I. TITTLE: Preparation of Making 250 mL AgNO3 0,1N from AgNO3 (s) II. DATE OF EXPERIMENT: 26th, Fe r!

ar" 201# III. OBJECTIVE: $o make so%!tion of 250 mL AgNO3 0,1N from AgNO3 (s) IV. BASIC THEORY:
A. The solutio s !"e#te$ s%e!i&i!#ll' #"e: 1. Preparation " mi&ing 5 m% of romine in 100 m% of 'ater ((aref!%%")) $he so%!tion

o taine* is sat!rate* so%!tion 'ith a (on(entration of appro&imate%" 0)25M)

2. +tar(h 'ater

Preparation is " taking 1g star(h an* heate* 'ith 100 m% of 'ater 'hi%e stirring) A** a sma%% (r"sta% of io*i*e so *!ra %e so%!tion)
3. Lime 'ater (,a%(i!m -"*ro&i*e)

Preparation is " entering into a eaker g%ass !p to as high as appro&imate%" 5 (m) A** to . f!%% of 'ater, stir an* %et it sett%e) After the other part *oes not fa%% to the ottom, po!r the (%ear part into the ott%e (aref!%%" so as not to e(ome t!r i*, or fi%tere* 'ith (otton)
4. ,h%orine 'ater

Preparation is " f%o'ing (h%orine gas into the 'ater !p to a sat!rate* so%!tion (appro&imate%" 0)1 M))
5. +ea /ater

$o rep%a(e the sea 'ater (an e ma*e " mi&ing a so%!tion of #5 g so*i!m (h%ori*e, 3)5 g of magnesi!m s!%fate) 5 g of magnesi!m (h%ori*e, 2 g of potassi!m s!%fate, 0)2 g of potassi!m romi*e in 2 %iters of 'ater)

6) Ammoni!m Mo%" *ate Preparation is " *isso%0ing 15 g of ammoni!m mo%" *ate in 10 m% of ammonia 0,110 an* 5 m% of 'ater) 2i%!te to 0o%!me to 100 m%, a** 100 m% of 5 M nitri( a(i* an* stirre* s%o'%") $he so%!tion (on(entration 'as 0)5 M)
7. 3ron (333) (h%ori*e

$o pre0ent h"*ro%"sis of ea(h 1 %iter so%!tion of 0)16 M (0)5 N) iron (333) (h%ori*e is a**e* to #0 m% of (on(entrate* h"*ro(h%ori( a(i*)
8. 3ron (33) +!%fate

3n making this so%!tion !se *isti%%e* 'ater ne'%" oi% an* then (oo%e* so that the so%!tion *oes not (ontain *isso%0e* o&"gen)
9. -"*rogen Pero&i*e

Preparation is " *i%!ting 100 m% of 10 0o%!me h"*rogen pero&i*e 'ith 40 m% of 'ater)

10. ,a%(i!m ("anoferrate (333)

Preparation is to 'ash the (r"sta%s 'ith 'ater efore it *isso%0e*) 5asi%" *e(ompose *!ring storage) 11) ,"anoferrat ,a%(i!m (33) $his s! stan(e is easi%" o&i*i6e*) ,an pre0ent " inserting a (%ean iron into so%!tion) 12) ,r!*e oi% ( (r!*e ) Preparation " mi&ing 35 m% of kerosene, gaso%ine 20 m% oi% 15 m% +A5 7 10 , +A5 7 50 oi% 15 m%, 10 m% gas 'ashing an* a it of tar ) 13) +i%0er nitrate 8se *isti%%e* 'ater to *isso%0e9 :e(a!se tap 'ater !s!a%%" (ontains %ess (h%ori*e 'hi(h makes the so%!tion (%o!*") 1#) :arfoe* reagent Preparation " mi&ing 13)3 g of (opper ( 33 ) a(etate an* 2 m% of g%a(ia% a(eti( a(i* ) A** 'ater !p to 200 m% so%!tion )

