INSTRUCTIONS

Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists
of three sections.
1. Section 1 contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE is correct.
2. Section 2 contains 3 paragraphs each describing theory, experiment and data etc. Six questions
relate to three paragraphs with two questions on each paragraph. Each question pertaining to a
particular passage should have only one correct answer among the four given choices (A), (B), (C)
and (D).
3. Section 3 contains 4 multiple choice questions. Each question has two lists (List-1, P, Q, R and
S; List-2 : 1, 2, 3 and 4). The options for the correct match are provided as (A), (B), (C) and (D)
out of which ONLY ONE is correct.
Marking Scheme
4. For each question in Section 1, 2, and 3 you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus
one (1) mark will be awarded.
Answers & Solutions
for for for for for
JEE (Advanced)-2014
Time : 3 hrs. Max. Marks: 180
DATE : 25/05/2014
CODE
1
Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456 Fax : 011-47623472
PAPER - 2 (Code - 1)
(2)
PARTI : PHYSICS
SECTION - 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE Option is correct.
1. A tennis ball is dropped on a horizontal smooth surface. It bounces back to its original position after hitting
the surface. The force on the ball during the collision is proportional to the length of compression of the ball.
Which one of the following sketches describes the variation of its kinetic energy K with time t most
appropriately? The figures are only illustrative and not to the scale.
(A)
K
t
(B)
K
t
(C)
K
t
(D)
K
t
Answer (B)
Hint :
t
v
t
v
K
t
v

t
v
2

t
2
K.E.

t
2
2. A wire, which passes through the hole in a small bead, is bent in the form of quarter of a circle. The wire
is fixed vertically on ground as shown in the figure. The bead is released from near the top of the wire and
it slides along the wire without friction. As the bead moves from A to B, the force it applies on the wire is
B
90
A
(A) Always radially outwards
(B) Always radially inwards
(C) Radially outwards initially and radially inwards later
(D) Radially inwards initially and radially outwards later
Answer (D)
(3)
3. During an experiment with a metre bridge, the galvanometer shows a null point when the jockey is pressed
at 40.0 cm using a standard resistance of 90 O, as shown in the figure. The least count of the scale used in
the metre bridge is 1 mm. The unknown resistance is
R 90 O
40.0 cm
(A) 60 0.15 O (B) 135 0.56 O
(C) 60 0.25 O (D) 135 0.23 O
Answer (C)
Hint :

-
1 2
(100 )
R R
x x
(Balanced Wheatstone)
For R,
90 90 40
40 60 60
R
R


90 100
R x
x

-
For AR,
ln ln ln(100 ) R x x - -
(100 )
(100 )
R x x
R x x
A A A -
-
-
(100 )
R x x
R x x
A A A
-
-
0.1 0.1
60
40 60
R

A -


AR = 0.25 O
= R = 60 0.25 O
4. Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and 3 of radii R/2, R
and 2R respectively, as shown in figure. If magnitudes of the electric fields at point P at a distance R from
the centre of sphere 1, 2 and 3 are E
1
, E
2
and E
3
respectively, then
R
P
2R
4Q
R
P
2Q Q
P
R
R/2
Sphere 1 Sphere 2 Sphere 3
(A) E
1
> E
2
> E
3
(B) E
3
> E
1
> E
2
(C) E
2
> E
1
> E
3
(D) E
3
> E
2
> E
1
(4)
Answer (C)
Hint :

1
2
KQ
E
R

2
2 2
(2 ) 2 K Q KQ
E
R R
Q

3
3 3
(4 )
8 2
K Q R KQ
E
R R
> >
2 1 3
E E E
5. A point source S is placed at the bottom of a transparent block of height 10 mm and refractive index 2.72.
It is immersed in a lower refractive index liquid as shown in the figure. It is found that the light emerging
from the block to the liquid forms a circular bright spot of diameter 11.54 mm on the top of the block. The
refractive index of the liquid is
Block
Liquid
S
(A) 1.21 (B) 1.30
(C) 1.36 (D) 1.42
Answer (C)
Hint :
10 mm
10 mm
0 = 30
S
1
sin
2.72
0

sin30
2.72

2.72
2

1.36 =
6. Parallel rays of light of intensity I = 912 Wm
2
are incident on a spherical black body kept in surroundings
of temperature 300 K. Take Stefan-Boltzmann constant o = 5.7 10
8
Wm
2
K
4
and assume that the energy
exchange with the surroundings is only through radiation. The final steady state temperature of the black
body is close to
(A) 330 K (B) 660 K
(C) 990 K (D) 1550 K
Answer (A)
Hint :
o r - r
2 4 4 2
0
4 .( ) 912 R T T R
-
-
o

4 4 8
0
8
912 912
40 10
4
4 5.7 10
T T
- -
4 8 4 8
40 10 (300) (40 81) 10 T
T = 330 K
(5)
7. A metal surface is illuminated by light of two different wavelengths 248 nm and 310 nm. The maximum
speeds of the photoelectrons corresponding to these wavelengths are u
1
and u
2
, respectively. If the ratio
u
1
: u
2
= 2 : 1 and hc = 1240 eV nm, the work function of the metal is nearly
(A) 3.7 eV (B) 3.2 eV
(C) 2.8 eV (D) 2.5 eV
Answer (A)
Hint :
-
/
2
1
1
1
2
hc
mu W
-
/
2
2
2
1
2
hc
mu W
-
/

-
/
2
1 1
2
2
hc
W
u
hc u
W
1
2 1 2
4
4 2

- -

/ /

u hc hc
W W
u
-
/ /
2 1
4
3
hc hc
W

-
4 1240 1240
3
310 248
W
= 16 5 = 3 W
= 11 = 3 W
= W = 3.7 eV
8. If /
Cu
is the wavelength of K
o
X-ray line of copper (atomic number 29) and /
Mo
is the wavelength of the K
o
X-ray line of molybdenum (atomic number 42), then the ratio /
Cu
//
Mo
is close to
(A) 1.99 (B) 2.14
(C) 0.50 (D) 0.48
Answer (B)
Hint :
2
2
Cu Mo
2
Mo
Cu
(Z 1) 41
2.14
28
(Z 1)
/ -


/
-
9. A planet of radius
1
(radius of Earth)
10
R has the same mass density as Earth. Scientists dig a well of
depth
5
R
on it and lower a wire of the same length and of linear mass density 10
3
kg m
1
into it. If the wire
is not touching anywhere, the force applied at the top of the wire by a person holding it in place is (take the
radius of Earth = 6 10
6
m and the acceleration due to gravity on Earth is 10 ms
2
)
(A) 96 N (B) 108 N
(C) 120 N (D) 150 N
(6)
Answer (B)
Hint :

