1

JEE 2013 B.MAT 4 (MAIN) SOLNS

BRILLIANTS FULL SYLLABUS TEST 4

FOR OUR STUDENTS TOWARDS JOINT ENTRANCE EXAMINATION, 2013

PHYSICS MATHEMATICS CHEMISTRY SOLUTIONS

PART A : PHYSICS

v cm =
1. (1) When the rod is in horizontal position, its total mechanical

L 2

3g L

energy is K.E. + P.E Here K.E. = 0 but

P.E. = Mg L relative to the lowest 2

1 3gL 2

position of its centre of mass, when position

P.E. = 0 and K.E. = 1 2 I 2

The velocity of the lowest position on the rod has a velocity 2v cm = 3gL Now
3 x 10 x L = 6 (given)

the

rod

is

in

vertical

3 x10 L = 36 L = 1.2 m

2. (2)

where I is the moment of inertia. By law of conservation of energy

1 1 MgL = I 2 2 2
= 11 mL2 2 2 3
3g L

velocity of the centre of mass is

When the rod makes an angle with the vertical, the forces acting on the rod are

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IIT/BMAT4/PMC(MAIN)/Solns - 1

2
(1) weight mg (2) normal reaction R and (3) tangential friction force F Taking moments about O we have
L = mg sin = I0 2

3. (3) The angular acceleration

= 120t 2 48t + 16 d = 120t 2 48t + 16 dt

0 t

d = 120t 2 48t + 16 dt
(i)
0

where I0 is the moment of inertia about O and

= 40t 3 24t 2 + 16t + c

Since t = 0,

the

angular

acceleration. Now I0 =

= 0,
2

c=0

mL2 L + m by parallel axis 12 2

= 40t 3 24t 2 + 16t

Then linear velocity

theorem

v = r

mL2 L2 +m 12 4

v = 1 x 40t 3 24t 2 + 16t

[ r = 1m]
mL2 = 3 d d d d Now = = . = dt d dt d
Tangential acceleration

at =

dv d = 40t 3 24t 2 + 16t dt dt

= 120t 2 48t + 16 dv dt = 120 48 + 16

t =1

mg

L mL d sin = x , 2 3 d
on using (1)

= 88 ms 2
4. (4)
mg sin
mg cos

3g Now d = sin d 0 02 L

2 3g = (1 cos ) 2 2L
2

a = 3 ms2

3g = (1 cos ) L

The forces acting on the block are as shown in figure. (1) weight mg (2) pseudo force ma (3) friction N, where N is normal reaction.

3 x 10 1 x =9 5 2 3

= 3 rad s 1

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IIT/BMAT4/PMC(MAIN)/Solns - 2

3
Normal reaction
N = mg cos + ma sin

For V to be a minimum sin = 1( max )

mg A

V =

friction force = ( mg cos + ma sin )

For equation of block, we have
ma cos + N = mg sin N = mg sin ma cos

6. (2) Let A be the weight of the cable.

Then mass per unit length of the

A cable is . Consider a length L

dx of the cable. The mass of the

i.e, ( mg cos + ma sin )

= mg sin ma cos

A cable is dx. L

Let this length

dx of the cable be raised through a distance x measured from A. Then work done against gravity

i.e, ( g cos + a sin )

= ( g sin a cos )
4 3 i.e, 10 x + 3 x 5 5 3 4 = 10 x 3 x 5 5
49 = 18

A dw = dx x g L
Then total work done in winding up the entire cable is
w o

dw =

A dx x g o L
L

18 49

w =

x2 A g 2 L o

5. (1) For the particle to move with

constant have velocity, we should

A L2 g L 2 A gL 2 103 9.81 20 = 98.1 103 J 2

i.e, V x A = mg
=

i.e, V A sin = mg
V = mg A sin

= 98.1kJ

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IIT/BMAT4/PMC(MAIN)/Solns - 3

4 7. (3)
From the ABC, sin =
10

3 10

v sin = 6

i.e, v = Let the pipe make an angle to the horizon. Let the cart move with a velocity v1 along xaxis Then
v c = v1 i

6 6 = 10 = 2 10 sin 3

= 40 ms 1
8. (4) Let u be the initial velocity and , the angle of projection. The direction of the projectile becomes horizontal after 3 seconds. Here the projectile is at its greatest height.

