Journal of the Taiwan Institute of Chemical Engineers 40 (2009) 105109

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Journal of the Taiwan Institute of Chemical Engineers

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Short communication

An empirical equation for temperature and pressure dependence of liquid heat

capacity
Jovan D. Jovanovic a, Andjela B. Knezevic-Stevanovic b, Dusan K. Grozdanic a,*
a
b

Chemical Engineering Department, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia
Ministry of Environment, Environmental Protection Division, 2080-A Labieux Road, Nanaimo BC V9T 6J9, Canada

A R T I C L E I N F O

A B S T R A C T

Article history:
Received 13 May 2008
Received in revised form 4 July 2008
Accepted 7 July 2008

A new empirical equation for liquid heat capacity calculation, as a function of temperature and pressure is
recommended. This four-parameter equation was tested and compared to the four-parameter equation
developed by Guseinov et al. (1988), ve-parameter equation developed by Garg et al. (1993) and nineparameter equation developed by Nakagawa et al. (1993), using 73 sets with 4395 literature
experimental heat capacity data for 46 chemical compounds. The obtained results indicate that the
proposed four-parameter equation gives in many cases better results than the tested four- and veparameter equations and in few cases even better than the nine-parameter equation.
2008 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.

Keywords:
Heat capacity
Correlation
Liquid
Model
High pressure

1. Introduction

model that includes pressure dependency. Remaining published

liquid heat capacity data cover mostly lower pressure regions (up
to 10 MPa) with insignicant pressure inuence (lower than
experimental error) and only limited number of data sets with
wide ranges of temperatures and pressures. At lower or constant
pressures, liquid heat capacity can be approximated with
saturated liquid heat capacity equations (Jovanovic and Grozdanic, 2004; Poling et al., 2001). As a result, experimental data sets
and correlation models coverinig wide ranges of pressure are very
rare. One of the models is a four-parameter equation developed by
Guseinov et al. (1988):

Calculation of liquid heat capacities of chemical compounds is

an important step in design of many unit operations. For heating
or cooling liquids, energy requirements are proportional to the
heat capacities. Values of this property are therefore necessary for
equipment design, calculation of energy requirements, equilibrium yields and separation ratios. Heat capacities of mixtures
may be determined from the heat capacities of the individual
components. Experimental liquid heat capacity data are available
for many substances (Palczewska-Tulinska, 1997; Zabransky
et al., 1996, 2002), but mostly at the saturation line or at low
pressures.

c p A BT C p DT p

2. Liquid heat capacity correlation equations

There is also a ve-parameter model developed by Garg et al.

(1993):

As a result of slight compressibility of liquids, majority of the

literature experimental data sets contain only temperature
dependency. Most of the data are measured at the saturation
line (only temperature dependent), or at the atmospheric or
constant pressure, and as such are not useful in development of a

* Corresponding author. Tel.: +381 11 3370 499; fax: +381 11 3370 387.
E-mail address: dule@tmf.bg.ac.yu (D.K. Grozdanic).

(1)

c p A BT CT 2 DT 3 ET p

(2)

and a nine-parameter model developed by Nakagawa et al.

(1993):
c pl
B
C
D
A

E p0;5
r
R
1  T r 0;5 1  T r 1  T r 3

F p0;5
r
0;5

1  T r

G p0;5
r
1  T r 1;5

H pr

1876-1070/$ see front matter 2008 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
doi:10.1016/j.jtice.2008.07.001

I pr
1  T r 1;5

(3)

J.D. Jovanovic et al. / Journal of the Taiwan Institute of Chemical Engineers 40 (2009) 105109

106

temperatures and pressures. The new model should provide a good

correlation from atmospheric to high pressures, does not include
dependency on critical parameters, is simple, with a limited
number of parameters and does not result in numerical problems.
On the basis of our preliminarlly study that covers a large number
of organic compounds, with the data sets presented in Table 1, the
following equation is recommended:

Nomenclature
A, B, C, D, E, F, G, H, I adjustable equation parameters
AAPE
average absolute percent error (%)
liquid heat capacity (J/mol K)
cp
calculated liquid heat capacity (J/mol K)
cp,cal
cp,exp
experimental liquid heat capacity (J/mol K)
n
number of experimental data points
N
number of data sets
p
pressure (MPa)
critical pressure (MPa)
pc
pmax
maximum pressure value per set (MPa)
minimum pressure value per set (MPa)
pmin
pr
reduced pressure p/pc
Pav
overall percent error (%)
R
universal gas constant (J/mol K)
T
temperature (K)
critical temperature (K)
Tc
maximum temperature value per set (K)
Tmax
Tmin
minimum temperature value per set (K)
reduced temperature T/Tc
Tr

