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CICLO: 2010-II
EXAMEN FINAL
1.
2.
200
400
600
1000
500 C
P(kN/m2)
7.33
8.53
10.5
11.9
t(min)
0
2.0
6.0
10.0
520 C
P(kN/m2)
7.33
9.67
12.3
13.6
t(min)
0
2.0
6.0
540 C
P(kN/m2)
7.33
11.2
13.9
5.
6.
SOLUCION preg.1
TIEMPO
Pt
Po=0
(horas)
(mmHg)
0
100
1
173
2
218
3
248
4
266
INF.
300
PRIMER ORDEN
Ln (a-x) = Ln a + (-k)*t
-k1=
Ln a=
r 1=
a=Pinf -Po
x=Pt - Po
a-x=Pinf Pt
200.0000
127.0000
82.0000
52.0000
34.0000
1/(a-x)
Ln(a-x)
0.0050000
0.0078740
0.0121951
0.0192308
0.0294118
5.2983
4.8442
4.4067
3.9512
3.5264
-0.4436857 k1=
5.292737
-0.99994
a=
Po=
0.443685705 hr-1
198.8870348
101.1129652
SEGUNDO ORDEN
1/(a-x)= 1/a +k*t
k2=
1/a=
r 2=
0.006018
0.0027063
0.97126
SOLUCION preg.2
a=
K=
Po=
369.5112228
0.006018028
-69.5112228
velocidad
(%A/min)
A
(%A)
Log v
Log A
11.88
8.94
4.63
3.13
18
16
10
6
1.0748
0.9513
0.6656
0.4955
1.2552725
1.2041200
1.0000000
0.7781513
v=kCn
logv = logK+nlogC
n=
LogK=
r 1=
1.1930652
-0.4670966
0.98285
n=
K=
1.193065171
0.341116998
SOLUCION 3
Pf= Po + Prd..(1)
Po-Prd= Pr(2)
De (1) y (2)
Pr = 2Po-Pf ..(3)
Reaccin de orden cero:
Reemplazando (3) en (4):
Po-(2Po-Pf)= Pf -Po = Kt
Pf = Po + Ko * t
Y =A + m
TIEMPO
(segundos)
200
400
600
1000
Pf
(kN/m2)
30.4
33.3
36.4
42.4
x= Po-Pr=kt .(4)
Regresin lineal
Pf = Po + Ko * t
Ko=
Po=
0.0150429
27.351429
a)
r 1=
0.99996
(reaccin es de orden cero)
SOLUCION PROB.4
773K
(kN/m2)
Po= 7.33
TIEMPO
(min)
Ln (Po/Pr)
Pt
Prd=Pt-Po
Pr=Po-Prd
0
2
6
10
(kN/m2)
7.33
8.53
10.5
11.9
0
1.2
3.17
4.57
Pr=2Po-Pt
7.33
6.13
4.16
2.76
0.0000
0.1788
0.5665
0.9767
PRIMER ORDEN
0.0978786 min-1
0.99971
Ln(Po/Pr)= Kt
K=
r 1=
793K
Po= 7.33
TIEMPO
(min)
(kN/m2)
Ln (Po/Pr)
Pt
Prd=Pt-Po
Pr=Po-Prd
0
2.34
4.97
6.27
Pr=2Po-Pt
7.33
4.99
2.36
1.06
0
2
6
10
(kN/m )
7.33
9.67
12.3
13.6
0.0000
0.3845
1.1333
1.9337
PRIMER ORDEN
0.1927798 min-1
0.99989
Ln(Po/Pr)= Kt
K=
r 1=
813K
Po= 7.33
TIEMPO
(min)
Pt
0
2
6
(kN/m2)
7.33
11.2
13.9
PRIMER ORDEN
(kN/m2)
Ln (Po/Pr)
Prd=Pt-Po
Pr=Po-Prd
0
3.87
6.57
Pr=2Po-Pt
7.33
3.46
0.76
0.0000
0.7507
2.2664
Ln(Po/Pr)= Kt
K=
r 1=
0.3779055 min-1
1.00000
k=Ae-E*/RT
ln k = ln A + (-E*/R) (1/T)
k
ln k
0.0979
0.1928
0.3779
-2.3240
-1.6462
-0.9731
T
(K)
773
793
813
1/T
0.001294
0.001261
0.001230
-42038.2 CAL/MOL
-176429 J/MOL
SOLUCION preg.8
TIEMPO
(seg)
0
25
50
75
100
150
200
250
INF.
Vt
Vo=0
a=Vinf -Vo
x=Vt - Vo
a-x=Vinf Vt
41.5000
35.2000
29.9000
25.2000
21.3000
15.4000
11.1000
8.0000
(cm3)
0
6.3
11.6
16.3
20.2
26.1
30.4
33.5
41.5
1/(a-x)
Ln(a-x)
0.0240964
0.0284091
0.0334448
0.0396825
0.0469484
0.0649351
0.0900901
0.1250000
3.7257
3.5610
3.3979
3.2268
3.0587
2.7344
2.4069
2.0794
PRIMER ORDEN
Ln (a-x) = Ln a + (-k)*t
-k1=
Ln a=
r 1=
-0.0065886 k1=
3.7238968
-0.99998
a=
0.006588554 seg-1
41.42550511
SEGUNDO ORDEN
1/(a-x)= 1/a +k*t
k2=
0.0003925
a=
67.22061949
1/a=
r 2=
0.0148764
0.97625
K=
0.000392465
Vt
Vo=16.45
(cm3)
16.45
13.8
12.25
11.25
10.55
8.6
(seg)
0
250
500
750
1000
INF.
PRIMER ORDEN
Ln (a-x) = Ln a + (-k)*t
-k1=
Ln a=
r 1=
a=Vo-Vinf
x=Vo-Vt
a-x=Vt-Vinf
7.8500
5.2000
3.6500
2.6500
1.9500
1/(a-x)
Ln(a-x)
0.1273885
0.1923077
0.2739726
0.3773585
0.5128205
2.0605
1.6487
1.2947
0.9746
0.6678
-0.0013838 k1=
2.0211511
-0.99815
a=
0.001383787 seg-1
7.547007509
SEGUNDO ORDEN
1/(a-x)= 1/a +k*t
k2=
1/a=
r 2=
0.0003824
0.1055866
0.98967
a=
K=
ln k
0.1130
0.1450
0.1900
0.2500
0.3250
-2.1804
-1.9310
-1.6607
-1.3863
-1.1239
T
(K)
643
648
653
658
663
1/T
0.001555
0.001543
0.001531
0.001520
0.001508
9.470897341
0.000382366
0.4100
0.5250
-0.8916
-0.6444
668
673
0.001497
0.001486
-44240.2 CAL/MOL
-185671 J/MOL