Let the rain fall vertically down. Then

v r = v2 j

u sin = 3, g

where

is

the

When the rain goes along the axis of the pipe making an angle to the horizon, then
vrc = v cos i v sin j (1 ) where v

angle of projection
u sin = 30

(1)

Let v be the velocity of the projectile after 2 seconds. Then

v cos 30 = u cos

is the magnitude of the velocity of the rain But vrc = v r v c

= v 2 j v1i

(2)

(horizontal component) Also v sin = u sin gt ...(2)

= 30 10 2 = 10

From (1) and (2) we get

v cos i v sin j = v 2 j v1i = 6j 2i
v cos = 2 v cos = 2 v sin = 6

v =

10 = 20 m / s sin 30

Putting the value of v in (2), we get (3)

20

3 = u cos 2
(3)

u cos = 10 3
.(4) From (1) and (3) we get

i.e, v sin = 6

(4) gives tan = 3 (3)

tan = 3 = 60
IIT/BMAT4/PMC(MAIN)/Solns - 4

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5 9. (1)
= 8 cm 1cm 8

The y coordinates of the centre of mass are

42+3 y=

9 5 + 1 2 2 4 + 3 +1

27 5 + 8 + 2 2 = 8 =
The given figure can be divided into two rectangles namely, OABC and CFED and one square, namely GHIJ. Let C1, C2 , and C3 be the centres of mass of the respective areas mentioned. The area of the rectangle OABC is 4 1 = 4 cm2 The area of the rectangle CFED is

16 + 27 + 5 48 = = 3 cm 2 8 16

10. (2) Considering angular momentum about the centre of mass of the bar, we get
m u1 y + m u2 y = I

(1)

Ml2 Here I = + 2 my 2 12

3 1 = 3 cm2
The area of the square GHIJ is

1 1 = 1cm2
The mass of any section will be proportional to its area. The 1 coordinates of C1 are ,2 2 The coordinates of
C2

0.16 (1.5)2 + 2 0.08 (0.5)2 12 1.44 0.16 + 48 4 1.44 + 1.92 3.36 = 48 48

are

3 9 , 2 2
The coordinates of
C3

= 0.07 kg m2
0.08 10 0.5 + 0.08 6 0.5

are

3 5 , 2 2
The x coordinates of the centre of mass are
4 x= 1 3 3 + 3 + 1 2 2 2 4 + 3 +1

= 0.07

i.e, 0.4 + 0.24 = 0.07

0.64 0.07

= 9.1rad s 1
IIT/BMAT4/PMC(MAIN)/Solns - 5

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6 11. (2)
dx
/2

GMm R2

cos d

/ 2

=2

/ 2 GMm

R2 1

cos d

=2
Consider an element dx on the ring. Let it subtend an angle d at the centre of curvature C. Then
dx = R d

GMm R2

Hence the interaction force on m due to M is 2 in units of

GMm R2

12. (3) When the glass ball is placed in

vacuum the change in pressure is

M The mass of dx is dx R M = R d R = M d

P = 1 105 Nm2 .

Corresponding

to this change in pressure there

V will be a fractional change V

in the volume of the ball. The percentage

V 100. we V

change have

is

The force on m due to dx is

dx dF sin

P B= V V

V where P is the stress and V

dF cos

the strain. Now P = 1 105 N m2 (given)

dF sin

dx

4.0 1010 =

dF = G

M m d along the radius

dx located

1 105 V V

towards dx. Consider a similar element symmetrically below P. The sin components on resolution get cancelled, components due to M is but get

V 1 105 = = 0.25 10 5 V 4.0 1010

cos
reinforced.

V 5 i.e, 100 = 0.25 10 100 V = 25 10 5 = 2.5 10 4

Hence the interaction force on m

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IIT/BMAT4/PMC(MAIN)/Solns - 6

7 13. (4)

( P1 P2 ) =

2 V2 2 V1 2

But ( P1 P2 ) is the work done per unit volume.

