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P-y(ica (tate Appearance Emer0ency o*er*ie2 7as. o8or8ess 8i9ue%ied -as. D+,75$ 5xtre!e8: %8a!!a;8e -as. Hi-h pressure -as. 7as reduces ox:-en a#ai8a;8e %or ;reathin-. ontact <ith 8i9ue%ied -as !i-ht cause %rost;ites. in so!e cases <ith tissue da!a-e. =n a %ire or i% heated. a pressure increase <i88 occur and the container !a: ;urst or exp8ode. Static accu!u8atin- %8a!!a;8e !ateria8s can ;eco!e e8ectrostatica88: char-ed e#en in ;onded and -rounded e9uip!ent. Spar6s !a: i-nite !ateria8 and #apor !a: cause %8ash %ire 2or exp8osion3. !SHA re0u atory (tatu( Potentia -ea t- effect( Route( of e3po(ure Eye( S4in In-a ation >his product is ha?ardous accordin- to 'SH+ 29 =nha8ation. 5:es. S6in. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. Su%%ocation 2asph:xiant3 ha?ard - i% a88o<ed to accu!u8ate to concentrations that reduce ox:-en ;e8o< sa%e ;reathin- 8e#e8s. ,asa8 and respirator: tract irritation. centra8 ner#ous s:ste! e%%ects inc8udin- excitation. euphoria. contracted e:e pupi8s. di??iness. dro<siness. ;8urred #ision. %ati-ue. nausea. headache. 8oss o% re%8exes. tre!ors. con#u8sions. sei?ures. 8oss o% consciousness. co!a. respirator: arrest and sudden death cou8d occur as a resu8t o% 8on- ter! andAor hi-h concentration exposure to #apors. Ma: a8so cause ane!ia and irre-u8ar heart rh:th!. >his !ateria8 is a -as under nor!a8 at!ospheric conditions and in-estion is un8i6e8:. $espirator: tract. 5:es. entra8 ner#ous s:ste!. Ma: cause centra8 ner#ous s:ste! e%%ects. o!ponents ha#e ;een sho<n to ;e <ea6 cardiac sensiti?ers <hich can resu8t in cardiac arrh:th!ia and #entricu8ar %i;ri88ation. ,ot expected to ;e har!%u8 to a9uatic or-anis!s. 4$ 1910.1200.
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012
Se8%-contained ;reathin- apparatus. operated in positi#e pressure !ode and %u88 protecti#e c8othin- !ust ;e <orn in case o% %ire. Mo#e container %ro! %ire area i% it can ;e done <ithout ris6. Do not extin-uish %ires un8ess -as %8o< can ;e stopped sa%e8:* exp8osi#e re-i-nition !a: occur. Pro!pt8: iso8ate the scene ;: re!o#in- a88 persons %ro! the #icinit: o% the incident. ,o action sha88 ;e ta6en in#o8#in- an: persona8 ris6 or <ithout suita;8e trainin-. 4or %ires in#o8#in- this !ateria8. do not enter an: enc8osed or con%ined %ire space <ithout proper protecti#e e9uip!ent. inc8udin- se8%-contained ;reathin- apparatus. Stop %8o< o% !ateria8. Use <ater to 6eep %ire exposed containers coo8 and to protect personne8 e%%ectin- shuto%%. =% a 8ea6 or spi88 has not i-nited. use <ater spra: to disperse the #apors and to protect personne8 atte!ptin- to stop 8ea6. Pre#ent runo%% %ro! %ire contro8 or di8ution %ro! enterin- strea!s. se<ers or drin6in- <ater supp8:.
ar;on oxides.
Stora0e
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012
%S. !SHA Ta8 e =#1 Limit( for Air Contaminant( +.> CFR 1>1?.1???, Component( Type Propane 2 +S 70-9E-)3 P5&
Canada. A 8erta !EL( +!ccupationa Hea t- @ Safety CodeA Sc-edu e 1A Ta8 e ., Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. Briti(- Co um8ia !EL(. +!ccupationa E3po(ure Limit( for C-emica Su8(tance(A !ccupationa Hea t- and Safety Re0u ation .>:6>;A a( amended, Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. !ntario !EL(. +Contro of E3po(ure to Bio o0ica or C-emica A0ent(, Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. $ue8ec !EL(. +Mini(try of La8or # Re0u ation Re(pectin0 t-e $ua ity of t-e Cor4 En*ironment, Component( Type 'a ue Propane 2 +S 70-9E-)3 En0ineerin0 contro ( >F+ 1E00 !-A!1 1000 pp!
Use process enc8osures. 8oca8 exhaust #enti8ation. or other en-ineerin- contro8s to contro8 air;orne 8e#e8s ;e8o< reco!!ended exposure 8i!its. >he en-ineerin- contro8s a8so need to 6eep -as. #apor. or dust concentrations ;e8o< an: 8o<er exp8osi#e 8i!its. Fear appro#ed sa%et: -8asses or -o--8es. Fear protecti#e c8othin- appropriate %or the ris6 o% exposure. =% en-ineerin- contro8s do not !aintain air;orne concentrations ;e8o< reco!!ended exposure 8i!its 2<here app8ica;8e3 or to an accepta;8e 8e#e8 2in countries <here exposure 8i!its ha#e not ;een esta;8ished3. an appro#ed respirator !ust ;e <orn. Do not eat. drin6 or s!o6e <hen usin- the product. Fash thorou-h8: a%ter hand8in-. Pro#ide e:e<ash station and sa%et: sho<er. Hand8e in accordance <ith -ood industria8 h:-iene and sa%et: practices.
