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1. The enthalpy change for a reaction does not depend upon (a) The physical states of reactants and products (b) Use of different reactants for the same product (c) The nature of intermediate reaction steps (d) The differences in initial or final temperatures of involved sustances 2. The heat required to raise the temperature of a body by 1 K is called (a) Specific heat (b) Thermal capacity (c)Water equivalent (d) None of these

3. The enthalpy change for the reaction H2(g)+C2H4(g) C2H6(g) is . The bond energies are, H-H=103, C-H=99, C-C=80& C=C 145 K cal mol-1 (a) -10 K cal mol-1 (b) +10 K cal mol-1 (c)-30 K cal mol-1 (d) +30 K cal mol-1

4. The heat of combustion of CH4(g),C(s) and H2(g) at 250C are -212.4 K cal, -94.0 K cal and 68.4 K cal respectively, the heat of formation of CH4 will be (a) +54.4 K cal (b) -18.4 K cal (c)-375.2 K cal (d) +212.8 K cal

5. At a certain temperature T, the endothermic reaction AB proceeds almost to completion. The entropy change is (a) S=0 (b) S<0 (c)S>0 (d) Cannot be predicted

6. It the equilibrium constant for a reaction is 10, the the value of G0 will be (R=8jk-1 mol-1, T=300K) (a) +5.527 KJ mol-1 (b) -5.527 KJ mol-1 (c)+55.27 KJ mol-1 7. If G0>0 for a reaction then (a) Kp>1 (d) -55.27 KJ mol-1

(b) Kp<1

(c)The products predominate in the equilibrium mixture (d) None 8. The total entropy change for a system & its surroundings increases if the process is (a) Reversible (b) Irreversible (c)Exothermic 9. In which reaction S is positive (a) H2O(l)H2O(s) (c)H2O(l)H2O(g) (d) Endothermic

(b) 3o2(g)2o3(g) (d) N2(g)+3H2O(g)2NH3(g)

10. The gaseous endothermic reaction P+Q2R+3S at 270C takes place spontaneously, because (a) H<O; S<O; (b) H>O; S>O (c)H<O; S>O (d) H>O; S<O

11. At 00C ice and water are in equilibrium and HO= 6.00kJ/mol for the process H2O(s) H2O(l) Value of S0 for the conversion of ice to liquid water is (a) 10.15 JK-1 mol-1 (b) 17.25 JK-1 mol-1 (c)21.98 JK-1 mol-1 (d) 30.50 JK-1 mol-1

12. For a spontaneous process the values of free energy and entropy change are respectively (a) Postiove and negative (b) Negative and Positive (c)Positive and Positive (d) Negative and negative

13. The bond dissociation energies of methane and ethane are 360 kcal mol-1 and 620 kcal mol-1 respectively. The C-C bond energy in kcal mol-1 is (a) 130 (b) 260 (c)180 (d) 80

14. Enthalpy of carbon, hytdrogen and ethyl alcohol on combusion at 250C are -94.0, -68.4 and 327.0 kcal per mole, then the formation enthaply of ethyl alcohol will be (a) -66.2 Kcal/mol (b) 58.2 kcal (c)60.2 kcal/mol 15. What is true for the reaction PCl5(g)PCl3(g)+Cl2(g) (a) H=E (c)H<E (d) 60.4 kcal/mole

(b) H>E (d) None of these

16. For the homogeneous reaction 4NH3+5O2 = 4NO+6H2O the equilibrium constant k, has the units of (a) Conc.+10 (b) Conc.+1 (c)Conc.-1 (d) It is dimension less

17. When NaNO3 is heated in a closed vessel, oxygen is liberated and NaNO2 is left behind. At equilibrium 1 Addition of NaNO2 favours reverse reaction 2 Addition of NaNO3 favours forward reaction 3 Increasing temperature favours forward reaction 4 Increasing pressure favours forward reaction correct answer is (a) a, b,c (b) b,c,d (c)a,b,c,d (d) a,d

18. for reaction PCl3(g)+Cl2(g) = PCl5(g) the value of kc at 2500C is 26. The value of kp at this temperature will be (a) 0.61 (b) 0.57 (c)0.83 (d) 0.46

19. CO and Cl2 are allowed to interact in a 500 ml flask to form COCl2 At equilibrium, concentrations of CO,Cl2 and COCl2 are found 0.1, 0.1 and 0.3 gm moles respectively. The equilibrium constant will be (a) 30 (b) 3 (c)15 (d) 0.3

20. Hi was heated in a sealed tube at 4400C till the equilibrium was reached. Hi was found to be 22% decomposed. The equilibrium constant for dissociation is (a) 0.282 (b) 0.0796 (c)0.0199 (d) 1.99

21. Oxidation of SO2 by O2 to SO3 is an exothermic reaction. The yield of SO3 will be maximum if (a) Temperature is increased and pressure is kept constant (b) Temperature is reduced and pressure is increased (c) Both temperature and pressure are pressure are increased (d) Both temperature and pressure are reduced 22. One mole of SO3 was placed in one litre vessel at a certain temperature. The following equilibrium was established 2SO3 = 2SO2+O2. At equilibrium 0.6 moles of SO2 were formed. The equilibrium constant of the reaction will be (a) 0.36 (b) 0.45

(c)0.54

(d) 0.675

23. The equilibrium constant for the reaction H2(g)+I2(g) = 2HI(g) is 49. If the equation of the reaction is written as H2+1/2 I2(g) = HI(g) then (a) The value of equilibrium constant would change (b) The value of equilibrium constant would remain the same (c) Mole fraction of hydrogen reacted would change (d) Mole fraction of HI formed will change 24. Equilibrium concentration of HI, I2 and H2 is 0.7, 0.1 and 0.1 moles/litre. Calculate equilibrium constant for reaction I2+H2 = 2HI is (a) 0.36 (b) 36 (c)49 (d) 0.49

25. for the reaction equilibrium N2O4(g) = 2NO2(g) The concentrations of N2O4 and NO2 at equilibrium are 4.8x10-2 and 1.2x10-2 mol L-1 respectively. The value ol kc for the reaction is (a) 3.3x102 mol L-1 (b) 3.3x10-1 mol L-1 (c)3.3x10-3 mol L-1 26. For the reaction CO(g)+Cl2(g) = COCl2(g) The kp/kc is equal to (a) (c) (b) 1.0 (d) RT (d) 3.3x10-4 mol L-1

27. For the reaction 2NO2(g) = 2NO(g)+O2(g) Kc = 1.8x10-6 at 1840C, R = 0.00831 kJ/(mol, K) when kp and kc are compared at 1840C it is found (a) Kp is greater than kc (b) Kp is less than kc (c) Kp = kc (d) Whether kp is greater than, less than or equal to kc depends upon the total gas pressure. 28. At constant pressure, the addition of argon in habers process (a) Reduces the formation of ammonia from N2 and H2 (b) Increases the formation of ammonia from N2 and H2 (c) Does not affect the equilibrium of the reaction in which ammonia is formed from N2 and H2 (d) Reduces the dissociation of ammonia 29. Pure NH3 is placed in a vessel at a temperature where its dissociation is appreciable. At equilibrium (a) Kp does not change significantly with pressure

(b) Concentration of N2 does not change with pressure (c) Concentration of NH3 does not change with pressure (d) Kp changes with pressure but does not change 30. For the equilibrium CO+H2O = CO2+H2 The relation between kp and kc at 250c and at 1000c are (a) Kp = kc, kp = kc (b) Kp = kc (RT)-1, kp = kc (c)Kp = kc (RT), kp = kc(RT) (d) Kp = kc (RT), kp = kc