1 Question No. 1 (a) b(i) (ii) c(i) (ii) Explanation No of electrons = 18, No of neutrons = 22 !

e total nu"ber of protons and neutrons in t!e nucleus of an ato" #$ 2.1 Mark 1-1 1 1 1 Mark

X X 2 d(i) (ii) (iii) %,& 'sotopes !a(e t!e sa"e nu"ber of (alence electrons.)proton nu"ber *arbon datin+ to esti"ate t!e a+e of fossils )artefacts),ood 1 1 1

Total Marks

10

Trial Johor 2008

Question No. 2(a)

Explanation 's a representation of a c!e"ical substance usin+ letters for ato"s and subscripts for eac! t.pe of ato"s present in t!e substance. / 0ble to na"e suitable acid and "etal and its e1uation 2 3or exa"ple 4.droc!loric acid and 5inc "etal 6n - 24*l 6n*l2 - 42 4.dro+en +as "ust be flo,ed)t!rou+!)into t!e co"bustion tube for a fe, "inutes before !eatin+) !e flo, of !.dro+en +as "ust be continuous t!rou+!out t!e experi"ent) / 0ccept an. one ans,er2

Mark 1

Mark

(b) (i) (ii) (c)

1 1

(d) (i)

Nu"ber of "ole of copper = 1.72 7# = $.$28"ole Nu"ber of "ole of ox.+en = $.#$ 17 = $.$28"ole Nu"ber of "ole of copper 9 Nu"ber of "ole of ox.+en $.$28 9 $.$28 !e si"plest ratio 1 9 1 !e e"pirical for"ula of copper('') oxide is *u: 'ron ) in ) ;ead ) <il(er) 0uru" ) =urnin+ of "etal in excess ox.+en

(ii)

1 1 1 1

(iii)

(e) (f)

10 Total marks

Trial Johor 2008

>

Question No. > (a)(i) (ii) (b)(i) (ii) c(i) (ii)

Explanation ?roup 1 and @eriod # ? A2; <oluble in ,ater)) !i+! "eltin+ ) boilin+ point)) conducts electricit. in "olten or a1ueous solution E !e nuclei attraction to,ards t!e (alence electrons is ,eaker in E. !us it is easier for E to lose ) release an electron to for" a positi(el. c!ar+ed ion. ;))M *o(alent bond

Mk 1-1 1 1 1 1 1 1 1 1

Mark

d(i) (ii)

Trial Johor 2008

# Total Marks Question No. # (a) (b) (c) (d) (e) Explanation 0 ,eak acid is an acid t!at dissociates partiall. in ,ater to produce !.dro+en ions <our *olourless to pink Neutralisation is an exot!er"ic reaction.) releases !eat <o"e of t!e ener+. produced durin+ t!e reaction bet,een a ,eak acid and stron+ base is used to ionise)dissociate co"pletel. t!e ,eak acid "olecules. 4- :4B 42: Mark 1 1 1 1 10 Mark

1 1

(f) (+) (i)

Nu"ber of "oles of "alic acid= 8.$$ 1># = $.$>C> "ol Nu"ber of "oles of sodiu" !.droxide used =2.$$ x >C.>$ 1$$$ = $.$C#7 "ol 1 "ole of 4- reacts ,it! 1 "ole of :4B. !us, nu"ber of "ole of 4- ions in t!e sa"ple = $.$C#7 $.$>C# "ole of "alic acid produces $.$C#7 "ole of !.dro+en ion. 4ence, 1 "ole of "alic acid produces $.$C#7 $.$>C> = 2 "ole of 4:r No of "ole of "alic acid 9 No of "ole of Na:4 1 9 2 !erefore, "alic acid is diprotic (pro(en) Total marks

(ii)

10

Trial Johor 2008

Question No. 8a(i) (ii) (iii) (b)

Explanation 4aber @rocess >42 - N2 2N4> *atal.st 9 'ron e"perature 9 #8$o* <ulp!ur trioxide is dissol(ed in concentrated 42<:# to for" oleu" :leu" is diluted ,it! ,ater to produce sulp!uric acid (N4#)2<:# D of N = 2(1#) x 1$$D 1>2 = 21.21D

Mark

Mark

1 1 1 1 1 1 1 1 1 1

(c)(i) (ii)

