Safety Data Sheet according to (EC) No 1907/2006

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sds no. : 210294 V002.1

Ceresit CC 92

Revision: 16.04.2012 printing date: 23.01.2014

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier Ceresit CC 92 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Additive 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr. 67 40589 Dsseldorf Germany Phone: Fax-no.: +49 (211) 797 0 +49 (211) 798 4008

ua-productsafety.de@henkel.com

1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0)211-797-3350 for exceptional cases. The product is notified at the 'Information Centers for Cases of Poisoning in Germany'. These centers provide information by telephone day and night in poisoning cases. Central emergency phone number: ++49 (0) 30 19240

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification (DPD): Xi - Irritant R41 Risk of serious damage to eyes. 2.2. Label elements

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Label elements (DPD): Xi - Irritant

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Risk phrases: R41 Risk of serious damage to eyes. Safety phrases: S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 Wear eye/face protection. Contains triisobutyl phosphate. May produce an allergic reaction. 2.3. Other hazards None if used properly.

SECTION 3: Composition/information on ingredients

General chemical description: Organic hydrophobicizing agent Base substances of preparation: Inorganic fillers Auxiliary

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components CAS-No. Calcium diformate 544-17-2 Calcium dihydroxide 1305-62-0 EC Number REACH-Reg No. 208-863-7 215-137-3 01-2119475151-45 content < 15 % < 2% Classification Serious eye damage/eye irritation 1 H318 Skin irritation 2; Dermal H315 Serious eye damage/eye irritation 1 H318 Specific target organ toxicity - single exposure 3; Inhalation H335 Skin sensitizer 1 H317

triisobutyl phosphate 126-71-6

204-798-3

< 1%

For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45:
Hazardous components CAS-No. Calcium diformate 544-17-2 Calcium dihydroxide 1305-62-0 triisobutyl phosphate 126-71-6 EC Number REACH-Reg No. 208-863-7 215-137-3 01-2119475151-45 204-798-3 content < 15 % < 2 % Classification Xi - Irritant; R41 Xi - Irritant; R37/38, R41

< 1 %

Xi - Irritant; R43

For full text of the R-Phrases indicated by codes see section 16 'Other Information'.

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Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Remove person from dust-contaminated zone, seek medical advice if necessary. Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting, sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital. Do not rub eyes; mechanical action may cause corneal damage. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice. 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis.

4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. 5.3. Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with eyes. 6.2. Environmental precautions Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. 6.3. Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Chapter 13. 6.4. Reference to other sections See advice in chapter 8

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SECTION 7: Handling and storage

7.1. Precautions for safe handling Avoid dust formation. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container protected against moisture. Store in a cool, dry place. Avoid strictly temperatures below 0 C and above + 50 C. Do not store together with food or other consumables (coffee, tea, tobacco, etc.). 7.3. Specific end use(s) Additive

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Valid for Germany
Ingredient ALLGEMEINER STAUBGRENZWERT 7631-86-9 ppm mg/m3 Type Category TRGS 901 - Explanations and basis for exposure limits in the workplace air - Number: AGW: If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). Time Weighted Average Indicative (TWA): AGW: 2 Short Term Exposure Classification: Remarks D901

Silicon dioxide 7631-86-9

TRGS 900

CALCIUM DIHYDROXIDE 1305-62-0 Triisobutyl phosphate 126-71-6 Triisobutyl phosphate 126-71-6

5 50

ECTLV TRGS 900

Category II: substances with a TRGS 900 resorptive effect.

Predicted No-Effect Concentration (PNEC):

Name on list Environmental Exposure Compartment period aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP soil 1080 mg/kg Value mg/l Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 ppm mg/kg others 0,49 mg/L 0,32 mg/L 0,49 mg/L Remarks

3 mg/L

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Derived No-Effect Level (DNEL):

Name on list Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Calcium dihydroxide 1305-62-0 Application Area worker Route of Exposure inhalation Health Effect Acute/short term exposure - local effects Long term exposure - local effects Acute/short term exposure - local effects Long term exposure - local effects Exposure Time Value 4 mg/m3 Remarks

worker

inhalation

1 mg/m3

general population general population

inhalation

4 mg/m3

inhalation

1 mg/m3

8.2. Exposure controls: Respiratory protection: When processing large amounts. Suitable breathing mask when there is inadequate ventilation. Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Appearance powder fine grey Odor paraffin-like

pH Initial boiling point Flash point Decomposition temperature Vapour pressure Density Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 9.2. Other information

