Cover

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Cover

Evaporative Emissions from Storage Tanks

API - Chapter 19 - Evaporative Loss Measurement
Formely API Publication 2518, 2517 & 2519 Print the instructions first (select the Introduction tab). Select the appropriate tab and get started!
If you encounter any problems, please contact L. Constantinou Shell Global Solutions GSNL-GSDM phone: +31 (0)70 377 4332 or +31 (0)6 552097660; email: L. Constantinou@shell.com
The copyright of this document is vested with Shell Global Solutions Intenational B.V, The Hague, the Netherlands. All rights reserved. Neither the whole nor any part of this document or software may be reproduced, stored in any retrieval system or transmitted in any form or by any means (electronic, mechanical, reprographic, recording or otherwise) without the prior written consent of the copyright owner.

SHELL GLOBAL SOLUTIONS INTERNATIONAL, THE HAGUE

Emission_V3.1 ; 21 December 2004

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Cover

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Evaporative Emissions from Storage Tanks - Property of OGBH/3, Shell Global Solutions, Shell International Oil Products B.V.

CONFIDENTIAL

Evaporative Emissions from Storage Tanks

1. Introduction
1.1 Purpose and Scope The American Petroleum Institute (API) has defined standards for the calculation of evaporative emissions from well maintained storage tanks: External Floating Roof Tanks (EFRTs), Fixed Roof tanks with Internal Floating Roof Tanks (IFRTs), Floating Roof tanks with domes (often referred to as Covered Floating Roof Tanks - CFRTs) and Fixed Roof Tanks. As these calculations are rather complex and time consuming, OGLM (then OGBH/3) set up a computer package which reproduces the manual calculations as laid out in the following API publications: Manual of Petroleum Measurement Standards Chapter 19--Evaporative Loss Measurement Section 2--Evaporative Loss From Floating-Roof Tanks FIRST EDITION, APRIL 1997 (FORMERLY, API PUBLICATIONS 2517 AND 2519) and Manual of Petroleum Measurement Standards Chapter 19--Evaporative Loss Measurement Section 1--Evaporative Loss From Fixed-Roof Tanks THIRD EDITION, MARCH 2002 (FORMERLY API PUBLICATION 2518) The original package was developed on Excel (Windows 95 version). This version is an upgrade of the previous one based on the changes of API MPMS Chapter 19 section 1. This spreadsheet package has been upgraded on Excel (Windows 2000 version) and supersedes the previous Windows 95 version Whilst the calculations strictly follow the methods described in the above mentioned publications, the input data is in SI units instead of British units. This package is intended to be used in oil refineries and oil products depots. However, it could equally be used to calculate emissions from storage tanks in chemical installations.

1.2 Copyright, Confidentiality and Security The copyright of this document is vested with Shell Global Solutions International B. V., The Hague, the Netherlands. All rights reserved. Neither the whole nor any part of this document or software may be reproduced, stored in any retrieval system or transmitted in any form or by any means (electronic, mechanical, reprographic, recording or otherwise) without the prior written consent of the copyright owner. This software product shall only be used by companies which have a service agreement with Shell Global Solutions International B.V. or have obtained written permission to use this product. 1.3. Details of third party licenses This package does not contain any third party license material.

1.4. Support for software supplied to customers Formal training is not available for this software package. For questions, remarks and support for this spreadsheet, please contact the custodian: Ed De Saegher OGNL - OGLM Shell Global Solutions International Postbus 541 2501 CM Den Haag The Netherlands Tel.: +31 (0)70 377 2515 or +31 (0)6 5512 4912 Fax: +31 (0) 70 377 2943 email: ed.desaegher@shell.com

2. The workbook
The computer program consists of six sheets. They all are write-protected, to avoid inadvertent erasure of the formulae or range names. These sheets are described in the sections underneath. 2.1 Cover sheet This is the first thing that you will see when you open this workbook. It is automatically loaded on start-up and corresponds to the Cover tab.

2.2 Guidelines This is where you are at the moment. It corresponds to the Introduction tab. You can print this sheet by pressing the button. Print

