Rayleigh scattering (named after Lord Rayleigh) is the scattering of light or other electromagnetic radiation by particles much smaller

than the wavelength of the light. It can occur when light travels in transparent solids and liquids, but is most prominently seen in gases. Rayleigh scattering of sunlight in clear atmosphere is the main reason why the sky is blue. Rayleigh and cloud-mediated scattering contribute to diffuse light (direct light being sunrays). Why is the sky blue?

When one looks at the sky during the day, rather than seeing the black of space, one sees light from Rayleigh scattering off the air. Rayleigh scattering is inversely proportional to the fourth power of wavelength, which means that the shorter wavelength of blue light will scatter more than the longer wavelengths of green and red light. This gives the sky a blue appearance. Conversely, when one looks towards the sun, one sees the colors that were not scattered away the longer wavelengths such as red and yellow light. When the sun is near the horizon, the volume of air through which sunlight must pass is significantly greater than when the sun is high in the sky. Accordingly, the gradient from a red-yellow sun to the blue sky is considerably sharper at sunrise and sunset.
Rayleigh Scattering

Rayleigh scattering refers to the scattering of light off of the molecules of the air, and can be extended to scattering from particles up to about a tenth of the wavelength of the light. It is Rayleigh scattering off the molecules of the air which gives us the blue sky. Lord Rayleigh calculated the scattered intensity from dipole scatterers much smaller than the wavelength to be: Rayleigh scattering can be considered to be elastic scattering since the photon energies of the scattered photons is not changed. Scattering in which the scattered photons have either a higher or lower photon energy is called Raman scattering. Usually this kind of scattering involves exciting some vibrational mode of the molecules, giving a lower scattered photon energy, or scattering off an excited vibrational state of a molecule which adds its vibrational energy to the incident photon. The scattering from molecules and very tiny particles (< 1 /10 wavelength) is predominantly Rayleigh scattering. For particle sizes larger than a wavelength, Mie scattering predominates. This scattering produces a pattern like an antenna lobe, with a sharper and more intense forward lobe for larger particles.

Mie scattering is not strongly wavelength dependent and produces the almost white glare around the sun when a lot of particulate material is present in the air. It also gives us the the white light from mist and fog.

Scattering of Light by small particles and molecules in the atmosphere

Different from reflection, where radiation is deflected in one direction, some particles and molecules found in the atmosphere have the ability to scatter solar radiation in all directions. The particles/molecules which scatter light are called scatterers and can also include particulates made by human industry.

Selective scattering (or Rayleigh scattering) occurs when certain particles are more effective at scattering a particular wavelength of light. Air molecules, like oxygen and nitrogen for example, are small in size and thus more effective at scattering shorter wavelengths of light (blue and violet). The selective scattering by air molecules is responsible for producing our blue skies on a clear sunny day. Another type of scattering (called Mie Scattering) is responsible for the white appearance of clouds. Cloud droplets with a diameter of 20 micrometers or so are large enough to scatter all visible wavelengths more or less equally. This means that almost all of the light which enters clouds will be scattered. Because all wavelengths are scattered, clouds appear to be white.

When clouds become very deep, less and less of the incoming solar radiation makes it through to the bottom of the cloud, which gives these clouds a darker appearance.