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They were discovered in 1991 by the Japanese electron microscopist Simio Iijima
who was studying the material deposited on the cathode during the arc-
evaporation synthesis of fullerenes. Carbon nanotubes are fullerene-related
structures which consist of graphene[1] cylinders closed at either end with caps
containing pentagonal rings. Examples of Nanotubes are Single-layer nanotubes
and nanotube "ropes" and nanohorns. Carbon nanotubes, therefore, are rolled-up
sheets of graphite - i.e. the same material that is used in pencils. A sheet of
graphite is composed of carbon atoms arranged in a flat hexagonal pattern similar
to chicken wire mesh.
Wires are not possible for use in nanoelectronic, because they are susceptible to
thinning and breakage. Despite recent interest in carbon nanotubes, they have
variable electronic properties, depending on their orientation, reducing their
functionality as electrical conductors.
One problem that plagues researchers looking to fashion circuit components from
nanotubes is separating metallic tubes from the ones that are semi-conducting.
Common synthesis procedures produce spaghetti-like mixtures of nanotube ropes
that are unusable for semiconductor applications because they contain both types
of tubes.
Theoretical models have predicted that nanotubes could behave as ideal one-
dimensional ‘quantum wires’ with either semi conducting or metallic behaviours.
Study of Transmission Electron Micrograph (TEM) images, however, has indicated
that the nanotubes also incorporate kinks and defects into their walls
Najib Altawell
© Altawell 2008