1
B
C
A 2 DT p
c pl
T T

(4)

3. Results and discussion

Accuracy of the presented equations was tested on 73 sets of
literature experimental data, with 4395 experimental points for 46
compounds. Selected data sets with pressures above 10 MPa are
presented in Table 1. A comparison of the Eqs. (1)(4) is included in
Table 1, with the number of experimental points per set, critical
temperature and pressure, temperature and pressure range, and an
average absolute percent error for tested equations.
Overall percent errors are calculated as follows:
PN
P av

The objective of this study was to continue our previous

investigation on saturated liquid heat capacity (Jovanovic and
Grozdanic, 2003, 2004, 2005) and develop a new empirical
equation, applicable to the wide range of experimental values of

ni AAPEi
PN
i1 ni

i1

(5)

n
X
jc p;exp;i  c p;cal;i j
AAPE 100
c p;exp;i
i1

(6)

The obtained results, shown (with the overall percent error

1.62%) in Table 1 indicate that the accuracy of the new
recommended equation is better then the Guseinov, Mirzaliev

Table 1
The literature data and results of correlation
No.

Compound

Authors

Tc
(K)

1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.

1,1,1,2,3,3,3-Heptauoropropane
1,1,1,2,3,3,3-Heptauoropropane
1,1,1,2-Tetrauoroethane
1,1,2-Trichlorotriuoroethane
1,2-Dimethylbenzene
1,3-Dimethylbenzene
1,4-Dimethylbenzene
1-Bromobutane
1-Bromoheptane
1-Bromohexane
1-Butanol
1-Decanol
1-Decanol
1-Heptanol
1-Heptanol
1-Hexanol
1-Hexanol
1-Nonanol
1-Octanol
1-Octanol
2,2,4-Trimethylpentane
2-Butoxyethanol
2-Methyl-1-propanol
2-Methylaniline
2-Methylbutane
2-Methylpentane
2-Propanol
3-Methyl-1-butanol
3-Methylaniline
3-Methylpentane

62
46
52
77
36
36
36
21
21
21
58
94
79
94
77
110
97
78
92
77
18
54
65
57
35
20
27
64
57
8

Hykrda et al. (2004)

Wirbser et al. (1992a)
Hykrda et al. (2004)
Wirbser et al. (1992b)
Garg et al. (1993)
Garg et al. (1993)
Garg et al. (1993)
Zaripov et al. (2004)
Zaripov et al. (2004)
Zaripov et al. (2004)
Naziev et al. (1986a)
Fulem et al. (2002)
Naziev and Bashirov (1988)
Fulem et al. (2002)
Naziev and Bashirov (1988)
Fulem et al. (2002)
Arutyunyan (1981)
Naziev et al. (1986b)
Fulem et al. (2002)
Naziev et al. (1986b)
Johnson et al. (1990)
Malhotra and Woolf (1993)
Naziev et al. (1992)
Guseinov et al. (1988)
Czarnota (1988)
Czarnota (1998)
Drehner (1979)
Naziev et al. (1992)
Guseinov et al. (1988)
Czarnota (1980)

375.9
375.9
374.1
487.3
630.3
617.0
616.2
569.4

562.0
687.3
687.3
632.6
632.6
610.3
610.3
670.7
652.5
652.5
543.8
643.0
547.7
717.0
460.4
497.7
508.3
577.2
709.1
504.6

pc
(MPa)
2.91
2.91
4.06
3.38
3.73
3.54
3.51
4.26

4.50
2.31
2.31
3.06
3.06
3.42
3.42
2.53
2.78
2.78
2.57
3.34
4.30
4.70
3.38
3.04
4.90
3.93
4.15
3.12

Tmin
(K)

Tmax
(K)

pmin
(MPa)

223.2
273.2
223.2
288.2
318.1
318.1
318.1
298.0
298.0
298.0
321.1
325.7
304.1
325.7
303.4
325.7
293.2
303.1
325.7
303.2
360.0
288.1
300.7
303.2
288.7
298.3
323.2
302.1
303.2
298.9