No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable 950 g/l No data available / Not applicable No data available / Not applicable No data available / Not applicable partially soluble No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable

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No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity Reaction with acids: production of heat and carbon dioxide. 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions See section reactivity 10.4. Conditions to avoid None if used for intended purpose. 10.5. Incompatible materials None if used properly. 10.6. Hazardous decomposition products None known

SECTION 11: Toxicological information

11.1. Information on toxicological effects General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Skin irritation: Primary skin irritation: slightly irritating, does not require labeling Eye irritation: Risk of serious damage to eyes Sensitizing: An allergic reaction cannot be excluded after repeated skin contact.

Acute toxicity:
Hazardous components CAS-No. Calcium diformate 544-17-2 triisobutyl phosphate 126-71-6 Value type LD50 LD50 LC50 LD50 Value 3.050 mg/kg > 5.000 mg/kg > 5,14 mg/l > 5.000 mg/kg Route of application oral oral inhalation dermal Exposure time Species rat rat rat rabbit OECD Guideline 403 (Acute Inhalation Toxicity) Method

4h

Skin corrosion/irritation:
Hazardous components CAS-No. Calcium diformate 544-17-2 Calcium dihydroxide 1305-62-0 triisobutyl phosphate 126-71-6 Result not irritating irritating not irritating 4h Exposure time Species rabbit rabbit rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Method

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Serious eye damage/irritation:

Hazardous components CAS-No. Calcium dihydroxide 1305-62-0 triisobutyl phosphate 126-71-6 Result Category 1 (irreversible effects on the eye) not irritating Exposure time Species rabbit rabbit Method OECD Guideline 405 (Acute Eye Irritation / Corrosion)

Respiratory or skin sensitization:

Hazardous components CAS-No. triisobutyl phosphate 126-71-6 Result sensitising Test type Species Method OECD Guideline 406 (Skin Sensitisation)

Guinea pig guinea pig maximisat ion test

Germ cell mutagenicity:

Hazardous components CAS-No. triisobutyl phosphate 126-71-6 triisobutyl phosphate 126-71-6 Result Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test) intraperitoneal Metabolic activation / Exposure time with and without Species Method

negative

OECD Guideline 471 (Bacterial Reverse Mutation Assay) mouse

negative

Repeated dose toxicity

Hazardous components CAS-No. triisobutyl phosphate 126-71-6 Result Route of application - oral: feed Exposure time / Frequency of treatment 13 weeks continious Species Method

NOAEL=68,4 84,3 mg/kg

rat

SECTION 12: Ecological information

General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water.

12.1. Toxicity
Hazardous components CAS-No. Calcium diformate 544-17-2 Calcium dihydroxide 1305-62-0 triisobutyl phosphate 126-71-6 triisobutyl phosphate 126-71-6 triisobutyl phosphate 126-71-6 Value type LC50 LC50 Value Acute Toxicity Study Fish Fish Exposure time 96 h 96 h Species Method

> 1.000 mg/l 160 mg/l

Brachydanio rerio (new name: Danio rerio) Gambusia affinis

OECD Guideline 203 (Fish, Acute Toxicity Test)

LC50 EC50 EC50

17,8 - 21,5 mg/l 11 mg/l 33 mg/l

Fish Daphnia Algae

96 h 48 h 72 h

Leuciscus idus Daphnia magna Scenedesmus subspicatus (new name: Desmodesmus subspicatus)

12.2. Persistence and degradability

Hazardous components CAS-No. Result Route of application Degradability Method

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Calcium diformate 544-17-2 triisobutyl phosphate 126-71-6

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aerobic

> 75 %

readily biodegradable

> 60 %

OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test)

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Hazardous components CAS-No. Calcium diformate 544-17-2 triisobutyl phosphate 126-71-6 LogKow Bioconcentration Exposure factor (BCF) time -2,47 3,72 Species Temperature Method

25 C

SECTION 13: Disposal considerations

13.1. Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code 08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances

SECTION 14: Transport information

General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 0,00 % VOC content (VOCV 814.018 VOC regulation CH)

National regulations/information (Germany):

WGK: Storage class VCI:

1, slightly water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method 11

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SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation.

Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.