P F, Jagger, S F, and Carissimo, B, 1999. Scientific
Model Evaluation techniques applied to dense gas dispersion models in complex
situations, Intl Conf. on Modelling the Consequences of Accidental Releases of
Hazardous Materials, CCPS, San Francisco, California, September 28 October 1.
29. Mudan, K S, and Croce, P A, 1988. Fire Hazard Calculations for Large Open
Hydrocarbon Fires, Fire Protection Engineering, Section 2 Chapter 4, Society of Fire
Protection Engineers, National Fire Protection Association.
30. Cleaver P, & Johnson, M, 2004. LNG Behaviour, Fire and Blast Issues related to LNG,
FABIG Technical Review Meeting, London & Aberdeen, October 6 7.

6.2 References for other data sources
31. CCPS 1994. Guidelines for Evaluating the Characteristics of Vapour Cloud Explosions,
Flash Fires and BLEVES, New York: American Institute of Chemical Engineers.
32. Fannelp, T K, and Bettelini, M, 2007. Very Large Deep-Set Bubble Plumes From
Broken Gas Pipelines, Report No. 6201, Project No. 99B43, Petroleum Safety Authority
Norway.
33. Tveit, O J, and Huser, A, 2008. Risiko knyttet til gassutslipp under vann. Viderefring
2007, Spredning over havet, Petroleum Safety Authority Norway.
For further information and publications,
please visit our website at
www.ogp.org.uk
209-215 Blackfriars Road
London SE1 8NL
United Kingdom
Telephone: +44 (0)20 7633 0272
Fax: +44 (0)20 7633 2350
165 Bd du Souverain
4th Floor
B-1160 Brussels, Belgium
Telephone: +32 (0)2 566 9150
Fax: +32 (0)2 566 9159
Internet site: www.ogp.org.uk
e-mail: reception@ogp.org.uk

434 7 PDF

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

434 7 PDF

Uploaded by

Copyright:

Available Formats

Risk Assessment Data Directory

Report No. 434 7

You might also like