6
5
6 10
6 10 m
10 10
e
P
R
R
p
P
= p
E
r p
3
2 2
4
3
GM G
g R
R R
r p
4
3
g G R
R
P
x
dx
.
2
1 m/s
10
e P P
P
e E
g g R
g
g R
Acceleration due to gravity at a depth x

-


1
x P
x
g g
R
Force on a small segment of wire at a depth x from surface
/ ( ) dF dx gx

/ -


1
x
dF gdx
R

. / -

/5
0
1
R x
F gdx
R

/5
2
0
2

/ -



R
x
x g
R

- -
( | |
/ -
| (
\
3 3 5
9 9
10 10 6 10 1
5 50 50 50
R R
g R g


540
108 N
5
10. A glass capillary tube is of the shape of a truncated cone with an apex angle o so that its two ends have cross
sections of different radii. When dipped in water vertically, water rises in it to a height h, where the radius
of its cross-section is b. If the surface tension of water is S, its density is p, and its contact angle with glass
is 0. the value of h will be (g is the acceleration due to gravity)
h
(A)
0 - o
p
2
cos( )
S
b g
(B)
0 - o
p
2
cos( )
S
b g
(C) 0 - o
p
2
cos( /2)
S
b g
(D)
0 - o
p
2
cos( /2)
S
b g
(7)
Answer (D)
Hint :
h
o
0
0
2
b
2
2 cos
2
o
r 0 - r p


S b b h
2 cos( )
2
o
0 -

p
S
h
bg
SECTION - 2 : Comprehension Type (Only One Option Correct)
This section contains 3 paragraphs, each describing theory, experiments, data etc. 6 questions related
to the three paragraphs with two questions on each paragraph. Each question has only one correct
answer among the four given options (A), (B), (C) and (D).
Paragraph For Questions 11 & 12
In the figure, a container is shown to have a movable (without friction) piston on top. The container and the
piston are all made of perfectly insulation material allowing no heat transfer between outside and inside the
container. The container is divided into two compartments by a rigid partition made of a thermally conducting
material that allows slow transfer of heat. The lower compartment of the container is filled with 2 moles of
an ideal monatomic gas at 700 K and the upper compartment is filled with 2 moles of an ideal diatomic gas
at 400 K. The heat capacities per mole of an ideal monatomic gas are
, ,
2 2
V P
C R C R
3 5
= =
and those for an
ideal diatomic gas are
5 7
,
2 2
V P
C R C R = =
.
11. Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved, the final
temperature of the gases will be
(A) 550 K (B) 525 K
(C) 513 K (D) 490 K
Answer (D)
Hint : Q
2
= Q
1
3 7
2 ( 700) 2 ( 400)
2 2
R R
T T - - -

=
6 6 700 14 400 14 T T - - -
= 5600 + 4200 = 20 T = T = 490 K
(8)
12. Now consider the partition to be free to move without friction so that the pressure of gases in both
compartments is the same. The total work done by the gases till the time they achieve equilibrium will be
(A) 250 R (B) 200 R
(C) 100 R (D) 100 R
Answer (D)
Hint :
1 2
1 2
( 700) (400 )
P P
n C T n C T - -
=
5 7
2 ( 700) 2 (400 )
2 2
R R
T T - -
5 3500 2800 7 T T - -
=
- 12 3500 2800 T
=
6300
525
12
T
AW = AU =
- - -
1 2
1 2
(525 700) (525 400)
V V
n C n C
- -
3 5
2 175 2 125
2 2
R R
= 525R + 625R
AW = AU = 100 R
Paragraph For Questions 13 & 14
A spray gun is shown in the figure where a piston pushes air out of a nozzle. A thin tube of uniform cross
section is connected to the nozzle. The other end of the tube is in a small liquid container. As the piston
pushes air through the nozzle, the liquid from the container rises into the nozzle and is sprayed out. For the
spray gun shown, the radii of the piston and the nozzle are 20 mm and 1 mm respectively. The upper end
of the container is open to the atmosphere.
13. If the piston is pushed at a speed of 5 mms
1
, the air comes out of the nozzle with a speed of
(A) 0.1 ms
1
(B) 1 ms
1
(C) 2 ms
1
(D) 8 ms
1
Answer (C)
Hint :
A
1
V
1
= A
2
V
2
=
2 2 2
(0.2) 0.005
L
V
-
r r(1O )
=
2 2
0.04 0.005
L
V
-
r r(1O )
=
4 4
10
L
V
- -
r 2 r1O
= V
L
= 2
14. If the density of air is p
a
and that of the liquid p
l
, then for a given piston speed the rate (volume per unit
time) at which the liquid is sprayed will be proportional to
(A)
p
p
a
l
(B) p p
a l
(C)
p
p
l
a
(D) p
l
(9)
Answer (A)
Hint :
- p
2
1 2
1
2
a a
P P v
1 2
3
2
3 2
1
2
l l
P P v - p
P
3
= P
1
.
2 2
1 1
2 2
l l a a
v v p p
=
p

p
a
l a
l
v v
. Volume flow rate
a
l
p
p
Paragraph For Questions 15 & 16
The figure shows a circular loop of radius a with two long parallel wires (numbered 1 and 2) all in the plane
of the paper. The distance of each wire from the centre of the loop is d. The loop and the wires are carrying
the same current I. The current in the loop is in the counterclockwise direction if seen from above.
Q S
d d
P R
Wire 2 Wire 1 a
15. When d
=
a but wires are not touching the loop, it is found that the net magnetic field on the axis of the
loop is zero at a height h above the loop. In that case
(A) Current in wire 1 and wire 2 is the direction PQ and RS, respectively and h
=
a
(B) Current in wire 1 and wire 2 is the direction PQ and SR, respectively and h
=
a
(C) Current in wire 1 and wire 2 is the direction PQ and SR, respectively and h
=
1.2a
(D) Current in wire 1 and wire 2 is the direction PQ and RS, respectively and h
=
1.2a
Answer (C)
Hint :
2
0 0
3 2 2
2 2
2
2
2 ( )
2( )
ia ia
a h
a h

r -
-
2
2 2
2 a a
a h

r
-
4 2
2 2 2
4 a a
a h

- r
2 2 2
10 4 4 a a h -
2 2
6 4 a h
2
2
3
2
a
h
1.2 h a =
(10)
16. Consider d

a, and the loop is rotated about its diameter parallel to the wires by 30 from the position shown
in the figure. If the currents in the wires are in the opposite directions, the torque on the loop at its new
position will be (assume that the net field due to the wires is constant over the loop)
(A)
2 2
0
I a
d
(B)
2 2
0
2
I a
d
(C)
2 2
0
3 I a
d
(D)

