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International Journal of Metallurgical & Materials
Science and Engineering (IJMMSE)
ISSN(P): 2278-2516; ISSN(E): 2278-2524
Vol. 4, Issue 2, Apr 2014, 9-18
TJPRC Pvt. Ltd.
SYNERGISTIC INHIBITION BETWEEN AMPICILLIN TRI-HYDRATE AND KI FOR
CORROSION OF CARBON STEEL IN 1M HCl SOLUTION
HAMEED HUSSEIN ALWAN
Department of Electrochemical Engineering, College of Engineering, Babylon University, Iraq
ABSTRACT
The effect of Ampicillin tri-hydrate C
16
H
19
N
3
O
4
S on the corrosion of carbon steel in 1 M HCl solution was
studied by weight loss and electrochemical polarization techniques at 30
=
un
n i
un
n i n u
i
i
w
i i
(1)
Where i
un
, and i
in
are the corrosion current densities for uninhibited and inhibited condition respectively. For
surface coverage, it was calculated by:
=
un
n i
un
n i n u
i
i
w
i i
1 (2)
Table (2) shows, the polarization data (potential versus logarithmic current density) for carbon steel in HCl
solution in absence and presence of different concentration of inhibitor (Ampicillin tri-hydrate) and additive
(potassium iodide) at 313K, the inhibitor efficiencies were listed in table (2), which calculated according to equation (1),
while the values of surface coverage () are listed in the last column in table (2), which calculated according to
equation (2).
250
300
350
400
450
500
550
600
200 300 400 500 600
-
E
(
m
V
)
Log I ( mA /cm2)
Balnk
Amp 0.001 M
Amp 0.002 M
Amp 0.003 M
Amp 0.004 M
Figure 4: Polarization Curves of Carbon Steel in 1 M HCl Alone and Contained
Different Concentration of Ampicillin Tri-Hydrate at 313 K
200
250
300
350
400
450
500
550
600
200 250 300 350 400 450 500 550 600
-
E
(
m
V
)
Log I ( mA /cm 2)
Blank
0.001 M KI
0.002 M KI
0.003 M KI
Figure 5: Polarization Curves of Carbon Steel in 1 M HCl Alone and Contained
Different Concentration of KI at 313 K
Synergistic Inhibition between Ampicillin Tri-Hydrate and KI for Corrosion of Carbon Steel in 1M HCL Solution 13
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200
250
300
350
400
450
500
550
600
200 300 400 500 600
-
E
(
m
V
)
Log I ( mA / cm2)
Blank
Amp 0.003 M + 0.001 M KI
Amp 0.003 M + 0.002 M KI
Amp 0.003 M + 0.003 M KI
Figure 6: Polarization Curves of Carbon Steel in 1 M HCl Solution with 0.003 M Ampicillin
Tri-Hydrate and Different Concentrations of KI at 313 K
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
%
KI concentration M
HCl solution + KI
HCl solution +Amp + KI
HCl solution + Amp
Figure 7: Increasing of Inhibition Efficiency by Synergistic Inhibition Effect
between Ampicillin Tri-Hydrate and Potassium Iodide
An increasing in Ampicillin tri-hydrate concentration shift the polarization curves towards more negative potential
for cathodic Tafel lines, and toward more positive potential for anodic Tafel lines , and this lead to decreasing in corrosion
current densities. It's clear from figure (7) there is an increasing in inhibition efficiency.
Absorption Isotherms
The inhibitor could form a thin layer on the metal surface and partly protect it. The protection action of organic
substances during metal corrosion is based on the adsorption ability of their molecules, where the resulting adsorption film
isolates the metal surface from the corrosive medium .Adsorption isotherms are used to understand the mechanism of
corrosion inhibition of metals and alloys. So adsorption isotherms are very important in determining the mechanism
organic electrochemical reaction. [9]
In order to test whether the inhibitor follows the one from adsorption isotherms, the collected data was fitted by
used adsorption isotherm equations. For this study we used the Freundlich adsorption isotherm, which is described by
equation.
n
ads
c K = (3)
C n K
ads
log log log + = (4)
Where C is additive concentration, K
ads
is the adsorptive equilibrium constant representing the interaction of the
14 Hameed Hussein Alwan
Impact Factor (JCC): 2.9076 Index Copernicus Value (ICV): 3.0
additive with the metal surfaceand, is the surface coverage and n is constant, to know the spontaneously of adsorption
process there is require to estimate adsorption free energy, G
ads
.
exp
5 . 55
1
=
RT
G
K
ads
ads
(5)
) K . ( -RT G
ads ads
5 55 ln =
(6)
Where R is universal gas constant; 8.314 J/ mol. K and, T is temperature in K.