15) :ene*i( reagent Preparation " mi&ing 1;)3 g of (opper ( 33 ) s!%phate (r"sta%s , 1;)3 g of so*i!m nitrate an* 100 g of anh"*ro!s so*i!m (ar onate ) 2isso%0e in 'ater !p to 1 %iter of so%!tion ) 16) :i!ret reagent Preparation is " *isso%0ing 0);5 g of (r"sta%s of (opper (33) s!%fate in 1 %iter of 2 M potassi!m h"*ro&i*e ) 1;) Mi%%on reagent Preparation is " *isso%0ing 100 g of mer(!r" in 200 m% of (on(entrate* nitri( a(i* " heating in a f!me (!p oar*, (o%* ) Po!re* #00 m% of 'ater )
18. Mo%is(h reagent

Preparation is " *isso%0ing 5 ga naphtho% in 100 m% of ethano%)

19. Ness%er reagent

Preparation is " *isso%0ing 35 g of potassi!m io*i*e in 'ater) Mo0e this so%!tion into por(e%ain *ash, then a** the fine%" po'*ere* mer(!r" (33) (h%ori*e 12)5 g) ,r!sh !nti% so%! %e) $hen po!r into a eaker an* a** a sat!rate* so%!tion of mer(!r" (33) (h%ori*e to form a pre(ipitate) $hen a** 120 g of so*i!m h"*ro&i*e so%!tion an* make to 1 %iter)
20. +(hiff rea(tion

Preparation is " *isso%0ing 0)5 g in 500 m% of 'ater F!hsin) Fa*e the (o%or so%!tion " f%o'ing s!%f!r gas)
21. +e%i'anoff reagent

Preparation is " *isso%0ing 0)5 g of resor(ino% (1,37 en6ene *io%) 'ith 1 %iter of h"*ro(h%ori( a(i* 3 M)
22. $o%ens <eagents= (amoniaka% si%0er nitat)

Preparation is " a**ing 3 *rops of 2 N NaO- in 5 m% of 0)2 M si%0er nitrate, ammoni!m h"*ro&i*e is then a**e* to a so%!tion right a'a")

23. $in (33) (h%ori*e

Preparation is " heating 11)3 g of tin (h%ori*e in 20 m% of (on(entrate* h"*ro(h%ori( a(i*, a** a fe' sma%% pie(es of tin, then a** 'ater !nti% the 0o%!me of so%!tion to 100 m%) $he so%!tion (on(entration 'as 0)5 M (1 N))
24. A(etate %ea*

Preparation is " a**ing a so%!tion of potassi!m io*i*e to a so%!tion of %ea* asetaten(er to pre0ent h"*ro%"sis an* maintain the (%arit" of the so%!tion)
25. >o* (L!go%)

Preparation in a so%!tion of potassi!m io*i*e for io*ine so%! %e in 'ater) Preparation is " *isso%0ing 12); g of io*ine an* 20 g of potassi!m io*i*e in 100 m% of 'ater)

B. I $i!#to" 1) Pheno%phta%ein (PP) Preparation is " *isso%0ing 1 g of so%i* PP in 250 m% of ethano%, then a so%!tion ma*e " a**ing 500 m% of 'ater) <o!te from 1)# to 10)0 (o%or%ess (o%or (hange from p!rp%e to re*) 2) Meth"% Orange (MO) Preparation is " *isso%0ing 1 g of the so%i* in 500 m% of a%(oho% 45?) ,hange (o%ors= <e*7>e%%o') <o!te = p- 2)1 to #)6) 3) Litm!s Preparation is " heating 10 g Litm!s (a6o%itmin) 'ith 500 m% of 'ater for a o!t ha%f an ho!r) A%%o' the so%!tion to stan* for 2 ho!rs, then fi%tere*) 3f "o! nee* the (o%or p!rp%e so%!tion ma*e " a**ing a fe' *rops of *i%!te nitri( a(i*) Litm!s so%!tion sho!%* e store* in a @ar 'ith a %i* %oose%" so air (an enter) :e(a!se if no so%!tion (an e easi%" *amage* air)

#) Meth"% <e* (MM) Preparation is " *isso%0ing 1 g of the so%i* in 500 m% of a%(oho% 45?) ,hanges in re* (o%or 7 "e%%o') <o!te p- #)# to 6)0) 5) >ama*a 8ni0ersa% 3n*i(ator Preparation " mi&ing 0)25 g :romtimo% %!e), 025 g $h"mo% %!e, 0)0625 g of meth"% re*, an* 0)5000 g Pheno%phta%ein) $hen the mi&t!re 'as *i%!te* 'ith 500 mL of ethano%, an* then *i%!te the so%!tion 'ith 'ater to a 0o%!me of 1 %iter) ,o%or (hanges <e* Orange >e%%o' Areen :%!e 2ark %!e P!rp%e p# 5 6 ; 1 4 10

