Chemistry, 6e (McMurry/Fay) Chapter 14 Aqueous Equilibria: Acids and Bases 14.

1 Multiple-Choice Questions 1) An Arrhenius acid is best defined as a A) hydroxide donor. B) proton acceptor. C) substance that dissociates in water to produce aqueous hydro en ions. !) substance that dissociates in water to produce aqueous hydroxide ions. Answer" C #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory &) 'hen dissol(ed in water) which of the followin co*pounds is an Arrhenius acid+ A) ,CB) -a., C) -a/ !) C,0C,&., Answer" A #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 0) An Arrhenius base is best defined as a A) proton donor. B) hydroxide acceptor. C) substance that dissociates in water to produce aqueous hydro en ions. !) substance that dissociates in water to produce aqueous hydroxide ions. Answer" ! #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 4) 'hen dissol(ed in water) which of the followin co*pounds is an Arrhenius base+ A) C,0., B) ,.Cl C) 1., !) 1Cl Answer" C #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 2) A Brnsted-%owry acid is best defined as a substance that can A) accept a hydroxide ion. B) donate a hydroxide ion. C) accept a proton. !) donate a proton. Answer" ! #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory

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8) 'hich one of the followin species acts as a Brnsted-%owry acid in water+ A) -a, B) -,49 C) C,0-,& !) C8,8 Answer" B #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory :) 7n the followin che*ical equation indicate the reactant that is a Brnsted-%owry acid. ,C-;aq) 9 ,&.;l) ,0.9;aq) 9 C--;aq) A) ,CB) ,&. C) ,0.9 !) C-Answer" A #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory <) 7ndicate all the Brnsted-%owry acids in the followin che*ical reaction. ,Cl;aq) 9 ,&.;aq) ,0.9;aq) 9 Cl-;aq) A) ,Cl) ,&. B) ,Cl) ,0.9 C) ,Cl) Cl!) ,Cl) ,&.) ,0.9 Answer" B #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory =) 'hat are the Brnsted-%owry bases in the followin che*ical reaction+ C2,2-;aq) 9 ,&.;l) C2,2-,9;aq) 9 .,-;aq) A) C2,2-) ,&. B) C2,2-) C2,2-,9 C) C2,2-) .,!) C2,2-) ,&.) .,Answer" C #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 14) 'hat are the Brnsted-%owry acids in the followin che*ical reaction+ ,Br;sol) 9 C,0C..,;sol) C,0C;.,)&9;sol) 9 Br-;sol) A) ,Br) C,0C.., B) ,Br) C,0C;.,)&9 C) C,0C..,) C,0C;.,)&9 !) C,0C..,) BrAnswer" B #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory
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11) 'hat are the con>u ate acid-base pairs in the followin che*ical reaction+ -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq) A) -,0) ,&. and -,49) .,B) -,0) -,49 and ,&.) .,C) -,0) .,- and ,&.) -,49 !) -,0 and -,49 Answer" B #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 1&) 7dentify the con>u ate acid?base pairs present in an aqueous solution of hydro en sulfate ion) ,$.4-. A) ,$.4-?$.4&- and ,0.9?,&. B) ,&$.4?,$.4- and ,&.?.,C) ,$.4-?,&. and ,0.9?$.4&!) ,$.4-?,&. and ,&$.4?.,Answer" A #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 10) 'hat is the con>u ate base of the Brnsted-%owry acid ,5.4&-+ A) ,05.4 B) ,&5.4C) ,5.4&!) 5.40Answer" ! #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 14) 'hat is the con>u ate acid of the Brnsted-%owry base ,As.4&-+ A) ,&As.4B) As.40C) ,&. !) ,0.9 Answer" A #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 12) 'hich one of the followin can beha(e either as a Brnsted-%owry acid or a Brnsted-%owry base in an aqueous solution reaction+ A) ,$.0B) -,0 C) ,7 !) ,05.4 Answer" A
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#opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 18) 'rite a balanced equation for the dissociation of the Brnsted-%owry acid ,$.4- in water. A) ,$.4-;aq) 9 ,&.;l) ,&$.4;aq) 9 .,-;aq) B) ,$.4-;aq) 9 ,&.;l) $.4&-;aq) 9 ,0.9;aq) C) ,$.4-;aq) 9 ,&.;l) $.0&-;aq) 9 .,-;aq) !) ,$.4-;aq) 9 ,&.;l) $.0;g) 9 .,-;aq) 9 ,&.;l) Answer" B #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory 1:) 'hich of the followin Brnsted-%owry acids does not beha(e as a stron acid when it is dissol(ed in water+ A) ,Br B) ,Cl C) ,-.& !) ,Cl.4 Answer" C #opic" $ection 14.& Acid $tren th and Base $tren th 1<) 'hich Brnsted-%owry base has the stron est con>u ate acid+ A) C,0C.&B) C-C) /!) -.0Answer" ! #opic" $ection 14.& Acid $tren th and Base $tren th 1=) 'hich Brnsted-%owry acid has the stron est con>u ate base+ A) ,Br B) ,Cl.4 C) ,/ !) ,7 Answer" C #opic" $ection 14.& Acid $tren th and Base $tren th &4) 'hat is the stron est Brnsted-%owry acid in the che*ical reaction shown below+ & ,-.0;aq) 9 Ba;.,)&;aq) @ Ba;-.0)&;aq) 9 & ,&.;l) A) ,-.0 B) Ba;.,)& C) Ba;-.0)& !) ,&. Answer" A #opic" $ection 14.& Acid $tren th and Base $tren th

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&1) /ro* the followin che*ical reactions deter*ine the relati(e Brnsted-%owry acid stren ths ;stron est to weaAest). ,Cl;aq) 9 ,&.;l) @ ,0.9;aq) 9 Cl-;aq) ,C-;aq) 9 ,&.;l) ,0.9;aq) 9 C--;aq) A) ,Cl B ,C- B ,0.9 B) ,Cl B ,0.9 B ,CC) ,0.9 B ,Cl B ,C!) ,C- B ,0.9 B ,Cl Answer" B #opic" $ection 14.& Acid $tren th and Base $tren th &&) /ro* the followin che*ical reactions deter*ine the relati(e Brnsted-%owry acid stren ths ;stron est to weaAest). ,Cl.4;aq) 9 ,&.;l) @ ,0.9;aq) 9 Cl.4-;aq) ,-.&;aq) 9 ,&.;l) ,0.9;aq) 9 -.&-;aq) A) ,Cl.4 B ,0.9 B ,-.& B) ,Cl.4 B ,-.& B ,0.9 C) ,0.9 B ,Cl.4 B ,-.& !) ,0.9 B ,-.& B ,Cl.4 Answer" A #opic" $ection 14.& Acid $tren th and Base $tren th &0) /ro* the followin che*ical reactions deter*ine the relati(e Brnsted-%owry acid stren ths ;stron est to weaAest). ,Cl.4;sol) 9 C,0C..,;l) @ C,0C&;.,)&9;sol) 9 Cl.4-;aq) ,&$.4;sol) 9 C,0C..,;l) C,0C;.,)&9;sol) 9 ,$.4-;sol) A) ,Cl.4 B ,&$.4 B C,0C.., B) ,Cl.4 B ,&$.4 B C,0C;.,)&9 C) ,Cl.4 B C,0C.., B ,&$.4 !) ,Cl.4 B C,0C;.,)&9 B ,&$.4 Answer" ! #opic" $ection 14.& Acid $tren th and Base $tren th

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&4) /ro* the followin che*ical reactions deter*ine the relati(e Brnsted-%owry base stren ths ;stron est to weaAest). ,-.0;aq) 9 ,&.;l) @ ,0.9;aq) 9 -.0-;aq) ,/;aq) 9 ,&.;l) ,0.9;aq) 9 /-;aq) A) ,-.0 B ,0.9 B ,/ B) -.0- B ,&. B /C) /- B ,&. B -.0!) /- B -.0- B ,&. Answer" C #opic" $ection 14.& Acid $tren th and Base $tren th &2) /ro* the followin che*ical reactions deter*ine the relati(e Brnsted-%owry base stren ths ;stron est to weaAest). & -a,;s) 9 ,&.;l) @ & -a., 9 ,&;g) -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq) A) ,- B .,- B -,0 B) ,- B -,0 B .,C) .,-B ,- B -,0 !) .,- B -,0 B ,Answer" A #opic" $ection 14.& Acid $tren th and Base $tren th &8) #he equilibriu* constant) K) for the reaction shown below has a (alue 1.< C 14D2. 7n this reaction which is the stron est acid and which is the stron est base+ C,0C.&,;aq) 9 ,&.;l) ,0.9;aq) 9 C,0C.&D;aq) A) C,0C.&, and C,0C.&D B) C,0C.&, and ,&. C) ,0.9 and ,&. !) ,0.9 and C,0C.&D Answer" ! #opic" $ection 14.& Acid $tren th and Base $tren th

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#he followin pictures represent aqueous solutions of binary acids of the type ,A where the water *olecules ha(e been o*itted for clarity.

