Professional Documents
Culture Documents
the
temporary IUPAC name for
the transactinide
element with the atomic number 118 and temporary element symbol Uuo.
It is also known as eka-radon or element 118, and on the periodic table of
the elements it is a p-block element and the last one of the 7th period.
Ununoctium is currently the only synthetic member of group 18. It has the
highest atomic number and highest atomic mass of all the elements
discovered so far.
The radioactive ununoctium atom is very unstable, due to its high mass,
and since 2005, only three or possibly four atoms of the
isotope 294Uuo have been detected. While this allowed for very little
experimental characterization of its properties and possible compounds,
theoretical calculations have resulted in many predictions, including some
unexpected ones. For example, although ununoctium is a member of
Group 18, it may possibly not be a noble gas, unlike all the other Group 18
elements. It was formerly thought to be a gas but is now predicted to be
a solid under normal conditions due to relativistic effects.
Ununoctium
118Uuo
Rn
Uuo
(Usb)
ununseptium ununoctium ununennium
Ununoctium in the periodic table
Appearance
unknown
General properties
Name,symbol,number ununoctium, Uuo, 118
Pronunciation
Element category
Group, period,block
/un.unktim/
oon-oon-OK-tee-m
unknown
but probably a noble gas
18 (noble gases), 7, p
solid (predicted)
Critical point
Heat of fusion
(extrapolated) 23.5kJmol1
Heat of vaporization
Oxidation states
Ionization energies
(predicted) 157 pm
Miscellanea
Discovery
NA
halflife
DM
DE (MeV)
11.65 0.06
DP
290
Lv
SF
History
The discovery of the elements known to exist today is presented here in
chronological order. The elements are listed generally in the order in which
each was first defined as the pure element, as the exact date of discovery
of most elements cannot be accurately defined.
Given is each element's name, atomic number, year of first report, name of
the discoverer, and some notes related to the discovery.
Unrecorded discoveries
Oldes
t
Eleme
Z
Earliest
existi
nt
use
ng
Place
Discoverers
sampl
of
oldest
Notes
sample
Copper
9000 BC
Anatolia
Lead
7000 BC
Abydos,
smelting began at
Egypt
Oldes
t
Eleme
Z
Earliest
existi
nt
use
ng
Place
Discoverers
sampl
of
oldest
Notes
sample
e
statuette found at the
temple of Osiris on the
site of Abydos dated
circa 3800 BC.
Archaeologists
suggest that the first
use of gold began with
the first civilizations in
79
Gold
Before
6000 BC
Egypt
Estimated to have
47
Silver
Before
ca.
5000 BC
4000 BC
Asia Minor
been discovered
shortly after copper
and gold.
Iron
Before
5000 BC
4000 BC
Unknown; seeHistory
of ferrous metallurgy
Egypt
Oldes
t
Eleme
Z
Earliest
existi
nt
use
ng
Place
Discoverers
sampl
of
oldest
Notes
sample
e
beads of meteoric
iron, made in Egypt in
about 4000 BC. The
discovery of smelting
around 3000 BC led to
the start of the iron
age around 1200
BC and the prominent
use of iron for tools
and weapons.
Carbon
3750 BC
Egyptians and
Sumerians
Sumerians. Diamonds
were probably known
as early as
2500 BC. The first
true chemical
analyses were made
in the 18th
century, and in 1789
carbon was listed
by Antoine
Oldes
t
Eleme
Z
Earliest
existi
nt
use
ng
Place
Discoverers
sampl
of
oldest
Notes
sample
e
Lavoisier as an
element.
First smelted in
combination with
50
Tin
3500 BC
2000 BC
copper around
Unknown; seeTin#Hi
3500 BC to
story
Sulfur
Before
2000 BC
Recognized as an
element by Antoine
Lavoisier in 1777.
Known to ancient
Chinese and Indians
80
Mercury
Before
2000 BC
1500 BC Chinese/Indians
Egypt
30
Zinc
Before
1000 BC
Indian
subcontine
Extracted as a metal
since antiquity (before
1000 BC) by Indian
Oldes
t
Eleme
Z
Earliest
existi
nt
use
ng
Place
Discoverers
sampl
of
Notes
oldest
sample
e
nt
Arsenic
age
European to isolate
A. Magnus
the element in
1250. In 1649, Johann
Schrder published
two ways of preparing
elemental arsenic.
