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FIGURE 78
CONCENTRATION OF OlETHYLENE GLYCOL AT
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GLYCOL INJECTION IN EXCHANGERS 35
maint ained in the system. However, if glycol is injected in two exchangers, the overa ll
glycol dilution will not necessarily apply to each of the two exchangers. Furthermor e, it
is almost impossible to get a sample of ri ch glycol leaving an exchanger to determine it s
diluti on in t hat exchanger . The point is that if the overall dilution is within the proper
range, the principal adjustment is that of properly dividing the glycol flow to the
exchangers. In the example on page 27 the glycol inj ection rate to the gas exchanger was
about 7 times as much as that to the chiller. Thi s is 8 fairly typical split of glycol
between the two exchangers.
If the glycol di lution is more than 10%, it is li kely that t he flow of glycol is not high
enough. The glycol flow rat e should be incr eased about 10% for each percentage of
dil uti on in excess of 10%. In other words. if the overall dilution is 12%, it is 2% more than
the maximum (l0%). The glycol flow rat e must be increased 2 x 10 = 20t in order to bring
the diluti on down to the allowabl e maximum of lOt .
The method for increasing the glycol flow will depend upon the type of pump. If it
is a gas driven pump, flow is increased by increasing gas pressur e t o the pump. If the
injection pump is electric driven, fl ow is increased by changing the length of the s troke or
some other variable means of controll ing t he output.
If the overa ll glycol diluti on is less than 3%, the glycol inj ection rate might be too
high, which results in a glycol spray pattern as shown in the middle drawing on page 30.
Reducing the glycol flow rate until the dilution is 4-5% will result in a better spray pa tt ern
inside the exchanger , and may prevent freeze-ups from occuring.
If freeze-ups are occuring when the dilution is in the proper range, the foll owing
procedure is suggested for making changes to prevent freeze-ups. Each change must be
made in a clean system with no hydrate present. If a change is made and a freeze-up
follows, thaw out the exchanger and proceed to t he next step.
1. Back flow the injection nozzle to remove dirt that may ha ve collected in it.
2. Increase the glycol flow rate 20%. If thi s <:bes not he lp, incr ease it another 20%.
3. If the above fai ls, reduce the glycol ci rculation 20% below its original rate. If
no improvement occurs, reduce it a nother 20%.
4. If no improvement is noted from changing t he fl ow rate, set the fl ow at its
original rat e a nd reduce the glycol concentration by 5%. Concentra ti on can be
reduced 5% by lowering the temperatur e of the reconcentrator 4 C [ 7 F J.
5. If no improvement is noted with a reduction in concentrat ion, repeat Steps 2
and 3 at the lower glycol concentration.
36 GLYCOL INJECTION IN EXCHANGERS
6. If no improvement is noted, set the flow at its original rate and increase the
temperatur e of the glycol a t the injection point, if possible. Hold the
concentration at its low point. The temperature should be raised at least 20C
[36 OF]. If no improvement is noted, change the flow rate as recommended in
Steps 2 and 3 at the lower concentration and higher temperature.
7. If the above does not improve the si tuation, the inj ecti on nozzle should be
moved or rotated in t he exchanger. Set the flow rat e at normal and maintain a
high glycol temperature and low concentr at ion. Each change in injection nozzle
position should be made in small steps. If a position change does not result in
improvement, follow it with a change of the same magnitude in the opposite
direction.
Problem 7
The chiller shown below is located in a low temper ature gas processing plant.
a. How much water can condense from the gas? ___________ _
b. How much glycol injection is required to inhibit hydrate from
forming? ____________ _
Temp
Press
Flow
0" C [32
0
Fl
kP. ( 800 pli 1
:: 5 million m' /d
(175 MMcf/dl
Inlet Gas t;:::EC!l::!!llll!llll:!!=
Outlet
Rich Glycol,
Vapor
Ref r iger an t
Liquid
-20
0
C (-4
0
F 1
__ .. Liquli' d Hydrocarbon
37
HYDRATE
INHIBITION
VALIDATION
SI UNITS
Trainee _______ _
METHANOL
. 10 000 kPa
2 million
m' /d
5500 kPa
--
Water Cant =
160 kg por
million m'
GAS CHILLER
r;::::=t GAS
WELLHEAD
GAS SEPARATOR
WELLS
GAS
DEHYDRA-
TION
15 km lklderground
Pipeline. Ground
Temp = 10 C
LNT
Six gas wells flow into a wellhead seperator. Gas from the separator passes through
a choke and enters a 15 kilometer pipeline to a dehydration plant. Gas from the
dehydration plant flows to a low temperature process plant, where it is chilled to -18 'C.
1. What is the hydrate formation temperature downstream of the choke?
'C.