&:) !eter*ine the stron est acid of the set. A) A B) B C) C !) ! Answer" B #opic" $ection 14.& Acid $tren th and Base $tren th &<) Arran e the acids in order of increasin acid stren th. A) ! E C E A E B B) ! E C E B E A C) ! E B E A E C !) ! E A E C E B Answer" ! #opic" $ection 14.& Acid $tren th and Base $tren th &=) Fsin the con>u ate acid-base pairs listed below) co*plete the followin equation with the pair that i(es an equilibriu* constant Kc B 1. GGGGG 9 ,$.0- GGGGG 9 ,&$.0 A) C,0C.&,? C,0C.&B) ,C.&,? ,C.&C) ,-.&?-.&!) ,-.0?-.0Answer" ! #opic" $ection 14.& Acid $tren th and Base $tren th

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04) Fsin the con>u ate acid-base pairs listed below) co*plete the followin equation with the pair that i(es an equilibriu* constant Kc B 1. GGGGG 9 ,&C.0 GGGGG 9 ,C.0A) ,/?/B) ,Cl?ClC) ,.Cl?.Cl!) ,$.4&-?$.4&Answer" C #opic" $ection 14.& Acid $tren th and Base $tren th 01) 'hat is the eo*etric shape of the hydrated protonH that is) the hydroniu* ion ,0.9+ A) an ular B) pyra*idal C) tri onal planar !) tetrahedral Answer" B #opic" $ection 14.0 ,ydrated 5rotons and ,ydroniu* 7ons 0&) 'hich is not a hydrate of a proton+ A) ,0.9 B) ,=.49 C) ,&2.119 !) ,40.&19 Answer" C #opic" $ection 14.0 ,ydrated 5rotons and ,ydroniu* 7ons 00) An acidic solution at &2IC has A) J,0.9K B J.,-K B 1 C 14-: M. B) J,0.9K B 1 C 14-: M B J.,-K. C) J,0.9K L J.,-K B 1 C 14-: M. !) J,0.9K E 1 C 14-: M B J.,-K. Answer" B #opic" $ection 14.4 !issociation of 'ater 04) At 24IC the (alue of Kw is 2.2 C 14-14. A basic solution at 24IC has A) J,0.9K E J.,-K E & C 14-: M. B) J,0.9K E & C 14-: M E J.,-K. C) J,0.9K L J.,-K E & C 14-: M. !) J,0.9K B & C 14-: M E J.,-K. Answer" B #opic" $ection 14.4 !issociation of 'ater

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02) Calculate the hydroniu* ion concentration in an aqueous solution that contains &.24 C 14-4 M in hydroxide ion. A) 4.44 C 14-= M B) 4.44 C 14-14 M C) 4.44 C 14-11 M !) 2.44 C 14-11 M Answer" C #opic" $ection 14.4 !issociation of 'ater 08) Calculate the hydroxide ion concentration in an aqueous solution that contains 0.24 C 14-0 M in hydroniu* ion. A) &.<8 C 14-4 M B) &.<8 C 14-11 M C) &.<8 C 14-1& M !) 0.24 C 14-1& M Answer" C #opic" $ection 14.4 !issociation of 'ater 0:) A solution with a hydro en ion concentration of 0.&2 C 14-& M is GGGGGGGG and has a hydroxide concentration of GGGGGGGG. A) acidic) 0.4< C 14-1& M B) acidic) 0.4< C 14-10 M C) basic) 0.4< C 14-1& M !) basic) 0.4< C 14-10 M Answer" B #opic" $ection 14.4 !issociation of 'ater 0<) A solution with a hydroxide ion concentration of 4.12 C 14-4 M is GGGGGGGG and has a hydro en ion concentration of GGGGGGGG. A) acidic) &.41 C 14-14 M B) acidic) &.41 C 14-11 M C) basic) &.41 C 14-14 M !) basic) &.41 C 14-11 M Answer" ! #opic" $ection 14.4 !issociation of 'ater 0=) 7f the ioniMation constant of water) Kw) at 44IC is &.=& C 14-14) then what is the hydroniu* ion concentration for a neutral solution+ A) J,0.9K E 1.44 C 14-: M B) J,0.9K B 1.:1 C 14-: M C) J,0.9K L 1.:1 C 14-: M !) J,0.9K E 1.:1 C 14-: M Answer" C #opic" $ection 14.4 !issociation of 'ater
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44) -or*al rainfall has a concentration of .,- that is 0.=< 14-=. #he concentration of ,0.9 in nor*al rainfall is A) reater than 0.=< 14-=) and the rain is acidic. B) reater than 0.=< 14-=) and the rain is basic. C) less than 0.=< 14-=) and the rain is acidic. !) less than 0.=< 14-=) and the rain is basic. Answer" A #opic" $ection 14.4 !issociation of 'ater 41) ,u*an tears ha(e a concentration of ,0.9 that is 0.18 14-<. #he concentration of .,- in hu*an tears is A) reater than 0.18 14-: and tears are acidic. B) reater than 0.18 14-: and tears are basic. C) less than 0.18 14-: and tears are acidic. !) less than 0.18 14-: and tears are basic. Answer" B #opic" $ection 14.4 !issociation of 'ater 4&) An acidic solution at &2IC will ha(e a hydroniu* ion concentration GGGGGGGG and a p, (alue GGGGGGGG. A) J,0.9K B 1 C 14-: M) p, B :.44 B) J,0.9K B 1 C 14-: M) p, E :.44 C) J,0.9K E 1 C 14-: M) p, B :.44 !) J,0.9K E 1 C 14-: M) p, E :.44 Answer" B #opic" $ection 14.2 #he p, $cale 40) 7f the ioniMation constant of water) Kw) at 44IC is &.=& C 14-14) then what is the hydroniu* ion concentration and p, for an acidic solution+ A) J,0.9K B 1.:1 C 14-: M and p, B 8.:: B) J,0.9K B 1.:1 C 14-: M and p, E 8.:: C) J,0.9K E 1.:1 C 14-: M and p, B 8.:: !) J,0.9K E 1.:1 C 14-: M and p, E 8.:: Answer" B #opic" $ection 14.2 #he p, $cale 44) Calculate the p, for an aqueous solution of acetic acid that contains &.12 C 14-0 M hydroniu* ion. A) 4.82 C 14-1& B) &.12 C 14-0 C) &.8: !) 11.00 Answer" C
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#opic" $ection 14.2 #he p, $cale 42) Calculate the p, for an aqueous solution of pyridine that contains &.12 C 14-4 M hydroxide ion. A) 4.82 C 14-11 B) &.12 C 14-4 C) 0.8: !) 14.00 Answer" ! #opic" $ection 14.2 #he p, $cale 48) 'hat is the hydroxide ion concentration and the p, for a hydrochloric acid solution that has a hydroniu* ion concentration of 1.24 C 14-4 M+ A) 8.8: C 14-14 M) 4.<& B) 8.8: C 14-14 M) =.1< C) 8.8: C 14-11 M) 0.<& !) 8.8: C 14-11 M) 14.1< Answer" C #opic" $ection 14.2 #he p, $cale 4:) 'hat is the hydroniu* ion concentration and the p, for an aqueous solution of -,0 that has a hydroxide ion concentration of &.&2 C 14-0 M+ A) 4.44 C 14-11 M) 0.82 B) 4.44 C 14-11 M) 14.02 C) 4.44 C 14-1& M) &.82 !) 4.44 C 14-1& M) 11.02 Answer" ! #opic" $ection 14.2 #he p, $cale 4<) 'hat is the hydroniu* ion concentration of an acid rain sa*ple that has a p, of 0.12+ A) 1.41 C 14-11 M B) :.4< C 14-4 M C) 0.12 M !) 14.<2 M Answer" B #opic" $ection 14.2 #he p, $cale 4=) 'hat is the hydroxide ion concentration of a lye solution that has a p, of 11.&4+ A) 8.01 C 14-1& M B) 1.2< C 14-0 M C) &.<4 M !) 11.&4 M Answer" B #opic" $ection 14.2 #he p, $cale

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24) 'hat state*ent is *ost consistent for an acid with a p, L 0+ A) one one-hundredth as stron as an acid with a p, of 2 B) half a stron as an acid with a p, L 2 C) twice as stron as an acid with a p, of 2 !) one hundred ti*es as stron as an acid with a p, L 2 Answer" ! #opic" $ection 14.2 #he p, $cale 21) At &2IC) the p, of a (ine ar solution is &.84. 'hat are the (alues of J,0.9K and J.,-K in the solution+ A) 0.== C 14-1& M) &.21 C 14-0 M B) &.21 C 14-0 M) 0.=< C 14-1& M C) &.21 C 14-0 M) 11.44 M !) &.84 M) 11.44 M Answer" B #opic" $ection 14.2 #he p, $cale 2&) 'hat is the approxi*ate p, of a solution N that i(es the followin responses with the indicators shown+ Indicators *ethyl oran e *ethyl red bro*othy*ol blue phenolphthalein HIn Inred-yellow red-yellow yellow-blue colorless-pinA pH range 0.&-4.4 4.<-8.4 8.4-:.8 <.&-14.4 Solution X yellow yellow reen colorless

