Proposal Objective :To provide Preliminary Basic Engineering services as per scope of work capacity enhancement of the liquid

plant. Scope of work :1) Designing modification in existing liquid plant for addition of equipment, piping and Instruments to match time cycle in line with existing liquid plant time cycle. The existing time cycle of the liquid plant for five products will be provided by the customer. 2) Preparing prliminary Basic engineering documents for increasing the capacity of the plant from 180 MT/yr to 320 MT/yr. Deliverables 1) 2) 3) 4) Time Cycle study Reports Process Flow Diagram Equipment list with (Dimension for static equipment and capacities and performance requirement for other boughtout items.) Equipment Layout

Assumptions :1 Cleaning time is assumed to be 60 minutes. Clening invoives reactor cleaning/Drying/CO2 sparger fixation. 2 30 RV 01 is in use till all filtration has been completed over period of time. 3 In all process for filtartion purpose Sparkler Filter 30 Fi 01 is considered, since, in given PFD filter 31 FI 01 is not shown anywhere.

16% BNP 31 RV 01 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Reactor Cleaning (Hot/Dry) Charge MTO and Butyl Carbitol Charge Nonyl Phenol Heat to 90 C Charge Barium Hydrauxide and silicon oil Close Manhole Reaction Time and Removal of water Dehydration Cool to 120 C Charge MTO Mixing and Sampling Transfer to 30 RV 01 Filtration Transfer to Storage Removal of Unfilter min hrs min 60 10 10 10 45 10 120 15 20 10 60 10 45 10 30 465 7.75 60 10 10 10 45 10 120 15 20 10 60 10 ---370 6.17

30 RV 01 ------------45 10 30 85.00 1.42

Filter ------------45 10 30 85 1.42

Heating deg (30-90)

Cooling deg (135-120)

Filtration is done at 75 deg C

Processing Time

370 6.2 85 1.4

min hrs min hrs

Time for which reaction mass is in reactor

Filtration and other out of reactor 31 RV 01

Description of the product on the basis of the batch time for processing. Product Name case Batch Fed Quantity kg 3017 2637 Batch Size kg --Batch time Overall 7.75 7.75 Batch Time 30 RV 01 1.42 1.42

31 RV 01 6.17 6.17

1) a 16 % BNP b 16 % BNP

Octahydrate Monohydrate

336 Heating deg (30-90)

Cooling deg (135-120)

Filtration is done at 75 deg C

Batch Time Filtration hrs 1.42 1.42

No of Batches Production per day Per Day kg 0 0

24% BNP 31 RV 01 min 1 2 3 4 5 6 7 8 9 Clean and dry reactor Fix Co2 Sparger in reactor 31RV01 Charge 502 kg Nonyl phenol + WPO 514 kg Heat and stirrer Charge Barium Hydrauxide + 15 silicon oil Close Manhole Heat & remove water Dehydration Release Vacuum 60 -60 10 75 10 150 10 5 10 30 300 30 10 30 10 120 20 40 min hrs 980 16.3 30 30 60 10 75 10 150 10 5 10 30 300 30 10 30 10 ---790 13.17 ---------------10 120 20 40 190 3.17 ----------------120 --120 2.00 30 RV 01 Filter

10 Charge 208 kg oleic Acid 11 Maintain temp 12 CO2 Sparging 13 Cool reaction mass from 180 to 100 deg. C 14 Charge Butyl carbitol & 206 kg MTO 15 Mixing 16 Transfer to 30 RV 01 17 Filtration 18 Transfer to Storage Tank 19 Remove unfiltrate and Rinse

Processing Time

790 13.2 190 3.17

min hrs min hrs

Time for which reaction mass is in reactor

Filtration and other out of reactor 31 RV 01

Description of the product on the basis of the year case Batch total Quantity Batch Size kg 1) 2) a b a b 16 % BNP 16 % BNP 24 % BNP 24 % BNP Octahydrate Monohydrate Octahydrate Monohydrate 3017 2637 3022 2537 kg ----Batch time Overall hrs 7.75 7.75 16.3 16.3 31 RV 01 hrs 6.17 6.17 13.2 13.2 Batch Time

Name of the Product

ii) Heating 30 to 85 degree iii) Heating 85 to 88 degree iv) Heat 88 to 135 degree under vacuum v) Heat 135 to 140 degree under vacuum vi) Min temp should remain 130 degree vii) Heat 135 to 140 degree viii) Heat 140 to 150 degree it is exothermic, temp reaches 180 , 180 to 100 deg cooing Cool to 100 to 80 degree

ich reaction mass is in reactor

Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 Filtration hrs 1.42 1.42 3.17 3.17