6) :!ffer so%!tion :!ffer so%!tion is a so%!tion if the (on(entration of h"*rogen ions or h"*ro&"% ions a**e*, the p- of the so%!tion *oes not (hange) A s"stem t"pi(a%%" (onsists of a !ffer so%!tion of a 'eak ase an* a sa%t of the ase) :!ffer so%!tion 'ith a p- et'een 2)2 to 1)0 $o make 100 m% of !ffer so%!tion, a** 0)2 M Na2-PO# at 0)1 M (itri( a(i* 'ith a ratio= %H 2,2 2,# 2,6 2,1 3,0 N#(HPO) *+l, 2,00 6,20 10,40 15,15 20,55 Cit"i! #!i$ *+l, 41,0 43,10 14,10 1#,15 ;4,#5 %H 5,2 5,# 5,6 5,1 6,0 N#(HPO) *+l, 53760 55,;5 51,00 60,#5 63,15 Cit"i! #!i$ *+l, #6,#0 ##,25 #2,00 34,#5 36,15

3,2 3,# 3,6 3,1 #,0 #,2 #,# #,6 #,1 5,0

2#,;0 21,50 32,10 35,50 31,55 #1,#0 #5,10 #6,;5 #0,30 51,50

;5,30 ;1, 50 6;,10 6#,50 61,#5 51,60 55,40 53,25 50,;0 #1,50

6,2 6,# 6,6 6,1 ;,0 ;,2 ;,# ;,6 ;,1 1,0

66,10 64,25 ;2,;5 ;;,25 12,35 16,45 41,15 43,65 45,;5 4;,5

33,40 30,;5 2;,25 22,;5 1;,65 13,05 4,15 6,35 #,25 2,;5

M#te"i#l S#&et' D#t# Sheet Sil-e" it"#te MSDS Se!tio .: Che+i!#l P"o$u!t # $ Co+%# ' I$e ti&i!#tio P"o$u!t N#+e: +i%0er nitrate S' o '+: L!nar (a!sti(B +i%0er (1C) nitrateB Nitri( a(i*, si%0er (1C) sa%t Che+i!#l N#+e: +i%0er Nitrate Che+i!#l Fo"+ul#: AgNO3 Se!tio (: H#/#"$s I$e ti&i!#tio Pote ti#l A!ute He#lth E&&e!ts: Der" ha6ar*o!s in (ase of skin (onta(t (irritant), of ingestion) -a6ar*o!s in (ase of skin (onta(t (permeator), of e"e (onta(t (irritant), of inha%ation) +%ight%" ha6ar*o!s in (ase of skin (onta(t ((orrosi0e)) $he amo!nt of tiss!e *amage *epen*s on %ength of (onta(t) 5"e (onta(t (an res!%t in (ornea% *amage or %in*ness) +kin (onta(t (an pro*!(e inf%ammation an* %istering) 3nha%ation of *!st 'i%% pro*!(e irritation to gastro7intestina% or respirator" tra(t, (hara(teri6e* " !rning, snee6ing an* (o!ghing) +e0ere o0er7e&pos!re (an pro*!(e %!ng *amage, (hoking, !n(ons(io!sness or *eath) Pro%onge* e&pos!re ma" res!%t in skin !rns an* !%(erations) O0er7 e&pos!re " inha%ation ma" (a!se respirator" irritation)

