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size
(B) atomic size
7. The atomic radii of palladium and platinum are nearly same why?
8. Pick out among the following,
and
in order of their
(a) Increasing effective nuclear charge (b) Increasing ionic radius
(c) Increasing ionization energy
10. Why the atomic radius of neon is greater than fluorine?
Section (C): Ionization Energy:
11. Pick out among the following
(g) from O is
endothermic, why?
19. Be and N have extremely low value of EA against the trend. Explain.
Section (E): Electronegativity:
20. Calculate the electronegativity of chlorine from the bond energy of bond (61
kcal
) and
electronegativity of fluorine is 4.0
21. The ionization potentials of atoms A and B are 400 kcal
respectively. The
electron affinities of these atoms are 80.0 and 85.0 kcal
Ni 2.49 8.80
Pt 2.66 6.70
[Title] Page 3
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2. Atomic Number Period Group no. Block
9 2
nd
17
th
p block
14 3
rd
14
th
p block
20 4
th
2
nd
s block
27 4
th
9
th
d block
3. (a) Al (b) Ti3
rd
or III B (d) As & Sb.
4. 47
5. (i) In lanthanides and actinides, the differentiating electron enters to (n 2)f
subshell.
(ii) In modern periodic table, elements have been place in order of their increasing
atomic numbers. The atomic number of argon is 18 and that of potassium is 19. Thus
argon has been placed before potassium.
6. (A)
; (B)
7. Due to lanthanide contraction.
8.
9. (a)
(b)
(c)
10 Vander waass radius is considered in case of neon not covalent radius
11.
12. In all the 3 cases an s electron in the unpaired state is to be removed. In the case of
Cu a 4s electron is to be removed which is closer to the nucleus than the 5s electron of
Ag. So I.P. decreasing from Cu to Ag. However from Ag to Au the 14 f electrons are added
which provide very poor shielding effect. The nuclear charge is thus enhanced and
therefore the outer electron of Au is more tightly held and so the IP is high.
13 The configuration of K is [Ar]4s while that of Cu is []3
Cu 744 1961
Zn 906 1736
of copper is less than that of zinc, because removed of electron takes palce from
4
and reverse
is the case in Pt.
17. (i) O, (ii) Cl
18. Addition of second electron is opposed by electrostatic repulsion of
19. In Be the extra electron is to be added in 2p-orbital because 2s orbital is completely
filled and in N, it is to added to a half filled 2p orbital. Since half filled and full filled
orbitals are more stable, reluctance in accept electron is found.
20.
20 *
322
21. Electronegativity of A = 3.84; electronegativity of B = 3.08. therefore A has higher
electronegativity.
22.
(
) (
) (
) (
) 02
43 02
35