Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Product Use Description : : Uniquat 2250M Corrosion inhibitor

Company

Lonza Inc. 90 Boroline Road Allendale, NJ 07401 1-201-316-9200 CHEMTREC 1-800-424-9300

Telephone Emergency telephone number

: :

SECTION 2. HAZARDS IDENTIFICATION Emergency Overview

Danger
Form: liquid, Colour: light yellow, Odour: alcohol-like Hazard Summary : Causes burns. Irritating to eyes. Harmful if swallowed. Handle in accordance with good industrial hygiene and safety practice. OSHA Hazards : CORROSIVE FLAMMABLE TOXIC Potential Health Effects Primary Routes of Entry : Eyes Skin Ingestion Inhalation : Harmful if inhaled. : Causes skin burns. : Causes eye irritation. : Harmful if swallowed.

Inhalation Skin Eyes Ingestion

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Environmental Effects Environmental Effects : Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. Revision Date 2013.05.08 Print Date 2013.05.08

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Didecyldimethylammonium chloride Ethanol Methanol Water CAS-No. 7173-51-5 64-17-5 67-56-1 7732-18-5 Weight percent 50.00 4.00 - 10.00 20.00 - 45.00 2.00 - 10.00

SECTION 4. FIRST AID MEASURES First aid procedures Inhalation : If breathed in, move person into fresh air. Get medical attention immediately if irritation develops and persists. : After contact with skin, wash immediately with plenty of soap and water. If skin irritation persists, call a physician. : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : Do not induce vomiting without medical advice. Immediately give large quantities of water to drink. Call a physician immediately. Never give anything by mouth to an unconscious person.

Skin contact

Eye contact

Ingestion

SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point : 59 F (15 C) Method: Pensky-Martens Closed Tester (ASTM D 93)

Fire fighting Suitable extinguishing media : Dry powder Water spray Page 2 / 11

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Foam Further information : Use water spray to cool unopened containers. Print Date 2013.05.08

Protective equipment and precautions for firefighters Specific hazards during firefighting Special protective equipment for firefighters : Heating or fire can release toxic gas. : In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use respirator when performing operations involving potential exposure to vapour of the product. : Do not flush into surface water or sanitary sewer system. : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Environmental precautions Methods for containment / Methods for cleaning up

SECTION 7. HANDLING AND STORAGE Handling Handling : Provide sufficient air exchange and/or exhaust in work rooms. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. : Highly flammable. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

Advice on protection against fire and explosion

Storage Requirements for storage areas and containers : Keep container tightly closed. To maintain product quality, do not store in heat or direct sunlight. Keep in a dry, cool and well-ventilated place. : Store containers in compliance with the most recent NFPA Code (NFPA 30). Ground all containers prior to pouring.

Further information on storage conditions

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components Ethanol CAS-No. 64-17-5 Value TWA Control parameters 1,000.000000 ppm Update 2008 Basis ACGIH

REL

1,000.000000 ppm 1,900.000000 mg/m3 1,000 ppm

2005

NIOSH/GUIDE

STEL

2009

ACGIH

Methanol

67-56-1

TWA

200 ppm

02 2012

ACGIH

STEL

250 ppm

02 2012

ACGIH

REL

200 ppm 260 mg/m3 250 ppm 325 mg/m3

2010

NIOSH/GUIDE

STEL

2010

NIOSH/GUIDE

Engineering measures

Personal protective equipment Eye protection Hand protection : Tightly fitting safety goggles : Suitable material : Nitrile rubber Break through time : > 480 min Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. No special protective equipment required. Page 4 / 11

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08

Respiratory protection

: In the case of vapour formation use a respirator with an approved filter. : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hygiene measures

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid : light yellow : alcohol-like

Safety data Flash point : 59 F (15 C) Method: Pensky-Martens Closed Tester (ASTM D 93) 149 F (65 C) Note: Solvent

Boiling point/boiling range

Density

: 0.876 g/cm3

SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid : Remarks: no data available : Remarks: Reducing agents Oxidizing agents

SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 rat Dose: 179.2 mg/kg : LD50 rat Dose: > 200 mg/kg : LC50 rat Dose: 0.064 - 0.54 mg/l : rabbit Page 5 / 11

Acute dermal toxicity

Acute inhalation toxicity

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08 Result: Corrosive Method: OECD Test Guideline 404 Exposure time: 4 h Remarks: Information refers to the main component. Eye irritation : rabbit Result: severe irritant Remarks: Information refers to the main component.