From have
A1 V1 = A 2 V2

continuity

equation

we

W 1.25 103 2 2 = ( 0.128 ) ( 0.02) V 2 = 10.0 J / m3

Now A 2 V2 = r 2 2 V2 = Q where Q is the volume rate of flow Hence V2 =

4 2

( )

14. (1) The work done in forming the bubble under isothermal conditions is stored as surface energy of the drop. The surface energy as per unit area is T, where T is the surface tension. The surface area of the bubble is

Q A2

= 2 4 R2 = 8R2
The surface energy is = 8R2 T
work done R2 (square of the

6.43 10

( 0.04 )

= 0.128 m / s

radius)

By virtue of equation of continuity

V1 =

A 2 V2 A1

15. (2) The situation is shown in figure below.

A P C B echo

r2 V1 = 2 V r2 2 1 0.04 = 0.128 0.1 4 = 0.128 25

= 0.02 m / s
2

By Bernoullis equation,

P1 +

1 2 1 2 V = P2 + V 2 2 1 2

Let v be the velocity of the motorist. He travels a distance of v metre in one second. The first echo is heard by the motorist after one second, that is, after the sound has travelled a distance of 330 m through the least path. Hence the path taken by sound is AB+BC as shown in the figure.

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IIT/BMAT4/PMC(MAIN)/Solns - 7

8
It is clear that, AP =
AB + BC = 330 m

v 2

2 0.51

Time taken = 2s

Speed v =
and AB2 = AP2 + PB2

2 0.51 2

165 , where 165 m is the 2 width of the road. PB =

v 165 2 + = 330 2 2 v 165 2 + = (165 ) 2 2
v 2 (165 ) 2 + = (165 ) 4 4
2 2

0.51 = 1.6 m / s

Since the image is erect, the particles sense of rotation as seen from A, is clockwise in the image.

17. (4) As per the problem, the condition for nth order fringe of longer wavelength L to coincide with
the (n + 1)th order of the shorter wavelength s is (n + 1) s = nL

( n + 1) = 6000 = 4
n 4500

v 2 = 3 (165 )

i.e, 3n + 3 = 4n
n = 3

v = 3 165
v = 286 m / s

18. (3)

16. (3) We have

1 1 1 + = u v t

i.e,

1 1 1 + = ( r = 2 f ) 10 v 10.5

1 1 1 = + v 10.5 10 10.5 10 = 5.12 m 20.5 v

v =

Let A be the amplitude of the resultant simple harmonic motion. If is the angular frequency of the particle, then

For magnification m =

( u)

v u

A = 1910

A2 = 599736 5.12 = = 0.51 10

The radius of the circular image is 0.51 The circumference of the circular image is

599736 1910

= 314 rad / s

Amplitude A =

1910 = 6.1cm 314

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IIT/BMAT4/PMC(MAIN)/Solns - 8

9
Now A =

( A x )2 ( A y )

dT =0 dP 2 Po P 3 P 2 = 0
2 Po = 3 P

Now A x = 4 + 3 cos

A y = 3 sin
( 6.08 )
2

i.e, P =
2

2 Po 3

(2)

= ( 4 + 3 cos ) + 3 sin2 37 = 16 + 9 cos2 + 9 sin2

+ 24 cos

substituting (2) in (1) we get

R2 T 2 = P

4Po2 8Po3 3 27

= 16 + 9 + 24 cos cos = 12 1 = 24 2 3

4Po3 8Po3 9 27 12Po3 8Po3 4Po3 = 27 27 4Po3 27 R2

1

= 60 =

T2 =

19. (1) For an ideal gas PV = RT

The given law is P = Po V 2 Substituting for given law

T =
the

V=

RT P

2Po Po 2 3R 3

in

20. (2) Work done W in an adiabatic change is

RT P = Po P

W=

Cp P2 V2 P1 V1 where = Cv 1

= Po R2 P
2

R2T 2 P
2

For an adiabatic process

P1 V1 = P2 V2
V P2 = P1 1 = P1 ( 3) V2
(1) Further CP = C v + R

T 2 = Po P

R2 T 2 = Po P2 P3

Differentiating both sides w.r.t., P we get

3R 5R +R= 2 2

R2 T

dT = 2 Po P 3 P 2 dP

dT For to be maximum dP

5R 5 = 2 = 3R 3 2

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IIT/BMAT4/PMC(MAIN)/Solns - 9

10
P1 3 P1 V1 1
2 T

W =

R x = No 2 = R2 2 R y = No 2

( as T = 1hr )

