REVlSlON DATE 30/11/2010

SAFETY DATA SHEET

Hydrosure 0-3670R
1 lDENTlFlCATlON OF THE SUBSTANCE/PREPARATlON AND OF THE COMPANY/UNDERTAKlNG
PRODUCT NO. O3670R
APPLlCATlON HYDROTEST CHEMlCAL
Champion Arabia, Co. Ltd. SUPPLlER
P.O.Box 3254
Al-Khobar 31952
Saudi Arabia
0096638122100
0096638122040
2 HAZARDS lDENTlFlCATlON
Causes burns. Contact with acids liberates toxic gas.
CLASSlFlCATlON (1999/45) C;R34. R31.
3 COMPOSlTlON/lNFORMATlON ON lNGREDlENTS
EC No. Name Classification (67/548/EEC) CAS-No. Content %
270-325-2 Quaternary ammonium chloride Xn;R22. C;R34. N;R50. 68424-85-1 10-30%
233-469-7 AMMONlUM BlSULPHlTE Xi;R36/37/38. R31. 10192-30-0 10-30%
252-104-2 DlPROPYLENE GLYCOL MONOMETHYL ETHER
(DPM)
- 34590-94-8 1-10%
203-473-3 ETHANEDlOL Xn;R22 107-21-1 < 1%
The Full Text for all R-Phrases is Displayed in Section 16
4 FlRST-AlD MEASURES
lNHALATlON
Move the exposed person to fresh air at once. lf respiratory problems, artificial respiration/oxygen. Get medical attention.
lNGESTlON
NEVER MAKE AN UNCONSClOUS PERSON VOMlT OR DRlNK FLUlDS! lmmediately rinse mouth and drink plenty of water (200-300
ml). DO NOT induce vomiting. Get medical attention immediately. lf vomiting occurs, keep head low so that stomach content doesn't get
into the lungs. Generates toxic gas in contact with acid.
SKlN CONTACT
Rinse the skin immediately with lots of water. Continue to rinse for at least 15 minutes. Remove contaminated clothes and rinse skin
thoroughly with water. Get medical attention immediately. Chemical burns must be treated by a physician.
EYE CONTACT
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. To hospital or
eye specialist.
5 FlRE-FlGHTlNG MEASURES
EXTlNGUlSHlNG MEDlA
Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.
SPEClAL FlRE FlGHTlNG PROCEDURES
Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out.
Avoid breathing fire vapours. Keep run-off water out of sewers and water sources. Dike for water control.
UNUSUAL FlRE & EXPLOSlON HAZARDS
May develop highly toxic or corrosive fumes if heated.
SPEClFlC HAZARDS
Fire or high temperatures create: Oxides of: Carbon. Nitrogen. Sulphur.
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REVlSlON DATE 30/11/2010
Hydrosure 0-3670R
PROTECTlVE MEASURES lN FlRE
Wear full protective clothing. Use air-supplied respirator during fire fighting.
6 ACClDENTAL RELEASE MEASURES
PERSONAL PRECAUTlONS
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes.
ENVlRONMENTAL PRECAUTlONS
Do not discharge into drains, water courses or onto the ground.
SPlLL CLEAN UP METHODS
Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers.
Flush area with plenty of water. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must
be properly labelled with correct contents and hazard symbol.
7 HANDLlNG AND STORAGE
USAGE PRECAUTlONS
Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above
accepted level. Observe good chemical hygiene practices. Keep away from heat, sparks and open flame. Eye wash facilities and
emergency shower must be available when handling this product.
STORAGE PRECAUTlONS
Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Acids. Alkalis. Oxidising material.
8 EXPOSURE CONTROLS/PERSONAL PROTECTlON
STD STEL - 15 Min TWA - 8 Hrs
Name
Notes
AMMONlUM BlSULPHlTE
50 ppm 308 mg/m3 WEL DlPROPYLENE GLYCOL MONOMETHYL ETHER
(DPM)
Sk
10 mg/m3 WEL 104 mg/m3 ETHANEDlOL Sk
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.
PROTECTlVE EQUlPMENT
PROCESS CONDlTlONS
Provide eyewash, quick drench.
ENGlNEERlNG MEASURES
Provide adequate general and local exhaust ventilation.