A) 0.& - 4.4 B) 4.< - 8.4 C) 8.4 - :.8 !) <.& - 14.4 Answer" C #opic" $ection 14.8 Measurin p,

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20) 'hat is the approxi*ate p, of a solution N that i(es the followin responses with the indicators shown+ Indicators *ethyl oran e *ethyl red bro*othy*ol blue phenolphthalein HIn Inred-yellow red-yellow yellow-blue colorless-pinA pH range 0.&-4.4 4.<-8.4 8.4-:.8 <.&-14.4 Solution X yellow oran e yellow colorless

A) 0.& - 4.4 B) 4.< - 8.4 C) 8.4 - :.8 !) <.& - 14.4 Answer" B #opic" $ection 14.8 Measurin p, 24) 'hat is the approxi*ate p, of a solution N that i(es the followin responses with the indicators shown+ Indicators *ethyl oran e *ethyl red bro*othy*ol blue phenolphthalein HIn Inred-yellow red-yellow yellow-blue colorless-pinA pH range 0.&-4.4 4.<-8.4 8.4-:.8 <.&-14.4 Solution X yellow yellow blue pinA

A) 4.< - 8.4 B) 8.4 - :.8 C) :.8 - <.& !) B <.& Answer" ! #opic" $ection 14.8 Measurin p, 22) 'hat is the p, of a 4.4&4 M ,Cl.4 solution+ A) 4.4&4 B) 4.444 C) 1.:4 !) 1&.04 Answer" C #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases

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28) 'hat is the p, of a 4.4&4 M Ob., solution+ A) 4.4&4 B) 4.444 C) 1.:4 !) 1&.04 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 2:) 'hat is the p, of a 4.4&4 M Ba;.,)& solution+ A) 1.44 B) 1.:4 C) 1&.04 !) 1&.84 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 2<) 'hat is the p, of a solution prepared by dissol(in 4.12 ra* of solid Ca. ;li*e) in enou h water to *aAe &.44 % of aqueous Ca;.,)& ;li*ewater)+ Ca.;s) 9 ,&.;l) @ Ca&9;aq) 9 & .,-;aq) A) &.2: B) &.<: C) 11.10 !) 11.40 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 2=) 'hat is the p, of a solution prepared by dilutin &2.44 *% of 4.14 M ,Cl with enou h water to produce a total (olu*e of 144.44 *%+ A) 1.44 B) 1.84 C) &.44 !) 0.&4 Answer" B #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 84) 'hat is the p, of a solution prepared by dilutin &2.44 *% of 4.4&4 M Ba;.,)& with enou h water to produce a total (olu*e of &24.44 *%+ A) &.44 B) &.:4 C) 11.04 !) 11.84 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases

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81) 'hat is the p, of a solution *ade by *ixin 144.44 *% of 4.&4 M ,Cl with 24.44 *% of 4.14 M ,Cl+ Assu*e that the (olu*es are additi(e. A) 4.12 B) 4.2& C) 4.:< !) 1.:4 Answer" C #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 8&) 'hat is the p, of a solution *ade by *ixin 144.4 *% of 4.14 M ,-.0) 24.4 *% of 4.&4 M ,Cl) and 144.4 *% of water+ Assu*e that the (olu*es are additi(e. A) 4.04 B) 4.<& C) 1.44 !) 1.14 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 80) 'hat is the p, of a solution prepared by *ixin 144.44 *% of 4.4&4 M Ca;.,)& with 24.44 *% of 4.144 M -a.,+ Assu*e that the (olu*es are additi(e. A) 1&.8: B) 1&.:< C) 1&.=2 !) 10.&2 Answer" B #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 84) 'hat is the equilibriu* constant expression ;1a) for the acid dissociation of hydrocyanic acid ,C-+ #he equation of interest is ,C-;aq) 9 ,&.;l) ,0.9;aq) 9 C--;aq). A) Ka L ;J,0.9KJC--K)?;J,C-KJ,&.K) B) Ka L ;J,0.9KJC--K)?;J,C-K) C) Ka L ;J,C-KJ,&.K)?;J,0.9KJC--K) !) Ka L ;J,C-K)?;J,0.9KJC--K) Answer" B #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids

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82) 'hat is the equilibriu* constant expression ;Ka) for the acid dissociation of nitrous acid ,-.&+ #he equation of interest is ,-.&;aq) 9 ,&.;l) ,0.9;aq) 9 -.&-;aq). A) Ka L ;J,0.9KJ-.&-K)?;J,-.&KJ,&.K) B) Ka L ;J,0.9KJ-.&-K)?;J,-.&K) C) Ka L ;J,-.&KJ,&.K)?;J,0.9KJ-.&-K) !) Ka L ;J,-.&K)?;J,0.9KJ-.&-K) Answer" B #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 88) !eter*ine the acid dissociation constant for a 4.14 M acetic acid solution that has a p, of &.<:. Acetic acid is a weaA *onoprotic acid and the equilibriu* equation of interest is C,0C..,;aq) 9 ,&.;l) ,0.9;aq) 9 C,0C.&0-;aq) A) 1.0 C 14-& B) 1.0 C 14-0 C) 1.< C 14-2 !) 1.< C 14-8 Answer" C #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 8:) !eter*ine the acid dissociation constant for a 4.414 M nitrous acid solution that has a p, of &.:4. -itrous acid is a weaA *onoprotic acid and the equilibriu* equation of interest is ,-.&;aq) 9 ,&.;l) ,0.9;aq) 9 -.&-;aq). A) <.4 C 14-0 B) &.4 C 14-0 C) 2.4 C 14-4 !) 4.4 C 14-4 Answer" C #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 8<) !eter*ine the acid dissociation constant for a 4.4&4 M for*ic acid solution that has a p, of &.:4. /or*ic acid is a weaA *onoprotic acid and the equilibriu* equation of interest is ,C..,;aq) 9 ,&.;l) ,0.9;aq) 9 ,C.&-;aq). A) 1.< C 14-0 B) 1.< C 14-4 C) 0.8 C 14-4 !) 0.8 C 14-2 Answer" B #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids

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8=) #he p, of 4.&22 M ,C- is 4.=2. 'hat is the (alue of Ka for hydrocyanic acid+ A) 1.0 C 14-14 B) 4.= C 14-14 C) 1.1 C 14-2 !) 4.4 C 14-2 Answer" B #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids :4) #he p, of 4.124 M C,0C.&,) acetic acid) is &.:<. 'hat is the (alue of Ka for acetic acid+ A) &.< C 14-8 B) 1.= C 14-2 C) 1.: C 14-0 !) 1.1 C 14-& Answer" B #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids :1) 'hat is the stron est *onoprotic acid of the followin set if all the acids are at 4.144 M concentration+ A) hydrofluoric acid with Ka L 0.2 C 14-4 B) benMoic acid with Ka L 8.2 C 14-2 C) acetic acid with Ka L 1.< C 14-2 !) hypochlorous acid with Ka L 0.2 C 14-< Answer" A #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids :&) 'hat is the hydroniu* ion concentration of a 4.144 M acetic acid solution with a Ka L 1.< C 14-2+ #he equation for the dissociation of acetic acid is" C,0C.&,;aq) 9 ,&.;l) ,0.9;aq) 9 C,0C.&-;aq). A) 1.0 C 14-& M B) 4.& C 14-& M C) 1.0 C 14-0 M !) 4.& C 14-0 M Answer" C #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids :0) 'hat is the hydroniu* ion concentration of a 4.144 M hypochlorous acid solution with Ka L 0.2 C 14-<+ #he equation for the dissociation of hypochlorous acid is" ,.Cl;aq) 9 ,&.;l) ,0.9;aq) 9 .Cl-;aq). A) 1.= C 14-4 B) 2.= C 14-4 C) 1.= C 14-2 !) 2.= C 14-2 Answer" !
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#opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids :4) 5ara-A*inobenMoic acid ;5ABA)) p-,&-C8,4;C..,)) is used in so*e sunscreens and hair conditionin products. Calculate the p, of an aqueous solution with J5ABAK L 4.404 M and Ka L &.& C 14-2. A) 1.2& B) 0.4= C) 4.88 !) 8.1< Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids :2) A tablet containin 244.4 * of aspirin ;acetylsalicylic acid or ,C=,:.4) was dissol(ed in enou h water to *aAe 144 *% of solution. Pi(en that Ka L 0.4 C 14D4 for aspirin) what is the p, of the solution+ A) 1.2: B) &.24 C) 0.2& !) 2.4< Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids :8) BenMoic acid ;C8,2C.&, L ,BM) solutions are so*eti*es used in experi*ents to deter*ine the *olarity of a basic solution of unAnown concentration. 'hat is the p, of a 4.144 M solution of benMoic acid if Ka L 8.2 C 14D2 and the equilibriu* equation of interest is ,BM;aq) 9 ,&.;l) ,0.9 9 BM-;aq)+ A) 1.44 B) &.2= C) 4.1= !) 2.1= Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids ::) 5otassiu* hydro en phthalate ;*olar *ass L &44.& ?*ol) is one of the *ost co**only used acids for standardiMin solutions containin bases. 1,5 is a *onoprotic weaA acid with Ka L 0.=1 C 14D8. Calculate the p, of the solution that results when 4.44 of 1,5 is dissol(ed in enou h water to produce &2.4 *% of solution. A) &.14 B) 0.&8 C) 4.04 !) 2.41 Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids

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:<) Qine ar is a 2.4R solution by wei ht of acetic acid ;C,0C.&,) in water. Pi(en that Ka L 1.< C 14D2 for acetic acid and assu*in the density of (ine ar to be 1.44 ?c*0) what is the p, of this (ine ar solution+ A) &.44 B) &.41 C) &.<: !) 4.:4 Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids :=) Qine ar is a 2.4R solution by wei ht of acetic acid ;C,0C.&,) in water. Pi(en that the p, for acetic acid is &.41) the Ka L 1.< C 14D2 and assu*in the density of (ine ar to be 1.44 ?c*0) what is the percent dissociation of acetic acid in (ine ar+ A) 4.4:R B) 1.2R C) 4.4R !) 2.4R Answer" A #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids <4) 'hat is the percent dissociation of a benMoic acid solution with p, L &.2=+ #he acid dissociation constant for this *onoprotic acid is 8.2 C 14D2. A) 4.24R B) 1.2R C) &.2R !) 0.2R Answer" C #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids <1) #he percent dissociation of acetic acid chan es as the concentration of the acid decreases. A 144-fold decrease in acetic acid concentration results in a GGGGGGGG fold GGGGGGGG in the percent dissociation. A) 14) increase B) 14) decrease C) 144) increase !) 144) decrease Answer" A #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids <&) 'hich of the followin are weaA diprotic acids+ A) carbonic acid - ,&C.0) hydrosulfuric acid - ,&$) acetic acid - C,0C.&, B) for*ic acid - ,C.&,) acetic acid - C,0C.&,) benMoic acid - C8,2C.&, C) carbonic acid - ,&C.0) oxalic acid - ,&C&.4) sulfurous acid - ,&$.0 !) hydrocyanic acid - ,C-) sulfuric acid - ,&$.4) phosphoric acid - ,05.4 Answer" C #opic" $ection 14.11 5olyprotic Acids <0) 'hat is the second stepwise equilibriu* constant expression for phosphoric acid ,05.4+
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A) Ka& L ;J,0.9KJ,&5.4-K)?;J,05.4K) B) Ka& L ;J,0.9K&J,5.4&-K)?;J,05.4K) C) Ka& L ;J,0.9K0J5.40-K)?;J,05.4K) !) Ka& L ;J,0.9KJ,5.4&-K)?;J,&5.4-K) Answer" ! #opic" $ection 14.11 5olyprotic Acids <4) Calculate the p, of a 4.4&4 M carbonic acid solution) ,&C.0;aq)) that has the stepwise dissociation constants Ka1 L 4.0 C 14-: and Ka& L 2.8 C 14-11. A) 1.:4 B) 4.40 C) 8.0: !) 14.&2 Answer" B #opic" $ection 14.11 5olyprotic Acids <2) Calculate the p, of a 4.&4 M ,&$.0 solution that has the stepwise dissociation constants Ka1 L 1.2 C 14-& and Ka& L 8.0 C 14-<. A) 1.&8 B) 1.0& C) 1.<& !) &.2& Answer" B #opic" $ection 14.11 5olyprotic Acids <8) Calculate the concentration of bicarbonate ion) ,C.0-) in a 4.414 M ,&C.0 solution that has the stepwise dissociation constants Ka1 L 4.0 C 14-: and Ka& L 2.8 C 14-11. A) 8.8 C 14-2 M B) 4.0 C 14-: M C) 4.0 C 14-= M !) 2.8 C 14-11 M Answer" A #opic" $ection 14.11 5olyprotic Acids <:) 'hat is the p, of a 4.14 M ,&$e solution that has the stepwise dissociation constants Ka1 L 1.0 C 14-4 and Ka& L 1.4 C 14-11+ A) &.44 B) 0.<= C) 4.<= !) 2.24 Answer" A #opic" $ection 14.11 5olyprotic Acids <<) 'hat is the selenide ion concentration J$e&-K for a 4.144 M ,&$e solution that has the stepwise
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dissociation constants of Ka1 L 1.0 C 14-4 and Ka& L 1.4 C 14-11+ A) 0.8 C 14-0 M B) 1.0 C 14-4 M C) 1.0 C 14-2 M !) 1.4 C 14-11 M Answer" ! #opic" $ection 14.11 5olyprotic Acids <=) 'hich of the followin can be classified as a weaA base+ A) C,0-,& B) -,&., C) Both C,0-,& and -,&., !) -either C,0-,& nor -,&., Answer" C #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases =4) 'hat is the p, of a 4.144 M -,0 solution that has Kb L 1.< C 14-2+ #he equation for the dissociation of -,0 is -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq). A) 1.<: B) &.<: C) 11.10 !) 1&.10 Answer" C #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases =1) 'hat is the p, of a 4.04 M pyridine solution that has a Kb L 1.= C 14-=+ #he equation for the dissociation of pyridine is C2,2-;aq) 9 ,&.;l) C2,2-,9;aq) 9 .,-;aq). A) 4.8& B) <.:& C) =.0< !) 14.0< Answer" C #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases =&) Aniline) ;C8,2-,&) Kb L 4.0 C 14-14 at &2IC) is an industrially i*portant a*ine used in the *aAin of dyes. !eter*ine the p, of an aniline solution *ade by dissol(in 0.=4 of aniline in enou h water to *aAe 144 *% of solution. A) 4.<: B) =.10 C) =.:4 !) 14.:4 Answer" B #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases
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=0) !eter*ine the a**onia concentration of an aqueous solution that has a p, of 11.24. #he equation for the dissociation of -,0 ;Kb L 1.< C 14-2) is -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq). A) &.2 M B) 4.22 M C) 2.: C 14-0 M !) 0.& C 14-0 M Answer" B #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases =4) ,ow *any ra*s of pyridine are there in 144 *% of an aqueous solution that has a p, of =.44+ #he Kb for pyridine is 1.= C 14-= and the equation of interest is C2,2-;aq) 9 ,&.;l) C2,2-,9;aq) 9 .,-;aq). A) 4.420 B) 4.4& C) 4.:= !) :.= Answer" B #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases =2) 'hat is the relationship between Ka and Kb at &2IC for a con>u ate acid base pair+ A) Ka C Kb L 1 C 14-14 B) Ka?Kb L 1 C 14-14 C) Kb?Ka L 1 C 14-14 !) Ka 9 Kb L 1 C 14-14 Answer" A #opic" $ection 14.10 Oelation Between 1a and 1b =8) A**onia -,0) has a base dissociation constant of 1.< C 14-2. 'hat is the con>u ate acid of a**onia and what is its acid dissociation constant+ A) -,49) 1.= C 14= B) -,49) 1.< C 14-2 C) -,49) 2.8 C 14-14 !) -,&-) 2.8 C 14-14 Answer" C #opic" $ection 14.10 Oelation Between 1a and 1b