No of Batches Production per day Per Day kg 0 0 0 0

BCR 602 IN min 31 RV 01 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 Clean/ dry reactor Charge MTO, Oleic Acid, Butyl Carbitol Charge Benzoic Acid, ZnO,CdO Close Manhole Heat applied to 95 deg Maintain 95 deg Open manhole & check reaction mass Charge Oleic Acid & Octoic acid Charge Ba(OH)2,Octahydrate,Stabiliser AO Close manhole Distillation and Dehydration Maintain temp at 135 and sample product Charge MTO, DPDP Unfiltered product fed Transfer to 30 RV 01 Filter Transfer to dilution Tank Charge MTO to dilution tank Mixing Packing Removal of unfiltered product min hrs 60 40 20 10 20 20 10 20 15 10 150 10 20 10 10 45 10 10 60 90 30 670 11.2 60 40 20 10 20 20 10 20 15 10 150 10 20 10 10 ------425.000 7.083

30 RV 01 --------------10 45 ----30 85.000 1.417

30 FI 01 Filtration ---------------45 10 ----55.000 0.917

Dilution Tank -----------------30 60 -120 210.00 3.50

Processing Time Filtration and other out of reactor

425.000 7.1

min hrs min hrs

Time for which reaction mass is in reactor 31 RV 01

Description of the product on the basis of the year Product Name 1) 2) 3) a b a b a b 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 case Batch Quantity Fed kg 3017 2637 3022 2537 3319 3234 Batch Size (Given) kg ----3139 -Batch time Overall hrs 7.75 7.75 16.3 16.3 11.2 11.2 Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 1.417 1.417

Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate

31 RV 01 hrs 6.17 6.17 13.2 13.2 7.1 7.1

Filtration hrs 1.42 1.42 3.17 3.17 0.917 0.917

ii) 30 to 95 deg

iii) 95 to 135

iv) what quantity it has to be fed ?

No of Batches Production performed per day kg 0 0 0 0 0 0

Production per year

min 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Clean/ dry reactor Charge MTO,Octoic acid,Oleic Acid, Benzoic acid Charge water,Silicon oil, cadmium Oxide Close manhole and mix Distillation and Dehydration sample reaction mass Charge Butyl Carbotol, Zinc Octoate and DPDP Mix it Charge 16% BNP,MTO and mixing Charge unfiltered from previous batch Charge to 30 RV 01 Filtration Transfer to dilution tank MTO chrging in dilution tank Mixing Analysys of metal content Filling and Packing Removal of unfiltered product min hrs 60 30 20 15 90 10 10 10 15 5 10 45 10 10 60 15 60 30 505 8.4

BCR 3610 IN 31 RV 01 30 RV 01 60 30 20 15 90 10 10 10 15 5 10 -------275.000 4.583 ----------10 45 -----55.000 0.917

30 FI 01 Filtration -----------45 10 -----55.000 0.917

Dilution Tank ------------10 10 60 15 60 30 185.00 3.08

Processing Time Filtration and other out of reactor

275.000 4.6

min hrs min hrs

Time for which reaction mass is in reactor 31 RV 01

Description of the product on the basis of the year Product Name 1) 2) 3) 4) a b a b a b a 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 BCR 3610 case Batch Quantity Fed kg 3017 2637 3022 2537 3319 3234 3336 Batch Size (Given) kg ----3139 -3296 Batch time Overall hrs 7.75 7.75 16.3 16.3 11.2 11.2 8.4 Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 1.417 1.417 0.917

Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate BCR 3610

31 RV 01 hrs 6.17 6.17 13.2 13.2 7.1 7.1 4.583

Filtration hrs 1.42 1.42 3.17 3.17 0.917 0.917 0.917

ii) Heat 30 to (70-75) deg and agitate

iii) Temp 135 deg C has to be maintained till all water goes off. iv) If sampled product is containg moisture more than 05 % reheat to the temperature of 155+2 deg C & reanalyse. v) Now, Temp will drop down to 115-120 deg C

vi) what quantity it has to be fed with ?

