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)a0+
-> (/ 1? mol
5
-2')l+
Diagram 2
a+ $ame one eample of strong asid and strong al1ali.
i+ 8trong acidKKKKKKKKKKKKKKKKKKKKKKKKKKKK
ii+ 8trong al1aliKKKKKKKKKKKKKKKKKKKKKKKKKKK..
G2 markH
(Knowledge)
b+ What is meant of heat of neutrali%ation?
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G5 markH
(Knowledge)
%7 An eperiment )eperiment **+ is carried out under the same condition2 that is (6
cm
"
of 5 mol dm
"
of ethanoic acid is mied with (6 cm
"
of 5 mol dm
"
strong
al1ali. !he temperature of the miture is increased by ,.(
6
C.
i+ Calculate the number of moles for strong al1ali used.
G5 markH
(Understanding)
ii+ Calculate the heat of neutrali%ation between ethanoic acid with strong al1ali.
Gspecific heat capacity of solution > &.2 ?g
5 6
C
5
<
density of solution > 5 g cm
"
H
G5 markH
(Understanding)
1,
d+ i+ Compare the heat of neutrali%ation for #periment * and #periment **
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.
G5 markH
(Analysis)
ii+ #plain your answer.
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G2 marksH
(Analysis)
e+ *f #periment ** is repeated by miing 566 cm
"
of 5 mol dm
"
ethanoic acid with 5
moldm
"
of strong al1ali with the same concentration2 the temperature increased is
still ,.(
6
C. #plain.
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G" marksH
(Synthesis)
&. 2( cm
"
of 6.( mol dm
"
barium chloride solution is measured by using a mesuring
cylinder and poured into a polystyrene cup. !he initial temperature is recorded. !hen2
2( cm
"
of 6.( mol dm
"
sodium sulphate solution is measured and the initial
temperature is recorded. 8odium sulphate solution is poured into barium chloride
solution. !he miture is stirred and the highest temperature is recorded.
!he following data is obtainedA
*nitial temperature of barium chloride solution > 2:.6
6
C
*nitial temperature of sodium sulphate solution > 2:.6
6
C
-ighest temperature of the miture > "5.6
6
C
G8pecific heat capacity > &.2 ?g
5 6
C
5
H
a+ What is the colour of barium sulphate precipitate?
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G5 marksH
(Knowledge)
b+ Calculate
i+ the number of moles of barium ion
18
ii+ the number of moles of sulphate ion
iii+ the heat released
G" marksH
(Aplication)
c+ Write an ionic e0uation for the formation of barium sulphate precipitate.
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G5 marksH
(Understanding)
d+ Calculate the heat of precipitation of barium sulphate
G2 marksH
(Aplication)
e+ Draw the energy level diagram for the reaction.
G2 marks
(Synthesis)
1'
Section B
G26 marksH
Answer any one question.
The time suggested to answer this section is 30 minutes.
5. Diagram " shows the energy level diagram for a reaction between nitrogen and oygen
gas.
#nergy
2$'2 )g+
=- > ;,, 1? mol
5
$2)g+ ; '2)g+
Diagram "
)a+ #plain how the energy changes during the brea1ing and formation of bond in the
reaction based on the value of = - itu.
G, marksH
Understanding
#periment Procedure
!emperature changes of
the miture
*
**
4iing 2(cm
"
of 5.6 moldm
"
sodium
hydroide solution with 2(cm
"
of 5.6
moldm
"
nitric acid in a plastic bea1er.
4iing 2(cm
"
of 5.6 moldm
"
sodium
hydroide solution with 2(cm
"
of 5.6
moldm
"
methanoic acid in a plastic
bea1er.
!emperature is increased
by ,./(
o
C
!emperature is increased
by ,."6
o
C
!able 5
2. )b+ i+ Based on the result of the eperiment shown in table 52 calculate the heat of
neutrali%ation for #periment * and #periment **.
G8pecific heat capacity of the solution > &.2 ? g
5o
C
5
H
G56 marksH
Aplication
ii+ Compare the values of the heat of neutrali%ation in b)i+. #plain.