2 2
0
3
2
I a
d
Answer (B)
Hint :
0
2
2

r
I
B
d
2 0
2 1
2 2

t r
r
I
I a
d

2 2
0
2

I a
d
SECTION - 3 : Matching List Type (Only One Option Correct)
This section contains 4 questions, each having two matching lists. Choice for the correct combination of elements
from List-I and List-II are given as options (A), (B), (C) and (D), out of which one is correct.
17. Four charges Q
1
, Q
2
, Q
3
and Q
4
of same magnitude are fixed along the x axis at x = 2a, a, +a and +2a,
respectively. A positive charge q is placed on the positive y axis at a distance b > 0. Four options of the signs
of these charges are given in List I. The direction of the forces on the charge q is given in List II. Match
List I with List II and select the correct answer using the code given below the lists.
Q
a
1
(2 ,0)
Q
a
2
( ,0)
Q
a
3
(+ ,0)
Q
a
4
(+2 ,0)
q b (0, )
List-I List-II
P. Q
1
, Q
2
, Q
3
, Q
4
all positive 1. +x
Q. Q
1
, Q
2
positive; Q
3
, Q
4
negative 2. x
R. Q
1
, Q
4
positive; Q
2
, Q
3
negative 3. +y
S. Q
1
, Q
3
positive; Q
2
, Q
4
negative 4. y
Code :
(A) P-3, Q-1, R-4, S-2 (B) P-4, Q-2, R-3, S-1
(C) P-3, Q-1, R-2, S-4 (D) P-4, Q-2, R-1, S-3
(11)
Answer (A)
Hint:
P. Not along +y Q. Not along +x
Q
1
Q
2
Q
3
Q
4
Q
1
Q
2
Q
3
Q
4
R. Not along y S. Not along x
Q
1
Q
2
Q
3
Q
4 Q
1
Q
2
Q
3
Q
4
18. Four combinations of two thin lenses are given in List I. The radius of curvature of all curved surfaces is
r and the refractive index of all the lenses is 1.5. Match lens combinations in List I with their focal length
in List II and select the correct answer using the code given below the lists.
List-I List-II
P. 1. 2r
Q. 2.
2
r
R. 3. r
S. 4. r
(12)
Code :
(A) P-1, Q-2, R-3, S-4
(B) P-2, Q-4, R-3, S-1
(C) P-4, Q-1, R-2, S-3
(D) P-2, Q-1, R-3, S-4
Answer (B)
Hint : (P)

- - -


1 1 1 2 1
( 1) (1.5 1) u
f r r r r
f r
-
1 2
1 1 1
'
' 2
r
f
f f f
P 2
(Q)

- -

1
1 1 1 0.5
(1.5 1)
f r r

1 2
2 f r f
- -
1 2
1 1 1 1 1 1
2 2
f r
f f f f r r
Q 4
(R)

- - - -

1
1
1 1 1 0.5
(1.5 1) 2 f r
f r r
( )

- - - - -

2
2
1 1 1 0.5
1.5 1 2 f r
f r r
- - -
1 2
1 1 1 1 1
2 2 f f f r r
- f r
R 3
(13)
(S)

- -

-

1
1
1 1 1 2 1
(1.5 1) 0.5 f r
f r r r r

- - - -

2
2 2
1 1 1 1 0.5
(1.5 1) 2 f r
f r f r
- -
1 2
1 1 1 1 1 1
2 2 f f f r r r
2 f r
. S 1
19. A block of mass m
1
= 1 kg another mass m
2
= 2 kg, are placed together (see figure) on an inclined plane
with angle of inclination 0. Various values of 0 are given in List I. The coefficient of friction between the
block m
1
and the plane is always zero. The coefficient of static and dynamic friction between the block m
2
and the plane are equal to = 0.3. In List II expressions for the friction on block m
2
are given. Match the
correct expression of the friction in List II with the angles given in List I, and choose the correct option.
The acceleration due to gravity is denoted by g.
[Useful information : tan(5.5) = 0.1; tan(11.5) = 0.2; tan(16.5) = 0.3]
0
m
2
m
1
List-I List-II
P. 0 = 5 1. m
2
g sin0
Q. 0 = 10 2. (m
1
+ m
2
)g sin0
R. 0 = 15 3. m
2
g cos0
S. 0 = 20 4. (m
1
+ m
2
)g cos0
Code :
(A) P-1, Q-1, R-1, S-3 (B) P-2, Q-2, R-2, S-3
(C) P-2, Q-2, R-2, S-4 (D) P-2, Q-2, R-3, S-3
Answer (D)
Hint :
0
m
2
m
1
2 1 2
cos ( ) sin m g m m g 0 - 0
(14)
=
2
1 2
tan 0.2
m
m m

0
-
So block m
2
starts sliding at 0 > 11.5.
When 0 = 5 and 0 = 10, then block will be rest, so friction will be
1 2
( ) sin m m g - 0
For 0 = 15 and 0 = 20, block starts sliding.
So friction will be
2
cos m g 0 .
So option (D) is correct.
20. A person in lift is holding a water jar, which has a small hole at the lower end of its side. When the lift is at rest, the
water jet coming out of the hole hits the floor of the lift at a distance d of 1.2 m from the person. In the following, state
of the lift's motion is given in List I and the distance where the water jet hits the floor of the lift is given in List II. Match
the statements from List I with those in List II and select the correct answer using the code given below the lists.
List-I List-II
P. Lift is accelerating vertically up 1. d = 1.2 m
Q. Lift is accelerating vertically down 2. d > 1.2 m
with an acceleration less than the
gravitational acceleration
R. Lift is moving vertically up 3. d < 1.2 m
with constant speed
S. Lift is falling freely 4. No water leaks out of the jar
Code :
(A) P-2, Q-3, R-2, S-4
(B) P-2, Q-3, R-1, S-4
(C) P-1, Q-1, R-1, S-4
(D) P-2, Q-3, R-1, S-1
Answer (C)
Hint :

2
2
h
R gh
g
x
d v t
a
H
h
2H g+a ( )
d
2 ( )
h
H g a
g a
2
-
-
d Independent of acceleration of lift.
(15)
PARTII : CHEMISTRY
SECTION - 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE Option is correct.
21. The acidic hydrolysis of ether (X) shown below is fastest when
Acid
OH + ROH OR
[X]
(A) One phenyl group is replaced by a methyl group
(B) One phenyl group is replaced by a para-methoxyphenyl group
(C) Two phenyl groups are replaced by two para-methoxyphenyl groups
(D) No structural change is made to X
Answer (C)
Hint : OCH
3
group has +R effect. It increases the stability of the carbocation.
22. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure.
and and
(I) (II) (III)
The correct order of their boiling point is
(A) I > II > III (B) III > II > I
(C) II > III > I (D) III > I > II
Answer (B)
Hint : As branching increases boiling point decreases, so order of boiling point is III > II > I.
23. The major product in the following reaction is
Cl
O
CH
3
1. CH MgBr, dry ether, 0 C
2. aq. acid
3
(A)
HC
3
O
CH
3
(B)
HC
2
OH
CH
3
CH
3
(C)
O
CH
2
(D)
O
CH
3
CH
3
(16)
Answer (D)
Hint :
Cl
O
CH MgI
3
Cl
O

