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Models of multiphase flow in porous media, including fluid-fluid interfaces S. Majid Hassanizadeh
Department of Earth Sciences, Utrecht University, Netherlands Soil and Groundwater Systems, Deltares, Netherlands Collaborators: Vahid Joekar-Niasar; Shell, Rijswijk, The Netherlands Nikos Karadimitriou; Utrecht University, The Netherlands Simona Bottero; Delft University of Technology, The Neth. Jenny Niessner; Stuttgart University, Germany Rainer Helmig; Stuttgart University, Germany Helge K. Dahle; University of Bergen, Norway Michael Celia; Princeton University, USA Laura Pyrak-Nolte; Purdue University, USA
Original Darcys law was proposed for 1D steady-state flow of almost pure incompressible water in saturated homogeneous isotropic rigid sandy soil under isothermal conditions
h x h =p / g + z q = -K
Extended Darcys law is assumed to apply to 3D unsteady flow of two or more compressible fluids, with any amount of dissolved matter, in heterogeneous anisotropic deformable porous media under nonisothermal conditions
h qi = - K ij x j h =p / g + z
We have added bells and whistles to a simple formula to make it (look more complicated and thus) applicable to a much more complicated system! One must follow a reverse process: - develop a general theory for a complex system - reduce it to a simpler form for a less complex system
kr
K( P g)
c Pn Pw = f ( S w ) = P
k r = k r ( S w )
Pext -Pext
Oil chamber
n Pext
Porous Medium
w Pext
Wetting curve
Scanning wetting curve
* * *
Often it takes more than one week to get a set of wetting and drying curves
Air chamber PPT NW back PPT W front Soil sample Water Hassanizadeh, Oung, and Manthey, 2004 PCE
Pc-S Curves
10 Static Pc inside
-2 0
0.1
0.2
0.3
0.4
Saturation, S
Hassanizadeh, Oung, and Manthey, 2004
0.7
0.8
0.9
0 P.drain Pair~16kPa P.drain Pair~20kPa P.drain Pair~25kPa -2 0 0.1 0.2 0.3 0.4 0.5 0.6 water saturation 0.7 0.8 0.9 1
Saturation, S
Hassanizadeh, Oung, and Manthey, 2004
M.drain PN~16kPa M.drain PN~20kPa M.drain PN~25kPa M.drain PN~30kPa 0.2 0.3 0.4 0.5 water saturation 0.6 0.7 0.8 0.9
-2 0.1
Saturation, S
Hassanizadeh, Oung, and Manthey, 2004
-2 0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
Dyn.M.D.
6.0
Dyn.P.D.
4.0
S.M.I. Dyn.M.I.
S.M.D. S.P.D.
2.0
-2.0 0
0.20
0.80
1.00
Saturation, S
Primary Imbibition Curve Main Imbibition Curve Main Scanning Imbibition Curves Secundary Scanning Imbibition Curves Dynamic Imbibition Curves
Saturation, S
Water and oil relative permeabilities in 43 sandstone reservoirs plotted as a function of water saturation; Berg et al. TiPM, 2008
Standard theory does not model the development of vertical infiltration fingers in dry soil
Non-monotonic distribution of saturation during infiltration into dry soil; experiments in our gamma system
Sand Column dia 1 cm 50 cm
Non-monotonic distribution of saturation during infiltration into dry soil; experiments in our gamma system At different flow rates q (in cm/min)
Saturation at a depth of 20 cm
Time (sec)
Non-monotonic distribution of pressure during infiltration into dry soil; experiments in our gamma system Pressure at different positions along the column
pressure
Time (sec)
Outline
Thermodynamic basis for macroscacle theories of twophase flow in porous media Experimental and computational determinations of capillary pressure under equilibrium conditions Experimental and computational determinations of capillary pressure under non-equilibrium conditions Non-equilibrium capillarity theory for fluid pressures Truly extended Darcys law
Averaging-Thermodynamic Approach
First, a microscale picture of the porous medium is given: Porous solid and the two phases form a juxtaposed superposition of three phases filling the space and separated by three interfaces: solid-water, water-oil, solid-oil, and a water-oil-solid common line. There is mass, momentum, energy associated with each domain.
Averaging-Thermodynamic Approach
First, a microscale picture of the porous medium is given: Porous solid and the two phases form a juxtaposed superposition of three phases filling the space and separated by three interfaces: solid-water, water-oil, solid-oil, and a water-oil-solid common line. Microscale conservation equations for mass, momentum, and energy are written for points within phases or points on interfaces and the common line. These equations are averaged to obtain macroscale conservation equations. No microscopic constitutive equations are assumed.
Averaging-Thermodynamic Approach
First, a microscale picture of the porous medium is given: Porous solid and the two phases form a juxtaposed superposition of three phases filling the space and separated by three interfaces: solid-water, water-oil, solid-oil, and a water-oil-solid common line. Microscale conservation equations for mass, momentum, and energy are written for points within phases or points on interfaces and the common line. These equations are averaged to obtain macroscale conservation equations. No microscopic constitutive equations are assumed. Macroscopic constitutive equations are proposed at the macroscale and restricted by 2nd Law of Thermodynamic.