283.2
374.2
283.2
487.2
373.1
373.1
373.1
348.0
348.0
348.0
522.1
570.7
523.0
570.7
522.1
570.7
533.2
522.5
570.7
523.2
550.0
348.1
519.3
523.2
299.3
299.5
498.2
521.1
523.2
299.4

1.10
.60
.75
.60
.10
.10
.10
.10
.10
.10
.10
2.00
.10
2.00
.10
2.00
.10
.10
2.00
.10
2.00
.10
.10
.10
.10
.10
4.76
.10
.10
.10

pmax
(MPa)

Eq. (1)
(%)

Eq. (2)
(%)

Eq. (3)
(%)

Eq. (4)
(%)

20.00
15.00
18.20
30.00
10.00
10.00
10.00
147.00
147.00
147.00
50.00
30.00
50.00
30.00
50.00
30.00
60.00
50.00
30.00
50.00
10.00
350.00
50.00
25.00
820.40
756.20
30.00
50.00
25.00
1014.67

0.29
12.91
0.73
4.23
0.04
0.06
0.06
1.00
0.47
0.54
0.94
1.28
0.48
1.58
0.62
1.63
4.35
0.53
1.28
0.61
1.48
0.92
0.76
0.13
6.28
3.78
4.80
1.12
0.08
1.85

0.28
12.77
0.75
4.17
0.04
0.06
0.06

0.94
0.25
0.48
0.62
0.58
0.78
4.29
0.53
0.47
0.61
1.48
0.92
0.66
0.13
6.19

4.45
0.95
0.08

0.22
5.54
0.39
1.91
0.03
0.06
0.05

0.49
1.35
0.13
2.12
0.36
2.68
0.94
0.16
1.68
0.15

0.29
1.66
0.05
1.91
3.80
1.87
1.47
0.04

0.27
6.50
0.66
3.20
0.04
0.06
0.06
0.88
0.88
0.38
0.60
0.77
0.33
1.04
0.48
1.07
2.85
0.38
0.79
0.40
1.08
0.84
0.39
0.07
6.10
3.73
3.42
0.81
0.14
1.77

J.D. Jovanovic et al. / Journal of the Taiwan Institute of Chemical Engineers 40 (2009) 105109

107

Table 1 (Continued )
Tmin
(K)

Tmax
(K)

pmin
(MPa)

Eq. (1)
(%)

Eq. (2)
(%)

Eq. (3)
(%)

Eq. (4)
(%)