In widespread use in
51
Antimony 3000 BC
Oldes
t
Place
Eleme
Earliest
existi
nt
use
ng
Discoverers
sampl
of
oldest
Notes
sample
Chromiu
m
Before 1 AD
Before
1 AD
weapons in China
Terracotta Army
China
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
Phosphorus
1669
1669
H. Brand
H. Brand
element to be
chemically
discovered.
Cobalt
1732
G. Brandt
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
First description of a
metal found in South
American gold was in
1557 by Julius Caesar
Scaliger. Ulloa
published his findings
78
Platinum
1735
1735
A. de Ulloa
A. de Ulloa
Found by attempting
to extract copper from
28
Nickel
1751
1751
F. Cronstedt
Definitively identified
83
Bismuth
1753
C.F. Geoffroy
by Claude Franois
Geoffroy in 1753.
Black observed
12
Magnesium
1755
1808
J. Black
H. Davy
that magnesia
alba (MgO) was
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
not quicklime (CaO).
Davy isolated the
metal
electrochemically
from magnesia.
although Paracelsus
around 1500, Robert
1
Hydrogen
1766
1500
H. Cavendish
Paracelsus
Obtained it by
heating mercuric
oxide and nitrates in
1771, but did not
publish his findings
8
Oxygen
1771
1771
W. Scheele
W. Scheele
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
element; he named it
in 1777
He discovered
Nitrogen while he was
studying at
the University of
Edinburgh. He
showed that the air in
which animals had
breathed, even after
removal of the
7
Nitrogen
1772
1772
D. Rutherford
D.
exhaled carbon
Rutherford
dioxide, was no
longer able to burn a
candle. Carl Wilhelm
Scheele, Henry
Cavendish, and
Joseph Priestley also
studied the element at
about the same time,
and Lavoisier named
it in 1775-6.
Obtained it
from hydrochloric
17
Chlorine
1774
1774
W. Scheele
W. Scheele
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
an element.
Distinguished pyrolusi
te as the calx of a
new metal. Ignatius
Gottfred Kaim also
discovered the new
25
Manganese
1774
1774
W. Scheele
G. Gahn
Scheele distinguished
a new earth (BaO) in
56
Barium
1772
1808
W. Scheele
H. Davy
Scheele recognised
42
Molybdenum 1778
1781
W. Scheele
J. Hjelm
the metal as a
constituent
of molybdena.
52
Tellurium
1782
F.-J.M. von
Reichenstein
Muller observed it as
H. Klaproth
an impurity in gold
ores from
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
Transylvania.
Bergman obtained
from scheelite an
oxide of a new
74
Tungsten
1781
1783
T. Bergman
J. and F.
Elhuyar
element. The
Elhuyars
obtainedtungstic
acid from wolframite a
nd reduced it with
charcoal.
Strontium
1787
1808
W. Cruikshank
H. Davy
A. Lavoisier
elements
containing, among
others, 23 elements
of those known
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
then. He also
redefined the term
"element". Until
then, no metals
except mercury
were considered
elements.
Klaproth identified a
40
Zirconium
1789
1824
H. Klaproth
J. Berzelius
new element
in zirconia.
Mistakenly identified
a uranium
oxide obtained
92
Uranium
1789
1841
H. Klaproth
E.-M. Pligot
from pitchblende as
the element itself and
named it after the
recently discovered
planet Uranus.
Gregor found an
oxide of a new metal
in ilmenite; Martin
22
Titanium
1791
1825
W. Gregor
J. Berzelius
Heinrich Klaproth
independently
discovered the
element in rutile in
1795 and named it.
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
The pure metallic
form was only
obtained in 1910
by Matthew A. Hunter.
Discovered
in gadolinite, but
39
Yttrium
1794
1840
J. Gadolin
G. Mosander
Mosander showed
later that its ore, yttria,
contained more
elements.
Vauquelin discovered
F.
Beryllium
1798
1828
N. Vauquelin
Whler and
A. Bussy
Vanadium
1801
1830
M. del Ro
N.G.Sefstr
Collet-
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
first place.
Niobium
1801
1864
C. Hatchett
W.
Roseproved in 1844
Blomstrand
Ekeberg found
another element in
minerals similar to
73
Tantalum
1802
G. Ekeberg
columbite and in
1844, Heinrich Rose
proved that it was
distinct from niobium.
Wollaston discovered
it in samples of
46
Palladium
1803
1803
H. Wollaston
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
intended to name it
after the newly
discovered asteroid,
Ceres, but by the time
he published his
results in 1804,
cerium had taken that
name. Wollaston
named it after the
more recently
discovered
asteroid Pallas.