105 3 V1 1

2 T

i.e, 957 =

105 ( 6.2 V1) 2 3

= R21 ( as T = 2 hr )

3 957 = 6.2 V1 2 105

R x 22 2 1 = = = R y 21 4 2

22. (4) N MSD = (N + 1) VSD

V1 = 6.2

3 957 2 105

1VSD =

N MSD N +1

= 6.2 0.014355

LC = 1MSD 1VSD

V1 = 6.2 0.01 = 6.19 But

V1 =3 V2 6.19 = 2.06 2 litres 3

N =a a N + 1
= a ( N + 1) Na

( N + 1)
a N + a Na ( N + 1) a

V2 =

21. (3) We have N = No e t (law Radioactivity)

of

L.C. =

Rate of disintegration R is
R= dN = No e t dt

(N + 1)

23. (1) The resistance of each coil after division is

dN When t = 0, Rate Ro = = No dt

R1 = R2 = ... = Rn =

R 6 = n n

At t = 2 hr, for R X , R x =

dN dt
2

When the coils are connected in parallel effective resistance Reff becomes

= No e N Since o = No e T 2
1

1 R R = n n n2
current is

Now steady state E 12 I= = . n2 Re ff R i.e, 8A =

e T = 2 or e = 2 T

12 2 .n A R 12 2 n = 2 n2 6

i.e, e = e

1 T

n2 = 4 i.e, n = 2

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IIT/BMAT4/PMC(MAIN)/Solns - 10

11 24. (3) 25. (4) The equation for the sawtooth wave is

V=

2Vo 2t t Vo = Vo 1 T T
T 2

Vdt

Vav =

0 T 2 0

22 2t = Vo 1 dt T 0 T

dt

Vav =
Let v be the maximum velocity of the bob in the equilibrium position. In the extreme position, its kinetic energy transforms into potential energy

2 T T V Vo = o T 4 2 2

26. (4) When the two equal capacitors are connected in series across a source emf E,
then p.d. across each is

1 mv 2 = mgh 2 v = 2gh
From the figure, (1)

E 2

(1)

h = CA =

(1 cos )
(2)

When one of the capacitors is filled with a dielectric the capacitance of that capacitor becomes EC. Then the effective capacitance of the series combination is given by

h = 2 sin2 / 2

Ceff =

C ( C ) C + C

C 1+

substituting (2) in (1) we get

v = 4g sin2 / 2 v = 2 sin / 2 g
The emf induced at any instant is

The charge on any one of the E C capacitors is Q = Ceff E = 1+ Then potential of the capacitor with the dielectric is

= =

Q E C 1 = . C 1 + C E 1+
(2)

e = Bv = B 2 sin / 2 g d =2B dt d 1 g cos / 2 dt 2

where is

=B

) cos / 2,

angular velocity

Decrease in potential of the capacitor with the dielectric E E = 2 1+

1 + 2 =E 2 (1 + )

d Now = emax when = 0 dt d Thus occurs at = 0 dt max

=E

( 1)
2 (1 + )

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IIT/BMAT4/PMC(MAIN)/Solns - 11

12 27. (2) Let R1 and R2 be the resistance

of the two coils. Then the highest resistance in series is (1) R1 + R2 = 16 The least resistance is obtained by connecting R1 and R2 in parallel. R R Then 1 2 = 3 R1 + R2
R1 R2 = 3 16 = 48

29. (4) En

1 n2 1

and Jn n

En

Jn2 1 Jn2
where k is a constant

En = k

(2) (3)

Let En = y and

R2 =

48 R1

1 Jn2

= x. then

substituting (3) in (1) we get 48 R1 + = 16 R1

2 R1

y = kx which is a straight line.