No of Batches Production performed per day kg 0 0 0 0 0 0

Production per year

min 1 2 3 4 5 6 7 8 9 10 11 12 Clean/ dry reactor 60 Charge Butyl carbitol,Exsol solvent, Octoic acid, Oleic60 acid Heat to 70 C and agitate 10 Charge ZnO, water 10 Charge calcium hydroxide & heat to reflux 20 Distillation and Dehydration 160 deg C 90 Cool reaction mass to 130 deg 10 Charge DPDP and Zn-Octoate, Exsol solvent, 60 Mix for 30 30 Transfer to 30 RV 01 10 Filtration and Packing 90 Removal of unfiltered 60 min 510 hrs 8.5

CT 9271 LI IN 31 RV 01 30 RV 01 60 60 10 10 20 90 10 60 30 10 --360.000 6.000 ---------10 90 60 160.000 2.667

30 FI 01 Filtration ----------90 -90.000 1.500

Dilution Tank ------------0.00 0.00

Processing Time Filtration and other out of reactor

360.000 6.0

min hrs min hrs

Time for which reaction mass is in reactor 31 RV 01

Description of the product on the basis of the year Product Name 1) 2) 3) 4) 5) a b a b a b a a 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 BCR 3610 CT 9271 LI case Batch Quantity Fed kg 3017 2637 3022 2537 3319 3234 3336 2183 Batch Size (Given) kg ----3139 -3296 2118 Batch time Overall hrs 7.75 7.75 16.3 16.3 11.2 11.2 8.4 8.5 Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 1.42 1.42 0.92 2.67

Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate BCR 3610 CT 9271 LI

31 RV 01 hrs 6.17 6.17 13.2 13.2 7.1 7.1 4.6 6.00

Filtration hrs 1.42 1.42 3.17 3.17 0.92 0.92 0.92 1.50

ii) Heat 30 to 70 deg and agitate

iii) Temp 160 deg C has to be maintained till all water goes off. iv) Now, Temp will drop down to 115-120 deg C

No of Batches Production performed per day -kg 0 0 0 0 0 0

Production per year

KK 3059 V IN min 1 2 3 4 5 6 7 8 9 Clean/ dry reactor Charge MTO, Ocoic acid close manhole Heat to 70 deg Rx.mass check Close manhole Distillation and Dehydration Open manhole and sample reaction mass Analysis time 60 45 10 5 10 10 90 10 10 10 20 10 90 30 60 min hrs 470 7.8 31 RV 01 60 45 10 5 10 10 90 10 10 10 20 10 ---290.00 4.83 30 RV 01 -----------10 90 30 -130.00 2.17 30 FI 01 Filtration ------------90 --90.00 1.50 ---------------0.00 0.00 Dilution Tank

10 Charge 24% BNP 11 Charge Zn Octoate & MTO 12 Transfer prod. To 30 RV 01 &charge MTO 13 Filtration & transfer to dilution tank 14 Removal of unfilter 15 Filling and packing

Processing Time Filtration and other out of reactor

290.000 4.8

min hrs min hrs

Time for which reaction mass is in reactor 31 RV 01

Description of the product on the basis of the year Product Name 1) 2) 3) 4) 5) 6) a b a b a b a a a 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 BCR 3610 CT 9271 LI KK 3059 V Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate BCR 3610 CT 9271 LI KK 3059 V case Batch Quantity Fed kg 3017 2637 3022 2537 3319 3234 3336 2183 2260 Batch Size (Given) kg ----3139 -3296 2118 2235 Batch time Overall hrs 7.75 7.75 16.3 16.3 11.2 11.2 8.4 8.5 7.8 31 RV 01 hrs 6.17 6.17 13.2 13.2 7.1 7.1 4.6 6.00 4.833 Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 1.42 1.42 0.92 2.67 2.167 Filtration hrs 1.42 1.42 3.17 3.17 0.92 0.92 0.92 1.50 1.50

i) Heat 30 to 70 deg and agitate

ii) Maintain Temp 70-80 deg C Assumed iv) Assuming that cooling to 120 deg is achieved within this 10 min.

iii) During fair distillation 95 deg temp. and at the end of dist. 140 deg, it is assumed that within this 90 min 140 deg is maintained so that all moisture rem

Assumed v) In all process for filtartion purpose Sparkler Filter 30 Fi 01 is considered,

No of Batches Production performed -per day kg 0 0 0 0 0 0

Production per year

his 90 min 140 deg is maintained so that all moisture removed.