Berzelius and
Hisinger discovered
the element
in ceria and named it
after the newly
discovered asteroid
(then considered a
H. Klaproth, J.
58
Cerium
1803
1839
Berzelius, and W.
Hisinger
planet), Ceres.
G. Mosander Klaproth discovered it
simultaneously and
independently in
some tantalum
samples. Mosander
proved later that the
samples of all three
researchers had at
least another element
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
in them,lanthanum.
Osmium
1803
1803
S. Tennant
S. Tennant
Iridium
1803
1803
S. Tennant
S. Tennant
Wollaston discovered
45
Rhodium
1804
1804
H. Wollaston
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
America.
Davy discovered it by
19
Potassium
1807
1807
H. Davy
H. Davy
using electrolysis
on potash.
Davy discovered it a
few days after
11
Sodium
1807
1807
H. Davy
H. Davy
potassium, by using
electrolysis on sodium
hydroxide.
Calcium
1808
1808
H. Davy
H. Davy
metal by electrolysis
of quicklime.
Boron
1808
1808
Lussac andL.J.
element in sedative
H. Davy
Thnard
Fluorine
1810
1886
A.-M. Ampre
H. Moissan
Andr-Marie Ampre
predicted an element
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
analogous to chlorine
obtainable
fromhydrofluoric acid,
and between 1812
and 1886 many
researchers tried to
obtain this element. It
was eventually
isolated by Moissan.
Courtois discovered it
53
Iodine
1811
1811
B. Courtois
B. Courtois
in the ashes
of seaweed.
Lithium
1817
1821
A. Arfwedson
W. T. Brande
Arfwedson discovered
the alkali in petalite.
1817
1817
Stromeyer, and
Stromeyer,
J.C.H. Roloff
48
Hermann, F.
and J.C.H.
Roloff
unknown metal in a
sample of zinc
oxide from Silesia, but
the name that
Stromeyer gave
became the accepted
one.
34
Selenium
1817
1817
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
a substance that they
thought was tellurium,
but realized after
more investigation
that it is different.
Humphry Davy
thought in 1800
that silica was an
element, not a
compound, and in
1808 suggested the
present name. In
1811 Louis-Joseph
14
Silicon
1824
1824
J. Berzelius
J. Berzelius
Gay-Lussac and
Louis-Jacques
Thnard probably
prepared impure
silicon, but Berzelius
is credited with the
discovery for
obtaining the pure
element in 1824.
Antoine Lavoisier
predicted in 1787
13
Aluminium
1825
1825
H.C.rsted
H.C.rsted
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
Humphry Davy tried
to decompose it.
Although he failed, he
suggested the present
name. Hans Christian
rsted was the first to
isolate metallic
aluminium in 1825.
Bromine
1825
1825
J. Balard and L.
J. Balard and
Gmelin
L. Gmelin
Thorium
1829
J. Berzelius
Mosander found a
new element in
samples of ceria and
57
Lanthanum
1838
G. Mosander
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
Mosander managed
to split the old yttria
68
Erbium
1842
G. Mosander
In 1842 Mosander
65
Terbium
1842
1842
G. Mosander
G. Mosander
Ruthenium
1807
1844
J. Sniadecki
J. Sniadecki
platinum samples,
and in 1844 Karl
Karlovich
Klaus confirmed that
there was a new
element. Klaus is
usually recognized as
the discoverer of the
element.
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
Caesium
1860
1882
R. Bunsen and R.
Kirchhoff
C. Setterberg
by its two
blue emission lines in
a sample
ofDrkheim mineral
water. The pure metal
was eventually
isolated in 1882 by
Setterberg.
Rubidium
1861
R. Bunsen and G.
R. Kirchhoff
R. Bunsen
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
Thallium
1861
1862
W. Crookes
C.-A. Lamy
green line in a
selenium sample;
later that year, Lamy
found the element to
be metallic.
Indium
1863
1867
F. Reich and T.
Richter
T. Richter
bright indigo-blue
spectroscopic
emission line. Richter
isolated the metal
several years later.
Helium
1868
1895
P. Janssen and N.
Lockyer
Ramsay, T.
Cleve,
and N.
Langlet
independently a
yellow line in the solar
spectrum that did not
match any other
element.
Years later, Ramsay,
Cleve, and Langlet
observed
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
independently the
element trapped
in cleveite about the
same time.
Mendeleev arranges
the 63 elements
known at that time
1869
D. I. Mendeleev
31
Gallium
P. E. L. de
Boisbaudran
1875
P. E. L. de
Boisbaudran
corresponding to the
eka-aluminium that
was predicted by
Mendeleev in 1871
and subsequently
isolated the element
by electrolysis.
