Name __________________________________ Batch _______Date_________

Sub CHEMISTRY QUIZ: Thermodynamics- 2

Sin!e Correc" #ns$ers
01. First law of thermodynamics state that
a) Energy is conserved b) Internal Energy can be changed by either wor or heat c) !E
" # $ % d) &ll
0'. (ow m)ch wor is done when ' moles of an ideal gas is com*ressed reversibly from 'atm to +atm
at ',-.
a) '.,/0 b) '.,1atm c) 2'.,/0
d) 2'.,1atm
03. %or done by an ideal gas when it is e4*anded freely from 51 to 101 against constant e4ternal
*ress)re of 'atm and isothermally is6
a) 7ero b) 2101atm c) 21/0 d) $1/0
08. If 1 mole of .9' is e4*anded from '1 to 81 in reversible adiabatic *rocess then the final *ress)re of
the gas is _____ if the initial *ress)re is 8atm
a) 'atm b) 0.5atm c) 1.5:atm d) 0.+3atm
05. %hat is the difference between heat at constant vol)me and heat at constant *ress)re for the
following reaction6
.3(,9(;l) $ 9';g) .9';g) $ ('9;l)
a) 21.5<= b) $1.5<= c) 0 d) $'<=
Mu!"i%!e Correc" #ns$ers
0+. %hich of the following gra*h re*resents correctly for the below *rocess
P
V
a
b
Isothermal
a)
T
V
a
b
b)
P
T
b
a
c)
P
1/V
a
b
d)
P
T
0,. (eat is re>)ired to raise the tem*erat)re by 10-. of ,.?grams of li>)id ben@ene is 13+ 0o)les then
which of the following statement;s) is;are) correct6
a) Aolar heat ca*acity of li>)id ben@ene is 13+ 0/
21
mole
21
b) B*ecific heat ca*acity of li>)id ben@ene is 1.,8 0/
21
g
21
c) Aolar heat ca*acity of solid ben@ene is 13+ 0/
21
mole
21
d) B*ecific heat ca*acity of solid ben@ene is 1.,8 0/
21
g
21
0?. .orrect relation
a) .* C .v " n< b) .mD* C .mDv " < c) =E
F21
" constant d) G
12F
=
F
"
constant
0:. %hen tem*erat)re of ' mole of &rgon gas is changed from 300/ to 800/ in reversible adiabatic
*rocess then which of the of the following statement;s) is;are) incorrect
a) %or done wo)ld be same if the *rocess is irreversible
b) !(sys " 0 d)ring the *rocess
c) %or done " '00.v
d) %or done " 300<
10. Incorrect statement
a) 1i>)id having high heat ca*acity re>)ires more amo)nt of heat to raise the tem*erat)re
b) %or done in isobaric *rocess is same as in adiabatic *rocess
c) (eat ca*acity is e4tensive *ro*erty
d) Aolar enthal*y is intensive *ro*erty
Com%rehension
Read "he &o!!o$in %arara%h and ans$er "he 'ues"ions be!o$:
Enthal*y change of a reaction de*ends on tem*erat)re and the relation is given by /irchhoffHs
e>)ation
01. If enthal*y change at ',-. is $5000 then enthal*y change for the same reaction at +00/
is________if !r.* " 2'.50/
21
a) 2'500 b) $,500 c) $'500
d)2,500
0'. !r.* for the following reaction is6
'&;g) $ 3B;g) .;g) $ 8D;g)
If .* ;&) " 80/
21
I .* ;B) " '0/
21
I .* ;.) " ?0/
21
I .* ;D) " 50/
21
a) 180/
21
b) ?0/
21
c) 0/
21
d)
180/
21
03. For the above >)estion !r.v is e>)al to
a) !r.* b) !r.* $ '< c) !r.* 2'< d) !r.* $ <