-1.2
-1
-0.8
-0.6
-0.4
-0.2
0
-0.6 -0.4 -0.2 0 0.2 0.4
L
o
g
Log C ( g / l)
HCl + Amp
Figure 8: Freund Lich Adsorption Isotherms for Ampicillin Tri-Hydrate on
Carbon Steel in 1 M HCl Solution at 313 K
-1.2
-1
-0.8
-0.6
-0.4
-0.2
0
-1 -0.8 -0.6 -0.4
L
o
g
Log C ( g / l)
HCl + KI
HCl + Amp + KI
Figure 9: Freund Lich Adsorption Isotherm for KI Alone and with Ampicillin
Tri-Hydrate on Carbon Steel in 1 M HCl Solution at 313 K
From table (3) it is noted that G
ads
, values have negative sign indicating that adsorption process proceeds
spontaneously and increase as the percentage inhibition increase, the high values of adsorption constant K
ads
values suggest
that molecules are strongly adsorbed onto mild steel surface.
Synergism Parameter (Effect of Halide Ions)
The increase of inhibition efficiency of organic compounds in presence of some anions has been observed by
several investigations and was ascribed to synergistic effect. In generally accepted that the presence of halide ions in acidic
media synergistically increases that inhibition efficiency of some organic compounds. It is thought that halide ions are able
to improve adsorption of organic cations by forming intermediate bridge between the positively charged metal surface and
positive end of the organic molecule. [8]
Synergistic Inhibition between Ampicillin Tri-Hydrate and KI for Corrosion of Carbon Steel in 1M HCL Solution 15
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All the experimental results have revealed that the addition of halide ions to the inhibited solution enhances the
inhibition efficiency and the surface coverage, . This behavior is attributed to the synergistic effect between added KI and
Ampicillin tri-hydrate.
To determine the existence of the synergism phenomenon between Ampicillin tri-hydrate and the halide ions,
synergism parameter was evaluated using the equation initially proposed by the Aramaki and Hackermann in 1964 and
reported elsewhere[10]
+
+
=
2 1
2 1
I
1
1
S (7)
Where
2 1 2 1 2 1
+ =
+
+2 1
+2 1
S
I
1 M HCl + 0.003 M Ampicillin tri-hydrate + 0.001 M KI 0.34 0.11 0.33 1.43
1 M HCl + 0.003 M Ampicillin tri-hydrate + 0.002 M KI 0.34 0.21 0.48 1.78
1 M HCl + 0.003 M Ampicillin tri-hydrate + 0.003 M KI 0.34 0.37 0.65 2.49
REFERENCES
1. Jones Denny A, Principles and prevention of corrosion, 2nd Edition, (1996), Prentice Hall, New Jersey.
2. E. E. Oguzie, Y .Li, F. H. Wang. Studies on the inhibitive effect of Occimumviridis extract on the acid corrosion
of mild steel, Mater. Chem. Phys. 99 (2006) 441-446.
3. S. A. Umoren, I.B. Obot, E. E. Ebenso, N.O. Obi-Egbedi, Synergistic Inhibition between Naturally Occurring
Exudate Gum and Halide Ions on the Corrosion of Mild Steel in Acidic Medium, Int. J. Electro chem.
Sci., 3 (2008) 1029 1043.
4. Alan W. Armoura and Dennis R. Robitailleb, Corrosion Inhibition by Sodium Molybdate, J. Chem. Tech.
Biotechnol. 29 (1979) 619-628.
5. Hameed Hussein Alwan , Adsorption Mechanism for Corrosion Inhibition of Carbon steel on HCl Solution by
Ampicillin Sodium Salt ,IJARET, Vol. 4, Issue 7, November December (2013) 236-246.
6. N. Caliskan and E. Akbas, Corrosion Inhibition of Austenitic Stainless Steel by Some Pyrimidine Compounds in
hydrochloric Acid , Materials and Corrosion , 3 ( 2012), 63
7. A.S.EL-GABER, A.S. FOUDA, A.M. EL DESOKY, Synergistic Inhibition of Zinc Corrosion by Some Anions in
Aqueous media, Ciencia & Tecnologia dos materiais , 20 ( 2008) 3/4 , 71-77.
8. E.Ouzie , Y. Li , W.H. Wang, Corrosion Inhibition and Adsorption Behavior of Methionine on Mild Steel in
Sulfuric Acid and Synergistic effect of iodide ion , Journal of Colloid and Interface Science , 310 ( 2007) 90-98.
9. E.E. Ebenso, N.O. Eddy, A.O. Odiongenyi, Corrosion Inhibition and Adsorption Properties of Methocarbamol on
Mild Steel in Acidic Medium , Portugaliae Electro chimica Acta,27( 2009) 13-22
10. Nnabuk O. Eddy 1, Eno E. Ebenso. Adsorption and Quantum Chemical Studies on Cloxacillin and Halides for the
Corrosion of Mild Steel in Acidic Medium, Int. J. Electrochem. Sci., 5 (2010) 731 750.