On October 22, 1878,
Marignac reported
70
Ytterbium
1878
1907
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
Delafontaine found it
in samarskite and
next year, Per Teodor
67
Holmium
1878
M. Delafontaine
69
Thulium
1879
1879
T. Cleve
T. Cleve
21
Scandium
1879
1879
F. Nilson
F. Nilson
62
Samarium
1879
1879
P.E.L. de
P.E.L. de
Boisbaudran
Boisbaudran
new earth in
samarskite and
named it samaria
after the mineral.
64
Gadolinium
1880
1886
Marignac initially
J. C. G. de
F. L. de
Marignac
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
later Boisbaudran
obtained a pure
sample from
samarskite.
Von Welsbach
59
Praseodymiu
m
A. von Welsbach
distinct elements in
ceria: praseodymium
and neodymium.
Von Welsbach
discovered two new
60
Neodymium
1885
A. von Welsbach
distinct elements in
ceria: praseodymium
and neodymium.
66
Dysprosium
De Boisbaudran
P.E.L. de
1886
Boisbaudran
erbia.
In February 1886
Winkler found
32
Germanium
1886
A. Winkler
Lord
18
Argon
1894
1894
Lord
Rayleigh and W.
Ramsay
nitrogen prepared
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
by liquefaction from
air and nitrogen
prepared by chemical
means. It is the first
noble gas to be
isolated.
On May 30, 1898,
36
Krypton
1898
1898
W. Ramsay and W.
Travers
W. Ramsay
Ramsay separated a
and W.
Travers
argon by difference in
boiling point.
In June 1898 Ramsay
10
Neon
1898
1898
W. Ramsay and W.
Travers
W. Ramsay
separated a new
and W.
Travers
argon by difference in
boiling point.
On July 12, 1898
Ramsay separated a
54
Xenon
1898
1898
W. Ramsay and W.
Travers
W. Ramsay
and W.
Travers
liquid argon by
difference in boiling
point.
In an experiment
84
Polonium
1898
1902
P. and M. Curie
W.
Marckwald
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
radioactivity in the
uranium obtained
from pitchblende,
which they ascribed to
an unknown element.
The Curies reported
on December 26,
1898, a new element
88
Radium
1898
1902
P. and M. Curie
M. Curie
different from
polonium, which
Marie later isolated
from uraninite.
Dorn discovered a
W. Ramsay
Radon
1898
1910
E. Dorn
and R.
Whytlaw-
radioactive decay of
Gray
86
radioactive gas
89
Actinium
1899
1899
A.-L. Debierne
A.-L.
Debierne
from pitchblende a
substance that had
properties similar to
those of thorium.
Demaray found
63
Europium
1896
1901
E.-A. Demaray
E.-A.
Demaray
element in Lecoq's
samarium, and
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
separated this
element several years
later.
Urbain and von
71
Lutetium
1906
1906
G. Urbain
and C.A. von
Welsbach
Welsbach proved
independently that the
old ytterbium also
contained a new
element
Ogawa found it
in thorianite but
assigned it as
element 43 instead of
75 and named
it nipponium. In
75
Rhenium
1908[contradiction] 1908
M. Ogawa
M. Ogawa
1922 Walter
Noddack, Ida Eva
Tacke and Otto
Berg announced its
separation
from gadolinite and
gave it the present
name.
Urbain claimed to
72
Hafnium
1911
1922
G. Urbain and V.
Vernadsky
D.
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
independently found it
in orthite. Neither
claim was confirmed
due to World War I.
After the war, Coster
and Hevesy found it
by X-ray
spectroscopic
analysis in Norwegian
zircon. Hafnium was
the next to last
element with stable
isotopes to be
discovered.
The two obtained the
first isotope of this
element that had
been predicted by
91
O.H.Ghring and K.
Mendeleev in 1871 as
Fajans
Protactinium 1913
a member of the
natural decay
of 238U.[107] Originally
isolated in 1900 by
William Crookes.
The two discovered a
43
Technetium
1937
1937
C. Perrier and E.
C. Perrier &
new element in a
Segr
E.Segr
molybdenum sample
that was used in
acyclotron, the
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
isolator
Notes
)
first synthetic
element to be
discovered. It had
been predicted by
Mendeleev in 1871 as
eka-manganese.