Total marks

10

Trial Johor 2008

Question No. 7(a)(i) (ii)

Explanation Et!anol :ne "ole of et!anol ,!en co"pletel. burnt in ox.+en (under standard conditions) ,ill release 127$ kE of !eat ener+. No of "oles of alco!ol = $.2> ) #7 = $.$$8 "ol 1 "ol of alco!ol burnt released 127$ kE !us, $.$$8 "ol of alco!ol burnt released 7.> kE

Mark 1

Mark

1 1 1 1 1 1

(b)(i)

(ii)

"cF = 7.> kE McF = 7.> x 1$$$ G = 7>$$) 2$$ x #.2 = C.8 $ * 4eat is lost to t!e surroundin+ )) 4eat is absorbed b. t!e apparatus or containers )) 'nco"plete co"bustion Ener+.

(c) (d)

*2 48 : 4 - > :2

I 4 = B 127$ kE"olB1 2 *:2 - 42 :

Heaction pat! ;abel ener+. and dia+ra" !as 2 different ener+. le(els =alanced c!e"ical e1uation (e) B 2787 kE"olB1 )) 28$$B2C$$ kE"olB1

1 1 1

Trial Johor 2008

C Total marks Question No. C(a) Explanation Mark 10 Mark

butB1Bene )

butB2Bene )

2B"et!.lpropene 1. *orrect structural for"ula 2. *orrect na"e /0n. t,o structural for"ulae and related na"es2 (b)(i) (ii) J9 propanol ) propanB1Bol ) propanB2Bol & 9 propanB1,2Bdiol 6 9 propane Heaction ' 9 *>47 - 42$ *>4C :4 Heaction '' 9 *>47 - 42$ - /:2 *>417(:4)2 Heaction ''' 9 *> 47 - 42 *>48 1. 4exene is a unsaturated !.drocarbon ,!ile !exane is a saturated !.drocarbon 2. 4exene !as a double bond bet,een carbon and carbon ato"s >. Knder+oes addition reaction ,!en it reacts ,it! bro"ine ,ater #. 4exane !as sin+le bond bet,een carbon and carbon ato"s 8. *annot react ,it! bro"ine ,ater 7. D of * in *741# = 7(12) x 1$$D 87 C. = 8>.C2D 8. D of * in *7412 = 7(12) x 1$$D 8# L. = 88.C1D 1$. !e percenta+e of carbon ato"s in *7412 is !i+!er t!an *741#

# 1-1-1

# >

1-1-1 1 1 1 1 1 1 1 1 1 1

>

(c)

1$ 20 Trial Johor 2008

8 Total marks

Trial Johor 2008

Question No. 8 (a)(i)

Explanation *orrect apparatus set up *orrect labellin+ Molu"e of +as ) c"> L

Mark 1 1

Mark

(b) (i)

i"e)"in (ii) *ur(e labellin+ axes ,it! units *a*:> 24*l *a*l2 - *:2 - 42 : 1 1 1 1

No. of "oles acid = ($.1)(8$) = 8 x 1$B> 1$$$ 2 "ol of 4*l reacted e(ol(e 1 "ol of *:2 $.$$8 "ol of 4*l reacted e(ol(e $.$$8 "ol of *:2 2 = $.$$28 "ol *:2 Molu"e of *:2 =($.$$28)(2#) = $.$7 d"> = 7$ c"> :(erall a(era+e rate of reaction = otal (olu"e of *:2 otal ti"e = 7$ c"> >$$ s = $.2 c"> sB1 Hate of reaction in Expt '' is !i+!er t!an Expt ' Experi"ent '' is at a !i+!er te"perature, t!e kinetic ener+. of t!e reactin+ particles increases and t!e particles "o(e faster 3re1uenc. of collision bet,een "arble and !.dro+en ions increases 3re1uenc. of effecti(e collision increases Hate of reaction in Expt ''' is !i+!er t!an Expt ' @o,dered "arble in Expt ''' !as +reater total surface area) bi++er surface area per unit (olu"e @o,dered "arble is "ore exposed to collision 3re1uenc. of collision bet,een "arble and !.dro+en ions increases

1 1 # 1 1 1 1 1 1 1 1 1 1 Trial Johor 2008 1 1 8 8

1$

Question No. L (a)(i)