2.3 Emissions from floating roof tanks

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This corresponds to the Floating Roof tab. This sheet will enable you to calculate hydrocarbon emissions from: - External Floating Roof Tanks (EFRTs); - Fixed Roof tanks with Internal Floating Roof Tanks (IFRTs); - Floating Roof tanks with domes, often referred to as Covered Floating Roof Tanks (CFRTs). Colour codes The following colour codes have been used for the fonts: Blue User input required: these are the only cells that are not write-protected. Black Calculated cell. Red Used to highlight specific items, e.g.. provide guidelines. Input requirements - General information: location, author, etc. - Climatic data - Ambient temperature in C. - Wind speed in m/s. - Atmospheric pressure in mbara. - Product data - Name and any comments. - Type: crude oil or product. - Net throughput in tonnes. This corresponds to the total quantity of stock withdrawn from the tank. If filling and emptying occur simultaneously so that the liquid level does not change, the net throughput is zero during the period concerned. Thus, the net throughput is not necessarily the total amount of hydrocarbons drawn from the tank. - Reid Vapour Pressure (RVP) in mbara. - The slope of the distillation curve at 10% evaporated in C/10%. This information is not required for crude oils. - Average density of the liquid at the average stock temperature in C. - Density of the condensed vapour in kg/m3. - Molecular weight of the condensed vapour in kg/kmol. Note that information may be partly available in the Product Data sheet. - Tank data - Type: EFRT, IFRT or CFRT (External Floating Roof Tank, Internal Floating Roof Tank, Covered Floating Roof Tank) - Type: Vertical or Horizontal tank - Tank diameter in m. - Shell condition. - Tank colour. - Storage temperature in C. If this information is not available, leave the cell blank: the spreadsheet will make an assessment of this value. - Deck construction: welded or bolted; refer to the notes for guidance in the appropriate cells. - Deck seam length factors in m/m2; refer to the notes for guidance in the appropriate cells. - Seals - Seal fitting: average or tight fitting. - Seal type. A wide selection is available here. Enter 1 against the appropriate type. - Deck fittings If the type and number of fittings (see below) is not known, enter 0. The spreadsheet will calculate typical types and numbers from the information you have entered so far. If this information is available, enter 1 and go to the Deck Fittings Selection Screen further down. Please carefully read the notes attached to the various cells and the guidelines given in each section (highlighted in red). The following fittings have been taken into account: - Guide poles / sample wells, - Access Hatches, - Fixed Roof Support Columns, including the effective column diameter, - Gauge-floats (automatic gauge), - Gauge-hatch / sample ports, - Vacuum breakers, - Deck Drains (directly draining into product), - Deck Legs, - Rim Vents, - Ladders passing through the deck. Spreadsheet operation In order to improve the ease of operation, a number of buttons are available to you: - The spreadsheet is normally protected and most of the calculations are hidden. However, if you wish to see them Unprotect or add columns to your spreadsheet, click on - If, for whatever reason, you have unprotected the spreadsheet, you are strongly advised to protect it again in order to avoid overtyping formulae. To do so, click on Protect
Print - To print, simply click on However, be aware that the macro will try and fit all the data in one single page; hence, if you have added columns the printed output may become very small indeed. In order to overcome this, change the settings, for example select File Page Setup Page Scaling Fit to 2 page(s) wide by 1 tall OK. Do not forget to save the workbook!

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Adding columns An allowance has been made for four columns. You may find this a bit restrictive at times. If you wish to have more, do the following: - Unprotect the spreadsheet. - Select one full column. DO NOT SELECT THE FIRST OR THE LAST COLUMN, as this would affect the built-in Print ranges. - Select Edit Copy Insert Copied Cells OK - Protect the spreadsheet. - Save the workbook. Hiding cell notes If you do not wish to display the notes attached to the cells, do the following: - Select Tools Options - Select the View tab and disable Note Indicator Equations The spreadsheet makes integral use of the information and equations laid out in: Manual of Petroleum Measurement Standards Chapter 19--Evaporative Loss Measurement Section 2--Evaporative Loss From Floating-Roof Tanks FIRST EDITION, APRIL 1997 (FORMERLY, API PUBLICATIONS 2517 AND 2519) published by the American Petroleum Institute. It is thus not the intention to repeat this information here. If you are interested, we advise you to order your copy from API, at the following address: API Publications and Distribution 1220 L Street, Northwest Washington, D.C. 20005-4070 USA Limitations The equations of the worksheet were developed for properly maintained equipment under normal working conditions for none boiling products. So for tanks with all weather shields intact, no leaks, seals with no gaps more than 2 cm wide over more than 50 cm, no oil on the deck etc. From DIAL emission measurements made by Shell Global Solutions followed that not well maintained tanks could have an emission 10 -100 times higher than calculated. This means that one bad maintained tank This means that one bad maintained tank can have a higher emission than the rest of the tank farm !!! From the DIAL emission measurments followed also that on average the measured emissions for floating roof tanks were a factor 2 to 4 higher than predicted by the API method. Therefore if the seals and the fittings are not regularly inspected (once a year a visual inspection of the whole seal and of all the fittings) it is adviced to multiply the calculated emissions by a factor 2 to 4. Seals and fittings can also be inspected by using a hand held electronic hydrocarbon sniffer (explosion proof). If the floating roof is at a high position the sniffer can be used to identify rapidly leaking seals and fittings. For a tank which is known to be in a bad state it is adviced to multiply the calculated emission by at least a factor 10. 2.4 Emissions from fixed roof tanks This corresponds to the Fixed Roof tab. As the name indicates, this sheet will enable you to calculate hydrocarbon emissions from fixed roof tanks. Colour codes See 2.3 above. Input requirements - General information: location, author, etc. - Climatic data - Daily maximum ambient temperature in C. - Daily minimum ambient temperature in C. - Average stock temperature in C. If this information is not available, leave the cell blank: the spreadsheet will make an assessment for this value. - Daily total solar insolation on a horizontal surface in W/m2. - Atmospheric pressure in mbara. - Product data - Name and any comments. - Type: crude oil or product. - Net throughput in tonnes. This corresponds to the total quantity of stock withdrawn from the tank. If filling and