Pote ti#l Ch"o i! He#lth E&&e!ts: ,A<,3NOA5N3, 5FF5,$+= Not a0ai%a %e) M8$AA5N3, 5FF5,$+= Not a0ai%a %e) $5<A$OA5N3, 5FF5,$+= Not a0ai%a %e) 25D5LOPM5N$AL $OE3,3$>= Not a0ai%a %e) $he s! stan(e is to&i( to %!ngs) $he s! stan(e ma" e to&i( to m!(o!s mem ranes, skin, e"es) <epeate* or pro%onge* e&pos!re to the s! stan(e (an pro*!(e target organs *amage) <epeate* e&pos!re of the e"es to a %o' %e0e% of *!st (an pro*!(e e"e irritation) <epeate* skin e&pos!re (an pro*!(e %o(a% skin *estr!(tion, or *ermatitis) <epeate* inha%ation of *!st (an pro*!(e 0ar"ing *egree of respirator" irritation or %!ng *amage) Se!tio 0: Fi"st Ai$ Me#su"es E'e Co t#!t: ,he(k for an* remo0e an" (onta(t %enses) 3n (ase of (onta(t, imme*iate%" f%!sh e"es 'ith p%ent" of 'ater for at %east 15 min!tes) ,o%* 'ater ma" e !se*) Aet me*i(a% attention) S1i Co t#!t: 3n (ase of (onta(t, imme*iate%" f%!sh skin 'ith p%ent" of 'ater for at %east 15 min!tes 'hi%e remo0ing (ontaminate* (%othing an* shoes) ,o0er the irritate* skin 'ith an emo%%ient) ,o%* 'ater ma" e !se*)/ash (%othing efore re!se) $horo!gh%" (%ean shoes efore re!se) Aet me*i(a% attention imme*iate%") Se"ious S1i Co t#!t: /ash 'ith a *isinfe(tant soap an* (o0er the (ontaminate* skin 'ith an anti7 a(teria% (ream) +eek imme*iate me*i(a% attention) I h#l#tio : 3f inha%e*, remo0e to fresh air) 3f not reathing, gi0e artifi(ia% respiration) 3f reathing is *iffi(!%t, gi0e o&"gen) Aet me*i(a% attention) Se"ious I h#l#tio : 50a(!ate the 0i(tim to a safe area as soon as possi %e) Loosen tight (%othing s!(h as a (o%%ar, tie, e%t or 'aist an*) 3f reathing is *iffi(!%t, a*minister o&"gen) 3f the 0i(tim is not reathing, perform mo!th7to7mo!th res!s(itation) /A<N3NA= 3t ma" e ha6ar*o!s to the person pro0i*ing ai* to gi0e mo!th7to7mo!th res!s(itation 'hen the inha%e* materia% is to&i(, infe(tio!s or (orrosi0e) +eek imme*iate me*i(a% attention) I 2estio :

2o NO$ in*!(e 0omiting !n%ess *ire(te* to *o so " me*i(a% personne%) Ne0er gi0e an"thing " mo!th to an !n(ons(io!s person) 3f %arge F!antities of this materia% are s'a%%o'e*, (a%% a ph"si(ian imme*iate%") Loosen tight (%othing s!(h as a (o%%ar, tie, e%t or 'aist an*) Se"ious I 2estio : Not a0ai%a %e)

Se!tio ): Fi"e # $ E3%losio D#t# Fl#++#4ilit' o& the P"o$u!t: Non7f%amma %e) Auto5I2 itio Te+%e"#tu"e: Not app%i(a %e) Fl#sh Poi ts: Not app%i(a %e) Fl#++#4le Li+its: Not app%i(a %e) P"o$u!ts o& Co+4ustio : Not a0ai%a %e) Fi"e H#/#"$s i P"ese !e o& V#"ious Su4st# !es: organi( materia%s, (om !sti %e materia%s E3%losio H#/#"$s i P"ese !e o& V#"ious Su4st# !es: <isks of e&p%osion of the pro*!(t in presen(e of me(hani(a% impa(t= Not a0ai%a %e) <isks of e&p%osion of the pro*!(t in presen(e of stati( *is(harge= Not a0ai%a %e) Fi"e Fi2hti 2 Me$i# # $ I st"u!tio s: Not app%i(a %e) S%e!i#l Re+#"1s o Fi"e H#/#"$s: ,onta(t 'ith (om !sti %e or organi( materia%s ma" (a!se fire) S%e!i#l Re+#"1s o E3%losio H#/#"$s: +i%0er nitrate mi&e* 'ith *r" po'*ere* magnesi!m ma" ignite e&p%osi0e%" on (onta(t 'ith a *rop of 'ater) An e&p%osi0e f!%minate ma" e forme* if si%0er nitrate is mi&e* 'ith a%(oho%s) -igh%" e&p%osi0e is forme* " the a**ition of (a%(i!m (ar i*e to si%0er nitrate so%!tion) Se!tio 6: A!!i$e t#l Rele#se Me#su"es S+#ll S%ill: 8se appropriate too%s to p!t the spi%%e* so%i* in a (on0enient 'aste *isposa% (ontainer) L#"2e S%ill: O&i*i6ing materia%) ,orrosi0e so%i*) +top %eak if 'itho!t risk) 2o not get 'ater insi*e (ontainer) A0oi* (onta(t 'ith a (om !sti %e materia% ('oo*, paper, oi%, (%othing))))) Geep s! stan(e *amp !sing 'ater spra") 2o not to!(h spi%%e* materia%) 8se 'ater spra" to re*!(e 0apors) Pre0ent entr"