3.12
4.89
4.89
4.89

110.3
298.3
322.1
302.6

291.1
298.6
498.4
561.8

.10
.10
.10
5.00

108.00
68.10
50.00
25.00

0.44
6.55
1.07
10.83

0.42

1.03
9.34

0.21
5.89

0.74
1.41
0.84
7.16

632.3
553.8
617.6
617.6
617.6
305.3
617.2
617.2
617.2
564.4

4.52
4.08
2.11
2.11
2.11
4.87
3.61
3.61
3.61
4.18

301.3
295.4
298.8
318.1
292.7
150.0
318.1
350.0
301.6
303.2

630.8
548.0
299.2
373.1
593.4
250.0
373.1
550.0
607.8
523.2

8.00
.50
.10
.10
.10
32.00
.10
2.00
8.00
.10

25.00
50.00
254.50
10.00
60.00
50.70
10.00
20.00
25.00
25.00

5.74
2.03
2.33
0.06
0.62
0.38
0.07
0.34
0.72
1.08

4.18
2.05

0.06
0.62
0.31
0.05
0.34
0.72
1.07

3.30
2.97

0.06
1.02

0.04
0.17
2.14
0.12

3.87
1.48
2.34
0.06
0.46
0.53
0.06
0.28
0.52
0.65

609.1
560.1
471.2
540.1

3.04
4.55
4.41
2.74

380.0
301.8
288.2
303.2

580.0
559.3
453.2
523.2

2.00
.50
.60
.10

10.00
15.00
30.00
25.00

0.32
9.56
3.20
1.00

0.30
8.09
3.22
1.02

4.33
1.50
0.62

0.33
6.65
2.37
0.80

540.1
720.6
507.9
507.9
507.9

2.74
1.40
3.02
3.02
3.02

292.5
318.1
298.1
313.1
303.2

534.8
373.1
348.2
373.1
503.2

5.00
.10
.10
.10
5.00

60.00
10.00
147.00
100.00
25.00

1.46
0.05
1.16
0.38
1.14

1.47
0.04

0.38
1.14

2.06
0.03

0.11
0.98

1.08
0.05
0.93
0.37
0.86

507.9

3.02

293.4

505.3

.50

60.00

0.95

0.95

1.44

0.85

507.9
507.9

3.02
3.02

308.4
313.2

496.7
503.2

.10
5.00

50.00
25.00

0.87
1.13

1.15
1.40

0.90
0.92

0.81
1.06

512.5
512.5
548.0

8.08
8.08
4.83

248.2
280.0
303.2

473.2
360.0
523.2

.50
.10
.10

12.50
15.00
25.00

1.08
1.46
1.73

0.92

1.61

0.41

0.46

0.60
1.46
1.00

594.6
594.6
568.8
568.8
568.8
582.3

2.29
2.29
2.49
2.49
2.49
3.79

318.1
323.8
298.1
318.1
329.1
303.2

373.1
589.6
299.1
373.1
543.8
523.2

.10
5.00
.10
.10
5.00
.10

10.00
60.00
473.60
10.00
60.00
25.00

0.07
1.05
3.06
0.05
0.69
0.72

0.07
1.05

0.05
0.85
0.72

0.06
1.41

0.05
0.46
0.15

0.07
0.73
2.91
0.05
0.66
0.47

591.7
591.7
591.7
591.7

4.11
4.11
4.11
4.11

297.5
255.5
300.0
302.9

423.9
401.5
580.0
582.0

3.36
3.50
5.00
.50

34.41
993.50
30.00
25.00

0.58
0.74
2.28
3.73

0.59
0.73
2.24
3.29

0.38
0.49
1.69
2.26

0.61
1.74
1.36
3.04

676.2
647.3
647.3
647.3

1.68
22.12
22.12
22.12

313.2
318.7
298.2
298.0

373.2
494.2
643.2
348.0

.10
.10
20.00
.10

10.00
50.00
50.00
98.00

0.12
0.40
10.75
0.35

1.11
0.39
9.42

0.05
0.16
1.79

0.12
0.40
7.36
0.36

2.26

1.99

1.42

1.62

No.

Compound

Authors

Tc
(K)

31.
32.
33.
34.

3-Methylpentane
Benzene
Benzene
Benzene

137
8
50
86

504.6
562.1
562.1
562.1

35.
36.
37.
38.
39.
40.
41.
42.
43.
44.

Chlorobenzene
Cyclohexane
Decane
Decane
Decane
Ethane
Ethylbenzene
Ethylbenzene
Ethylbenzene
Ethylcyanide

240
128
12
72
69
21
36
33
72
64

45.
46.
47
48.

Ethylcyclohexane
Fluorobenzene
Fluorotrichloromethane
Heptane

21
146
52
52

49.
50.
51.
52.
53.

Heptane
Hexadecane
Hexane
Hexane
Hexane

47
60
18
73
42

54.

Hexane

65

55.
56.

Hexane
Hexane

57
44

57.
58.
59.

Methanol
Methanol
Methylcyanide

57
10
63

60.
61.
62.
63.
64.
65.

Nonane
Nonane
Octane
Octane
Octane
Propylcyanide

72
41
18
60
34
65

66.
67.
68.
69.

Toluene
Toluene
Toluene
Toluene

70.
71.
72.
73.

Tridecane
Water
Water
Water

Oguni et al. (1982)

Czarnota (1991)
Naziev et al. (1986a)
Akhundov and Sultanov
(1974)
Akhundov et al. (1986a)
Sar et al. (1975)
Czarnota (1993b)
Banipal et al. (1991)
Kuznecov et al. (1988)
Grini et al. (1996)
Garg et al. (1993)
Johnson et al. (1990)
Akhundov et al. (1975)
Guseinov and Mirzaliev
(1985)
Johnson et al. (1990)
Akhundov et al. (1986b)
Wirbser et al. (1992b)
Guseinov and Mirzaliev
(1984)
Kuznecov et al. (1988)
Banipal et al. (1991)
Zaripov et al. (2002)
Bessieres et al. (2000a)
Guseinov and Mirzaliev
(1984)
Gerasimov and Grigorev
(1978)
Naziev et al. (1986b)
Guseinov and Mirzaliev
(1985)
Dettmann et al. (2006)
Tanaka et al. (2007)
Guseinov and Mirzaliev
(1984)
Banipal et al. (1991)
Kuznecov et al. (1988)
Czarnota (1993a)
Banipal et al. (1991)
Kuznecov et al. (1988)
Guseinov and Mirzaliev
(1985)
Sun et al. (2002)
Shulga et al. (1986)
Nefedov and Filippov (1980)
Akhundov and Eksaev
(1973)
Bessieres et al. (2000b)
Naziev et al. (1986a)
Ernst and Philippi (1990)
Zaripov et al. (2004)