Perey discovered it as
a decay product
of 227Ac.[111] Francium
is the last element to
be discovered in
nature, rather than
synthesized in the lab,
87
Francium
1939
M. Perey
R. Corson, R.
85
Astatine
1940
with alpha
Mackenzie and E.
particles Later
Segr
determined to occur
naturally in minuscule
quantities (<25 grams
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
in earth's crust).
Obtained by
E.M.
Neptunium
McMillan and H.
1940
Abelson
93
irradiating uranium
first transuranium
elementdiscovered.
Glenn T.
Prepared by
Seaborg,Arthur C.
94
Plutonium
19401941
bombardment of
Wahl, W.
uranium with
deuterons.
McMillan
Prepared by
G. T. Seaborg, A.
95
Americium
irradiating plutonium
James, O.
1944
Morganand A.
the Manhattan
Ghiorso
Project.
Prepared by
G. T. Seaborg, R.
Curium
A. James and A.
1944
Ghiorso
96
bombarding plutonium
during the Manhattan
Project
Charles D.
61
Promethium
1942
1945
S. Wu, E.G.
Segrand A. Bethe b A.
Marinsky,La
wrence E.
bombarding
neodymium and
praseodymium with
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
Glendenin,
neutrons, but
G. Thompson, A.
Berkelium
Ghiorso and G. T.
Seaborg (University of
1949
bombardment of
americium with alpha
California, Berkeley)
97
Created by
particles.
S. G. Thompson, K.
Street,Jr., A.
Californium
Ghiorso and G. T.
1950
Seaborg(University of
98
Bombardment of
particles.
California, Berkeley)
Einsteinium
1952
1952
Alamos Laboratoryand
University of California,
Berkeley)
thermonuclear
explosion in
November 1952, by
irradiation of uranium
with neutrons; kept
secret for several
years.
A. Ghiorso et
100
Fermium
1952
al.(Argonne Laboratory,
thermonuclear
explosion in
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
University of California,
November 1952, by
Berkeley)
irradiation of uranium
with neutrons; kept
secret for several
years.
A. Ghiorso, G.
Harvey, R.
101
Mendelevium 1955
Choppin, S. G.
Thompson and G.
T. Seaborg
Prepared by
bombardment of
einsteinium with
helium.
A. Ghiorso, T.
Lawrencium
1961
Waltonand G. T.
Sikkeland, E.
bombardment of
Larshand M.
Latimer
103
1958
bombardment of
A. Ghiorso, T.
Nobelium
Sikkeland, R.
Seaborg
102
First prepared by
atoms
A. Ghiorso, M.
104
Rutherfordiu
m
Nurmia, J.
1968
Harris, K.
Eskola and P.
Eskola
Prepared by
bombardment of
californium with
carbon atoms.
A. Ghiorso, M.
105
Dubnium
1970
Prepared by
Nurmia, K. Eskola,
bombardment of
J. Harris and P.
californium with
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
)
Eskola
nitrogen atoms.
A. Ghiorso, J.
Nitschke, J.
Alonso,C. Alonso,
Seaborgium
1974
M. Nurmia, G. T.
of californium-249
Seaborg, K.
106
Prepared by collisions
with oxygen atoms.
Hulet and W.
Lougheed
107
Bohrium
1981
G.Mnzenberg et
al.(GSI in Darmstadt)
G. Mnzenberg, P.
109
Meitnerium
1982
Armbruster et
al. (GSI in Darmstadt)
Obtained by
bombarding bismuth
with chromium.
Prepared by
bombardment of
bismuth with iron
atoms.
G. Mnzenberg, P.
110
111
Hassium
Darmstadtiu
m
1984
1994
Roentgenium 1994
Armbruster et
bombardment of lead
108
Prepared by
with iron atoms
S. Hofmann et
al. (GSI in Darmstadt)
S. Hofmann et
al. (GSI in Darmstadt)
Prepared by
bombardment of lead
with nickel.
Prepared by
bombardment of
bismuth with nickel.
Isolate
Observed
or
(widely
predicted
d
known
Element
Observer
First
Notes
isolator
112
Copernicium 1996
S. Hofmann et
al. (GSI in Darmstadt)
Prepared by
bombardment of lead
with zinc.