CH
3
O
CH
3
CH
3
24. Hydrogen peroxide in its reaction with KIO
4
and NH
2
OH respectively, is acting as a
(A) Reducing agent, oxidising agent
(B) Reducing agent, reducing agent
(C) Oxidising agent, oxidising agent
(D) Oxidising agent, reducing agent
Answer (A)
Hint : H
2
O
2
acting as a reducing agent with KIO
4
and H
2
O
2
acting as an oxidising agent with NH
2
OH.
25. The product formed in the reaction of SOCl
2
with white phosphorous is
(A) PCl
3
(B) SO
2
Cl
2
(C) SCl
2
(D) POCl
3
Answer (A)
Hint :
- - -
4 2 3 2 2 2
(White)
P 8SOCl 4PCl 4SO 2S Cl
26. Under ambient conditions, the total number of gases released as products in the final step of the reaction
scheme shown below is
XeF
6
Complete
Hydrolysis
P + Other product
Q
OH /H O

2
Products
Slow disproportionation in OH/HO

2
(A) 0 (B) 1
(C) 2 (D) 3
Answer (C)
Hint : XeF
6
Complete
Hydrolysis
XeO + HF
3 2 2
HXeO
4

OH /H O

2
XeO + Xe(g) + HO + O (g)
6 2 2
4
Slow disproportionation in OH/HO

2
(17)
27. For the identification of -naphthol using dye test, it is necessary to use
(A) Dichloromethane solution of -naphthol (B) Acidic solution of -naphthol
(C) Neutral solution of -naphthol (D) Alkaline solution of -naphthol
Answer (D)
Hint :
O H
NaOH
O
N Cl
2
+
O H
N N
28. For the elementary reaction M N, the rate of disappearance of M increases by a factor of 8 upon doubling
the concentration of M. The order of the reaction with respect to M is
(A) 4 (B) 3
(C) 2 (D) 1
Answer (B)
Hint :
o

2 2
1 1
r [M]
r [M]
8 = (2)
o
o = 3
So, order of reaction is 3.
29. For the process
H
2
O(I) H
2
O(g)
at T = 100 C and 1 atmosphere pressure, the correct choice is
(A) AS
system
> 0 and AS
surroundings
> 0
(B) AS
system
> 0 and AS
surroundings
< 0
(C) AS
system
< 0 and AS
surroundings
> 0
(D) AS
system
< 0 and AS
surroundings
< 0
Answer (B)
Hint : Given conditions are boiling conditions for water due to which
AS
total
= 0
AS
system
+ AS
surroundings
= 0
AS
system
= AS
surroundings
For process, AS
system
> 0
AS
surroundings
< 0
30. Assuming 2s-2p mixing is NOT operative, the paramagnetic species among the following is
(A) Be
2
(B) B
2
(C) C
2
(D) N
2
Answer (C)
Hint : Be
2
= o1s
2
o*1s
2
o2s
2
o*2s
2
B
2
= o1s
2
o*1s
2
o2s
2
o*2s
2
o2p
z
2
C
2
= o1s
2
o*1s
2
o2s
2
o*2s
2
o2p
z
2
r2p
x
1
r2p
y
1
N
2
= o1s
2
o*1s
2
o2s
2
o*2s
2
o2p
z
2
r2p
x
2
r2p
y
2
(18)
SECTION - 2 : Comprehension Type (Only One Option Correct)
This section contains 3 paragraphs, each describing theory, experiments, data etc. 6 questions related
to the three paragraphs with two questions on each paragraph. Each question has only one correct
answer among the four given options (A), (B), (C) and (D).
Paragraph For Questions 31 & 32
Schemes 1 and 2 describe sequential transformation of alkynes M and N. Consider only the major products formed
in each step for both the schemes.
HO
1. NaNH (excess)
2. CH CH I (1 equivalent)
2
3 2
3. CH I (1 equivalent)
4. H , Lindlars catalyst
3
2
H X
M
Scheme-1
1. NaNH ( )
2
2 equivalent
H Y
N
Scheme-2
Br
OH
2.
3. H O , (mild)
3
4. H , Pd/C
2
5. CrO
3
31. The product X is
(A)
H H
H CO
3
(B)
H
H
H CO
3
(C)
H H
CH C O
3
H
2
(D)
H
H
CH C O
3
H
2
Answer (A)
Hint :
H
NaNH
2
Na
+
O
C Na
+
CH
2
I CH
3
(1 eq)
C
I CH
3
O CH
3
H
2
Lindlar's
catalyst H H
CH
3
O
HO Na
+
O

32. The correct statement with respect to product Y is

(A) It gives a positive Tollens test and is a functional isomer of X
(B) It gives a positive Tollens test and is a geometrical isomer of X
(C) It gives a positive iodoform test and is a functional isomer of X
(D) It gives a positive iodoform test and is a geometrical isomer of X
(19)
Answer (C)
Hint :
1. NaNH ( )
2
2 eq
H
Br
OH
2.
3. H O (mild)
3
+
4. H , Pd/C
2
5. CrO
3
O
Paragraph For Questions 33 & 34
An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to give tetrahedral and
square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral
complexes with these reagents. Aqueous solution of M2 on reaction with reagent S gives white precipitate which
dissolves in excess of S. The reactions are summarized in the scheme given below :
Scheme :
Tetrahedral
Tetrahedral
Excess
Excess
Q
Q
M1
M2
Excess
Excess
S, stoichiometric amount
R
R
Square planar
Tetrahedral
White precipitate
Excess
R
Precipitate dissolves
33. M1, Q and R, respectively are
(A) Zn
2+
, KCN and HCl (B) Ni
2+
, HCl and KCN
(C) Cd
2+
, KCN and HCl (D) Co
2+
, HCl and KCN
Answer (B)
Hint : Ni
+2
+ HCl [NiCl
4
]
2
Ni
+2
+ KCN [Ni(CN)
4
]
2
34. Reagent S is
(A) K
4
[Fe(CN)
6
] (B) Na
2
HPO
4
(C) K
2
CrO
4
(D) KOH
Answer (D)
Hint :
OH 2 2
2 4
white ppt Soluble
Zn OH Zn(OH) [Zn(OH) ]
-
- - -
-
Paragraph For Questions 35 & 36
X and Y are two volatile liquids with molar weights of 10 g mol
1
and 40 g mol
1
respectively. Two cotton plugs,
one soaked in X and the other soaked in Y, are simultaneously placed at the ends of a tube of length L = 24 cm,
as shown in the figure. The tube is filled with an inert gas at 1 atmosphere pressure and a temperature of 300
K. Vapours of X and Y react to form a product which is first observed at a distance
d cm from the plug soaked in X. Take X and Y to have equal molecular diameters and assume ideal behaviour
for the inert gas and the two vapours.
L = 24 cm
d
Cotton wool
soaked in X
Initial formation
of the product
Cotton wool
soaked in Y
(20)
35. The value of d in cm (shown in the figure), as estimated from Graham's law, is
(A) 8 (B) 12 (C) 16 (D) 20
Answer (C)
Hint :