30. (1) Photon energy E = h =

c is the
34

16 R1 + 48 = 0 12 R1 4 R1 + 48 = 0
velocity
8

hc where
of light

2 R1

R1 (R1 12) 4 (R1 12) = 0 ( R1 12) (R1 4 ) = 0

Hence R1 = 4 or 12 Hence the resistance values are 4 and 12 28. (3) The current i ABC in part ABC of the outer coil is equal to the current iADC which is equal to 2.5 A. The current in the portion iGPH of the inner coil is equal to the current in the portion iGQH of the inner coil. Since the currents in the two halves of the coils are in opposite direction, the net magnetic induction at O by each coil is zero. Hence magnetic induction at O due to i the long wires is = 2 o 4 ro where ro is the radius of the outer coil

(6.6 10 ) (3 10 )
4.8 10 7

= 4.125 10 19 J
The rate of emission of photon from the source

1.0 4.125 10 19

= 2.425 1018 sec

Number of photons striking per square metre per second on the plate is

n=

2.425 1018 4 3.14 22 2.425 1018 32 3.14

cos 60

n=

n = 2.41 1016
In multiple of 1016 , n = 2.41

= 2

4 10 7 2.5 = 10 5 T 5 10 2 4

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IIT/BMAT4/PMC(MAIN)/Solns - 12

13 PART B: MATHEMATICS s 31. (3) If , are the roots, then

Its integrating factor is e 1 x

+ = sin 2, = (1+ sin )

sum of squares of the roots,

x
2

dx

=e

1/ 2 log 1 x 2

S = 2 + 2 = ( + ) 2 = ( sin 2 ) + 2 (1+ sin ) = sin2 2 sin + 6 = ( sin 1) + 5

S is least sin = 1 = 2
2 2

1 if 1 < x < 1 1 x 2 = 1 if x 2 > 1 2 x 1

1 1 x
2

ax dx

(1 x )
2

3/2

32. (2) Let P ( t1) , Q ( t2 ) and R ( t3 )

=
Equation of normal to y = 4ax is y + xt = 2at + at This passes through
2 3

1 a. 2

2x

1 x 2

3/2

dx

(h,

k)

1 1 x
2

a 1 x 2

+c

k + th = 2at + at3

at3 + ( 2a h) t k = 0

y = a + c 1 x 2
( y a) = c2 1 x 2
2

t1, t2 , t3

are the roots of this

)
which

equation.

( y a ) + c2 x 2 = c2 ,

t1 + t2 + t3 = 0 Now, centroid PQR is

a 2 2 2 2a G t1 + t2 + t3 , ( t1 + t2 + t3 ) 3 3

represents an ellipse for 1 < x < 1 . If x 2 > 1 , then the solution is of the form ( y a) c2 x 2 = c2 , which represents a hyperbola.
2a ( t1 + t2 + t3 ) = 0 3
2

We have t1 + t2 + t3 = 0

34. (1) x + iy = 1 2t + i 4t2 + 2t + 2

G lies on y = 0

x = 1 2 t and y = 4t2 + 2t + 2
3 7 Eliminating t, y 2 x = 2 4 which is a hyperbola.
2

33. (1) The given equation is linear in y and can be written as

dy x ax + y= dx 1 x 2 1 x 2

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IIT/BMAT4/PMC(MAIN)/Solns - 13

14 35. (2) , , are the cube roots of P < 0 38. (2) Multiplying c1 by ( x a) , c2 by ( x b )
and c3 by ( x c ) , we get A B C 1 3 3 = A B C3 , ABC ABC ABC ABC where A = x a, B = x b, C = x c. A = A 1
3

(given) , , = (P )
1/ 3

= P, P, P2

Let E =

2 x 2 + 2 y 2 + 2 z 2 2 x 2 + 2 y 2 + 2 z 2
P2 x 2 + P22 y 2 + P2z 2 P22 x 2 + P2y 2 + P2 z 2

E=

B B 1
3

C C3 1
1 1 B 1 C

E=

x 2 + 2 y 2 + z 2 2 x 2 + y 2 + z 2

x 2 + 2 y 2 + z 2 =

3 x 2 + 2 y 2 + z 2

)=

= ( 1) ( 1) A

A3 B3 C3 = (B C) ( C A) ( A B ) ( A + B + C) = ( c b ) ( a c ) (b a )

36. (4) p = probability of getting sum 9

when two dice are thrown = 4/36 = 1/9 Let x be the random variable of getting sum 9 when two dice are thrown three times. Now, x follows binomial

( 3x ( a + b + c) )
Now, = 0 when

x=

distribution with parameters n = 3, p = 1/9. Now q = 8/9.