26
G& marksH
Analysis
Section C
G26 marksH
Answer any one question.
The time suggested to answer this section is 30 minutes.
5. )a+ !he following e0uations represent neutrali%ation reactions.
.eaction * A
-Cl)a0+ ; $a'-)a0+ $aCl)a0+ ; -2')l+ = - > J 1? mol
5
.eaction ** A
C-"C''-)a0+ ; $a'-)a0+ C-"C''-$a)a0+ ;-2')l+ = - > C 1? mol
5
!he heat of neutrali%ation for both reactions are different. 8tate the differences and
eplain.
G& marksH
)b+ Diagram & shows the energy level diagram of a reaction.
#nergy
Ag
;
; Cl
- > negative
AgCl
Diagram &
i+ $ame the reactants involved.
G2 marksH
ii+ Write the chemical e0uation for the reaction.
G5 markH
iii+ What is the assumption made in calculating the heat of precipitation in this
eperiment.
G2 marksH
)c+ Describe an eperiment to determine the heat of neutrali%ation of sulphuric acid2
-28'& with pottassium hydroide solution2 D'-. Cour eplaination should include
chemical e0uation for the reaction2 calculations involved and precautions in getting
a more accurate results.
G56 marksH
21
Paper 3
Answer all question in this section
5. Diagram 5 shows the set up of the apparatus to determine the heat of displacement of
iron by magnesium metal.
Displacement of iron by magnesium occurs as shown in the e0uation below A
4g ; Ie8'& 4g8'& ; Ie
a+ i+ Based on the information in diagram 52 complete the table A
*nitial temperature of iron )**+ sulphate solution)
o
C+
-ighest temperature of iron )**+ sulphate
solution)
o
C+
iii+ 8tate the type of reaction that occurs?
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b+ 8tate one observation in the eperiment.
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22
Initi!3 te.#er!ture
Hig4est te.#er!ture
T4er.o.eter
8e!suring /ott3e
9:%ess .!gnesiu.
#ow$er
166%.
3
iron ;II7
su3#4!te
so3ution
stir
&i!gr!. 1
<in$ s4ie3$
T4er.o.eter
Co##er %!n
Tri#o$ st!n$
S#irit 3!.#
A3%o4o3
<oo$en /3o%1
c+ i+ Predict the change of temperature if the eperiment is repeated by using a bigger
base polystyrene cup.
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ii+ #plain.
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c+ Why is magnesium used in this eperiment is in powder form ?
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2. Diagram 2 shows the set up of the apparatus used to determine the heat of combustion
for different type of alcohol
water
Diagram 2
23
T4er.o.eter
=o3ystyrene %u#
Bigger /!se
stir
!able 2 shows the results obtained from the eperiment.
Alcohol
$umber of carbon atoms per
alcohol molecule
-eat of combustion of
alcohol )1? mol
L5
+
4ethanol2 C-"'- 5 L/5&
#thanol2 C2-('- 2 L5"(&
Propan@5@ol2 C"-/'- "
Butan@5@ol2 C&-&'- & L2(,&
a+ i+ Draw a graph of the heat of combustion of alcohol against the number of carbon
atoms per alcohol molecule.
iii+ Based on the graph2 determine the heat of combustion of propanol.
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b+ 8tate the variables for the eperiment.
i+ .esponding variable
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ii+ 4anipulated variable
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iii+ Constant variable
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c+ 8tate the hypothesis for the eperiment.
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d+ What is the relationship between the number of carbon atoms with the value of
the heat of combustion of alcohols
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24
".
!he following information shows the heat of combustion of two types of alcohols.
Plan an eperiment to compare the heat of combustion of the alcohols. Cour planning should
include the following aspects.
)a+ Problem statement
)b+ All the variables
)c+ statement of the hypothesis
)d+ 9ist of substances and apparatus
)d+ Procedure of the eperiment
)e+ !abulation of data.
G5/ markH
Heat of combustion of ethanol = - 1376 kJ mol
-1
Heat of combustion of propan- 1- ol = - 2016 kJ mol
-1
2(