The Al-Noor Post Graduate College Tail-Wala

Test: Organic Chemistry Marks: 17 Chapter:7-13

Time:20 mint

SECTION I
Q#1. Select The Most Suitable Option. I. II. III. IV. V. VI. VII. Which types of reactions are given by alkanes? a) Polymerization b) elimination c) substitution d) Addition 0 Benzene on catalytic oxidation at 500 c with V2O5 gives a) Benzoic acid b) Maleic acid c) Maleic anhydride d) Acetylene Which one is used as dehydrating agent for alcohol a) H2SO4 b) Al2O3 c) c) H3PO4 d) All Bakelite is obtained from phenol by reacting with a) Acetaldehyde b) Formaldehyde c) Chlorobenzene d) Acetone Acetic acid reacts with LiAlH4 to give a) C2H6 b) C2H7OH c) C2H5OH d) CH3OH When calcium carbide is treated with water we get a) Ethyne b) ethane c) Ethene d) ethanol SN2 reactions are given by a) Primary alkyl halide b) Secondary alkyl halide b) Tertiary alkyl halide d)Primary alcohols Tetraethyl lead is added to petrol to a) prevent its freezing point b) increase its boiling point b) prevent its knocking d) increase its viscosity The presence of double bond in a compound is viscosity. a) Saturated b) unsaturation c) substitution d) dehydrogenation Ethyl chloride reacts alcoholic KOH to give a) C2H4 b) C2H4OH c) C2H6 d) C2H4O Organic compounds having fruity smell are a) Carboxylic acids b) esters c) alcohols d) ether Which of the following is a heterocyclic compound a) Naphthalene b) Anthracene c) pyridine d) Nitrobenzene Which of the following reagent will react with both aldehyde and ketone a) Tollens reagent b) Benedicts reagent b) Grignard reagent d) Fehling solutions reagent preparation of vegetable ghee involves a) Halogenation b) hydrogenation c) hydroxylation d) dehydration Ethanol can be converted into ethanioc acid by a) hydrogenation b) hydration c) oxidation d) fermentation Which of the following can be used as catalyst in fridal craft reaction a) HNO3 b) BeCl2 c) NaCl d) AlCl3 Linear shape is associated with which set of hybrid group orbitals a) SP b)SP2 c) SP3 d) dsp2

VIII.

IX. X. XI. XII. XIII.

XIV. XV. XVI. XVII.

SECTION II
I. II. III. IV. V. VI. VII. VIII. IX. X. XI. XII. I. II. III. IV. Attempt any Eight Questions interpret that cis-trans isomerism is only possible in there compounds which contain double and. Ethylene glycol is obtained by the oxidation of ethane give reaction. How unsaturation is identify. give chemical reactions Give the chemical equation for the conversion of benzene into Maleic acid. Give best method for preparation of alkly halide. Give general mechanism of SN1reaction Why alcohols are miscible with water. Phenol is acidic but alcohol is not. Explain. What is nitroprusside test? For what purpose it use? How acetone react with (a) hydrazine (b) hydroxylamine. How mustard gas can be prepared? What happen when benzene is react with oxygen in presence of V2 O5 Attempt any Eight Questions What are functional group and functional group isomerism What is Baeyer test? Give its use How will you distinguish between an alcohol and phenol by chemical reaction?

V.
VI.

VII.
VIII. IX. X. XI. XII.

How Bakelite is prepared from phenol. Write difference between SN1& SN2 reactions. What is silver mirror test Draw the possible resonance structures for benzene

Give the use of Formaldehyde and Acetaldehyde? Give a chemical test to differentiate between aldehyde and Ketone. Describe chemistry of Fehlings solution. What are Canizaro reactions? What is a peptide bond? Write the formula of dipeptide? Attempt any Six Questions I. How does formaldehyde react with NaHSO3 II. Give a test to differentiate between Methanol and Ethanol? III. What is Glacial acetic acid? IV. Alcohols react with concentrated H2So4 and give different products at different temperature. V. What is formaline? VI. Defile the following terms a) Absolute Alcohal b) Methylated spirit, c) Denaturing of Alcohal? VII. What is Raney Nickel and how it can be prepared? VIII. How hexane and Heptane can be converter to Benzene? IX. Convert Alkyl halides to Propanic Acid Q#3 Attempt any 3 1. a) Prepare Ethene by Kolbs method and also give mechanism of the mechanism. b) What products are products are formed when the following compounds are treated with ethyl magnesium bromide following by hydrolysis (i) HCHO (ii) CH3CHo (iii) Co2 2. a) Explain Sp2 hybridization. Give one example b) How benzene is converted into acetophenone. Give its one mechanism. 3. a) Give mechanism of Canizaro reaction. b) What is meant by aromatic hydrocarbon? How aromatic hydrocarbons are classified. Give at least one example. 4. a) How propyne react with (i) H2O (ii) CuCl2/NH4 OH b) How does aldehyde react with (i) I2/NaOH (ii) NaHSO3 5. a) What are a-amino acid? Show amino acids have acidic as well as basic properties. b) Describe the halogenations of alkane.

Practical Portion
1. How Sodium Extract solution can be prepared and give identification test for nitrogen and Halogens 2. How Aspirin Can be prepared

a) b) Q#06: a) b) Q#07: a) b) Q#08: a) b) Q#09: a) b)

i. ii.