1 8 p ( x = 2 ) = 3C2 9 9
2 32

1 (a + b + c) 3

39. (2) A adj A = A I det A = 4

= 8 243

Now, det (adj A) = ( det A) = 42 = 16

40. (3) If 0 < x <
/4

37. (3) f (1) = 0, f ( 2 ) = 1, f ( 3 ) = 1 ,

f ( 4 ) = 2, f ( 5 ) = 2, f ( 6 ) = 3, ... f 1 (m) = 2m + 1 when m is positive and f 1 (m) = 2m when m is

, then x = 0 4

sin x d ( x x ) =
/ 4

negative. f : N Z is one-one onto.

sin x dx = 1

1 2

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IIT/BMAT4/PMC(MAIN)/Solns - 14

15 41. (3) If the last two digits are equal to zero, then the first digit may be any digit from 1 to 9.
If the last two digits are equal to any number other than 0, then the first digit may be selected in 8 ways.
The required number

Since the origin is the same, the distance of origin from the plane is also the same. 1 1 a2 + 1 b2 + 1 c2 = 1 1 p2 + 1 q2 + 1 r2

(1) is the correct choice.

= 9 + 9 8 = 81

45. (2) c = 3a + 4b, 2c = a 3b 42. (1) Required number of

arrangements 1 1 1 1 = 5! + 2! 3! 4! 5! = 60 20 + 5 1 = 44
5c = 13b c =

13 b 5 opposite

and

have

direction and c =

13 b >2 b 5

43. (3) a0 + a1 x + a2 x 2 + a3 x 3
+ .... + a2n x 2n = 1+ x + x 2 Differentiating w.r.t. x, a1 + 2a2 x + 3a3 x 2 + .... +2na2nx = n 1+ x + x 2 x=1
a1 + 2a2 + 3a3 + ... + ( 2n) a2n
2n 1

46. (1)

a b c + + = 1+ i a1 b1 c1

a2
2 a1

b2
2 b1

c2
2 c1

ab bc ca = 2i 2 + + a b b c c 1 1 1 1 1a1

n1

(1+ 2x )

= 2i 2

abc c1 b1 a1 + + a1b1c1 c b a

= 2i 0 = 2i
47. (3) 183! has 10 as a factor.

= 3n . 3 = n . 3n

n1

Now, 3183 = 3 32
= 3 (10 1)
91

( )

91

44. (1) Equations of systems are

planes

in

two

= 3 (10 k 1) = 10t + 7

x y z x y z + + = 1and + + = 1 a b c P q r

The required digit at the unit

place is 7.
IIT/BMAT4/PMC(MAIN)/Solns - 15

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16 48. (4) f ( 0 ) = 0, Lt f ( x )
x 0

500 499 22003 = 8. (17 ) 500C (17 ) 1

= Lt Lt f ( x ) = Lt

x 0

( x x )
2 2

+... 500C 22003 8 = 8 + , where 17 17 = (17 )

499

499

(17) + 1

x 0

x 0

( 0 1) = 1 (0 0) = 0

x 0+

Lt f ( x ) = Lt

x 0

500C (17 )
1

498

f ( x ) is discontinuous at x = 0

and also discontinuous on z. Now,

2 f (1) = 0, Lt f ( x ) = Lt x 2 x =0 x 1 x 1

+ ... 500C499 such that I is an integer

f (x)

is discontinuous at all

22003 8 = 17 17

integers except at 1.
/2

51. (2) f ( x ) = x +

49. (2) Let I =

3 sec x + 5 cos ec x dx sec x + cos ec x

1 1 f ( x ) = 1 2 x x 1 x2 =0

f ( x ) = 0 1
x = 1

/2

3 cosec x + 5 s ec x dx sec x + cos ec x

f ( x ) =

/2 /2 f x 2x = f x dx ( ) 2 0 0
/2

2 x3

f (1) = 2 > 0

f ( x ) has minimum at x = 1.
52. (2)

2 =

8 sec x + 8 cos ec x dx sec x + cos ec x

B ( z 2 )

= 8.

= 4 2

= 2

50. (3) 22003 = 24

( )

500

. 23
As ABC is an isosceles right
= 8 (17 1)
500

22003 = 8. (16 )

500

triangle, right angled at B,

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IIT/BMAT4/PMC(MAIN)/Solns - 16

17
BA = BC and ABC = 90

2.