Prepared by
114
Flerovium
1999
Y. Oganessian et
bombardment of
al.(JINR in Dubna)
plutonium with
calcium
116
Livermorium 2000
Y.Oganessian et
al.(JINR in Dubna)
Prepared by
bombardment of
curium with calcium
Unconfirmed discoveries
Z
Name
Discovery
year
Discoverer
Notes
Prepared by
bombardment of
californium with calcium
2003
Alpha decay of
ununpentium
Prepared by
bombardment of
118 Ununoctium
113 Ununtrium
2002
Laboratory
Joint Institute for Nuclear
Research in Dubna and
Lawrence Livermore National
Laboratory
Graphics
Development in discovery
Unsuccessful synthesis attempts
In late 1998, Polish physicist Robert Smolaczuk published calculations on
the fusion of atomic nuclei towards the synthesis ofsuperheavy atoms,
including ununoctium. His calculations suggested that it might be possible
to make ununoctium by fusing leadwith krypton under carefully controlled
conditions.
In 1999, researchers at Lawrence Berkeley National Laboratory made use
of these predictions and announced the discovery oflivermorium and
ununoctium, in a paper published in Physical Review Letters, and very
soon after the results were reported inScience. The researchers reported to
have performed the reaction
86
208
Kr +
Pb
293
Uuo + n
36
82
118
48
Ca
20
294
Uuo + 3n
118
Lv
He
116
48
Cm +
96
290
Ca
20
Lv + 3n
116
and checking that the 290Lv decay matched the decay chain of
the 294Uuo nuclei. The daughter nucleus 290Lv is very unstable, decaying
with a lifetime of 14 milliseconds into 286Fl, which may experience
either spontaneous fission or alpha decay into 282Cn, which will undergo
spontaneous fission.
In a quantum-tunneling model, the alpha decay half-life of 294 Uuo was
predicted to be 0.66+0.23 0.18 ms with the experimental Q-value
published in 2004. Calculation with theoretical Q-values from the
macroscopic-microscopic model of MuntianHofmanPatykSobiczewski
gives somewhat low but comparable results.
Ununoctium-294 nuclear.svg
Naming
Until the 1960s ununoctium was known as eka-emanation (emanation is
the old name for radon). In 1979 the IUPAC published recommendations
according to which the element was to be called ununoctium, a systematic
element name, as a placeholder until the discovery of the element is
confirmed and the IUPAC decides on a name.
Before the retraction in 2002, the researchers from Berkeley had intended
to name the element ghiorsium (Gh), after Albert Ghiorso (a leading
member of the research team).
The Russian discoverers reported their synthesis in 2006. In 2007, the
head of the Russian institute stated the team were considering two names
for the new element: flyorium, in honor of Georgy Flyorov, the founder of
the research laboratory in Dubna; and moskovium, in recognition of
the Moscow Oblast where Dubna is located. He also stated that although
name
proposed
for
element
116
was
No name has yet been officially suggested for the element as no claims for
discovery have yet been accepted by the IUPAC. According to current
guidelines from IUPAC, the ultimate name for all new elements should end
in "-ium", which means the name for ununoctium will almost certainly end in
"-ium", not "-on", even if ununoctium turns out to be anoble gas, which
traditionally have names ending in "-on" (with the exception of helium,
which was not known to be a noble gas when it was discovered).
Characteristics
would be a gas under standard conditions, and as the liquid range of the
other gases is very narrow, between 2 and 9 kelvins, this element should
be solid at standard conditions. If ununoctium forms a gas under standard
conditions nevertheless, it would be one of the densest gaseous
substances at standard conditions (even if it is monatomic like the other
noble gases).
Because of its tremendous polarizability, ununoctium is expected to have
an anomalously low ionization energy (similar to that of lead which is 70%
of that of radonand significantly smaller than that of flerovium) and a
standard state con densed phase
Predicted compounds
No compounds of ununoctium have been synthesized yet, but calculations
on theoretical compounds have been performed since 1964. It is expected
that if the ionization energy of the element is high enough, it will be difficult
to oxidize and therefore, the most common oxidation state will be 0 (as for
other noble gases);[ nevertheless, this appears not to be the case.
Calculations on the diatomic molecule Uuo2 showed a bonding interaction
roughly equivalent to that calculated for Hg2, and a dissociation energy of 6
kJ/mol, roughly 4 times of that of Rn2. But most strikingly, it was calculated
to have a bond length shorter than in Rn2 by 0.16 , which would be
indicative of a significant bonding interaction. On the other hand, the
compound UuoH+ exhibits a dissociation energy (in other words proton
affinity of Uuo) that is smaller than that of RnH+.