RESPlRATORY EQUlPMENT
ln case of inadequate ventilation use suitable respirator.
HAND PROTECTlON
Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves
supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent
change is advisable.
EYE PROTECTlON
Use approved safety goggles or face shield.
OTHER PROTECTlON
Wear appropriate clothing to prevent any possibility of skin contact.
HYGlENE MEASURES
DO NOT SMOKE lN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if
skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
9 PHYSlCAL AND CHEMlCAL PROPERTlES
APPEARANCE Liquid
COLOUR Light (or pale) Coloured
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REVlSlON DATE 30/11/2010
Hydrosure 0-3670R
ODOUR Pungent Sulphur.
SOLUBlLlTY Miscible with water
RELATlVE DENSlTY 1.045 - 1.075 @ 20 c
pH-VALUE, CONC. SOLUTlON 4.0-6.0
REFRACTlVE lNDEX 39-41
10 STABlLlTY AND REACTlVlTY
STABlLlTY
Stable under normal temperature conditions.
CONDlTlONS TO AVOlD
Avoid heat, flames and other sources of ignition.
HAZARDOUS POLYMERlSATlON
Will not polymerise.
MATERlALS TO AVOlD
Strong acids. Strong oxidising substances.
HAZARDOUS DECOMPOSlTlON PRODUCTS
Oxides of: Carbon. Nitrogen. Sulphur.
11 TOXlCOLOGlCAL lNFORMATlON
lNHALATlON
Gas or vapour may irritate respiratory system.
lNGESTlON
Causes burns. May cause chemical burns in mouth and throat. Generates toxic gas in contact with acid.
SKlN CONTACT
Causes burns.
EYE CONTACT
Causes burns. Risk of serious damage to eyes.
12 ECOLOGlCAL lNFORMATlON
ECOTOXlClTY
The product contains a substance which is very toxic to aquatic organisms.
MOBlLlTY
The product is soluble in water.
BlOACCUMULATlON
No data available on bioaccumulation.
13 DlSPOSAL CONSlDERATlONS
GENERAL lNFORMATlON
Empty containers should be taken for local recycling, recovery or waste disposal
DlSPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
WASTE CLASS
For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer
has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.
14 TRANSPORT lNFORMATlON
PROPER SHlPPlNG NAME CORROSlVE LlQUlD, AClDlC, ORGANlC, n.o.s. (contains quaternary ammonium chloride)
3265 UN NO. ROAD
8 ADR CLASS NO.
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REVlSlON DATE 30/11/2010
Hydrosure 0-3670R
Class 8: Corrosive substances. ADR CLASS
lll ADR PACK GROUP
80 Corrosive or slightly
corrosive substance.
HAZARD NO. (ADR)
80 HAZARD No. (ADR)
2X HAZCHEM CODE
3265 UN NO. SEA
8 lMDG CLASS
lll lMDG PACK GR.
F-A S-B EMS
3265 UN NO. AlR
8 lCAO CLASS
lll AlR PACK GR.
15 REGULATORY lNFORMATlON
LABELLlNG
Corrosive
CONTAlNS Quaternary ammonium chloride
RlSK PHRASES
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.
S26 ln case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 ln case of accident or if you feel unwell, seek medical advice immediately
(show label where possible).
S60 This material and its container must be disposed of as hazardous waste.
UK REGULATORY REFERENCES
Approved Supply List.
STATUTORY lNSTRUMENTS
The Chemicals (Hazard lnformation and Packaging for Supply) Regulations 2009 (S.l 2009 No. 716).
APPROVED CODE OF PRACTlCE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
GUlDANCE NOTES
Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply.
16 OTHER lNFORMATlON
REVlSlON COMMENTS
NOTE: Lines within the margin indicate significant changes from the previous revision.
lSSUED BY
GC
REVlSlON DATE 30/11/2010
REV. NO./REPL. SDS
GENERATED
4
RlSK PHRASES lN FULL
Causes burns. R34
Contact with acids liberates toxic gas. R31
Harmful if swallowed. R22
lrritating to eyes, respiratory system and skin. R36/37/38
Very toxic to aquatic organisms. R50
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REVlSlON DATE 30/11/2010
Hydrosure 0-3670R
DlSCLAlMER
The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process unless specified in the text.
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