UBZ 670 IN min 1 2 3 4 5 6 7 8 9 Clean/ dry reactor Charge MTO,Ocoic acid, Butyl carbitol Charge ZnO, water, Silicon Oil Close manhole Heat to 70 deg. Maintain temp at 70 deg Open manhole and check reacion mass Charge Ba(OH)2 & Close manhole Distillation & Dehydration 60 40 10 10 10 10 10 10 120 10 10 15 5 10 10 90 10 10 60 30 60 min hrs 600 10.0 -----340.00 5.67 31 RV 01 60 40 10 10 10 10 10 10 120 10 10 15 5 10 10 30 RV 01 --------------10 90 10 --30 -140.00 2.33 90 -----90.00 1.50 -10 10 60 --80.00 1.33 30 FI 01 Filtration ----------------------------Dilution Tank

10 Open manhole and sample reaction mass 11 Analysys time 12 Charge Butyl carbitol, MTO 13 Charge unfilterred 670 from previous batch 14 mixing for 10 min Transfer to 30 RV 01 15 Filtration 16 Transfer prod. To Dilution tank 17 Charge MTO 18 Mixing is done in Dilution tank 19 Removal of unfilter 20 Filling and packing

Processing Time Filtration and other out of reactor

340.000 5.7

min hrs min hrs

Time for which reaction mass is in reactor 31 RV 01

Description of the product on the basis of the year Product Name 1) 2) 3) 4) 5) 6) 7) a b a b a b a a a a b 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 BCR 3610 CT 9271 LI KK 3059 V UBZ 670 UBZ 670 Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate BCR 3610 CT 9271 LI KK 3059 V Octahydrate Monohydrate case Batch Quantity Fed kg 3017 2637 3022 2537 3319 3234 3336 2183 2260 4089 3893 Batch Size (Given) kg ----3139 -3296 2118 2235 3738 -Batch time Overall hrs 7.75 7.75 16.3 16.3 11.2 11.2 8.4 8.5 7.8 10.0 10.0 31 RV 01 hrs 6.17 6.17 13.17 13.17 7.08 7.08 4.58 6.00 4.83 5.67 5.67 Batch Time 30 RV 01 hrs 1.42 1.42 3.17 3.17 1.42 1.42 0.92 2.67 2.17 2.33 2.33 Filtration hrs 1.42 1.42 3.17 3.17 0.92 0.92 0.92 1.50 1.50 1.50 1.50

water Quantity removed Octa Mono i) Heat 30 to 70 degC ii) Maintain at 70 deg 353 137

iii) Temp reaches 135 during last drop distillation. Assumed iv) 10 min temp 135 deg C is maintained and prod. Is sampled. M/C 0.8 max Assumed v) During analysys period cool reactor to 120 deg C Assumed vi) Assumed unfitered charging time 5 min but its quantity is not given.Assuming that max unfiltered could be 200 kg. Assumed vii) Assuming 10 min time to transfer prod.to reactor 30 RV 01 Assumed viii) In all process for filtration purpose Sparkler Filter 30 Fi 01 is considered, since, in given PFD filter 31 FI 01 is not shown anywhere.

Assumed ix) Assuming 30 min to remove unfiltered material. Assumed x) Assuming 60 min to packing and filling

90 min is broken into vi & vii

No of Batches Production performed -per day kg 0 0 0 0 0 0 0 0 0 0 0

Production per year

Batch time Product Name 16 % BNP 16 % BNP 24 % BNP 24 % BNP BCR 602 BCR 602 BCR 3610 CT 9271 LI KK 3059 V UBZ 670 UBZ 670 Case Octahydrate Monohydrate Octahydrate Monohydrate Octahydrate Monohydrate BCR 3610 CT 9271 LI KK 3059 V Octahydrate Monohydrate Batch Quantity 3017 2637 3022 2537 3319 3234 3336 2183 2260 4089 3893 Batch time 7.75 7.75 16.3 16.3 11.2 11.2 8.4 8.5 7.8 10.0 10.0 no batch /yr time/yr 0 0 0 0 0 0 0 0 0 0 0 Batch time 6.17 6.17 13.17 13.17 7.08 7.08 4.58 6 4.84 5.67 5.67

31 RV 01 no batch /yr time/yr 0 0 0 0 0 0 0 0 0 0 0

0
8000 max

30 RV 01 Batch time 1.42 1.42 2.17 2.17 1.417 1.417 1.417 2.67 2.167 1.5 1.5 no batch /yr time/yr 0 0 0 0 0 0 0 0 0 0 0

30 FI 01 Batch time 1.42 1.42 2.17 2.17 0.917 0.917 0.917 1.5 1.5 2.33 2.33

Filtration no batch /yr time/yr