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=:) Methyla*ine C,0-,&) has a base dissociation constant of 0.: C 14-4. 'hat is the con>u ate acid of *ethyla*ine and what is its acid dissociation constant+ A) C,0-,09) &.: C 140 B) C,0-,09) 0.: C 14-4 C) C,0-,09) &.: C 14-11 !) C,0-,&-) &.: C 14-11 Answer" C #opic" $ection 14.10 Oelation Between 1a and 1b =<) Acetic acid C,0C..,) has an acid dissociation constant of 1.< C 14-2. 'hat is the con>u ate base of acetic acid and what is its base dissociation constant+ A) C,0C;.,)&9) 2.8 C 144 B) C,0C;.,)&9) 2.8 C 14-14 C) C,0C..,) 2.8 C 14-14 !) C,0C.&-) 2.8 C 14-14 Answer" ! #opic" $ection 14.10 Oelation Between 1a and 1b ==) !ihydro en phosphate ,&5.4-) has an acid dissociation constant of 8.& C 14-:. 'hat is the con>u ate base of ,&5.4- and what is its base dissociation constant+ A) ,05.4) 1.8 C 148 B) ,05.4) 1.8 C 14-< C) ,5.4&-) 1.8 C 148 !) ,5.4&-) 1.8 C 14-< Answer" ! #opic" $ection 14.10 Oelation Between 1a and 1b 144) 'hich of the followin salts are acidic+ A) %iCl) -aCl) 1Cl B) -,4Cl) CuCl&) AlCl0 C) -aC,0C.&) 1C,0C.&) ObC,0C.& !) -aCl) -,4Cl) -a&C.0 Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 141) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the highest p,+ A) -a,$.4 B) %iCl.4 C) M . !) C,0-,07 Answer" C #opic" $ection 14.14 Acid-Base 5roperties of $alts
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14&) 7f an equal nu*ber of *oles of the weaA acid ,C- and the stron base 1., are added to water) is the resultin solution acidic) basic) or neutral+ A) acidic B) basic C) neutral !) #here is insufficient infor*ation pro(ided to answer this question. Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 140) Arran e the followin 4.14 M aqueous solutions in order of increasin p," -a.,) ,Br) -aC,0C.&) 1Br) -,4Br. A) ,Br) 1Br) -,4Br) -aC,0C.&) -a., B) -a.,) -aC,0C.&) -,4Br) 1Br) ,Br C) -a.,) -aC,0C.&) 1Br) -,4Br) ,Br !) ,Br) -,4Br) 1Br) -aC,0C.&) -a., Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 144) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the highest p,+ A) 17 B) 1Br C) 1Cl !) 1/ Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 142) 'hich one of the followin salts) when dissol(ed in water) produces the solution with a p, closest to :.44+ A) -,4Cl B) Ba. C) -a,$.4 !) Ob7 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 148) Calculate the p, of a 4.144 M -aC,0C.& solution. Ka for acetic acid) C,0C.&,) is 1.< C 14-2. A) &.<: B) 2.10 C) <.<: !) 11.10 Answer" C #opic" $ection 14.14 Acid-Base 5roperties of $alts

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14:) Calculate the p, of a of 4.144 M 1Br. solution. Ka for hypobro*ous acid) ,Br.) is &.4 C 14-=. A) 0.12 B) 4.<2 C) =.12 !) 14.<2 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 14<) Calculate the p, of a 4.144 M C,0-,0Cl solution. Kb for *ethyla*ine) C,0-,&) is 0.: C 14-4. A) &.&& B) 2.:< C) <.&& !) 11.:< Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 14=) 6qual (olu*es of 4.14 M -,0 ;Kb L 1.< C 14-2) and 4.14 M ,C- ;Ka L 4.= C 14-14) are *ixed to ether. 'ill the resultin solution be acidic) basic) or neutral+ A) acidic B) basic C) neutral !) insufficient infor*ation to sol(e Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 114) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the lowest p,+ A) -aCl B) -,4Cl C) M Cl& !) AlCl0 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 111) 'hat is the identity of M in the hydrate M;,&.)8n9 that has the 4.14 M solution with the lowest p,+ A) %i9 B) -a9 C) M &9 !) Al09 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts

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11&) 'hat is the identity of M in the hydrate M;,&.)8n9 that has the 4.14 M solution with the hi hest p,+ A) %i9 B) -a9 C) M &9 !) Al09 Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 110) 'hat is the stron est acid a*on the followin + A) ,/ B) ,Cl C) ,Br !) ,7 Answer" ! #opic" $ection 14.12 /actors #hat Affect Acid $tren th 114) 'hat is the stron est acid a*on the followin + A) ,&. B) ,&$ C) ,&$e !) ,&#e Answer" ! #opic" $ection 14.12 /actors #hat Affect Acid $tren th 112) 'hat is the stron est acid a*on the followin + A) ,/ B) ,Cl C) ,&. !) ,&$ Answer" B #opic" $ection 14.12 /actors #hat Affect Acid $tren th 118) 'hat is the weaAest acid a*on the followin + A) $i,4 B) 5,0 C) ,&$ !) ,Cl Answer" A #opic" $ection 14.12 /actors #hat Affect Acid $tren th

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11:) 'hich acid of the followin set has the stron est con>u ate base+ A) C,4 B) -,0 C) ,&. !) ,/ Answer" A #opic" $ection 14.12 /actors #hat Affect Acid $tren th 11<) 'hat is the stron est base a*on the followin + A) Cl.B) Cl.&C) Cl.0!) Cl.4Answer" A #opic" $ection 14.12 /actors #hat Affect Acid $tren th 11=) 'hat is the stron est acid a*on the followin + A) ,&$.0 B) ,&$.4 C) ,&$e.0 !) ,&$e.4 Answer" B #opic" $ection 14.12 /actors #hat Affect Acid $tren th 1&4) 'hat is the stron est acid of the followin + A) ,.7 B) ,.Br C) ,.Cl !) All are equi(alent. Answer" C #opic" $ection 14.12 /actors #hat Affect Acid $tren th 1&1) 'hat is the stron est acid a*on the followin + A) ,7. B) ,7.& C) ,7.0 !) ,7.4 Answer" ! #opic" $ection 14.12 /actors #hat Affect Acid $tren th

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1&&) 'hat is the stron est acid a*on the followin + A) C,0C.&, B) ClC,&C.&, C) Cl&C,C.&, !) Cl0CC.&, Answer" ! #opic" $ection 14.12 /actors #hat Affect Acid $tren th 1&0) 7dentify the %ewis acid that acts as a reactant in the followin reaction. /e;,&.)809;aq) 9 8 C--;aq) @ /e;C-)80-;aq) 9 8 ,&.;l) A) /e09 B) ,&. C) C-!) /e;,&.)809 Answer" A #opic" $ection 14.18 %ewis Acids and Bases 1&4) 7dentify the %ewis acid that acts as a reactant in the followin reaction. Co;,&.)809;aq) 9 8 -,0;aq) @ Co;-,0)809;aq) 9 8 ,&.;l) A) Co;,&.)809 B) Co09 C) -,0 !) ,&. Answer" B #opic" $ection 14.18 %ewis Acids and Bases 1&2) /or Cu&9 and C.&) which will beha(e as a %ewis acid toward .,- in water+ A) only Cu&9 B) only C.& C) Cu&9 and C.& !) neither Cu&9 nor C.& Answer" C #opic" $ection 14.18 %ewis Acids and Bases 1&8) 'hich one of the followin is not considered to be a %ewis base+ A) ,&. B) -,0 C) -,49 !) ClAnswer" C #opic" $ection 14.18 %ewis Acids and Bases

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1&:) 'hich one of the followin is least able to beha(e as a %ewis base+ A) C,0-,& B) ;C,0)&-, C) ;C,0)0!) ;C,0)0-,9 Answer" ! #opic" $ection 14.18 %ewis Acids and Bases 1&<) #he co*pound B/0 can be described as a;n) GGGGGGGG. A) Arrhenius acid B) Brnsted-%owry acid C) %ewis acid !) %ewis base Answer" C #opic" $ection 14.18 %ewis Acids and Bases 1&=) 7dentify the set of %ewis acids. A) B,0) B/0) Cu&9) C.& B) Cl-) .,-) -,0) ,&. C) ,05.4) ,&5.4-) ,5.4&-) 5.40!) C,0-) -,&-) .,-) /Answer" A #opic" $ection 14.18 %ewis Acids and Bases 104) 'hich one of the followin is expected to be the stron est %ewis acid+ A) /e B) /e9 C) /e&9 !) /e09 Answer" ! #opic" $ection 14.18 %ewis Acids and Bases

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7n the followin reaction the unshaded spheres represent , ato*s.

101) 7dentify the Brnsted-%owry acids. A) ;1) and ;0) B) ;1) and ;4) C) ;&) and ;0) !) ;&) and ;4) Answer" B #opic" Conceptual 5roble*s 10&) 7dentify the Brnsted-%owry bases. A) ;1) and ;0) B) ;1) and ;4) C) ;&) and ;0) !) ;&) and ;4) Answer" C #opic" Conceptual 5roble*s 7n the followin reaction the unshaded spheres represent , ato*s.

100) 7dentify the Brnsted-%owry acids. A) ;1) and ;0) B) ;1) and ;4) C) ;&) and ;0) !) ;&) and ;4) Answer" C #opic" Conceptual 5roble*s

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104) 7dentify the Brnsted-%owry bases. A) ;1) and ;0) B) ;1) and ;4) C) ;&) and ;0) !) ;&) and ;4) Answer" B #opic" Conceptual 5roble*s 7n the followin reaction the unshaded spheres represent , ato*s.

102) 7dentify the Brnsted-%owry acid?base con>u ate pairs. A) ;1)?;&) and ;0)?;4) B) ;1)?;0) and ;&)?;4) C) ;1)?;4) and ;&)?;0) Answer" B #opic" Conceptual 5roble*s 7n the followin reaction the unshaded spheres represent , ato*s.

108) 7dentify the Brnsted-%owry acid?base con>u ate pairs. A) ;1)?;&) and ;0)?;4) B) ;1)?;0) and ;&)?;4) C) ;1)?;4) and ;&)?;0) Answer" B #opic" Conceptual 5roble*s

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#he followin pictures represent aqueous solutions of three acids ,A ;A L N) S) or T)H water *olecules ha(e been o*itted for clarity.