----
2. How much hydrate Temperature Reduction is required? ______ 'C
3. What is the water content of gas leaving the choke? kg/million m 3
4. What is the water content of gas at the lowest temperature it can reach in the
pipeline? kg/million'
5. What methanol injection rate is required to prevent hydrate from forming in the
pipeline? L/hr
6. How much w ~ t r can condense in the gas chiller? ____ .kg/million m 3
7. How much glycol must be injected in the gas chiller? L/hr
38 SOLUTIONS TO PROBLEMS -51 UNITS
1. 8. From Figure 1 A, hydrates will form at 5000 kPa and 14.5C.
b. From Figure lA, the pressure at which hydrate forms at 18C is 9000 kPa.
2.
3.
4.
5.
7.
Temperature of gas entering the pipeline
Water conlent of gas entering the pipeline at
7000 kPa and 25'C. (Figure 3A)
Water content of gas at ground temp, -5C. (Figure 28)
Water that can condense :;: 470 -76 :;::
Total daily weight of water that can condense 394 x 3 :;:
Hydrate formation temperature at 7000 kPa (Figure lA)
Lowest temperature in pipeline
Hydrate tempel'sture reduction:;:: 16.6 - (-5) = 21.6, use
a. Hydrate temperature reduction (Problem 3)
Water that can condense (Problem 2)
Methanol injection fate (Figure 3A)
Gus flow rate
Methanol injection rate for 3 million m 3/d :;:: 770 x 3 :;::
Hourly methanol injection rate:; 2310 .;. 24 :;
b. Glycol injection rate when condensed water is 417
kg/million m 3 and hydrate temperature reduction is
22 'C. (Figure 4A)
e
5
a
d
Gas flow rate
Glycol injection rate for 3 million rn 3 ;; 220 x 3 ;;
Hourly glycol injection rate = 660 .;. 24 ;;
1 6. a. Glycol
2 b. Methanol
3 c. :vI ethanol
4
5
Inlet gas tempct'lltur'e
Lowest possible gas temperature
Water content of inlet gas, 5500 kPa and OC (Figure 2A)
Water content at lowest temp, 5500 kPa and -20C (Figure 2A)
8. Water than can condense,
Glycol dilution: 70% lean - 60% rich:;
Glycol injection rate with 70% lean sol'n and
10% dilution (Figure 6A)
Injection rate for 100 kg of water:; 100 x 5.5:;
Gas flow rate
Injection rate for 5 million m 3/d ;:; 5 x 550 :;
b. Hourly injection rate;; 2750 f 24 :;
25C
470 kg/million m 3
76 kg/million m 3
394 kg/million m 3
1182 kg/d
16.6'C
-5'C
22 'c
22 'c
394 kg/million m 3
770 L/million m 3
3 millionm
3
/d
2310 L/d
96.3 L/hr
220 L/million m 3
3 million m 3/d
660 L/d
27.5 L/d
O'C
-20'C
130 kg/million m 3
30 kg/million m 3
100 kg/million m 3
10%
5.5 L/kg water
550 L/million m 3
5 million m 3/
d
2750 L/d
115 L/min
HYDRATE
INHIBITION
VALIDATION
ENGLISH UNITS
METHANOL
MMcf/d
10 mile under-
ground pipeline.
Ground Temp =
50' F
-+-
39
Trainee ______ _
75%
Lean
GAS Glycol
DEHYDRA-
TION
UNIT
Water Cant ;;;
10 Ib/MMcf
GAS CHILLER
f'Plll=:t GAS
Six gas wells flow into a wellhead separator. Gas from the separator passes through.
a choke and enters a 10 mile pipeline to a dehydration plant . Gas from the dehydration
plant flows to a low temperature process plant, where it is chilled to O'F.
1. What is the hydrate formation temperature downstream of the choke?
'F.
----
2. How much hydrate Temperature Reduction is required? ______ 'F
3. What is the water cont ent of gas leaving the choke? _____ lb/MMcf
4. What is the water content of gas at the lowest temperature it can reach in the
pipeline? Ib/MMcf
5. What methanol injection rate is required to prevent hydrate from forming in the
pipeline? gal/hr
6. How much water can condense in the gas chiller?
____ lb/MMcf
____ gal/hr
7. How much glycol must be injected in the gas chiller?
40 SOLUTIONS TO PROBLEMS - ENGLISH UNITS
1. a . From Figure IB, hydrates will form at 750 psi and 59'F.
b. Fro.m Figure 18, the pressure at which hydrate forms at 64F is 1100 psi.
2.
3.
4.
5.
7.