Per(ona protecti*e e9uipment Eye 6 face protection S4in protection Re(piratory protection
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012
F amma8i ity imit( in airA o2erA D 8y *o ume Auto#i0nition temperature '!C E*aporation rate Mo ecu ar 2ei0-t Mo ecu ar formu a !t-er data Critica temperature
2.2 H E09.) G4 2012 G 3 100 H I 1 25ther 2anh:drous3J13 00.11 -A!o8 1-HE 205.9 G4 29).) G 3
Su%%ocation 2asph:xiant3 ha?ard - i% a88o<ed to accu!u8ate to concentrations that reduce ox:-en ;e8o< sa%e ;reathin- 8e#e8s. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. Ma: cause centra8 ner#ous s:ste! e%%ects.
C-ronic effect(
2.1)
Pac4a0in0 non 8u 4 Pac4a0in0 8u 4 Reporta8 e 9uantity IATA %" num8er %" proper (-ippin0 name Tran(port -a1ard c a((+e(, ER& code IMD& %" num8er %" proper (-ippin0 name Tran(port -a1ard c a((+e(, EmS "o. TD& Proper (-ippin0 name Ha1ard c a(( %" num8er Marine po utant
100 110. 115 100 U,197E Propane 2.1 10& U,197E P$'P+,5 2.1 4-D. S-U P$'P+,5 2.1 U,197E ,o
TSCA Section 1.+8, E3port "otification +/? CFR ;?;A Su8pt. D, ,ot re-u8ated. C ean Air Act +CAA, Section 11. Ha1ardou( Air Po utant( +HAP(, Li(t ,ot re-u8ated. CERCLA +Superfund, reporta8 e 9uantity + 8(, +/? CFR 5?../, PropaneD 100 Superfund Amendment( and Reaut-ori1ation Act of 1><: +SARA, Ha1ard cate0orie( =!!ediate Ha?ard - Les De8a:ed Ha?ard - ,o 4ire Ha?ard - Les Pressure Ha?ard - Les $eacti#it: Ha?ard - ,o Section 5?. e3treme y -a1ardou( (u8(tance +/? CFR 577A Appendi3 A, Section 511651. +/? CFR 5;?, C ean Cater Act +CCA, Section 11.+r, +/? CFR :<.15?, Dru0 Enforcement Admini(tration +DEA, +.1 CFR 15?<.11#17, Canadian re0u ation( CHMIS (tatu( CHMIS c a((ification CHMIS a8e in0 Les
>his product has ;een c8assi%ied in accordance <ith the ha?ard criteria o% the contains a88 the in%or!ation re9uired ;: the P$. ontro88ed + - o!pressed 7as (1 - 48a!!a;8e 7ases
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012
In*entory (tatu( Country+(, or re0ion +ustra8ia anada anada hina 5urope 5urope Mapan /orea ,e< Nea8and Phi8ippines United States O Puerto $ico State re0u ation( %S # Ca ifornia Propo(ition :7 # Carcino0en( @ Reproducti*e To3icity +CRT,E Li(ted (u8(tance ,ot 8isted. %S # "e2 Ger(ey RTH # Su8(tance(E Li(ted (u8(tance Propane 2 +S 70-9E-)3 &isted. %S. Ma((ac-u(ett( RTH # Su8(tance Li(t Propane 2 +S 70-9E-)3 &isted. %S. "e2 Ger(ey Cor4er and Community Ri0-t#to#Hno2 Act Propane 2 +S 70-9E-)3 500 &(S %S. Penn(y *ania RTH # Ha1ardou( Su8(tance( Propane 2 +S 70-9E-)3 &isted. In*entory name +ustra8ian =n#entor: o% he!ica8 Su;stances 2+= S3 !n in*entory +ye(6no,F Les Les ,o hina 2=5 S 3 he!ica8 Les Les ,o Les Les Les he!ica8s and he!ica8 Su;stances Les Les
Do!estic Su;stances &ist 2DS&3 ,on-Do!estic Su;stances &ist 2,DS&3 =n#entor: o% 5xistinhe!ica8 Su;stances in o!!ercia8 5uropean =n#entor: o% 5xistinSu;stances 25=,5 S3 5uropean &ist o% ,oti%ied 5xistin=n#entor: o% 5xistin- and ,e< he!ica8s &ist 25 &3 ,e< Nea8and =n#entor: Phi8ippine =n#entor: o% 2P= S3 >oxic Su;stances
*+ @Les@ indicates this product co!p8ies <ith the in#entor: re9uire!ents ad!inistered ;: the -o#ernin- countr:2s3
"FPA ratin0(
Di(c aimer
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012