10:) Arran e the three acids in order of increasin acid stren th. A) ,T E ,S E ,N B) ,S E ,T E ,N C) ,T E ,N E ,S !) ,N E ,T E ,S Answer" ! #opic" Conceptual 5roble*s 10<) 'hich acid) if any) is a stron acid+ A) All are stron acids. B) ,N and ,T C) ,S !) -one are stron acids. Answer" C #opic" Conceptual 5roble*s 10=) 'hich acid has the s allest (alue of Ka+ A) ,N B) ,S C) ,T !) All ha(e the sa*e Ka (alue. Answer" A #opic" Conceptual 5roble*s

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144) 'hich acid has the lowest percent dissociation+ A) ,N B) ,S C) ,T !) All ha(e the sa*e percent dissociation. Answer" A #opic" Conceptual 5roble*s 141) 'hich acid solution has the lowest p,+ A) ,N B) ,S C) ,T !) All ha(e the sa*e p,. Answer" B #opic" Conceptual 5roble*s

14&) 'hich of the abo(e pictures represents a solution of a weaA diprotic acid ,&A for which Ka1 BB Ka&+ ;'ater *olecules ha(e been o*itted for clarity.) A) picture ;a) B) picture ;b) C) picture ;c) !) picture ;d) Answer" C #opic" Conceptual 5roble*s

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140) 'hich of the abo(e pictures represents a solution of a diprotic acid ,&A for which Ka1 L and Ka& is exceptionally s*all. ;'ater *olecules ha(e been o*itted for clarity.) A) picture ;a) B) picture ;b) C) picture ;c) !) picture ;d) Answer" B #opic" Conceptual 5roble*s #he followin pictures represent equal (olu*es of aqueous solutions of three acids ,A ;A L N) S) or T)H water *olecules ha(e been o*itted for clarity.

144) Arran e the acids in order of increasin acid stren th. A) ,T E ,S E ,N B) ,S E ,T E ,N C) ,T E ,N E ,S !) ,N E ,T E ,S Answer" B #opic" Conceptual 5roble*s 142) Arran e the acids in order of increasin (alue of Ka. A) Ka;,T) E Ka;,S) E Ka;,N) B) Ka;,S) E Ka;,T) E Ka;,N) C) Ka;,T) E Ka;,N) E Ka;,S) !) Ka;,N) E Ka;,T) E Ka;,S) Answer" B #opic" Conceptual 5roble*s 148) Arran e the acids in order of increasin (alue of percent dissociation. A) ,T E ,S E ,N B) ,S E ,T E ,N C) ,T E ,N E ,S !) ,N E ,T E ,S Answer" B #opic" Conceptual 5roble*s

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14:) Arran e the acids in order of increasin p,. A) ,T E ,S E ,N B) ,S E ,T E ,N C) ,T E ,N E ,S !) ,N E ,T E ,S Answer" ! #opic" Conceptual 5roble*s 14<) Arran e the con>u ate bases ;A- L N-) S-) or T-) in order of increasin base stren th. A) T- E S- E NB) S- E T- E NC) T- E N- E S!) N- E T- E SAnswer" ! #opic" Conceptual 5roble*s 14=) Arran e the con>u ate bases ;A- L N-) S-) or T-) in order of increasin (alue of Kb. A) Kb;T-) E Kb;S-) E Kb;N-) B) Kb;S-) E Kb;T-) E Kb;N-) C) Kb;T-) E Kb;N-) E Kb;S-) !) Kb;N-) E Kb;T-) E Kb;S-) Answer" ! #opic" Conceptual 5roble*s

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124) #he followin pictures represent solutions of three salts -aA ;A- L N-) S-) or T-)H water *olecules and -a9 ions ha(e been o*itted for clarity. Arran e the three A- ions in order of decreasin base stren th.

A) N- B S- B TB) N- B T- B SC) S- B T- B N!) T- B S- B NTAnswer" B #opic" Conceptual 5roble*s

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#he followin pictures represent solutions of three salts MAH water *olecules ha(e been o*itted for clarity. !otted spheres represent Ay- ionsH ray spheres represent Mx9 ionsH blacA spheres represent oxy en ato*sH and unshaded spheres represent hydro en ato*s.

121) 'hich picture represents an acidic salt+ A) ;1) B) ;&) C) ;0) !) -one of these Answer" B #opic" Conceptual 5roble*s 12&) 'hich picture represents a neutral salt+ A) ;1) B) ;&) C) ;0) !) -one of these Answer" C #opic" Conceptual 5roble*s 120) 'hich picture represents a basic salt+ A) ;1) B) ;&) C) ;0) !) -one of these Answer" A #opic" Conceptual 5roble*s

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124) .f the ele*ents indicated on the periodic table shown abo(e) which for*s the stron est binary acid) ,&N or ,N) where N L A) B) C) or !+ A) A B) B C) C !) ! Answer" ! #opic" Conceptual 5roble*s 122) .f the ele*ents indicated on the periodic table shown abo(e) which for*s the weaAest binary acid) ,&N or ,N) where N L A) B) C) or !+ A) A B) B C) C !) ! Answer" A #opic" Conceptual 5roble*s 128) .f the ele*ents indicated on the periodic table shown abo(e) which for*s the stron est oxoacid acid with the for*ula ,&N.0 or ,N.0) where N L A) B) C) or !+ A) A B) B C) C !) ! Answer" B #opic" Conceptual 5roble*s 12:) .f the ele*ents indicated on the periodic table shown abo(e) which for*s the weaAest oxoacid acid with the for*ula ,&N.0 or ,N.0) where N L A) B) C) or !+ A) A B) B C) C !) ! Answer" C #opic" Conceptual 5roble*s
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12<) $.0 reacts with ,&. to for* ,&$.4. 'hich picture below correctly represents the cur(ed arrow notation for the initial %ewis acid-%ewis base interaction in this reactionH what is the %ewis acid and the %ewis base+

A) 5icture ;1) is correctH ,&. is the %ewis acid and $.0 is the %ewis base. B) 5icture ;1) is correctH $.0 is the %ewis acid and ,&. is the %ewis base. C) 5icture ;&) is correctH ,&. is the %ewis acid and $.0 is the %ewis base. !) 5icture ;&) is correctH $.0 is the %ewis acid and ,&. is the %ewis base. Answer" ! #opic" Conceptual 5roble*s 12=) C.& reacts with ,&. to for* ,C.0- and ,9. 'hich picture below correctly represents the cur(ed arrow notation for the initial %ewis acid-%ewis base interaction in this reactionH what is the %ewis acid and the %ewis base+

;1)

;&)

A) 5icture ;1) is correctH ,&. is the %ewis acid and C.& is the %ewis base. B) 5icture ;1) is correctH C.& is the %ewis acid and ,&. is the %ewis base. C) 5icture ;&) is correctH ,&. is the %ewis acid and C.& is the %ewis base. !) 5icture ;&) is correctH C.& is the %ewis acid and ,&. is the %ewis base. Answer" B #opic" Conceptual 5roble*s

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184) B/0 and -,0 under o a %ewis acid-base reaction for*in an adduct. 'hich picture below correctly represents the cur(ed arrow notation for the initial %ewis acid-%ewis base interaction in this reactionH what is the %ewis acid and the %ewis base+

A) 5icture ;1) is correctH -,0 is the %ewis acid and B/0 is the %ewis base. B) 5icture ;&) is correctH B/0 is the %ewis acid and -,0 is the %ewis base. C) 5icture ;0) is correctH -,0 is the %ewis acid and B/0 is the %ewis base. !) 5icture ;4) is correctH B/0 is the %ewis acid and -,0 is the %ewis base. Answer" B #opic" Conceptual 5roble*s 14.& Al orith*ic Questions 1) 'hen dissol(ed in water) which co*pound is enerally considered to be an Arrhenius acid+ A) , -.& B) 1., C) %i / !) C,0., Answer" A #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory &) 'hich Brnsted-%owry acid is not considered to be a stron acid in water+ A) , 7 B) , Br C) ,&$ .0 !) , -.0 Answer" C #opic" $ection 14.& Acid $tren th and Base $tren th

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0) Calculate the hydroniu* ion concentration in an aqueous solution that contains &.24 C 14- 8 M in hydroxide ion. A) 4.44 C 14- : M B) 4.44 C 14- < M C) 4.44 C 14- = M !) 2.44 C 14- = M Answer" C #opic" $ection 14.4 !issociation of 'ater 4) Calculate the hydroxide ion concentration in an aqueous solution that contains 0.24 C 14- 4 M in hydroniu* ion. A) &.<8 C 14- 0 M B) &.<8 C 14- 14 M C) &.<8 C 14- 11 M !) 0.24 C 14- 11 M Answer" C #opic" $ection 14.4 !issociation of 'ater 2) A solution with a hydro en ion concentration of 0.&2 C 14- 8 M is GGGGGGGG and has a hydroxide ion concentration of GGGGGGGG. A) acidic) 0.4< C 14- < M B) acidic) 0.4< C 14- = M C) basic) 0.4< C 14- < M !) basic) 0.4< C 14- = M Answer" B #opic" $ection 14.4 !issociation of 'ater 8) A solution with a hydroxide ion concentration of 4.12 C 14- 8 M is GGGGGGGG and has a hydro en ion concentration of GGGGGGGG. A) acidic) &.41 C 14- < M B) acidic) &.41 C 14- = M C) basic) &.41 C 14- < M !) basic) &.41 C 14- = M Answer" ! #opic" $ection 14.4 !issociation of 'ater :) Calculate the p, for an aqueous solution of acetic acid that contains &.12 C 14-0 M hydroniu* ion. A) 4.82 C 14-1& M B) &.12 C 14-0 M C) &. 8: !) 11. 00 Answer" C #opic" $ection 14.2 #he p, $cale