Explanation @recipitation )) Exot!er"ic 0+ - - *l

B

Mark 1 1

Mark

0+*l

(b)

<alt & is added into a test tube and distilled ,ater is added to dissol(e it. !e a1ueous solution is separated into > portions. <odiu" !.droxide solution is added into one portion until in excess %!ite precipitate for"ed dissol(es in excess sodiu" !.droxide solution s!o,in+ 5inc ion , lead ion N alu"iniu" ion "a. be present in salt &. 0""onia solution is added to anot!er portion until in excess . %!ite precipitate dissol(es confir"in+ t!e presence of ion 5inc in salt &. Ailute sulp!uric acid is added to t!e last portion , follo,ed b. acidified iron ('') sulp!ate solution and

1 1 1 1 1 1

Trial Johor 2008

11 concentrated sulp!uric acid. =ro,n rin+ for"ed s!o,s t!e presence of N:>B ion in salt &. Preparation of zinc sulphate salt (c) 0bout 8$ c"> of 1 "ol d"B> sulp!uric acid is poured into a beaker. !e beaker containin+ t!e sulp!uric acid is !eated +entl. . 6inc oxide po,der is added little b. little into t!e ,ar" sulp!uric acid, and stirred continuousl. till t!e 5inc oxide po,der no lon+er dissol(es in t!e acid. !e excess 5inc oxide is re"o(ed b. filterin+. !e solution of 5inc sulp!ate )t!e filtrate is poured into an e(aporatin+ dis! and !eated until it beco"es saturated ) concentrated. !e !ot saturated 5inc sulp!ate solution is allo,ed to cool and cr.stals of 5inc sulp!ate are for"ed. !e 5inc sulp!ate cr.stals are filtered and t!en dried bet,een s!eets of filter papers. !e e1uation for t!e reaction is9 6n: - 42<:#O 6n<:#- 42: (accept procedures in acti(e (oice) Total marks 1 1 1 1 1 1 1 1 1 1 1$ 1 1 1

Max 8

20

Trial Johor 2008

12 Question No. 1$ (a) Explanation *!e"ical E1uations 9 '' and ''' Heasons 9 'n(ol(in+ oxidation and reduction occurrin+ si"ultaneousl.)at t!e sa"e ti"e Heaction '' :xidation9 *u loses electron to for" *u2Heduction9 0+- +ain electron to for" 0+ )) Electron transfer fro" *u to 0+or :xidation9 :xidation nu"ber of *u increase fro" $ to 2Heduction9 :xidation nu"ber of 0+- decrease fro" -1 to $ Heaction ''' :xidation9 6n loses electron to for" 6n2Heduction9 24- +ain electron to for" 42 or :xidation9 :xidation nu"ber of 6n increase fro" $ to 2Heduction9 :xidation nu"ber of 4- decrease fro" -1 to $ )) Electron transfer fro" 6n to 4(b)(i) (ii) =ro"ine ,ater er"inal ne+ati(e positi(e 4alfB e1uation 3e2- 3e>- - e =r2 - 2e 2=rB :bser(ation ?reen to bro,n).ello, bro,n to colourless )decolourises Mark Mark 1-1 1

1-1

1-1 1 1-1 1-1

Max 7

(iii)

(d)

Ara, out 1 c"> of t!e solution fro" ter"inal ne+ati(e into a test tube. 0dd Na:4 ) N4> solution ) @otassiu" 4exanoc.anoferrate('') solution to t!e test tube :bser(ation9 =ro,n ppt ) bro,n ppt ) dark blue ppt respecti(el.. <!o,s t!at iron('') ion is c!an+ed ) oxidised to iron(''') ion

1 1 1 >

Ener+. c!an+e

Electrolytic Cells Electrical ener+. *!e"ical ener+.

Chemicals Cells *!e"ical Ener+. Electrical Ener+.

1-1

Trial Johor 2008

1> 4alfBe1uation at anode Electron flo, *u *u2- - 2e Electrons flo, fro" anode to cat!ode. 6n 6n2- - 2e Electrons flo, fro" 5inc to copper.)

1-1 1-1 7

/ B1 if students does not construct a table 2 Total marks 20

ENA :3 M0HP'N? <*4EME

Trial Johor 2008