The bonding between ununoctium and hydrogen in UuoH is predicted to be
very limp and can be regarded as a pure van der Waals interaction rather
than a true chemical bond. On the other hand, with highly electronegative
elements, ununoctium seems to form more stable compounds than for
example copernicium or flerovium. The stable oxidation states +2 and +4
have been predicted to exist in the fluorides UuoF2 and UuoF4. The +6
state would be less stable due to the strong binding of the
7p1/2 subshell. This is a result of the same spin-orbit interactions that make
ununoctium unusually reactive.
For example, it was shown that the reaction of ununoctium with F
2 to form the compound UuoF2 would release an energy of 106 kcal/mol of
which about 46 kcal/mol come from these interactions.
For comparison, the spin-orbit interaction for the similar molecule RnF
2 is about 10 kcal/mol out of a formation energy of 49 kcal/mol. The same
interaction
stabilizes
the tetrahedral
Td configuration for UuoF
4,
as
distinct
from
the square
planar
D4h one of XeF
4 which RnF4 is also expected to have. The UuoF bond will most probably
be ionic rather than covalent, rendering the UuoFncompounds non-volatile.
UuoF2 is
predicted
to
be
partially ionic due
to
ununoctium's
high electropositivity. Unlike the other noble gases (except possibly xenon),
ununoctium was predicted to be sufficiently electropositive to form a Uuo
Cl bond with chlorine.
Name: Ununoctium
Symbol: Uuo
98
This research was reported at an IUPAC conference in China (Yu. Ts. Oganessian,
"Synthesis and decay properties of superheavy elements", Pure Appl. Chem., 2006, 78,
889-904.) in August 2006 and then more recently in Phys Rev C [Yu. Ts. Oganessian,
V. K. Utyonkov, Yu. V. Lobanov, F. Sh. Abdullin, A. N. Polyakov, R. N. Sagaidak, I. V.
Shirokovsky, Yu. S. Tsyganov, A. A. Voinov, G. G. Gulbekian, S. L. Bogomolov, B. N.
Gikal, A. N. Mezentsev, S. Iliev, V. G. Subbotin, A. M. Sukhov, K. Subotic, V. I.
Zagrebaev, G. K. Vostokin, M. G. Itkis, K. J. Moody, J. B. Patin, D. A. Shaughnessy, M.
A. Stoyer, N. J. Stoyer, P. A. Wilk, J. M. Kenneally, J. H. Landrum, J. F. Wild, and R. W.
Lougheed, "Synthesis of the isotopes of elements 118 and 116 in the 249Cf
and 245Cm+48Ca fusion reactions", Phys. Rev. C, 2006,74, 044602].
Earlier, a team of Berkeley Lab scientists announced in 1999 the observation of what
appeared to be element 118 but retracted the claim after several confirmation
experiments failed to reproduce the results. Please see this page for more details. In
this work it was claimed that elements 118 and 116 were formed by accelerating a
beam of krypton-86 (8636Kr) ions to an energy of 449 million electron volts and directing
the beam onto targets of lead-208 (20882Pb). After 11 days work, just three atoms of the
new element were identified. The production rates for element 118 are approximately
one in every 1012 interactions.
208
82
Pb + 8636Kr 293118Uuo + 1n
Read more
Read more
Isolation
Isolation: experiments conducted at Dubna in Russia at the Flerov Laboratory of
Nuclear Reactions (by workers from the Joint Institute for Nuclear Research in Russia
and the Lawrence Livermore National Laboratory in the USA) indicate that element 118
(ununoctium, Uuo) was produced. Not too much though, one atom in the spring of 2002
and two more in 2005.
The 2002 experiment involved firing a beam of 4820Ca at 24998Cf. The experiment took 4
months and involved a beam of 2.5 x 1019 calcium ions to produce the single event
believed to be the synthesis of element 118 (ununoctium) as the294118Uuo isotope. Three
neutrons are released during this process.
249
98
This ununoctium isotope then loses three alpha particles in rapid succesion:
294
118
290
286
116
114
The 282112Cn species then undergoes spontaneous fission (denoted SF) to other species.
An important part of this work was additional work synthesising isotopes of element 116
through irradiation of 245Cm (as opposed to 249Cm referred to above).
245
98
Analysis of this reaction very clearly indicates that 290116Lv is indeed a decomposition
product of 294118Uuo. This research was reported at an IUPAC conference in China (Yu.
Ts. Oganessian, "Synthesis and decay properties of superheavy elements", Pure Appl.
Chem., 2006, 78, 889-904.) in August 2006 and then more recently in Phys Rev C [Yu.
Ts. Oganessian, V. K. Utyonkov, Yu. V. Lobanov, F. Sh. Abdullin, A. N. Polyakov, R. N.