24
80
60
193
77
52
69
10

Overall percent
error, Pav

and Shakhmuradov and GargBanipalAhluwalia equations and

slightly worse then NakagawaHoriSatoWatanabe equation,
despite the lower number of parameters. Furthermore, some
difculties in evaluation of inverse coefcient matrix of normal
equations, during testing of GargBanipalAhluwalia and
NakagawaHoriSatoWatanabe equations, were encountered
models are inapplicable to certain experimental data sets.
Obtained results with error above 20% were not considered
useable, and as such are not included in Table 1. Usability of
NakagawaHoriSatoWatanabe correlation model is furthemore

pc
(MPa)

pmax
(MPa)

limited to data sets with at least eleven data points and known
values for critical temperature Tc and pressure pc. Unlike the other
models, the new model is useful even for correlation at xed
presures. At xed pressure, some terms in Eqs. (1)(3) are the same
and that is believed to be a cause of numerical problems. As it can
be seen from Table 1, new recommended model is accurate and
applicable to lower and higher pressures, except near the critical
temperature where the NakagawaHoriSatoWatanabe model
is recommended. Parameter values in Eq. (4) are presented in
Table 2.

J.D. Jovanovic et al. / Journal of the Taiwan Institute of Chemical Engineers 40 (2009) 105109

108
Table 2
Values of parameters in Eq. (4)
No.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
71.
72.
73.

Compound
1,1,1,2,3,3,3-Heptauoropropane
1,1,1,2,3,3,3-Heptauoropropane
1,1,1,2-Tetrauoroethane
1,1,2-Trichlorotriuoroethane
1,2-Dimethylbenzene
1,3-Dimethylbenzene
1,4-Dimethylbenzene
1-Bromobutane
1-Bromoheptane
1-Bromohexane
1-Butanol
1-Decanol
1-Decanol
1-Heptanol
1-Heptanol
1-Hexanol
1-Hexanol
1-Nonanol
1-Octanol
1-Octanol
2,2,4-Trimethylpentane
2-Butoxyethanol
2-Methyl-1-propanol
2-Methylaniline
2-Methylbutane
2-Methylpentane
2-Propanol
3-Methyl-1-butanol
3-Methylaniline
3-Methylpentane
3-Methylpentane
Benzene
Benzene
Benzene
Chlorobenzene
Cyclohexane
Decane
Decane
Decane
Ethane
Ethylbenzene
Ethylbenzene
Ethylbenzene
Ethylcyanide
Ethylcyclohexane
Fluorobenzene
Fluorotrichloromethane
Heptane
Heptane
Hexadecane
Hexane
Hexane
Hexane
Hexane
Hexane
Hexane
Methanol
Methanol
Methylcyanide
Nonane
Nonane
Octane
Octane
Octane
Propylcyanide
Toluene
Toluene
Toluene
Toluene
Tridecane
Water
Water
Water

B
4

9.54190  10
2.15776  102
1.13484  103
2.82977  103
7.21345  104
1.29594  103
2.44676  103
1.69931  102
7.60578  103
7.92513  103
7.60306  104
3.60921  103
2.28772  104
4.66609  103
2.94171  104
5.40113  103
3.59687  103
2.02861  104
4.33262  103
1.09651  104
3.54377  103
4.46313  103
3.88920  103
3.07407  104
3.16445  101
4.23623  101
6.32866  103
3.74971  103
3.17055  104
1.28947  103
2.77503  103
1.27784  102
1.69641  103
1.01631  102
4.59917  103
1.17836  103
1.25886  102
1.14589  103
3.01236  104
4.56179  103
7.48653  104
1.25063  105
8.41236  105
4.95362  103
1.05969  103
1.43987  102
2.46023  103
1.23610  103
4.62877  104
4.51408  104
1.95017  103
1.62087  103
2.03048  103
3.57039  104
1.20980  104
1.77665  103
1.42183  102
5.04351  107
1.01932  102
4.23478  103
1.35992  104
6.71674  101
1.53729  103
2.17712  104
2.53424  103
6.18488  105
5.96242  104
1.12358  103
5.38051  103
5.19242  104
2.41920  103
2.23608  102
1.16732  103