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emptying occur simultaneously so that the liquid level does not change, the net throughput is zero during the period concerned. Thus, the net throughput is not necessarily the total amount of hydrocarbons drawn from the tank. - Reid Vapour Pressure in mbara. - True Vapour Pressure (RVP) in mbara. - The slope of the distillation curve at 10% evaporated in C/10%. This information is not required for crude oils. - Average density of the liquid at the average stock temperature in C. - Density of the condensed vapour in kg/m3. - Molecular weight of the condensed vapour in kg/kmol. Note that information may be partly available in the Product Data sheet. - Tank data - Tank diameter in m. - Tank shell height in m. - Maximum liquid height in m. - Average liquid height in m. - Roof type: cone or dome - For cone roof only: slope of cone roof in m; refer to the notes for guidance in the appropriate cells. - For dome roof only: dome radius in m; refer to the notes for guidance in the appropriate cells. - Pressure setting of the breather vent in mbar. - Vacuum setting of the breather vent in mbar; this figure is either 0 or negative. - Solar absorptance of the paint - For the roof. - For the shell. Spreadsheet operation See 2.3 above. Adding columns See 2.3 above. Hiding cell notes See 2.3 above. Equations The spreadsheet makes integral use of the information and equations laid out in: Manual of Petroleum Measurement Standards Chapter 19--Evaporative Loss Measurement Section 1--Evaporative Loss From Fixed-Roof Tanks (FORMERLY API PUBLICATION 2518) THIRD EDITION, MARCH 2002 published by the American Petroleum Institute. It is thus not the intention to repeat this information here. If you are interested, we advise you to order your copy from API, at the following address: API Publications and Distribution 1220 L Street, Northwest Washington, D.C. 20005-4070 USA Limitations The equations of the worksheet were developed for properly maintained equipment under normal working conditions for none boiling products. The accuracy of the emission calculation for fixed roof tanks is much better than for floating roof tanks. However the accuracy can not be expected to be better than +/- 50% for an individual tank. 2.5 Key crude and product information This corresponds to the Product Data tab. It is meant to give you indications on key properties for a range of crudes, feedstocks and products, required for the assessment of hydrocarbon emissions from storage tanks, oils, namely: - Reid Vapour Pressure (RVP) in mbara; - Slope of the distillation curve at 10% evaporated (S) in C/10%; - Liquid product density at 15 C (Wl) in kg/m3; - Vapour product density at 15 C (Wv) in kg/m3; - Vapour molecular weight (Mv) in kg/kmol; - Initial Boiling point (IBP) in C.

2.6 Macro sheet It corresponds to the Macro tab. The various routines allow you to print, protect and unprotect the various spreadsheets. If the protection features are activated, this sheet is hidden.

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Location Case Made on Made by

SRC PD Oil Loss_v0 1-Nov-12 DMA/434; DMA/426

E n d o

Input Data: Evaporative Emissions from Floating Roof Tanks

N-tank Com-1 Com-2 Weather Ta V Pa Product Tank name Comments 1 Comments 2 Average annual ambient temperature Average ambient wind speed at site Average atmospheric pressure at location Product name Comments 1 Comments 2 Product type: crude =1, refined products/chemicals = 0 Annual net throughput Reid vapour pressure Slope of distillation curve at 10% evaporated Average liquid density at average stock temperature Density of condensed vapour Molecular weight of condensed vapour Type of tank: EFRT = 1, CFRT = 2, IFRT =3 Tank diameter
Shell condition: light rust = 0, dense rust =1, gunning lining =2 Tank colour: white =0, aluminium = 1, grey/light color =2, black = 3 Storage temperature (if unknown: leave blank) Deck construction: welded deck = 0, bolted deck = 1
text text text C m/s mbara text text text 1 or 0 t/yr mbara C/10% kg/m3 kg/m3 kg/kmol 1, 2 or 3 m 0, 1 or 2 0, 1, 2 or 3 C 0 or 1 m/m2 1 or 0