The following toxicological data refer to:

Didecyldimethylammonium chloride (CAS-No.: 7173-51-5) Acute oral toxicity : LD50 rat Dose: 238 mg/kg Method: OECD Test Guideline 401 : LD50 rabbit Dose: 3,342 mg/kg : rabbit Classification: Causes burns. Result: irritating Method: OECD Test Guideline 404 Exposure time: 3 min : Buehler Test guinea pig Classification: Did not cause sensitisation on laboratory animals. Result: not sensitizing Method: US-EPA

Acute dermal toxicity

Skin irritation

Sensitisation

SECTION 12. ECOLOGICAL INFORMATION Environmental Effects : Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. : Information given is based on data on the components and the ecotoxicology of similar products.

Additional ecological information

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08

The following ecotoxicological data refer to:

Didecyldimethylammonium chloride (CAS-No.: 7173-51-5) Biodegradability : Modified Sturm Test Concentration: 10 mg/l Exposure time: 28 d Result: Readily biodegradable. 72 % Method: OECD Test Guideline 301B Die-Away Test Concentration: 0.016 mg/l Exposure time: 28 d 93.3 % OECD Confirmatory Test Exposure time: 24 - 70 d 91 % Method: OECD Test Guideline 303 A Remarks: The surfactant(s) contained in this mixture complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Acute Fish toxicity : Acute toxicity LC50 Species: Pimephales promelas (fathead minnow) Concentration: 0.19 mg/l Exposure time: 96 h Analytical monitoring: yes Method: US-EPA Chronic toxicity NOEC Species: Danio rerio (zebra fish) Concentration: 0.03 mg/l Exposure time: 34 d Analytical monitoring: yes Method: OECD Test Guideline 210 Toxicity to daphnia and other aquatic invertebrates / 000000015149 : Immobilization EC50 Species: Daphnia magna (Water flea) Page 7 / 11

Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Concentration: 0.06 mg/l Exposure time: 48 h Analytical monitoring: yes Method: EPA-FIFRA Reproduction Test NOEC Species: Daphnia magna (Water flea) Concentration: 0.01 mg/l Exposure time: 21 d Analytical monitoring: yes Method: OECD Test Guideline 211 Toxicity to algae : Growth inhibition ErC50 Species: Pseudokirchneriella subcapitata (green algae) Dose: 0.02 mg/l Exposure time: 96 h Analytical monitoring: yes Method: OECD Test Guideline 201 : Respiration inhibition EC50 Species: activated sludge Dose: 11.00 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Print Date 2013.05.08

Toxicity to bacteria

SECTION 13. DISPOSAL CONSIDERATIONS Further information : Dispose of in accordance with local regulations. Contact waste disposal services. : Dispose of as unused product. Do not burn, or use a cutting torch on, the empty drum.

Contaminated packaging

SECTION 14. TRANSPORT INFORMATION DOT UN number Description of the goods Class Packing group Labels

: : : : : :

3286 Flammable liquid, toxic, corrosive, n.o.s. (Methanol, Didecyldimethylammonium chloride) 3 II 3 (6.1, 8)

IATA / 000000015149 Page 8 / 11

Material Safety Data Sheet

Uniquat 2250M
Version 1.0 UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods Class Packing group Labels EmS Number 1 EmS Number 2 Marine pollutant RID UN number Description of the goods Class Packing group Classification Code Hazard identification No Labels Revision Date 2013.05.08 Print Date 2013.05.08 : 3286 : Flammable liquid, toxic, corrosive, n.o.s. (Methanol, Didecyldimethylammonium chloride) : 3 : II : 3 (6.1, 8) : 363 : 352 : Y340

: 3286 : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (Methanol, Didecyldimethylammonium chloride) : 3 : II : 3 (6.1, 8) : F-E : S-C : yes

: 3286 : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (Methanol, Didecyldimethylammonium chloride) : 3 : II : FTC : 368 : 3 (6.1, 8)

SECTION 15. REGULATORY INFORMATION OSHA Hazards WHMIS Classification : Corrosive, Flammable, Toxic : B2 Flammable liquid E Corrosive Material D2B Toxic Material Causing Other Toxic Effects : Acute Health Hazard Fire Hazard

SARA 311/312 Hazards

EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 SARA 302 Components Revision Date 2013.05.08 Print Date 2013.05.08 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

: Methanol

67-56-1

US State Regulations Massachusetts Right To Know Components : Methanol Listed Ethanol Listed Pennsylvania Right To Know Components : Methanol Listed Ethanol Listed New Jersey Right To Know Components : Methanol Listed Ethanol Listed California Prop. 65 Components 67-56-1

64-17-5

67-56-1

64-17-5

67-56-1

64-17-5

: WARNING! This product contains a chemical known to the State of California to cause cancer.

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 3 Flammability: 3 Reactivity: 0

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Material Safety Data Sheet

Uniquat 2250M
Version 1.0 Revision Date 2013.05.08 Print Date 2013.05.08 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by: : Product Safety Americas Email: regcomamer@lonza.com

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