x 40
24 x 10

x
2
24 x
x = 16
36. The experimental value of d is found to be smaller than the estimate obtained using Graham's law. This is
due to
(A) Larger mean free path for X as compared to that of Y
(B) Larger mean free path for Y as compared to that of X
(C) Increased collision frequency of Y with the inert gas as compared to that of X with the inert gas
(D) Increased collision frequency of X with the inert gas as compared to that of Y with the inert gas
Answer (D)
Hint : Increased collision frequency of X with the inert gas as compared to that of y with the inert gas. Therefore,
the experimental value of d is found to be smaller than the estimate obtained using Graham's law.
SECTION - 3 : Matching List Type (Only One Option Correct)
This section contains 4 questions, each having two matching lists. Choice for the correct combination of elements
from List-I and List-II are given as options (A), (B), (C) and (D), out of which one is correct.
37. Different possible thermal decomposition pathways for peroxyesters are shown below. Match each pathway
from List I with an appropriate structure from List II and select the correct answer using the code given
below the lists.
R
O
O
O
R
R + R O
- -

R + R O
- -
R + X
- -
+ carbonyl compound
RCO + R O
2
- -
R + X
- -

+ carbonyl compound
CO
2
RCO + R O
2
- -
R + R O
- -

CO
2
CO
2
P
CO
2
Q
R
S
(Peroxyester)
List-I List-II
P. Pathway P 1.
C HCH
6 5 2
O
O
O
CH
3
Q. Pathway Q 2.
C H
6 5
O
O
O
CH
3
R. Pathway R 3.
C HCH
6 5 2
O
O
O
CH
3
CH
3
CHC H
2 6 5
S. Pathway S 4.
C H
6 5
O
O
O
CH
3
CH
3
C H
6 5
(21)
Code :
P Q R S
(A) 1 3 4 2
(B) 2 4 3 1
(C) 4 1 2 3
(D) 3 2 1 4
Answer (A)
Hint : (1) C H CH C O
6 5 2
CH
3
O
O
C H CH + CO + CH O
6 5 2 2 3
(3) C H CH C O
6 5 2
CH
3
O
O
CO +
2
C H CH + CH C O
6 5 2 3
CH
3
CH
3
CH C H
2 6 5
CH C H
2 6 5
C
(4) C H
6 5
C CH
3
C
O
C H C O + O C CH
6 5 3
CH
3
CH
3
O
CH
3
CH
3
O
O
(2)
C H
6 5
CH
3
C C
O O
O + CH O
3
C H
6 5
O
O
38. Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes
(I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.
List-I List-II
P.
H H
1. Scheme I
(i) KMnO , HO, heat (ii) H, HO
(iii) SOCl (iv) NH
4 2
2 3
? C HN O
7 6 2 3
Q.
OH
OH
2.
Scheme II
(i) Sn/HCl (ii) CHCOCl (iii) conc. HSO
(iv) HNO (v) dil. H SO , heat (vi) HO
3 2 4
3 2 4
? C HN O
6 6 2 2
R.
NO
2
3.
Scheme III
(i) red hot iron, 873 K (ii) fuming HNO , H SO , heat
(iii) H S.NH (iv) NaNO , H SO (v) hydrolysis
3 2 4
2 3 2 2 4
? C HNO
6 5 3
S.
NO
2
CH
3
4.
Scheme IV
(i) conc. H SO , 60C
(ii) conc. HNO , conc. H SO (iii) dil. H SO , heat
2 4
3 2 4 2 4
? C HNO
6 5 4
(22)
Code :
P Q R S
(A) 1 4 2 3
(B) 3 1 4 2
(C) 3 4 2 1
(D) 4 1 3 2
Answer (C)
Hint :
Scheme I
NO
2
CH
3
(S)
Scheme II
NO
2
(R)
Scheme III H C C H (P) =
Scheme IV
OH
OH
39. Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select
the correct answer using the code given below the lists.
{en = H
2
NCH
2
CH
2
NH
2
; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}
List-I List-II
P. [Cr(NH
3
)
4
Cl
2
]Cl 1. Paramagnetic and exhibits ionisation isomerism
Q. [Ti(H
2
O)
5
Cl](NO
3
)
2
2. Diamagnetic and exhibits cis-trans isomerism
R. [Pt(en)(NH
3
)Cl]NO
3
3. Paramagnetic and exhibits cis-trans isomerism
S. [Co(NH
3
)
4
(NO
3
)
2
]NO
3
4. Diamagnetic and exhibits ionisation isomerism
Code :
P Q R S
(A) 4 2 3 1
(B) 3 1 4 2
(C) 2 1 3 4
(D) 1 3 4 2
(23)
Answer (B)
Hint : Magnetic character Isomerism
P. [Cr(NH
3
)
4
Cl
2
]Cl Paramagnetic cis/trans
Q. [Ti(H
2
O)
5
Cl](NO
3
)
2
Paramagnetic ionization
R. [Pt(en)(NH
3
)Cl]NO
3
Diamagnetic ionization
S. [Co(NH
3
)
4
(NO
3
)
2
]NO
3
Diamagnetic cis/trans
40. Match the orbital overlap figures shown in List-I with the description given in List-II and select the correct
answer using the code given below the lists.
List-I List-II
P. 1. p d r antibonding
Q. 2. d d o bonding
R. 3. p d r bonding
S. 4. d d o antibonding
Code :
P Q R S
(A) 2 1 3 4
(B) 4 3 1 2
(C) 2 3 1 4
(D) 4 1 3 2
Answer (C)
Hint :
P. d d (o bonding)
Q. p d (r bonding)
R. p d (r antibonding)
S. d d (o antibonding)
(24)
PARTIII : MATHEMATICS
SECTION - 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE Option is correct.
41. The function y = f(x) is the solution of the differential equation
4
2
2
2
1
1
-
-
-
-
dy xy x x
dx
x
x
in (1, 1) satisfying
f(0) = 0. Then
3
2
3
2
( )
-

f x dx
is
(A)
3
3 2
r
-
(B)
3
3 4
r
-
(C)
3
6 4
r
-
(D)
3
6 2
r
-
Answer (B)
Hint :
4
2
2
2
1
1
-
-