T1103 Test API EFRT 28.2 2.6 996 Crude Oil

T1104 Test API EFRT 28.2 2.6 996 Crude Oil

T1105 Test API EFRT 28.2 2.6 996 Crude Oil

T1106 Test API EFRT 28.2 2.6 996 Crude Oil

T1107 Test API EFRT 28.2 2.6 996 Crude Oil

T1108 Test API EFRT 28.2 2.6 996 Crude Oil

T1109 Test API EFRT 28.2 2.6 996 Crude Oil

T1110 Test API EFRT 28.2 2.6 996 Crude Oil

T1111 Test API EFRT 28.2 2.6 996 Crude Oil

T1253

T1254

T1263

Test API EFRT 28.2 2.6 996 TOPS

Test API EFRT 28.2 2.6 996 TOPS

Test API EFRT 28.2 2.6 996 TOPS

T1259 Test API EFRT 28.2 2.6 996 CCG

T1260 Test API EFRT 28.2 2.6 996 CCG

T1276 Test API EFRT 28.2 2.6 996 CCG

T1277 Test API EFRT 28.2 2.6 996 CCG

T1264 Test API EFRT 28.2 2.6 996 JetA1

T1261 Test API EFRT 28.2 2.6 996 Lt. Kero

T1262 Test API EFRT 28.2 2.6 996 Lt. Kero

T-prod Q RVP S Wl Wv Mv Tank data T-tank D

1 202,725 486 788 480 50 1 48.8 0 1 30.7 0 0.00 0

1 438,912 189 837 480 50 1 48.8 0 1 43.1 0 0.00 0

1 448,983 169 839 480 50 1 48.8 0 1 43.1 0 0.00 0

1 559,729 205 836 480 50 1 54.9 0 1 47.8 0 0.00 0

1 627,423 199 834 480 50 1 61.0 0 1 43.6 0 0.00 0

1 779,409 221 858 480 50 1 61.0 0 1 33.0 0 0.00 0

1 582,253 231 861 480 50 1 69.2 0 1 35.0 0 0.00 0

1 0

1 986,358 223 864 480 50 1

480 50 1 69.1 0 1 35.0 0 0.00 0 0 0 0 1

0 114,737 800 0.08 643 635 73 1 24.4 0 1 32.8 0 0.00 0

0 73,800 800 0.08 643 635 73 1 19.5 0 1 32.1 0 0.00 0

0 4,780 800 0.08 643 635 73 1 19.5 0 1 31.8 0 0.00 0

0 22,389 500 0.50 739 640 73 1 20.7 0 1 30.9 0 0.00 0

0 28,255 500 0.50 739 640 73 1 20.7 0 1 31.0 0 0.00 0

0 116,873 500 0.50 734 640 73 1 33.0 0 1 37.5 0 0.00 0

0 311,352 500 0.50 735 640 73 1 33.0 0 1 36.1 0 0.00 0

0 6,153 7 0.65 779 730 130 1 17.1 0 1 30.5 0 0.00 0

0 84,586 7 0.65 778 730 130 1 19.5 0 1 31.5 0 0.00 0

0 89,750 7 0.65 778 730 130 1 19.5 0 1 31.7 0 0.00 0

69.3

Ts T-constr Sd Seals

34.0 0.00

Deck seam length factors

Seals fitting (average = 0, tight =1) Select type of seal by putting 1 against the appropriate seal. * Mechanical-shoe seal, welded tanks primary only (most typical seal for EFRT/CFRT) primary + shoe mounted secondary primary + rim mounted secondary * Liquid-mounted resilient-filled seal primary only primary + weather shield primary + rim mounted secondary * Vapour-mounted resilient seal primary only (most typical seal for IFRT) primary + 'weather shield primary + rim mounted secondary * Mechanical-shoe seal, riveted tanks primary only shoe mounted secondary primary + rim mounted secondary Deck Fittings Df-known Number/type of deck fittings: known = 1, unknown = 0

1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0 1 or 0

1 or 0 1 If the number of deck fittings is known (Df-known =1), select fittings on the "Deck Fittings Selection Screen" below. If Df-known = 0 is entered, typical types and numbers of deck fittings will be used automatically in the calculations.

Results: Evaporative Emissions from Floating Roof Tanks

Lr Lf Ld Ls Lw Lt Lr Lf Ld Ls Lw Lt Total rim seal loss Total deck fitting loss Total deck seam loss Total Standing Storage Emissions Withdrawal Emissions (product sticking on tank wall) Total Evaporative Emissions Total rim seal loss Total deck fitting loss Total deck seam loss Total Standing Storage Emissions Withdrawal Emissions (product sticking on tank wall) Total Evaporative Emissions
t/yr t/yr t/yr t/yr t/yr t/yr m3/yr m3/yr m3/yr m3/yr m3/yr m3/yr

T1103 0.75 1.08 0.00 1.83 0.17 2.00 1.56 2.24 0.00 3.80 0.22 4.02

T1104 0.29 0.42 0.00 0.71 0.37 1.08 0.61 0.87 0.00 1.48 0.44 1.92

T1105 0.25 0.39 0.00 0.64 0.38 1.01 0.52 0.80 0.00 1.33 0.45 1.78

T1106 0.44 0.69 0.00 1.12 0.42 1.54 0.91 1.43 0.00 2.34 0.50 2.84

T1107 0.40 0.49 0.00 0.89 0.42 1.31 0.83 1.02 0.00 1.85 0.51 2.35

T1108 0.31 0.37 0.00 0.67 0.52 1.20 0.64 0.77 0.00 1.40 0.61 2.01

T1109 0.40 0.50 0.00 0.90 0.35 1.24 0.83 1.04 0.00 1.87 0.40 2.27

T1110 #NUM! #NUM! #NUM! #NUM! #DIV/0! #NUM! #NUM! #NUM! #NUM! #NUM! #DIV/0! #NUM!

