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time (hrs)
0
6
12
24
36
48
60
80
100
120
140
160
10
12.4
14.5
17.9
20.8
23.2
25.6
10
15.4
19.6
25.7
30.4
34.9
38.8
10
21
27.8
37.7
45.8
52.4
58.3
10
29.5
40.5
56
68.6
79
88
10
46.9
65.5
90.5
112.8
129.3
144.9
(Phenetole)
160
140
Liquid level below tube opening (mm)
all measurements in mm
Antoine Equation
120
100
80
60
40
20
0
0
For Phenetole:
A
B
C
4.1447
1507.267
-78.793
T (C)
PA
yA
80
100
120
140
160
0.044451 0.105087 0.222663 0.431241 0.775125
0.043869 0.103713 0.219752 0.425601 0.764989
Using the Arnold Diffusion Cell Method with the given data
Constants
R
A
MA
MB
Where:
T (C)
T (K)
time (hrs)
80
353
120
393
140
413
160
433
8.63E-06
8.62E-06
8.5E-06
8.6E-06
8.6E-06
8.56E-06
8.58E-06
4.76E-08
9.44E-06
9.42E-06
9.09E-06
9.46E-06
9.34E-06
9.39E-06
9.36E-06
1.36E-07
DAB
0
6
12
24
36
48
60
Average
Std Deviation
100
373
6.36E-06
6.52E-06
6.52E-06
6.56E-06
6.48E-06
6.57E-06
6.5E-06
7.63E-08
7.02E-06
7.28E-06
7.18E-06
7.04E-06
7.16E-06
7.2E-06
7.14E-06
9.79E-08
8.12E-06
8.01E-06
7.87E-06
7.93E-06
7.87E-06
7.86E-06
7.94E-06
1.04E-07
Diffusivity ve
old Diffusion Cell Values)
1.00E-05
9.50E-06
C
H
O
Ring
16.5
1.98
5.48
-20.2
vA
127.18
vB
50.36
T (C)
2
DAB (cm /s)
2
DAB (m /s)
80
100
120
140
160
0.065389 0.072006 0.078895 0.086052 0.093474
6.54E-06
7.2E-06 7.89E-06 8.61E-06 9.35E-06
Absolute Error
Diffusivity (m^2/s)
(Arnold Diffusion Cell Values)
1.00E-05
9.50E-06
9.00E-06
8.50E-06
8.00E-06
7.50E-06
7.00E-06
6.50E-06
6.00E-06
350.00
DAB
Relative Error
0.57%
0.78%
0.66%
0.24%
0.10%
Average relative error
0.47%
This error is under the suggested error of ca. 5% in perry's chemical engineering handbook
References
Raw Data
80 Degrees Celcius
100 Degrees Celcius
10
20
30
40
50
60
70
Time (hrs)
From the above graph is already clear that there is an increase in the gradient with increasing temperature
indicating a strong dependence of diffusivity on temperature
Constants
8.314
967
122.1644
46.0684
Nm/mol K
kg/m3
kg/kmol
kg/kmol
9.50E-06
1.00E-05
9.50E-06
9.00E-06
8.50E-06
8.00E-06
y = 2E-10x1.7867
7.50E-06
7.00E-06
6.50E-06
6.00E-06
350.00
370.00
390.00
410.00
430.00
450.00
Temperature in K
As can be seen from the graph, a power relationship in this case can be found:
1.786
T(K)
Which is very similar to the suggested relationship of as in the Fuller, Schettler and Giddings relationship
T(K)1.75
A
B
C
4.1447
1507.267
-78.793
ok.cgi?ID=C103731&Units=SI&Mask=4#ref-10