-
-
dy x x x
y
dx
x
x
I.F.
2
2
1
1
-
-

-
x
dx
x
e x
So
5
2 4 2
1 ( 2 )
5
- - - -

x
y x x x dx x c
Given f(0) = 0 = c = 0
So
5
2
2
5
( )
1
-

-
x
x
y f x
x
5 3 3 3
2
2 2 2 2
2 2
0 3 3
2 2
5
( ) 2
1 1
- -
-

- -

x
x
x dx
I f x dx dx
x x
Let x = sin0
3
2
0
2 sin
r
0 0

I d
3
0
(1 cos2 )
r
- 0 0

d

r
0 r
0 - -


3
0
sin2 3
2 3 4
(25)
42. The following integral
2
17
4
(2cosec )
r
r

x dx is equal to
(A)
log(1 2)
16
0
2( )
-
-
-

u u
e e du (B)
log(1 2)
17
0
( )
-
-
-

u u
e e du
(C)
log(1 2)
17
0
( )
-
-
-

u u
e e du (D)
log(1 2)
16
0
2( )
-
-
-

u u
e e du
Answer (A)
Hint :
2
17
4
(2cosec )
r
r

I x dx

16
2
4
1
cosec cot 2cosec
cosec cot
r
r

- -

-

x x xdx
x x
Let cosecx + cotx = e
u
= cosecxdx = du
=
0
16
ln( 2 1)
2 ( )
-
-
- -

u u
I e e du
-
-
-

ln( 2 1)
16
0
2( )
u u
e e du
43. Coefficient of x
11
in the expansion of (1 + x
2
)
4
(1 + x
3
)
7
(1 + x
4
)
12
is
(A) 1051 (B) 1106
(C) 1113 (D) 1120
Answer (C)
Hint : Power of Coefficient of x
11

2 3 4
0 1 2
2 1 1
4 1 0
1 3 0
x x x
4 7 12
4 7 12
4 7 12
4 7 12
C C C
C C C
C C C
C C C
0 1 2
2 1 1
4 1 0
1 3 0
1113
44. Let f : [0, 2] be a function which is continuous on [0, 2] and is differentiable on (0, 2) with f(0) = 1.
Let
2
0
( ) ( )

x
F x f t dt for x = [0, 2]. If F(x) = f(x) for all x = (0, 2), then F(2) equals
(A) e
2
1 (B) e
4
1
(C) e 1 (D) e
4
(26)
Answer (B)
Hint : F(x) = f(x).2x = f (x)
=

'( )
2
( )
f x
x
f x
=
2
( )
x
f x ke
Given f(0) = 1 =
2
( )
x
f x e
So
2
0
( )

x
x
F x e dx
2
1 -
x
e
So F(2) = e
4
1
45. The common tangents to the circle x
2
+ y
2
= 2 and the parabola y
2
= 8x touch the circle at the points P, Q
and the parabola at the poitns R, S. Then the area of the quadrilateral PQRS is
(A) 3 (B) 6
(C) 9 (D) 15
Answer (D)
Hint : x
2
+ y
2
= 2
Equation of tangent to circle x
2
+ y
2
= 2 is
2
2 1 - y mx m
Equation of tangent to y
2
= 8x is
2
- y mx
m
2
2
2( 1 ) - m
m
(2, 4)
(1, 1)
(1, 1)
(2, 4)
2
2
4
2(1 ) - m
m
m
2
(1 + m
2
) = 2
m
4
+ m
2
2 = 0
(m
2
+ 2)(m
2
1) = 0
m = 1
y = x + 2
y = x 2
Area
1
3 1 3 3 2
2

-


= 6 + 9 = 15 sq. unit
46. For x = (0, r), the equation sinx + 2sin2x sin3x = 3 has
(A) Infinitely many solutions (B) Three solutions
(C) One solution (D) No solution
(27)
Answer (D)
Hint : sinx + 2sin2x sin3x = 3
2cos2x(sinx) + 4sinxcosx = 3
2sinx[2cosx cos2x] = 3
2sinx(2cosx (2cos
2
x 1)) = 3
2sinx(1 + 2cosx 2cos
2
x) = 3
2
3 1
2sin 2 cos 3
2 2
(
| |
( - -
|
( \ .

x x
Possible only when
sinx = 1 (i)
and
2
1
cos 0
2

-


x
=
1
cos
2
x
(ii)
From (i) and (ii)
No solution.
47. In a triangle the sum of two sides is x and the product of the same two sides is y. If x
2
c
2
= y, where c is
the third side of the triangle, then the ratio of the in radius to the circum-radius of the triangle is
(A)
3
2 ( ) -
y
x x c
(B)
3
2 ( ) -
y
c x c
(C)
3
4 ( ) -
y
x x c
(D)
3
4 ( ) -
y
c x c
Answer (B)
Hint : a + b = x, ab = y, x
2
c
2
= y
Now, (a + b)
2
c
2
= ab
a
2
+ b
2
c
2
= ab
2 2 2
1
2 2
- -
-
a b c
ab
=
1
cos
2
- c
= Zc = 120
2
2
sin
3

c c
R
c
=
3

c
R
( ) tan
2
-
c
r s c
3
2
-
-


x c
r c
( ) 3
2
-

x c
r

- -

( ) 3 3( )
3
2 2
r x c x c
R c c
3( )( )
2 ( )
- -

-
x c x c
c x c
2 2
3( )
2 ( )
-

-
x c
c x c
3
2 ( )

-
y
c x c
(28)
48. Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in envelopes so that each
envelope contains exactly one card and no card is placed in the envelope bearing the same number and
moreover the card numbered 1 is always placed in envelope numbered 2. Then the number of ways it can
be done is
(A) 264 (B) 265
(C) 53 (D) 67
Answer (C)
Hint :
1 1 1 1 1 1
6! 1
1! 2! 3! 4! 5! 6!
5