into se'ers, asements or (onfine* areasB *ike if nee*e*) ,a%% for assistan(e on *isposa%) :e (aref!% that the pro*!(t is not present at a (on(entration %e0e% a o0e $LD) ,he(k $LD on the M+2+ an* 'ith %o(a% a!thorities)

Se!tio 7: H# $li 2 # $ Sto"#2e P"e!#utio s: Geep (ontainer *r") Geep a'a" from heat) Geep a'a" from so!r(es of ignition) Geep a'a" from (om !sti %e materia%)) 2o not ingest) 2o not reathe *!st) Ne0er a** 'ater to this pro*!(t) 3n (ase of ins!ffi(ient 0enti%ation, 'ear s!ita %e respirator" eF!ipment) 3f ingeste*, seek me*i(a% a*0i(e imme*iate%" an* sho' the (ontainer or the %a e%) A0oi* (onta(t 'ith skin an* e"es) Sto"#2e: Geep (ontainer tight%" (%ose*) Geep (ontainer in a (oo%, 'e%%70enti%ate* area) +eparate from a(i*s, a%ka%ies, re*!(ing agents an* (om !sti %es) +ee NFPA #3A, ,o*e for the +torage of LiF!i* an* +o%i* O&i*i6ers) +ensiti0e to %ight) +tore in %ight7resistant (ontainers)

V. TOOLS AND MATERIALS: Tools +pat!%a (1) /at(h g%ass (1) :a%an(e (1) F!nne% (1) Pipette (1) Do%!metri( f%ask 250mL (1) /ash ott%e (1) VI. PROCED8RE: 1) /eighting AgNO3 (s) for #)25 g in a%an(e " !sing 'at(h g%ass 2) $aking AgNO3 (s) into 0o%!metri( f%ask " !sing f!nne% Materials AgNO3 (s) AF!a*est

3) /ashing the 'at(h g%ass an* f!nne% " !sing 'ash ott%e, so there is no so%i* of AgNO3 that %eft in oth 'at(h g%ass an* f!nne%) #) A**ing aF!a*est into 0o%!metri( f%ask !nti% f!%fi%% H of the f%ask) 5) +haking the 0o%!metri( f%ask !nti% the so%!tion *isso%0e 6) A**ing aF!a*est !nti% the %imite* sign in 0o%!metri( f%ask is rea(he*) ;) $aking the so%!tion that has een ma*e o!t to the other ott%e for so%!tion of AgNO3 0)1N VII. DESI9N OF EXPERIMENT:

VIII. CONCL8SION: 250mL AgNO3 0)1N (an e ma*e " *i%!ting #)25 g AgNO3 in 0o%!metri( f%ask 250mL)

ATTACHMENT Pi!tu"e E3%l# #tio

/eighing AgNO3 so%i*

La e%%ing the so%!tion

C#l!ul#tio : Known: Mr AgNO3 I 164,1; gJmmo% D I 250 mL N I 0)1N Unknown: -o' to make preparation so%!tion of 250mL AgNO3 0)1N from AgNO3 (s)K Solution:

So, mass that nee*e* to *i%!te AgNO3 (s) in 250mL is ).(6 2"#+

LABORATORY OR9ANI:ATION Preparation of so%!tion

Member of Group Ar"sta Ningt"as N!r!% ,hoiri"ah N!r!% -i*a"ah +"ifa +a%ima Lin*a /iriant" +!'iton (11314#002) (11314#006) (11314#00;) (11314#010) (11314#013) (11314#201)

3nternationa% ,hemistr" 5*!(ation 2011

8N3D5<+3$A+ N5A5<3 +8<A:A>A FAG8L$A+ MA$5MA$3GA 2AN 3LM8 P5NA5$A-8AN ALAM

L8<8+AN G3M3A 201#