(a + h) + m
b2 + mb + n

z1 z 2 = z 3 z 2 and
=

(a

+ ma + n

z z2 arg 3 = z z 2 1 2
z3 z2 z z2 = 3 z1 z 2 z1 z 2

ba

( a + h) + m = (b + a) + m
a+b 2

a + h =

+ + cos + i sin = i 2 2
( z 3 z 2 ) = ( z1 z 2 )

2 2

h =

ba ba (b a ) = 2 2

=
55. (4) The

1 2 equation x 2 + y2 1+ 1 y2 x2 can be

( z1 z 2 )2 + ( z 2 z 3 )2 = 0

given

53. (3) y = x + is a tangent to

x2 a
2

written as

x dy y dx

= dx

y2 b
2

= 1 2 = a2 2 b2

x dy y dx x2

= dx

Locus of ( , ) is y 2 = a2 x 2 b2

1+ + b2 , which is a

d y = dx y 2 dx x x2

x2 =

1 a2

(y

Integrating, we get

parabola.

54. (1) f ( x )

is continuous in a, b and

y tan1 = x + c x y = x tan ( c x )
56. (4) Let a = cis A, b = cis B, c = cis C
Then a + b+ c = cis A + cis B + cis C = ( cos A + cos B + cos C ) + i ( sin A + sin B + sin C ) =0

differentiable in (a, b). Also f ( x ) = 2 x + m

By Lagranges Mean value

Theorem, there exists ( 0,1) such that f ( a + h ) = where h = b a. f (b ) f ( a) ba

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IIT/BMAT4/PMC(MAIN)/Solns - 17

18

a3 + b3 + c3 = 3 abc
cos 3A + cos 3B + cos 3C

h (h a) + k 2 + (h a)(h 2a) +
k 2 + (h 2a )(h 3a ) + k 2 = b2

= 3 cos ( A + B + C )

1 1 31 1 3 57. (3) A2 = 5 2 6 5 2 6 2 1 3 2 1 3 0 = 3 0 3 0 9
59. (2)

3 h2 + k 2 9ah + 8a2 = b2 The required locus of (h, k) is 3 x 2 + y 2 9ax + 8a2 b2 = 0

1 1 3 0 0 0 A3 = 3 3 9 1 1 3 0 0 0 = 0 0 0 0 0 0 A is a nilpotent matrix of 1 1 3 5 2 6 2 1 3

(A = 7)
= {07, 16, 25, 34, 43, 52, 61, 70}

(B = 0 )
= {00, 01 , ... 09, 10, 20, ....90}

( A = 7 ) (B = 0 ) = {07, 70}
P ( A = 7 /B = 0 ) P {( A = 7 ) (B = 0 )} P (B = 0 ) 2 19

index 3.
58. (2) AP = PQ = QB

60. (3) log2 ( sin x ) log2 ( cos x )

log2 1 tan2 x = 1 tan x log2 = 1 1 tan2 x tan x 1 tan2 x 2 tan x 1 tan2 x = 2 1 = 1 2

The coordinates of P are (a, 0), and of Q are (2a, 0). Equations of the circles on AP, PQ and QB as diameters are respectively

( x 0 ) ( x a) + y2 = 0, ( x a)( x 2a) + y2 = 0 ( x 2a) ( x 3a) + y2 = 0

So if (h, k) be any point on the locus, then and

=1

tan 2x = 1

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IIT/BMAT4/PMC(MAIN)/Solns - 18

19 PART C : CHEMISTRY s 61. (2) (2) Mass of 1 mole of sulphur

Correct order of O O- bond length H2O2 > O3 > O2

66. (1) 67. (2) 68. (4)

( S8 ) = 32 8 = 256g
(1) Mass of 1 gram atom of sodium = 23 g (3) 22.4 L of N2 at STP = 1 molar mass of N2 = 28g