T1111 0.36 0.46 0.00 0.82 0.58 1.41 0.76 0.96 0.00 1.71 0.68 2.39

T1253 2.24 4.71 0.00 6.95 0.05 7.00 3.53 7.41 0.00 10.94 0.08 11.02

T1254 1.71 4.42 0.00 6.14 0.04 6.18 2.70 6.96 0.00 9.66 0.06 9.72

T1263 1.68 4.49 0.00 6.17 0.00 6.18 2.65 7.07 0.00 9.72 0.00 9.72

T1259 0.86 2.10 0.00 2.96 0.01 2.97 1.35 3.28 0.00 4.62 0.02 4.64

T1260 0.87 2.11 0.00 2.97 0.01 2.99 1.35 3.29 0.00 4.65 0.02 4.67

T1276 1.89 3.09 0.00 4.99 0.04 5.02 2.96 4.83 0.00 7.79 0.05 7.84

T1277 1.77 2.89 0.00 4.65 0.10 4.75 2.76 4.51 0.00 7.27 0.13 7.40

T1264 0.01 0.03 0.00 0.05 0.00 0.05 0.02 0.05 0.00 0.06 0.00 0.07

T1261 0.01 0.04 0.00 0.05 0.04 0.10 0.02 0.05 0.00 0.07 0.06 0.13

T1262 0.01 0.04 0.00 0.05 0.05 0.10 0.02 0.05 0.00 0.07 0.06 0.13

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Location Case Made on Made by

SRC PD Oil Loss_v0 1-Nov-12 DMA/434; DMA/426

Input Data: Evaporative Emissions from Fixed Roof Tanks

Tank name Comments 1 Comments 2 Weather Tax Tan Tb I Pa Product Daily maximum ambient temperature Daily minimum ambient temperature Average stock temperature (if unknown: leave blank) Daily total solar insolation on a horizontal surface Average atmospheric pressure at location Product name Comments 1 Comments 2 Product type: crude =1, refined products = 0 Annual net throughput Reid vapour pressure True Vapour Pressure Slope of distillation curve at 10% evaporated Average liquid density at average stock temperature Density of condensed vapour Molecular weight of condensed vapour
text text text C C C W/m2 mbara text text text 1 or 0 t/yr mbara mbara C/10% kg/m3 kg/m3 kg/kmol 0 or 1 m m m m m m 0 or 1 m/m m mbar mbar

T1582

T1583

T1273

T1275

T1221

T1216

T1229

T1230

T1218

T1214

T1215

T1217

T1219

T1231

T1232

T1251

T1270

T1601

T1222

T1223

T1224

T1225

T1226

T1271

T1272

32.9 24.8 40.3 300 996 Gasoil

32.9 24.8 33.5 300 996 Gasoil

32.9 24.8 32.2 300 996 Gasoil

32.9 24.8 32.2 300 996 Gasoil

32.9 24.8 46.0 300 996 LGO

32.9 24.8 33.8 300 996 LSGO

32.9 24.8 33.8 300 996 LSGO

32.9 24.8 33.0 300 996 LSGO

32.9 24.8 51.9 300 996 HGO

32.9 24.8 49.1 300 996 Gasoil

32.9 24.8 45.5 300 996 Gasoil

32.9 24.8 36.0 300 996 Gasoil

32.9 24.8 62.9 300 996 L.Resid

32.9 24.8 81.7 300 996 L.Resid

32.9 24.8 80.9 300 996 L.Resid

32.9 24.8 32.1 300 996 Naphtha

32.9 24.8 33.9 300 996 Naphtha

32.9 24.8 33.4 300 996 Naphtha

32.9 24.8 36.6 300 996 Lt. Kero

32.9 24.8 35.5 300 996 Lt. Kero

32.9 24.8 34.9 300 996 Lt. Kero

32.9 24.8 31.7 300 996 Lt. Kero

32.9 24.8 32.2 300 996 Lt. Kero

32.9 24.8 30.8 300 996 JetA1

32.9 24.8 32.5 300 996 JetA1

Q RVP TVP S Wl Wvc Mv Tank data

0 226,574 2.7 0.0204 1.48 822 730 129 0 25.0 22.6 21.4 8.4 n/a n/a 0 0.2000 n/a 2.1 (2.1) n/a n/a n/a