C
0

1.72780  10
1.45927  101
2.52547  100
4.87320  100
1.88541  100
1.46678  100
4.04775  100
1.34461  101
6.82886  100
7.11681  100
9.41577  101
1.58784  100
9.17780  101
2.16604  100
1.17915  100
2.63602  100
4.29753  100
1.03810  100
2.01110  100
1.21415  100
4.56754  100
1.22939  100
1.07625  100
2.86922  100
1.84871  102
2.53590  104
3.38924  100
1.43883  100
2.86635  100
7.71669  105
9.80343  101
7.62661  104
1.62396  100
1.06962  101
6.55675  100
3.08496  100
7.53133  104
2.21691  100
1.27003  100
5.80953  100
2.79335  100
2.32943  100
2.44538  100
7.67762  100
1.38332  100
1.40844  101
5.82673  100
2.87586  100
2.30948  100
1.30670  100
3.42604  100
3.47425  100
3.57759  100
1.99573  100
1.94962  100
3.33076  100
1.31040  101
3.67990  100
1.23489  101
4.39834  100
1.75933  100
4.01109  104
2.76746  100
1.63566  100
5.39044  100
3.04252  100
2.43212  100
3.47279  100
6.87094  100
8.77852  101
7.31050  100
2.50925  101
8.98355  100

D
2

1.46716  10
2.00082  103
2.28402  102
6.96109  102
1.47383  102
5.82277  101
5.02559  102
1.93596  103
9.85906  102
9.97240  102
1.56612  102
3.94315  102
6.23329  101
5.58774  102
7.62632  101
6.79321  102
6.06128  102
7.60159  101
5.07371  102
1.00186  102
7.22415  102
2.92294  102
4.69025  102
3.40201  102
2.76039  104
3.79459  106
1.00169  103
4.97034  102
3.48666  102
1.15449  108
6.02195  101
1.13790  107
4.24096  101
1.69652  103
9.93524  102
2.50691  102
1.12641  107
2.76906  102
1.23351  102
4.53114  102
2.83041  102
2.20235  102
2.52097  102
1.01745  103
1.17054  102
2.40646  103
7.98834  102
3.56999  102
2.52676  102
1.72578  102
3.87743  102
4.37501  102
4.43744  102
1.73002  102
1.44812  102
3.86565  102
1.54993  103
1.39245  101
1.64077  103
6.24177  102
2.03128  102
5.98872  106
3.38870  102
1.55080  102
7.26305  102
3.26635  102
2.13262  102
3.84017  102
1.04032  103
8.93392  101
1.23238  103
4.41440  103
1.39189  103

3.96857  108
2.09206  107
7.13385  108
6.53305  108
5.22623  109
6.66316  109
7.62192  109
1.42484  108
9.57057  109
1.11147  108
8.56591  109
3.04769  109
2.68463  109
7.34137  109
4.49391  109
9.68319  109
2.93109  108
2.95724  109
5.55320  109
3.92716  109
3.28378  108
1.75710  108
1.39273  108
1.14398  108
7.14365  1010
1.42235  109
5.06121  108
1.66921  108
1.26971  108
3.90047  109
3.63866  109
2.65612  108
1.54380  108
9.35451  108
7.92612  108
1.53304  108
3.12136  109
3.97509  109
3.48202  109
2.56609  108
6.84095  109
1.32618  108
1.50509  108
4.56861  108
1.75655  108
1.19459  107
8.05627  108
1.45871  108
1.01604  108
9.79770  1010
1.63574  108
5.30452  109
3.20838  108
1.11886  108
1.18366  108
3.26472  108
4.88051  108
3.95453  108
8.64977  108
4.37328  109
4.80689  109
3.90741  109
7.45005  109
5.68401  109
2.72408  108
6.50729  109
3.90260  109
3.86501  108
4.22872  108
4.48936  1010
2.85331  108
1.08367  107
2.04880  108

J.D. Jovanovic et al. / Journal of the Taiwan Institute of Chemical Engineers 40 (2009) 105109

4. Conclusions
According to this study, a new equation for accurate correlation
of liquid heat capacity over a wide temperature and pressure range
was recommended. New model is an accurate four-parameter
liquid heat capacity equation and this correlation ts available data
within experimental errors.
Acknowledgements
This work was supported by a grant from the Research Fund of
Serbia, Belgrade and the Faculty of Technology and Metallurgy,
University of Belgrade (project no. 142064).
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