N2 + 3H2

2NH3 ; K1

(4) 1 Avogadro number of CO2 = 1mole of CO2 = 44 g

62. (1)
K 2Cr2O7 + 4H2 SO4 K2 SO4 + Cr2 ( SO4 ) 3 + 4H2O + 3 O

Reversing the above equation

2 NH3 N2 + 3H2 ; 1 K1 II

N2 + O2

2NO ; K2

III

3SO2 + 3 O + 3H2O 3H2SO4

K2Cr2O7 + H2 SO4 + 3SO2 K2 SO4 + Cr2 ( SO4 )3 + H2O

H2 +

1 O 2

H2O ; K3

IV

63. (3)

x p =

h 4

Multiply equation IV by 3
3 3H2 + 3 / 2 O 3H2O = K4 = K 3

h x = 4 p
= 6.626 10
34

Js

2NH3 +

5 O 2 2

2NO + 3H2O; K 5

4 3.14 1 105 kg ms1

= 5.27 1030 m
64. (1) 69. (4) 65. (3)

K5 =

3 1 K 2 K 3 3 = K = K2K3 5 K1 K1

d=

H2O2 Bond order 1, largest bond length O3 Bond order 1.5, medium

PM , RT

Pressure = 82 atmos,

Molar mass of H2 = 2, T = 27 + 273 = 300K. R = 0.082 Latmos deg1mol1 82 2 = 6.667 g/L 0.082 300

bond length O2 Bond order 2.0, shortest bond length.

d=

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IIT/BMAT4/PMC(MAIN)/Solns - 19

20 70. (3) 71. (4) Unit of rate constant and rate of

( 2 )(NH4 )2 C2O4 ( 3 ) CH3COONH4

(4) KC

+ 2NH4 ( aq) + C2O

reaction are same mol L s zero order reactions.

72. (2)

1 1

Neutral. + CH3COO( aq) + NH4

4( aq)

for

( aq) (aq)
H2O

K+ + C

Tf = i Kf m
74. (4)

TP f = 1.1 Kf H2O = 1.86

m = 0.2

NaOH( S)

(aq)

Na + OH

( aq)

complete ionization. M(NaOH) = 0.4 1000 = 0.1 = 101 40 1000

i=

Tf 1.1 = = 2.95 Kfm 1.86 0.2

OH1 in solution 101M

14 H+ = kW = 10 = 1013 OH 101

i = 1+ (n 1) n = number of ions formed by the dissociation electrolyte

n = K2 SO4 = 2K + + SO4 =3

of

mole

of

pH = log H+ = log 1013 = 13

75. (3)

- degree of dissociation of electrolyte in solution. 2.95 = 1 + ( 3 1) 2 = 1.95

= 0.975 or 97.5%

C ( g ) ( g) + C ( g) Bond energy =
Bond energy of reactants Bond energy of product

= 107 + 121 (18 ) J mol1

73. (1)
(1) Salt formed by the neutralization of weak base with strong acid will be acidic

= 210 J mol1
76. (4)

Negatively charged particles are precipitated by oppositely

NH4C ( s ) NH4 + + H2O

+ NH4 (aq) + C

charged + ions only

77. (4) IIT/BMAT4/PMC(MAIN)/Solns - 20

+ NH4OH + H( aq)

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21 78. (1)

CH3CH2CHO + HCN
H OH
RCOCH3 + 2 PC
5

RCC 2CH3
3

| |

CH3 CH2 C C N

+ 2POC

+ 2H2O
5

CH3 CH2 O CH3 + PC

4 CH3 CH2 CHOHCH2NH2

LiA H

CH3CHC O CH3 + POC

3

1 amine

+ H2O

79. (2) meso2, 3 butane diol

Me H OH

84. (2) It is a linear complex with Ag in sp

hybridised state
Me

Me

HO

OH

HO

Me

85. (2) 86. (2) 87. (4) Pure

copper is obtained by

H
HO

OH Me

H H
C

Me A

electrolysis

80. (4) 81. (1) 82. (2) More the electron withdrawing
nitrogroups by resonance and I effects at ortho and para positions with respect to Br, make it to ionise easily facilitating NO2 nucleophilic substitution.

88. (2)

CaSO4 .2H2O is used in cement to delay the setting of cement

89. (2) In metals valency electrons form

of pool of electrons responsible for specific properties of metals called metallic bond.

90. (1)

group at meta position can act as I group only.

83. (4)

RCH2OH + PC

RCH2C
3

+ POC RCOOH + PC
5

+ H2O

RCOC
3

+ POC

+ H2O

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IIT/BMAT4/PMC(MAIN)/Solns - 21