- - - - - -



265
53
5

49. Three boys and two girls stand in a queue. The probability, that the number of boys ahead of every girl is
at least one more than the number of girls ahead of her, is
(A)
1
2
(B)
1
3
(C)
2
3
(D)
3
4
Answer (A)
Hint : n(S) = 5!
Case I :
G
1
2 4! = 48
Case II :
G
1
2 3! = 12
n(E) = 60
60 1
( )
5! 2
P E
50. The quadratic equation p(x) = 0 with real coefficients has purely imaginary roots. Then the equation
p(p(x)) = 0 has
(A) Only purely imaginary roots (B) All real roots
(C) Two real and two purely imaginary roots (D) Neither real nor purely imaginary roots
Answer (D)
Hint : Let p(x) = x
2
+ a (a > 0) (

roots are purely imaginary)

p(p(x)) = (x
2
+ a)
2
+ a (a = R)
x
4
+ 2a(x
2
) + a
2
+ a = 0
= x
2
=
- - -
2 2
2 4 4 4
2
a a a a
=
- a ai
x =
-
1 1
a ai x iy
(29)
SECTION - 2 : Comprehension Type (Only One Option Correct)
This section contains 3 paragraphs, each describing theory, experiments, data etc. 6 questions related
to the three paragraphs with two questions on each paragraph. Each question has only one correct
answer among the four given options (A), (B), (C) and (D).
Paragraph For Questions 51 & 52
Let a, r, s, t be nonzero real numbers. Let P(at
2
, 2at), Q, R(ar
2
, 2ar) and S(as
2
, 2as) be distinct points on
the parabola y
2
= 4ax. Suppose that PQ is the focal chord and lines QR and PK are parallel, where K is the
point (2a, 0).
51. The value of r is
(A)
1
t
(B)
+
2
1 t
t
(C)
1
t
(D)

2
1 t
t
Answer (D)
Hint :
Let co-ordinates of Q be (at
2
2
, 2at
2
)
Since PQ is focal chord
t t
2
= 1
2
1
t
t
=
. Co-ordinates of Q
2
2
,
a a
t
t

Slope of PK =
2 2
2 0 2
2 2
at t
at a t

=

P
a
t
a
t
(
,

2
)
2
S
( 0) a,
R
( , 2 ) ar ar
2

2a
t
a
t
2
,
2a
t
2
a
t
2
,
Q
K a, (2 0)
Slope of RQ
2 2
2 2
1
2
2
2
1
a
r
ar
t
t
a
ar r
t t

+
+

= =


2
1
r
t
=

Slope of PK = Slope of RQ
2
2 2
1
2
t
t
r
t
=

2 2
1 2 1 t t
r r
t t t

= =
(30)
52. If st = 1, then the tangent at P and the normal at S to the parabola meet at a point whose ordinate is
(A)
+
2 2
3
( 1)
2
t
t
(B)
+
2 2
3
( 1)
2
a t
t
(C)
+
2 2
3
( 1) a t
t
(D)
+
2 2
3
( 2) a t
t
Answer (B)
Hint :
Since st = 1
s =
1
t
Co-ordinates of S =
2
2
,
a a
t
t



Equation of tangent at P
y =
1
t
(x + at
2
)
2
x yt at = ....(i)
Slope of normal at S = s
1
t
=
Equation of normal
2
2 1 a a
y x
t t
t

=


2
2
a
ty a x
t
+ =
=
2
2
a
x ty a
t
= + +
....(ii)
From (i) and (ii)
y.t at
2
= ty + 2a +
2
a
t
2ty = at
2
+
2
a
t
+ 2a
2ty = a
2
1
t
t

+


= y =
2
1
2
a t
t
t

+


2 2
3
( 1)
2
a t
y
t
+
=
Paragraph For Questions 53 & 54
Given that for each a = (0, 1),
+

1
1
0
lim (1 )
h
a a
h
h
t t dt
exists. Let this limit be g(a). In addition, it is given that the function g(a) is differentiable on (0, 1).
53. The value of g



1
2
is
(A) r (B) 2r
(C)

2
(D)

4
(31)
Answer (A)
Hint : g(a) =
(1 )
1
0
lim (1 )
h
a a
h
h
t t dt
+

g
1
2



=
( )
(1 )
1/2
1/2
0
lim 1
h
h
h
t t dt
+

(1 )
0
1
lim
(1 )
h
h
h
dt
t t
+

1
1
0
1
2
lim sin
1
2
h
h
h
t
+

=



1 1
0
lim [sin (2(1 ) 1)) sin (2 1)]
h
h h
+

=
2 2

= + =
54. The value of g'



1
2
is
(A)

2
(B) r
(C)

2
(D) 0
Answer (D)
Hint : g(a) =
1
1
0
lim (1 )
h
a a
h
h
t t dt
+

-
-
- -

-
-

1
1
0
1
'( ) lim (1 ) ln
h
a a
h
h
t
g a t t dt
t
-
-
- -

-
-

1 1 1
2 2
0
1 1
' lim (1 ) ln
2
h
h
h
t
g t t dt
t
=

1
' 0
2
g
Paragraph For Questions 55 & 56
Box 1 contains three cards bearing numbers 1, 2, 3; box 2 contains five cards bearing numbers 1, 2, 3, 4, 5;
and box 3 contains seven cards bearing numbers 1, 2, 3, 4, 5, 6, 7. A card is drawn from each of the boxes.
Let x
i
be number on the card drawn from the i
th
box, i = 1, 2, 3.
55. The probability that x
1
+ x
2
+ x
3
is odd, is
(A)
29
105
(B)
53
105
(C)
57
105
(D)
1
2
(32)
Answer (B)
Hint :
1 1
2 2 B
1
B
2
3
3
4
5
1
2 B
3
3
4
5
6
7
x
1
+ x
2
+ x
3
= odd
CaseI : One odd (2 3 2) + (4 1 2) + (3 3 1)
Two even = 12 + 8 + 9 = 29
CaseII : 3 odd 2 4 3 = 24
= 29 + 24 = 53
Total cases = 3 5 7 = 105
Probability =
53
105
56. The probability that x
1
, x
2
, x
3
are in an arithmetic progression, is
(A)
9
105
(B)
10
105
(C)
11
105
(D)
7
105
Answer (C)
Hint : 2x
2
= x
1
+ x
3
x
1
and x
3
must be even number.
both x
1
= {1, 3}
x
1
and x
3
odd x
3
= {1, 3, 5, 7}
also x
1
+ x
3
= {2, 4, 6, 8, 10}
x
1
x
3
1
3
(1, 3, 5, 7)
(1, 3, 5, 7)
8 cases
x
1
and x
3
both even
x
2
= 2
x
3
= (2, 4, 6) 3 cases
Total = 11 cases
Required probability =
11
105
(33)
SECTION - 3 : Matching List Type (Only One Option Correct)
This section contains 4 questions, each having two matching lists. Choice for the correct combination of elements
from List-I and List-II are given as options (A), (B), (C) and (D), out of which one is correct.
57. Let
r r
-


2 2
cos sin
10 10
k
k k
z i ; k = 1, 2, ..., 9.
List-I List-II
P. For each z
k
there exists a z
j
such that z
k
. z
j
= 1 1. True
Q. There exists a k = {1, 2, ..., 9} such that z
1
.z = z
k

has 2. False
no solution z in the set of complex numbers
R.
- - -
1 2 9
|1 ||1 |...|1 |
10
z z z
equals 3. 1
S.
r
- Z