Temperature of gas entering the pipeline
Wat er cont ent of gas entering the pipeline at
1, 000 psi and 77 'F. (Figure 28)
Water content of gas at ground temp, 23 'C. (Figure 28)
Water that can condense;: 31 - 4.8 ;:
Total dail y water that can condense 26. 2 x 100 =
Hydrate formation temperature at 1000 psi (Figure IB)
Lowest temperature in pipeline
Hydrate temperature reduction;: 63 - 23 ;:
a. Hydrat e temperature reduction (Problem 3)
Water that can condense (Problem 2)
Methanol injection rate (Figure 38)
Gas flow rat e
Methanol inj ection rat e for 100 MMcf/ d = 100 x 6.2 =
Hourly methanol injection rote;;; 620 ~ 24 ;:
b. Glycol injection rate when condensed water i s 6 2 ~
Ib/ MMcf and hydrat e temperatur e reduction is
40'F. (Figur e 48)
c
c
~
a
d
Gas now rate
Glycol injection ral e for 100 MMcf/d = 100 x 1.8 =
Hourl y glycol injection rate = 180 f 24 =
1 6. a . Glycol
2 b. Methanol
3 c. Methanol
4
5
Inlet gas temperature
Lowest possibl e gas temper ature
Water content of inlet gas, 800 psi and 32 'F. (Figure 2B)
Wat e, content a t lowest temp, 800 psi and _4 '1'. (Figur e 28)
a. 'Vater that can condense,
Glycol dilution: 70% lean - 60% rich =
Glycol injection rate with 70% lean sol'n and
10% di lution (Figure 68)
Injecl ion rat e for 6.0100 of water = 6.0 x 0.67 =
Gas now rate
Injection rate for 175 MMcf/d = 175 x 4 =
b. Hourly injection rate = 700 f 24 =
77' F
31.0Ib/ MMcf
4. 8Ib/ MMcf
26. 2 Ib MMcf
2620 Ib/d
63 'F
23 'F
40"F
40F
26.2Ib/ MMcf
6. 2 gal/MMcf
100 MMcf/ d
620 gal/d
25. 8 gal/hr
1.8 gal / MMcf
100 MMcf/d
180 gal/d
7.5 gal / hr
32 'F
-4 'F
8. 0Ib/ MMcf
2. 01b/MMcf
6.01b/ MMcf
10%
0. 67 gal/lb water
4 gal/ MMcf
175 MMcf / d
700 gal/d
29 ga l/ hr
40 SOLUTIONS TO PROBLEMS - ENGLISH UNITS
1. a. From Figure 18, hydrates will form at 75 0 psi and 59F.
b. Fro.m Figure 18, the pressur e at which hydrate forms at 64F is 1100 psi.
2.
3.
4.
5.
7.
Temperature of gas entering the pipeline
Water content of gas entering the pipeline at
1,000 psi and 77'F. (Figure 2B)
Water content of gas at ground temp, 23C. (Figure 28)
Water that can condense;; 31 - 4. 8:;
Total daily water that can condense 26.2 x 100 :;
Hydrate formation temperature at 1000 psi (Figure 18)
Lowest temperature in pipeline
Hydrate temperature reduction = 63 - 23 =
a. Hydrate temperature reduction (Problem 3)
Water that can condense (Problem 2)
Methanol injection rate (Figure 38)
Gas flow rate
Methanol injection rate for 100 YIlVicf/d = 100 x 6. 2 :::
Hourly methanol injection rate = 620 .;. 24 =
b. Glycol injection rate when condensed water is 26.2 "
Ib/MMcf and hydrate temperature reduction is
40F. (Figur e 4B)
e
a
d
Gas flow rate
Glycol injection rate for 100 MMcfld = 100 x 1.8 =
Hourly glycol injection rate = 180 .:. 24 =
6. a . Glycol
2 b. Methanol
3 c. Methanol
4
5
Inlet gas temperature
Lowest possible gas temperature
Water content of inlet gas, 800 psi and 32 of. (Figur e 28)
Water content at lowest temp, 800 psi and _4
0
F. (Figure 28)
a. Water that can condense,
Glycol dilution: 707. lean - 60% rich =
Glycol injection rate with 70% lean so1'n and
107. dilution (Figure 6B)
Injection rate for 6.0 100 of water = 6. 0 x 0. 67 =
Gas flow rate
Inj ection rate for 175 MMcf/d = 175 x 4 =
b. Hourly injection rate = 700 .:. 24 =
77F
31.0
4.8lb/MMci
26.2 lb MMcf
2620 Ibid
63 F
23' F
40F
40' F
26. 2 1b/MMcf
6.2 gal/MYlcf
100 MMcf /d
620 gal/d
25.8 gal/hr
1. 8 gal/MMcf
100 MMcf/d
180 galld
7.5 gallhr
32 OF
-4 OF
8. 0lb/MMcf
2. 0 lbl MMcf
6. 0lb/ MMcf
10%
0. 67 gallib water
4 gallMMcf
175 MMcf/ d
700 galld
29 gal/hr