0 236,644 2.7 0.0131 1.48 827 730 129 0 36.1 22.5 21.4 9.1 n/a n/a 0 0.2000 n/a 2.1 (2.1)

0 67,331 2.7 0.0120 1.48 828 730 129 0 25.0 22.5 21.0 6.3 n/a n/a 0 0.2000 n/a 2.1 (2.1)

0 681,049 2.7 0.0120 1.48 828 730 129 0 36.0 21.5 20.1 8.4 n/a n/a 0 0.2000 n/a 2.1 (2.1)

0 194,089 0.9 0.0079 1.82 808 740 144 0 34.1 14.3 12.9 6.8 n/a n/a 0 0.2000 n/a 2.1 (2.1)

0 48,266 0.9 0.0033 1.82 817 740 144 0 21.3 12.5 11.5 6.3 n/a n/a 0 0.0625 n/a 2.1 (2.1)

0 62,051 0.9 0.0033 1.82 817 740 144 0 21.3 13.1 11.5 5.0 n/a n/a 0 0.2000 n/a 2.1 (2.1)

0 56,732 0.9 0.0031 1.82 817 740 144 0 21.3 13.3 11.5 5.8 n/a n/a 0 0.2000 2.1 (2.1)

0 76,290 0.3 0.0036 2.01 834 780 157 0 42.7 15.2 13.9 8.4 n/a n/a

0 48,448 2.7 0.0350 1.48 816 730 129 0 21.3 13.1 11.5 8.3 n/a n/a

0 95,846 2.7 0.0281 1.48 819 730 129 0 21.3 13.1 11.5 5.6 n/a n/a

0 33,991 2.7 0.0154 1.48 825 730 129 0 21.3 12.4 11.5 6.4 n/a n/a

0 57,333 0.09 0.0022 1.94 916 780 170 0 42.7 15.5 13.9 10.4

0 157,489 0.09 0.0085 1.94 903 780 170 0 39.1 23.1 20.9 13.1 n/a n/a

0 167,328 0.09 0.0080 1.94 904 780 170 0 39.1 23.1 20.9 15.4 n/a n/a n/a n/a

0 17,928 370.1 5.4604 0.56 698 650 76 0 14.6 19.5 17.4 7.0 n/a n/a

0 47,403 370.1 5.7730 0.56 697 650 76 0 34.1 18.9 17.3 8.4 n/a n/a

0 22,114 370.1 5.6848 0.56 697 650 76 0 14.6 13.8 12.2 6.9 n/a n/a

0 60,478 7.3 0.0533 0.65 775 730 130 0 15.2 11.7 10.3 6.1 n/a n/a

0 37,853 7.3 0.0500 0.65 776 730 130 0 10.6 16.2 14.5 6.7 n/a n/a

0 75,666 7.3 0.0483 0.65 776 730 130 0 15.2 13.0 11.5 8.2 n/a n/a

0 46,535 7.3 0.0400 0.65 778 730 130 0 15.2 12.5 11.5 4.7 n/a n/a

0 32,840 7.3 0.0412 0.65 778 730 130 0 14.6 15.7 13.9 8.3

0 187,882 7.3 0.0379 0.65 779 730 130 0 27.5 19.5 17.5 10.3 n/a n/a n/a n/a

0 170,391 7.3 0.0419 0.65 778 730 130 0 27.5 19.5 17.5 9.7

Vertical or Horizontal Tank : Vertical =0, Horizontal =1 D Tank diameter Hs Tank shell height Hlx Maximum liquid height Hl Average liquid height Dh Diameter of a vertical cross-section of the horizontal tank Lh Length of the Horizontal Tank T-roof Roof type: cone roof =0, dome roof =1 Sr Slope of cone roof (only for cone roof) Rr Dome radius (only for dome roof tank) P bp Breather vent pressure setting P bv Breather vent vacuum setting (enter 0 or negative number) Solar absorptance of paint
Paint color Aluminium specular Aluminium diffuse White Light Grey Medium Grey Red Primer Good paint condition 0.39 0.60 0.17 0.54 0.68 0.89 Poor paint condition 0.49 0.68 0.34 0.63 0.74 0.91

1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.2000 0.2000 0.2000 0.0625 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.0625 0.0625 0.2000 0.2000 0.2000 101.0 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1) (2.1)