Sagaidak, I. V. Shirokovsky, Yu. S. Tsyganov, A. A. Voinov, G. G. Gulbekian, S. L.
Bogomolov, B. N. Gikal, A. N. Mezentsev, S. Iliev, V. G. Subbotin, A. M. Sukhov, K.
Subotic, V. I. Zagrebaev, G. K. Vostokin, M. G. Itkis, K. J. Moody, J. B. Patin, D. A.
Shaughnessy, M. A. Stoyer, N. J. Stoyer, P. A. Wilk, J. M. Kenneally, J. H. Landrum, J.
F. Wild, and R. W. Lougheed, "Synthesis of the isotopes of elements 118 and 116 in
the 249Cf and245Cm+48Ca fusion reactions", Phys. Rev. C, 2006, 74, 044602].
Earlier, a team of Berkeley Lab scientists announced in 1999 the observation of what
appeared to be element 118 but retracted the claim after several confirmation
experiments failed to reproduce the results. This means that the following apparently is
wrong. Please see this page for more details. In this work it was claimed that elements
118 and 116 were formed by accelerating a beam of krypton-86 (8636Kr) ions to an
energy of 449 million electron volts and directing the beam onto targets of lead-208
(20882Pb). After 11 days work, just three atoms of the new element were identified. The
production rates for element 118 are approximately one in every 10 12 interactions.
208
82
Pb + 8636Kr 293118Uuo + 1n
The element 118 nucleus was said to decay less than a millisecond after its formation
by emitting an -particle resulting in an isotope of element 116 (mass number 289,
containing 116 protons and 173 neutrons). This isotope of element 116 undergoes
further -decay processes to an isotope of element 114 and so on down to at least
element 106 (seaborgium).
293
289
118
116
285
281
277
273
114
112
Ununoctium
Ununoctium
o
o
o
o
o
Ununoctio
Ununoctium
Ununoctium
Ununoctio
Ununoctium
Ununoctio
Ununoctium
Essential data: names, symbol, atomic number, and atomic
weight; block, period, and group in periodic table; description;
standard state; registry number; and isolation
History: meaning of name; discovery; and history of the element
Uses
Find a property
Ununoctium around us
Geology: Abundance of elements in the universe; the sun;
meteorites; Earth's crust; oceans; and streams
Biology: Abundance in humans; biological role; and health
hazards)
Search Chemistry Web
o
o
o
o
o
o
o
o
o
o
o
Ununoctium Ununoctium
The Ununoctium was discovered by V. Ninov and many of collaborates that was
A.Ghiorso, W.J. Siatecki,C.A. Laue, J.B. Patin, D.A. Shaughnessy, D.A. Strellis,
and P.A.Wilk in the year of 1996 in Berkeley, California and the university of the
state of Oregon inUSA.
Basic Information: Name: Ununoctium.
Symbol: Uuo
Atomic Number: 118
Atomic Mass: 293
The origin: Temporary name proposed by the IUPAC.From Latin: Un(one)un
(one) octium (eight) as the element 118 of the periodic table.Characteristics and the
main properties of Ununoctium.
Characteristics:
1. Scientists at the Joint Institute for Nuclear Research in Russia showed that in
the element 118 has been produced an atom in the spring in 2002 and two more in
2005.
2. Ununoctium is a radioactive element and has a half life that seems to be less
than a millisecond.
3. Colour: unknown, but probably a colourless gas.
4. Classification: Non-metallic.
5. Availability: Not commercially available.
6. Group in the periodic table was 8.
7. The Ununoctium structure was crystal
Properties:
1. The atomic number of Ununoctium was 118
2. The symbol of Ununoctium was Uuo.
3. The atomic weight was 293.
4. Ununoctium is a member of group 18. Members of this group tend to be material
inert to mostcommon chemical reactions (for example the combustion), as the
outer valence shell is completelyfilled with eight electrons. This produces a stable
form, minimum energy in which the configurationthe outer electrons are closely
linked.
The electron Configuration of Ununoctium:1s2 2s2 2p6 3s2 3p6 4s2 3d1 4p6 5s2
4d1 5p6 6s2 4f4 5d1 6p6 7s2 5f4 6d1 7p6
Uses:Since only three atoms of Ununoctium have ever been produced, it currently
has no uses outside of basic scientific research. It would constitute a radiation
hazard if enough were ever assembled inone place.
Ionization Energy (1st) kJ mol-1
Ionization Energy (2nd) kJ mol-1
IonizationEnergy (3rd) kJ mol-1