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<) Calculate the p, for an aqueous solution of pyridine that contains &.12 C 14-4 M hydroxide ion. A) 4.82 C 14-11 B) &.12 C 14-4 C) 0. 8: !) 14. 00 Answer" ! #opic" $ection 14.2 #he p, $cale =) 'hat is the hydroxide ion concentration and the p, for a hydrochloric acid solution that has a hydroniu* ion concentration of 1.24 C 14-& M+ A) 8.8: C 14- 1& M) &.<& B) 8.8: C 14- 1& M) 11.1< C) 8.8: C 14- 10 M) 1.<& !) 8.8: C 14- 10 M) 1&.1: Answer" C #opic" $ection 14.2 #he p, $cale 14) 'hat is the hydroniu* ion concentration and the p, for an aqueous solution of -,0 that has a hydroxide ion concentration of &.&2 C 14-& M+ A) 4.44 C 14- 1& M and &.82 B) 4.44 C 14- 1& M and 11.02 C) 4.44 C 14- 10 M and 1.82 !) 4.44 C 14- 10 M and 1&.02 Answer" ! #opic" $ection 14.2 #he p, $cale 11) 'hat is the hydroniu* ion concentration of an acid rain sa*ple that has a p, of 0. 42+ A) &.<& C 14-11 M B) 0.22 C 14-4 M C) 0. 42 M !) 14. 22 M Answer" B #opic" $ection 14.2 #he p, $cale 1&) 'hat is the hydroxide ion concentration of a lye solution that has a p, of =.&4+ A) 8.01 C 14- 14 M B) 1.2< C 14- 2 M C) 4.<4 M !) =.&4 M Answer" B #opic" $ection 14.2 #he p, $cale

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10) 'hat is the p, of a 4. 4&4 M ,Cl.4 solution+ A) 4. 4&4 B) 4. 444 C) 1.:4 !) 1&.04 Answer" C #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 14) 'hat is the p, of a 4.4 44 M Ba;.,)& solution+ A) 1.14 B) 1.44 C) 1&.84 !) 1&.=4 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 12) 'hat is the p, of a solution prepared by dissol(in 4. 42 ra*s of solid Ca. ;li*e) in enou h water to *aAe &.44 % of aqueous Ca;.,)& ;li*ewater)+ Ca.;s) 9 ,&.;l) @ Ca&9;aq) 9 & .,-;aq) A) &.14 B) &.44 C) 11.84 !) 11.=4 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 18) 'hat is the p, of a solution prepared by dilutin &4.44 *% of 4.14 M ,Cl with enou h water to produce a total (olu*e of 144.44 *%+ A) 1.44 B) 1. :4 C) &.44 !) 0.44 Answer" B #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 1:) 'hat is the p, of a solution prepared by dilutin 144.44 *% of 4.4&4 M Ba;.,)& with enou h water to produce a total (olu*e of &24.44 *%+ A) 1.<4 B) &. 14 C) 11.=4 !) 1&.&4 Answer" ! #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases

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1<) 'hat is the p, of a solution prepared by *ixin 144.44 *% of 4.&4 M ,Cl with 124.44 *% of 4. 14 M ,Cl+ Assu*e that the (olu*es are additi(e. A) 4. 1: B) 4. 2& C) 4. <2 !) 1.:4 Answer" C #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 1=) 'hat is the p, of a solution prepared by *ixin 144.44 *% of 4.4&4 M Ca;.,)& with 24.44 *% of 4. 044 M -a.,+ Assu*e that the (olu*es are additi(e. A) 10.42 B) 10.14 C) 10.&< !) 10.2< Answer" B #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases &4) 'hat is the hydroniu* ion concentration of a 4. 244 M acetic acid solution with Ka L 1.< C 14-2+ #he equation for the dissociation of acetic acid is" C,0C.&,;aq) 9 ,&.;l) ,0.9;aq) 9 C,0C.&-;aq). A) 0.4 C 14-& M B) 4.& C 14-& M C) 0.4 C 14-0 M !) 4.& C 14-0 M Answer" C #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids &1) 'hat is the hydroniu* ion concentration of a 4. 124 M hypochlorous acid solution with Ka L 0.2 C 14-<+ #he equation for the dissociation of hypochlorous acid is" ,.Cl;aq) 9 ,&.;l) ,0.9;aq) 9 .Cl-;aq). A) 1.= C 14-4 M B) :.& C 14-4 M C) &.< C 14-2 M !) :.& C 14-2 M Answer" ! #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids

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&&) 5otassiu* hydro en phthalate ;*olar *ass L &44.& ?*ol)is one of the *ost co**only used acids for standardiMin solutions containin bases. 1,5 is a *onoprotic weaA acid with Ka L 0.=1 C 14-8. Calculate the p, of the solution that results when 4. 24 of 1,5 is dissol(ed in enou h water to produce &2.4 *% of solution. A) &.42 B) 0. &1 C) 4. 44 !) 2.41 Answer" B #opic" $ection 14.= Calculatin 6quilibriu* Concentrations in $olutions of 'eaA Acids &0) Calculate the p, of a 4. 4<4 M carbonic acid solution) ,&C.0;aq)) that has the stepwise dissociation constants Ka1 L 4.0 C 14-: and Ka& L 2.8 C 14-11. A) 1.14 B) 0.:0 C) 8.0: !) 14.&2 Answer" B #opic" $ection 14.11 5olyprotic Acids &4) Calculate the p, of a 4. 84 M ,&$.0) solution that has the stepwise dissociation constants Ka1 L 1.2 C 14-& and Ka& L 8.0 C 14-<. A) 1.4& B) 1.48 C) 1.<& !) &.44 Answer" B #opic" $ection 14.11 5olyprotic Acids &2) Calculate the concentration of bicarbonate ion) ,C.0-) in a 4.4 14 M ,&C.0 solution that has the stepwise dissociation constants Ka1 L 4.0 C 14-: and Ka& L 2.8 C 14-11. A) 8.8 C 14- 2 M B) 4.0 C 14-: M C) 4.0 C 14- = M !) 2.8 C 14-11 M Answer" A #opic" $ection 14.11 5olyprotic Acids &8) 'hat is the p, of a 4. 44 M ,&$e solution that has the stepwise dissociation constants Ka1 L 1.0 C 14-4 and Ka& L 1.4 C 14-11+ A) &. 14 B) 0.<= C) 4. &< !) 2. 2: Answer" A #opic" $ection 14.11 5olyprotic Acids
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&:) 'hat is the selenide ion concentration J$e&-K for a 4. 144 M ,&$e solution that has the stepwise dissociation constants of Ka1 L 1.0 C 14-4 and Ka& L 1.4 C 14-11+ A) 0.8 C 14-0 M B) 1.0 C 14-4 M C) 1.0 C 14-2 M !) 1.4 C 14-11 M Answer" ! #opic" $ection 14.11 5olyprotic Acids &<) 'hat is the p, of a 4. &44 M -,0 solution that has Kb L 1.< C 14-2+ #he equation for the dissociation of -,0 is -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq). A) &.4& B) &. :& C) 11. =< !) 11.&< Answer" ! #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases &=) 'hat is the p, of a 4.04 M pyridine solution that has 1b L 1.= C 14-=+ #he equation for the dissociation of pyridine is C2,2-;aq) 9 ,&.;l) C2,2-,9;aq) 9 .,-;aq). A) 4. 8& B) <.:& C) =. 0< !) 14. 0< Answer" C #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases 04) Aniline) ;C8,2-,&) Kb L 4.0 C 14-14 at &2IC) is an industrially i*portant a*ine used in the *aAin of dyes. !eter*ine the p, of an aniline solution *ade by dissol(in 8.=4 of aniline in enou h water to *aAe 144 *% of solution. A) 4. :2 B) =. &2 C) =. 24 !) 14. 24 Answer" B #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases

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01) !eter*ine the a**onia concentration of an aqueous solution that has a p, of 11. 44. #he equation for the dissociation of -,0 ;Kb L 1.< C 14-2) is -,0;aq) 9 ,&.;l) -,49;aq) 9 .,-;aq). A) 0.4 M B) 4. 428 M C) 1.< C 14- & M !) 1.4 C 14-0 M Answer" B #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases 0&) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the highest p,+ A) 1, C.0 B) CsCl.4 C) Oa. !) C,0C,0-,0Cl Answer" C #opic" $ection 14.14 Acid-Base 5roperties of $alts 00) 7f an equal nu*ber of *oles of the weaA acid ,C- and the stron base 1., are added to water) is the resultin solution acidic) basic) or neutral+ A) acidic B) basic C) neutral !) #here is insufficient infor*ation pro(ided to answer this question. Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 04) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the highest p,+ A) Ob7 B) ObBr C) ObCl !) Ob/ Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 02) 'hich one of the followin salts) when dissol(ed in water) produces the solution with a p, closest to :.44+ A) -,4Br B) Ca . C) 1 ,$.4 !) Cs 7 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts

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08) Calculate the p, of a 4.<44 M -aC,0C.& solution. Ka for acetic acid) C,0C.&,) is 1.<= C 14-2. A) &. 4& B) 4.8< C) =.0& !) 11. 2< Answer" C #opic" $ection 14.14 Acid-Base 5roperties of $alts 0:) Calculate the p, of a 1.84 M 1Br. solution. Ka for hypobro*ous acid) ,Br.) is &.4 C 14-=. A) &.22 B) 4.&2 C) =. :2 !) 11.42 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts 0<) Calculate the p, of a 1.84 M C,0-,0Cl solution. Kb for *ethyla*ine) C,0-,&) is 0.: C 14-4. A) 1.81 B) 2. 1< C) <. <& !) 1&.0= Answer" B #opic" $ection 14.14 Acid-Base 5roperties of $alts 0=) 'hich one of the followin salts) when dissol(ed in water) produces the solution with the lowest p,+ A) -aCl B) 1Cl C) M Cl& !) AlCl0 Answer" ! #opic" $ection 14.14 Acid-Base 5roperties of $alts

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14.0 $hort Answer Questions 1) #he Brnsted-%owry acids in the che*ical equation below are GGGGGGGG and GGGGGGGG. ,-.&;aq) 9 ,&.;l) ,0.9;aq) 9 -.&D;aq) Answer" ,-.&) ,0.9 #opic" $ection 14.1 Acid-Base Concepts" #he Bronsted-%owry #heory &) #he equilibriu* constant for the reaction below has the (alue Ka L 0.2 C 14-4. 7n this reaction the stron er Brnsted-%owry acid is GGGGGGGG and the weaAer Brnsted-%owry acid is GGGGGGGG. ,/;aq) 9 ,&.;l) ,0.9;aq) 9 /D;aq) Answer" ,0.9) ,/ #opic" $ection 14.& Acid $tren th and Base $tren th 0) A proton hydrated by four water *olecules has the for*ula GGGGGGGG. Answer" ,=.49 #opic" $ection 14.0 ,ydrated 5rotons and ,ydroniu* 7ons 4) #he nu*ber of waters of hydration in the hydrate proton ,:.09 is GGGGGGGG. Answer" 0 #opic" $ection 14.0 ,ydrated 5rotons and ,ydroniu* 7ons 2) An acidic solution with hydroniu* ion concentration J,9K L 1.84 C 14D0 M has a hydroxide ion concentration J.,DK L GGGGGGGG. Answer" 8.&2 C 14D1& M #opic" $ection 14.4 !issociation of 'ater 8) #he concentration of ,0.9 in hu*an sweat can be as low as &.2 14-8. #he concentration of .,- in the sweat is GGGGGGGG) and this solution is GGGGGGGG ;acidic) basic) neutral). Answer" 4.4 14-=) acidic #opic" $ection 14.4 !issociation of 'ater :) Fndersea flora prefer a *axi*u* concentration of .,- of 1.2< 14-2. #he concentration of ,0.9 in the seawater is GGGGGGGG) and this solution is GGGGGGGG ;acidic) basic) neutral). Answer" 8.01 14-14) basic #opic" $ection 14.4 !issociation of 'ater <) At the nor*al body te*perature of 0:IC) Kw L &.4& 14-14. #he ,0.9 concentration of nor*al blood ran es fro* 0.2 14-< to 4.2 14-<. #he .,- concentration of nor*al blood ran es fro* GGGGGGGG to GGGGGGGG) and blood is GGGGGGGG ;acidic) basic) neutral). Answer" &.& 14-:) &.= 14-:) basic #opic" $ection 14.4 !issociation of 'ater

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=) At 24IC the (alue of Kw is 2.2 C 14D14) and the p, of a neutral solution at 24IC is GGGGGGGG. Answer" 8.80 #opic" $ection 14.2 #he p, $cale 14) .ne way to prepare a solution with a p, of 14.44 is to dissol(e GGGGGGGG ra*s of Ca. in enou h water to *aAe 244 *% of solution. Answer" 1.4 14-0 #opic" $ection 14.2 #he p, $cale 11) Bro*othy*ol blue indicator chan es color fro* yellow at a p, of 8.4 to blue at a p, of :.8. 5henol red indicator chan es color fro* yellow at a p, of 8.< to red at a p, of <.4. A sa*ple of pancreatic fluid ha(in J.,-K L 1.&2< 14-8 would i*part a GGGGGGGG color to bro*othy*ol blue and a GGGGGGGG color to phenol red. Answer" blue) red #opic" $ection 14.8 Measurin p, 1&) Bro*othy*ol blue indicator chan es color fro* yellow at a p, of 8.4 to blue at a p, of :.8. Methyl red indicator chan es color fro* red at a p, of 4.4 to yellow at a p, of 8.&. A sa*ple of sali(a ha(in J,0.9K L 8.014 14-: would i*part a GGGGGGGG color to bro*othy*ol blue and a GGGGGGGG color to *ethyl red. Answer" yellow) yellow #opic" $ection 14.8 Measurin p, 10) #he p, of a 4.4&2 M 1., solution is GGGGGGGG. Answer" 1&.44 #opic" $ection 14.: #he p, in $olutions of $tron Acids and $tron Bases 14) #he (alue of Ka for a 4.&24 M ,C- solution ha(in a p, of 4.=28 is GGGGGGGG. Answer" 4.=4 C 14D14 #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 12) 7n order for the reaction ,A 9 ,$.0- A- 9 ,&$.0 to ha(e an equilibriu* constant Kc E 1) the Ka of ,A *ust be GGGGGGGG ; reater) less) than the Ka of ,$.0-. Answer" less #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 18) 7n order for the reaction A- 9 ,&C.0 ,A 9 ,C.0- to ha(e an equilibriu* constant Kc E 1) the Ka of ,A *ust be GGGGGGGG ; reater) less) than the Ka of ,&C.0. Answer" reater #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids 1:) A 1.&2 14-4 M solution of the anti-infla**atory dru naproxen has a p, L 4.&. #he Ka and pKa of naproxen are GGGGGGGG and GGGGGGGG. Answer" 8.0 14-2) 4.& #opic" $ection 14.< 6quilibria in $olutions of 'eaA Acids
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1<) 5henobarbital is an antiepileptic dru with a water solubility of 4.0 14-0 M and pKa L :.4. 'hat is the p, and percent ioniMation of 4.0 14-0 M phenobarbital+ Answer" 4.<<) 4.04R #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids 1=) 5henobarbital has a pKa L :.4. Co*pared to a 1.4 14-0 M solution) 1.4 14-4 M phenobarbital will ha(e a GGGGGGGG ;hi her) lower) p, and a GGGGGGGG ;hi her) lower) percent ioniMation. Answer" hi her) hi her #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids &4) 6rythro*ycin is a basic anti*icrobial with pKb L 2.&. A 1.4 14-0 M solution of erythro*ycin has a p, of and a percent ioniMation. Answer" =.=) <R #opic" $ection 14.14 5ercent !issociation in $olutions of 'eaA Acids &1) A 4.424 M solution of hydroxyla*ine) -,&.,) ha(in Kb L =.1 C 14D= has a p, of GGGGGGGG. Answer" =.00 #opic" $ection 14.1& 6quilibria in $olutions of 'eaA Bases &&) A 4.14 M 1-.& solution will ha(e a p, GGGGGGGG se(en. Answer" reater than #opic" $ection 14.14 Acid-Base 5roperties of $alts &0) #he acid stren th of an oxoacid ha(in the eneral for*ula ,nS.m increases as the electrone ati(ity of S GGGGGGGG and as the oxidation nu*ber of S GGGGGGGG. Answer" increases) increases #opic" $ection 14.12 /actors #hat Affect Acid $tren th &4) 7n the aquation reaction Co&9 9 8 ,&. @ JCo;,&.)8K&9) the %ewis acid is GGGGGGGG and the %ewis base isGGGGGGGG. Answer" Co&9) ,&. #opic" $ection 14.18 %ewis Acids and Bases &2) 7n the reaction between -.& and ,&. that produces ,-.0) the %ewis acid is GGGGGGGG and the %ewis base is GGGGGGGG. Answer" -.&) ,&. #opic" $ection 14.18 %ewis Acids and Bases

21 Copyri ht 3 &41& 5earson 6ducation) 7nc.