Alpha-r Alpha-s

Solar absorptance roof Solar absorptance shell

0.17 0.17 T1582 1.10 3.55 4.65 1.51 4.86 6.37

0.17 0.17 T1583 1.89 3.02 4.91 2.59 4.13 6.72

0.17 0.17 T1273 1.01 0.83 1.83 1.38 1.13 2.51

0.17 0.17 T1275 1.78 7.62 9.40 2.44 10.44 12.87

0.17 0.17 T1221 0.52 1.30 1.81 0.70 1.75 2.45

0.17 0.17 T1216 0.11 0.22 0.33 0.14 0.30 0.44

0.17 0.17 T1229 0.15 0.28 0.43 0.20 0.38 0.58

0.17 0.17 T1230 0.13 0.25 0.38 0.18 0.34 0.52

0.17 0.17 T1218 0.33 0.22 0.55 0.43 0.28 0.71

0.17 0.17 T1214 0.39 0.98 1.37 0.53 1.34 1.87

0.17 0.17 T1215 0.52 1.75 2.27 0.71 2.39 3.11

0.17 0.17 T1217 0.31 0.47 0.78 0.43 0.64 1.07

0.17 0.17 T1219 0.13 0.07 0.20 0.16 0.09 0.26

0.17 0.17 T1231 0.32 0.36 0.69 0.41 0.47 0.88

0.17 0.17 T1232 0.25 0.38 0.63 0.32 0.48 0.80

0.17 0.17 T1251 8.96 24.32 33.27 13.78 37.40 51.18

0.17 0.17 T1270 50.10 66.64 116.74 77.06 102.50 179.55

0.17 0.17 T1601 8.62 30.78 39.40 13.26 47.34 60.61

0.17 0.17 T1222 0.43 2.20 2.63 0.59 3.01 3.60

0.17 0.17 T1223 0.31 1.43 1.74 0.42 1.96 2.38

0.17 0.17 T1224 0.34 2.39 2.72 0.46 3.27 3.73

0.17 0.17 T1225 0.48 1.64 2.12 0.66 2.25 2.91

0.17 0.17 T1226 0.44 1.18 1.62 0.61 1.61 2.22

0.17 0.17 T1271 1.90 6.45 8.35 2.60 8.84 11.44

0.17 0.17 T1272 2.07 6.17 8.24 2.83 8.45 11.28

Results: Evaporative Emissions from Fixed Roof Tanks

Ls Lw Lt Ls Lw Lt Standing Storage Emissions Working Emissions Total Evaporative Emissions Standing Storage Emissions Working Emissions Total Evaporative Emissions
t/yr t/yr t/yr m3/yr m3/yr m3/yr

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Fixed Roof

Printed 11/30/2013 4:36 AM

Evaporative Emissions from Storage Tanks - Property of OGBH/3, Shell Global Solutions, Shell International Oil Products B.V.

CONFIDENTIAL

Product Data
RVP
Reid Vapour Pressure mbara

S
Slope distillation curve at 10% evaporated C/10%

Wl
Liquid Product Density at 15 C kg/m3

Wv
Vapour Product Density at 15 C kg/m3

Mv
Vapour Molecular Weight kg/kmol

IBP
Initial Boiling Point C

Chemical Formula

Oil Products Gasoline range Motor Gasoline (summer quality) Motor Gasoline (winter quality) Aviation Gasoline Gas Condensate/ Natural Gasoline Full Range Naphtha Light Naphta/Isomer Feed/Tops Heavy Naphtha/Platormer Feed i-Pentane Stabilised Isomerate Stabilised Alkylate Stabilised Full Range Platformate Stabilised Light Platformate Benzene Heartcut (50% benzene) Heavy Platformate Stabilised Light Cat Cracked Gasoline Stabilised Full Range Cat Cracked Gasoline Heavy Cat Cracked Gasoline MTBE Kerosene range Jet naphtha (JP 4) Jet A1 (flash point 40 C) Jet A1 (flash point 50 C) Gasoil range Gasoil/Diesel (flash point 60 C) Gasoil/Diesel (flash point 80 C) Light Gasoil (flash point 80 C) Heavy Gasoil (flash point 100 C) Heavy Gasoil (flash point 120 C) Residual Fueloil/Bitumen Fueloil (flash point 60 C) Fueloil (flash point 80 C) - LCO Fueloil (flash point 100 C) - HCO Fueloil/Residue (flash point 120 C) Bitumen (flash point 200 C) Cutback (flash point 40 C) Cutback (flash point 60 C) Petrochemicals Paraffins i-Pentane n-Pentane i-Hexane n-Hexane n-Heptane n-Octane n-Nonane n-Decane Cycloparaffins Cyclopentane Cyclohexane Methylcyclohexane Aromatic Hydrocarbons

700 900 450 800 370 800 150 1375 1000 300 375 1100 250 50 900 500 100 539

0.9 1.0 0.6 0.2 0.6 0.077 0.5 0.0 0.1 0.5 1.3 0.1 0.1 0.4 0.2 0.5 0.4 -0.0012

750 750 720 670 710 655 730 625 650 710 800 650 790 860 690 750 805 740

620 606 650 625 650 635 695 625 630 650 640 620 765 835 635 640 750 740

68 65 76 71 76 73 87 72 72 76 71 69 82 92 73 73 80 88

48 40 62 44 67 44 92 28 37 73 69 34 75 117 42 58 102 55 C5 - C10, small amount C4 C5 - C10, small amount C4 C5 - C6, small amount C4 C6 - C10 C5H11 iC5 + iC6, small amount C4 iC5-iC9 C5 - C10, small amount C4 C5 -C6, small amount C4 C6 C7-C10 C5-C7 C5-C10 C7-C10 C5H12O

