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METALLURGICA
V o l . S, pp. 1 2 7 - 1 3 0 , Printed in t h e U n i t e d
1971 States
Pergamon
Press,
Inc.
STRESS-ASSISTED
MARTENSITE
FORMATION IN TiNi
R. J. Wasilewski
A s and Af.
loop is very wide, and A >>M . s s the hysteresis may be quite small, as in AuCd (i), In-Tl (2), or TiNi (3). the hysteresis
martenslte Khandros
is very small, and in fact was not observed at all by Kurdyumov and
(4) in Cu-AI-Ni alloys. formation can be initiated above the M The maximum temperature temperature by the s at which martensite can be thus specimen orientaas an inherent to as
formed is denoted as M d.
This temperature depends on the stress conditions, other factors, itself. and thus cannot be considered
The transformation
"strain martensite".
Such transformations
~-titanium low
alloys, where the ~' (strain martensite) stress levels. As shown by Kulin et al.,
formati~n provides useful ductility at relatively (5) under some conditions formation. transformations,
A phenomenon which is related to some martensitic In-Tl alloys, (6,7) is the ability of the material
twinned martensite
this rationalization
is in fair agreement with the few available observations. Firstly, such a reversible twin-boundary of "elastic
some reservations
to it can be raised.
is certainly untypical
in twinned structures,
127
128
Vol.
5, No.2
completely uniform, single-crystal, orientation (i0); inasmuch as no lattice damage is involved in the migration and the implied disappearance of these coherent twin boundaries, it is difficult to rationalize the reappearance of these twin boundaries, in what is now a martenslte single crystal, on the relaxation of the stress. Rather one would expect that the (now only Thirdly, a martensite
formed from an ordered parent structure is also ordered, and twin formation in ordered lattices is energetically unfavorable (ii). We shall propose here an alternative explanation for this
behavior, based directly on the effect of the applied stress on the transformation. Most of the observations to date have been interpreted in terms of materials in which the strain martenslte was observed after the deformation. The stability of such a transformation product
on the removal of the applied stress depends primarily on the temperature relative to the Mf and Af temperatures of the "stress-free" transformation. In ferrous materials M s < M d < A s. Thus,
although an applied stress results in martenslte formation significantly above Ms, the reverse transformation requires subsequent heating about the As-A f range; remains stable. The situation is significantly different when the thermal hysteresis of "stress-free" transformation is small. In particular, the Md temperature may well lie above Af, in which case the otherwise, the martensite
martensite formed on the application of stress at temperatures Af < T < M d will be unstable in the absence of the applied stress. To check this effect, the stress-straln behavior of a Ti-51 at.% Ni specimen was in6O SO vestigated. This material was processed to
~'40
exhibit an (As-Af) range of -5 to +10C, and tested at 20C in compression (4:1 length:diameter ratio). The stress-straln
data were obtained from an x-y recorder plot of the outputs from the load cell and a resistance strain gage for successive loading to increasing levels. The behavior observed, shown in Figure i, is consistent with the expected instability of the martensite. The apparent yield
2O I0
/
Anelastic Martensite Formation in Ti-51% Ni (A~ <I0C) at 20C; Final e <0.02%--
FIG i.
unloading, there is a distinct hysteresis effect, the hysteresis loop broadening with increasing maximum load. The absence of residual plastic deformation has been confirmed by
measurement of the specimen after the completion of the tests; the permanent set was <--0.02 percent.
Vol.
5,
No.
STRESS-ASSISTED
MARTENSITE
FORMATION
IN T i N i
129
product cannot be considered as "elastic" martensite. deformation, the term "anelastic martensite"
irreversible
regu-
Thus, the recovery cannot have been due to a reversible twln-boundary movement
twin-
in the transforma-
MI
B' + M"
in the orientation
trans-
orientation m o s t compatible
We note that this may, but not necessarily will, b__eethe second "twinobtained under stress-free that form transformation conditions. In general, the
We further note that the return to the original configuration be accounted for. Assuming
untransformed,
are sufficient
It is probable damage
as it seems unlikely
that no irreversible
that the origin of the anelastic behavior observed stems directly from
structure transformation, and that the prior existence of any specific condition. It is suggested that to regard the heterogeneous tranforma(12). The
tion of the parent lattice to two or more alternate martensite apparent twin-like coherency observed in some heterogeneous structure,
structures
to the particular
The most striking published account of such as twin formation that (13),
and formed the basis for a theory of "continuous mechanical these observations merely indicate the remarkable sitic transformations and of deformation twinning.
It is suggested
similarities
transformation,
and
of the mechanism of the "mechanical memory" in TiNi, will be reported elsewhere. been sponsored by the Battelle Memorial Institute Columbus Laboratories.
130
STRESS-ASSISTED
MARTENSITE
FORMATION
IN T i N i
Vol.
5~ No.
References 1. D. S. Lieberman, "The Mechanism of Phase Transformations in Crystalline Sollds", Inst. of Metals Monograph, #33, 167 (1969). J. W. Bowles, C. S. Barrett, and L. Guttman, Trans. AIME, 188, 1478 (1950). R. J. Wasilewskl, S. R. Butler, and J. E. Hanlon, Met. Sci. J., ~, 104 (1967). G. V. Kurdyumov and L. G. Khandros, Doklady A. N. SSSR, 66, 211 (1949). S. A. Kulin, M. Cohen, and B. L. Averbach, Trans. AIME, 194, 661 (1952). M. W. Burkart and T. A. Read, Trans. AIME, 197, 1516 (1953). Z. S. Baslnski and J. W. Christian, ActaMet., ~, i01 (1954). D. S. Lieberman, M. S. Wechsler, and T. A. Read, J. appl. Phys., 26, 473 (1955). R. I, Garber, Zh. Exp. Teor. Fiz., 17, 63 (1947). H. K. Birnbaum and T. A. Read, Trans. AIME, 218, 662 (1960). F. Laves, Acta Met., 14, 58 (1966). K. Otsuka and K. Shimlzu, Japan J. appl. Phys., 8, 1106 (1969). G. F. Bo11Ing and R. H. Richman, Acta Met., 13, 723 (1965).