) +
q ) =
r
,
S n + q = 0 t
+ ( a w ) = r , + r ,
( a ) t
Divide by a constant :
a + ( a w ) = E t
H is macroscopic Helmholz free energy, which depends on state variables such as Sw, a, , T, etc.
P c = F ( S w , a wn ) or a wn = F ( P c , S w )
? n P = P Pw
c
P = (
n
n 2
H n n
P = (
w
w 2
H w w
Imbibition
Capillary pressure head, Pc/g Capillary pressure head, Pc/g
Drainage
Saturation
Saturation
Capillary pressure and saturation are two independent quantities Imbibition Drainage
Capillary pressure
Saturation
Capillary pressure
Saturation
Pore body
Pore throat
R2=0.98
Joekar-Niasar et al. 2008
Pc-Sw-awn Surface
A micro-model (made of PDMS) with a length of 35 mm and width of 5 mm; It has 3000 pore bodies and 9000 pore throats with a mean pore size of 70 m and constant depth of 70 m
Karadimitriou et al., 2012
The average difference between the surface for drainage and the surface with all the data points is 9.7%. The average difference between the surface for imbibition and the surface with all the data points is 5.77%.
The coefficient is a material property which may depend on saturation. It has been determined through column experiments, as well as computational models, by many authors.
S n + q = 0 t 1 q = K ( P g)
S w P P = P t
n w c
u u 2u = D + t x x x xt
Development of vertical wetting fingers in dry soil; Simulations based on dynamic capillarity theory
Experimental Set-up for measurement of dynamic capillarity effect; Bottero et al., , 2011
Pressure Regulator
Brass filter
PCE
TDR3 TDR2 TDR1
Water Air
No membranes Steady-state flow of invading fluid with incremental pressure increase Primary drainage Main drainage Main imbibition Transient drainage with large injection pressure
Pressure transducer
Water Pump
Differential pressure
S w P P = P t
n w c
Bottero, 2009
q = K i( G g )
where G is the Gibbs free energy of a phase:
G = G ( , a wn , S , T )
q =
kr
Ki( P g aawn SS )
G wn = G wn ( , a wn , S , T )
q =
a wn S K P g a S ( )
S n + q = 0 t
a wn + ( a wn w wn ) = E wn t
wn wn wn w w wn = K wn a + S
S w P P = P t
n w c
P c = f ( S w , a wn )
Equilibrium moisture distribution from standard two-phase flow equations with no hysteresis
Sw
Initial distribution
Final distribution
x interface
S n + q = 0 t 1 q = K P
Pn P w = fd ( S w )
P n P w = fi ( S w ) if
if
S <0 t
S >0 t
q =
a wn S K p g a S ( )
S n + q = 0 t
a wn + ( a wn w wn ) = E wn ( a wn , S w ) t
wn wn wn w w wn = K wn a + S
S w p p = P t
n w c
P c = f ( S w , a wn )
CONCLUSIONS
Under nonequilibrium conditions, the difference in fluid pressures is a function of time rate of change of saturation as well as saturation. Resulting Eq. will lead to nonmonotonic solutions. Fluid-fluid interfacial areas should be included in multiphase flow theories. Hysteresis can be modelled by introducing interfacial area into the two-phase flow theory
q =
kr
K ( p g aawn SS )
kr p q K q g) ( r = k K=
p / x
q =
kr
K ( p g aawn SS )
q =
kr
K ( p g aawn SS )
Rate of generation/destruction of interfacial area as a function of saturation and rate of change of saturation
CONCLUSIONS
The driving forces in Darcys law should be gradient of Gibbs free energy and gravity. Difference in fluid pressures is equal to capillary pressure but only under equilibrium conditions. Under nonequilibrium conditions, the difference in fluid pressures is a function of time rate of change of saturation as well as saturation. Fluid-fluid interfacial areas should be included in multiphase flow theories. Hysteresis can be modelled by introducing interfacial area into the two-phase flow theory
Development of vertical wetting fingers in dry soil; Simulations based on new capillarity theory
Development of vertical wetting fingers in dry soil; Simulations based on new capillarity theory
Dynamic Capillary Pressure Mechanism for Instability in Gravity-Driven Flows; Review and Extension to Very Dry Conditions; JOHN L. NIEBER, RAFAIL Z. DAUTOV, ANDREY G. EGOROV, and ALEKSEY Y. SHESHUKOV; TiPM Stability analysis of gravity-driven infiltrating flow; Andrey G. Egorov, Rafail Z. Dautov, John L. Nieber, and Aleksey Y. Sheshukov
indicating calliper
pamb
pwater
green: hydrophilic membrane grey: sealing dotted: sample (GDL) red: hydrophobic membrane blue: syringe pump
400
period II 1 200
period I: initial state period II: pumping water into the sample period III: relaxation period
Micromodel experiments
(a) (b)
(a)
(b)
J.-T. Cheng, L. J. Pyrak-Nolte, D. D. Nolte and N. J. Giordano, Geophysical Research Letters, 2004