210 7.3 4.2

0.5 0.6 0.9

770 790 790

700 730 730

76 130 132

83 164 182

C5-C15 C9-C15 C9-C15

2.7 0.9 0.9 0.3 0.08

1.5 1.9 1.8 2.0 1.9

840 840 830 860 870

730 740 740 780 790

129 143 144 157 173

205 242 241 273 297

2.7 0.9 0.3 0.09 0.0001 8.5 2.7

1.5 1.9 2.0 1.9 1.5 1.9 1.5

950 950 950 950 970 930 930

730 740 740 780 800 730 730

128 142 156 170 296 114 128

205 242 273 298 387 184 205

1375 934 407 295 98 34 13 5.0

0.0 0.0 0.0 0.1 0.3 0.5 0.3 0.6

625 630 669 663 687 706 721 733

625 630 669 663 687 706 721 733

72 72 86 86 100 114 128 142

28 36 63 69 98 126 151 174

C5H12 C5H12 C6H14 C6H14 C7H16 C8H18 C9H20 C10H22

718 186 107

-0.3 0.3 0.2

759 783 774

759 783 774

70 84 98

49 81 101

C5H10 C6H12 C7H14

192346286.xls.ms_office

Product Data

Printed 11/30/2013 4:36 AM

Evaporative Emissions from Storage Tanks - Property of OGBH/3, Shell Global Solutions, Shell International Oil Products B.V.

CONFIDENTIAL

Product Data
RVP
Reid Vapour Pressure mbara

S
Slope distillation curve at 10% evaporated C/10%

Wl
Liquid Product Density at 15 C kg/m3

Wv
Vapour Product Density at 15 C kg/m3

Mv
Vapour Molecular Weight kg/kmol

IBP
Initial Boiling Point C

Chemical Formula

Oil Products Benzene Toluene Styrene Ethylbenzene o-Xylene Isopropylbenzene Naphthalene Alcohols Methyl alcohol Ethyl alcohol Allyl alcohol Isopropyl alcohol Tertiary butyl alcohol Furfuryl alcohol Esters Methyl acetate Vinyl acetate Methyl acetate Ethyl acetate Methyl methacrylate Ethers Diethyl ether MTBE Amines Diethyl amine Chlorine compounds Methylene chloride Chloroform Carbon tetrachloride Vinylidene chloride 1,2 Dichloroethane Trichlorethylene 1,1,1-Trichlorethane Allyl chloride Cynano compounds Acrylonitrile Phenols Phenol o-Cresol Sulphur compounds Carbon disulphide

167 63 19 25 17 12 0.37

0.1 0.6 0.7 0.7 0.4 0.4 -0.2

882 873 908 873 884 867 1145

882 873 908 873 884 867 1145

78 92 104 106 106 120 128

80 111 145 136 144 152 218

C6H6 C7H8 C8H8 C8H10 C8H10 C9H12 C10H8

205 143 67 111 99 2.1

-0.4 -0.4 -0.3 -0.5 -0.7 0.1

796 796 859 792 789 1129

796 796 859 792 789 1129

32 46 58 60 74 98

65 78 97 82 82 170

CH4O C2H6O C3H6O C3H8O C4H10O C5H5O2

420 256 201 192 89

0.0 -0.1 0.0 0.0 0.1

940 938 953 904 950

940 938 953 904 950

74 86 86 88 100

57 73 81 77 100

C3H6O2 C4H6O2 C4H6O2 C4H8O2 C5H8O2

998 539

-0.2 0.0

719 740

719 740

74 88

34 55

C4H10O C5H12O

480

0.0

712

712

73

56

C4H11N

995 379 217 1451 171 169 276 848

-1.5 0.0 0.3 -2.2 0.2 0.1 0.0 -0.5

1336 1498 1600 1218 1259 1466 1345 938

1336 1498 1600 1218 1259 1466 1345 938

85 119 154 97 99 131 133 77

40 61 77 37 83 87 74 45

CH3Cl2 CHCl3 CCl4 C2H2Cl2 C2H4Cl2 C2HCl3 C2H3Cl3 C3H5Cl

244

0.0

806

806

53

78

C3H3N

1.9 1.4

0.6 0.4

1071 1048

1071 1048

94 108

182 191

C6H6O C7H8O

702

0.0

1269

1269

76

46

CS2

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Product Data

Printed 11/30/2013 4:36 AM