Mass & Heat Balance - Existing Feed Flowrate

Colour Key Mannual Input Select number for Hlookup function Reads value from the Hlookup cells Important Results Heat Imbalance/doubts UNITS Maximum feed rate [without caustic] % Caustic addition Total Feed Rate UNITS 15 T/hr 10% 16.5 T/hr 16,500 kg/hr Steam flowrate Feed composition: Water NH3 Water NH3 SELECT input number from 1 to 10 4 3.2 T/hr 3,200 kg/hr 85% by wt% 15% by wt% 10% by wt% 90% by wt% 70 oC Given at 1.4barg, at 126 deg C Given Given Total heat input in the stripper Stripper top composition: Given Given Average from Plant Data between 60 to 80 deg C HEAT OUT HEAT IN Heat in with steam Heat in with feed = = NOTES Given Given Sensible heat with feed@feed temperature = Total heat of inlet steam@stripper bottom temp =

text

Stripper top temperature Total heat at stripper TOP temperature Sensible heat at stripper TOP temperature Bottom Target for NH3 Weight %

Bottom : Sensible heat of water at column bottom temperature Total heat out with bottom stream

2626.3 293 Average from Plant Data between 200 to 330 ppm

= =

350 ppm by wt 0.035 by wt%

Top: Total heat of water at stripper top temperature

Stripper bottom composition:

Water

99.965% by wt%

NH3 Stripper bottom temperature Total heat at stripper BOTTOM temperature Sensible heat at stripper bottom temperature SELECT input number from 1 to 10 SELECT input number from 1 to 10 5

0.035% by wt% 105 oC 2683 439 Average from Plant Data

Total heat out with top stream

Total heat output from the stripper DIFFERENCE of heat IN and OUT Difference of heat IN and heat OUT

Feed temperature Sensible Heat at the boiling temperature

45 oC 188

Given

Taking NH 3 and water balance around ammonia stripper

2475 = 17225 =

90% Y+ 10% Y+

0.035% X -----------------Equation (1) 99.965% X -----------------Equation (2)

Where, X and Y are the total mass flowrate at bottom and top of ammonia stripper ( kg/hr ) Solving simultaneous equation (1) and (2) Coefficients 90% 10% 0.035% 99.965% Constants 2475 17225 Solution Y X 2,743 16,957 Unit kg/hr kg/hr

Mass flowrate of water and NH3 in with feed (In Feed) Mass flowrate of water Mass flowrate of NH3 TOTAL = = 14,025 2,475 16,500 kg/hr kg/hr kg/hr F

Mass flowrate of water and NH3 in vapour phase (Top of stripper) Mass flowrate of water Mass flowrate of NH3 TOTAL = = 274 2,469 2,743 kg/hr kg/hr kg/hr Y

Mass flowrate of water and NH3 in liquid phase (bottom of stripper) Mass flowrate of water Mass flowrate of NH3 TOTAL = = 16,951 6 16,957 kg/hr kg/hr kg/hr X

HLOOKUP FUNCTION TABLE FOR TOTAL HEAT AT DIFFERENT STRIPPER TOP TEMPERATURE/PRESSURE Input Number Temperature Total Heat Sensible Heat Absolute Pressure 1 55 2600.3 230.2 N/A 2 60 2609 251.1 N/A 3 65 2617.7 272 N/A 4 70 2626.3 293 N/A 5 75 2634.7 313.9 N/A 6 80 2643.2 334.9 N/A 7 85 2651.5 355.9 N/A 8 90 2659.7 376.9 0.7011 9 102 2680 429 1.1

C kJ/kg kJ/kg Bara

HLOOKUP FUNCTION TABLE FOR TOTAL HEAT AT DIFFERENT STRIPPER BOTTOM TEMPERATURE/PRESSURE Input Number Temperature Total Heat Sensible Heat Absolute Pressure 1 90 2659.7 376.9 0.7011 2 95 2667.8 398 0.8453 3 100 2675.8 419.1 1.01325 4 102 2680 429 1.1 5 105 2683 439 1.2 6 107 2687 449 1.3 7 109 2690 458 1.4 8 111 2693 467 1.5 9 117 2702 491 1.8

C kJ/kg kJ/kg Bara

HLOOKUP FUNCTION TABLE FOR SENSIBLE HEAT AT DIFFERENT FEED TEMPERATURE Input Number Temperature Sensible Heat Absolute Pressure 1 30 125.7 N/A 2 35 147 N/A 3 40 167.5 N/A 4 45 188 N/A 5 50 209.3 N/A 6 55 230.2 N/A 7 60 251.1 N/A 8 65 272 N/A 9 80 334.9 N/A

C kJ/kg Bara

2,683 kJ/kg

This is at stripper bottom temperature. Should I consider this at steam pressure 1.4barg [i.e. 2715 kJ/kg]?

188 kJ/kg

8,585,600 kJ/hr 3,102,000 kJ/hr 11,687,600

439 kJ/kg 7,444,095 kJ/hr

2,626 kJ/kg

3,356,622 kJ/hr

10,800,717 kJ/hr

886,883 kJ/hr

Heat Imbalance?

10 105 2683 439 1.2

10 119 2704 498 1.9

10 85 355.9 N/A

HEAT CAPACITY AT COLUMN BOTTOM TEMPERATURE

Heat Capacity of Liquid, Cp = A+BT+CT2+DT3
t(C) Water NH3 105 105 T (K ) 378.15 378.15 A 92.053 -182.157 B -0.03995 3.3618 C D

-0.000211 5.3469E-07 -0.014398 0.000020371

Average Cp ( kJ/kg K)

HEAT CAPACITY AT COLUMN TOP TEMPERATURE

Heat Capacity of Gas, Cp = A+BT+CT2+DT3+ET4

Where,

Cp = joules/mol K T =K

t(C) Water NH3 70 70

T (K ) 343.15 343.15

A 33.933 33.573

B -0.00842 -0.01258

C 2.991E-05 8.891E-05

D -1.7825E-08 -7.18E-08

E 3.6934E-12 1.86E-11

Average Cp ( kJ/kg K)

Colour Key Mannual Input Values pulled from 'Mass & Heat Balance Sheet'

Cp (joules/mol K) 75.68 131.78

Molecular Weight (g/mol) 18.00 17.03

Cp Bottom conc Composition Partial Cp (kJ/kg (ppm) (%) (kJ/kg K) K) 4.20 N/A 99.965 4.20 7.74 350 0.035 0.00271 4.21

Cp (joules/mol K) 33.90 37.08

Molecular Weight (g/mol) 18.00 17.03

Cp Composition (kJ/kg (%) K) 1.88 10% 2.18 90%

Partial Cp (kJ/kg K) 0.19 1.96 2.15

Colour Key Mannual Input Values pulled from 'Mass & Heat

Heat of Vaporisation, Hvap= A(1-T/Tc)n

Where, Hvap = kJ/mol T =K A,Tc and n are regression coefficients for NH3 A= Tc= n= t= T= Molecular Wt, M= Hvap= Hvap= 31.523 405.65 K 0.364 70 343.15 K 17.03 g/mol 15.96 kJ/mol 937.01 kJ/kg

ulled from 'Mass & Heat Balance Sheet'