9
1
2
1 cos
10
k
k
equals 4. 2
P Q R S
(A) 1 2 4 3
(B) 2 1 3 4
(C) 1 2 3 4
(D) 2 1 4 3
Answer (C)
Hint : z
k
=
2
10
2 2
cos sin
10 10
i k k
i e

+ =


(P) z
k
.z
j
= 1
=
2
( )
10
1
i k j
e

+
=
=
2 ( ) 2 ( )
cos 1 and sin 0
10 10
k j k j + +
= =


= k + j = 10n and k + j = 5m; so true
(Q)
2
( 1)
10
1
i k
k
z
z e
z

= =
So, if k = {1, 2, .....9}, z has solution; i.e., false
(Q) 2
(R) z
10
1 = 0
= (z z
1
)(z z
2
).....(z z
9
) = 1 + z + z
2
+ ..... + z
9
So, |1 z
1
||1 z
2
|.......|1 z
9
| = 10
i.e., (R) 3
(S)
2 4 18
1 cos cos ..... cos
10 10 10

+ + +


4 2
8
10 10
1 cos 2
2

+

= =



(34)
58. List-I List-II
P. The number of polynomials f(x) with non-negative integer 1. 8
coefficients of degree s 2, satisfying f(0) = 0 and

1
0
( ) 1, is f x dx
Q. The number of points in the interval
- [ 13, 13]
at 2. 2
which f(x) = sin(x
2
) + cos(x
2
) attains its maximum value, is
R.
-
-

2
2
2
3
(1 )
x
x
dx
e
equals 3. 4
S.
-

-


-



-



-

1
2
1
2
1
2
0
1
cos 2 log
1
1
cos 2 log
1
x
x dx
x
x
x dx
x
equals 4. 0
P Q R S
(A) 3 2 4 1
(B) 2 3 4 1
(C) 3 2 1 4
(D) 2 3 1 4
Answer (D)
Hint : (P) Let f(x) = a
0
x
2
+ a
1
x + a
2
; a
0
, a
1
, a
2
> 0
Now, a
2
= 0 and
1
0
( ) 1

f x dx
=
1
3 2
0 1
0
1
3 2


-



a x a x
=
0 1
1
3 2
-
a a
= 2a
0
+ 3a
1
= 6
i.e., for integral solution
for
0 1
0 1
either 3, 0
or 0, 2

a a
a a
i.e., f(x) = 3x
2
or f(x) = 2x
P (2)
(Q)
max
( ) 2 f x
at
2
9
,
4 4
r r
x
=
r r

9
,
4 4
x
So, number of points = 4
Q (3)
(35)
(R)
2
2
2
3
1
-

x
x
I dx
e
again,
2
2
2
3
1
-
-

x
x
I dx
e
Adding,
2
2 3 2
2
2
2 3 { } 16
-
-

I x dx x
= I = 8
R (1)
(S) As
1
cos2 log
1
-

-

x
x
x
is an odd function
So,
1
2
1
2
1
cos2 log 0
1
-
-


-

x
x dx
x
S (4)
59. List-I List-II
P. Let y(x) = cos(3 cos
1
x), = -
3
[ 1,1],
2
x x . Then 1. 1


- -



2
2
2
1 ( ) ( )
( 1)
( )
d y x dy x
x x
y x dx
dx
equals
Q. Let A
1
, A
2
, ... , A
n
(n > 2) be the vertices of a regular 2. 2
polygon of n sides with its centre at the origin.
Let

k
a be the position vector of the point A
k
,
k = 1, 2, ... , n. If
- -
- -
Z

1 1
1 1 1 1
( ) ( . )
n n
k k k k k k
a a a a
,
then the minimum value of n is
R. If the normal from the point P(h, 1) on the ellipse 3. 8
-
2 2
1
6 3
x y
is perpendicular to the line x + y = 8,
then the value of h is
S. Number of positive solutions satisfying the equation 4. 9
- - -

-

- -

1 1 1
2
1 1 2
tan tan tan
2 1 4 1 x x
x
is
P Q R S
(A) 4 3 2 1
(B) 2 4 3 1
(C) 4 3 1 2
(D) 2 4 1 3
(36)
Answer (A)
Hint : (P)
1
2
3
sin(3cos )
1
-
-
-
-
dy
x
dx
x
=
2
2 2 1 2
(1 ) 9(1 cos (3cos )) 9(1 )
-

- - -


dy
x x y
dx
=
2
2
2 2
2
(1 ) ( 2 ) 18

- - - -


dy d y dy dy
x x y
dx dx dx
dx
=
2
2
2
( 1) 9

- -


d y dy
x x y
dx
dx
(Q)
2 2
2 2
( 1) sin ( 1) cos
r r
- -


n R n R
n n
=
2
tan 1
r

n
= n = 8
(R) As, equation of normal is
6 3
3
cos sin
-
0 0
x y
(i)
Given its slope = 1 =
1
tan
2
0
Also (i) passes through (h, 1)
So,
6 3
3
1
2
3
3
-





h
= h = 2
(S)
1 1
2
1 1
2
2 1 4 1
tan tan
1
1
(2 1)(4 1)
- -

-


- -




-

- -

x x
x
x x
=
2 2
6 2 2
8 6
-

-
x
x x x
=
3 1 2
4 3
-

-
x
x x
(where x 0)
= 3x
2
7x 6 = 0
=
2
3,
3
- x
But 2x + 1 > 0 and 4x + 1 > 0
So, solution are x = 3
60. Let
1
: f , f
2
: [0, ) , f
3
: and f
4
: [0, ) be defined by
<

1
| | if 0,
( )
if 0;
x
x x
f x
e x
f
2
(x) = x
2
;
f
3
(x) =
<

sin if 0,
if 0
x x
x x
(37)
and
<

2 1
4
2 1
( ( )) if 0,
( )
( ( )) 1 if 0.
f f x x
f x
f f x x
List-I List-II
P. f
4
is 1. Onto but not one-one
Q. f
3
is 2. Neither continuous nor one-one
R. f
2
of
1
is 3. Differentiable but not one-one
S. f
2
is 4. Continuous and one-one
P Q R S
(A) 3 1 4 2
(B) 1 3 4 2
(C) 3 1 2 4
(D) 1 3 2 4
Answer (D)
Hint :
(P) f
4
(x) =
2 1
2 1
[ ( )], 0
[ ( )] 1, 0
f f x x
f f x x
<

Onto but not one-one =

2
2
, 0
1, 0
x
x x
e x

<

Now f(x) is not differentiable at x = 0, not one-one but continuous.

(P) 1
(Q) Now, f
3
=
sin , 0
, 0
x x
x x
<

Differentiable but not one-one.

(Q) 3
(R) f
2
of
1
=
2
2
, 0
, 0
x
x x
e x

<

(R) 2
(S) f
2
: [0, ] R, f
2
(x) = x
2
(S) 4