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Jun 99
2. Sulphonyl chloride, SO2Cl2 is a very reactive gas. It decomposes as follows when heated:
SO2Cl2(g) SO2(g) + Cl2(g)
A sample of 3.50 g SO2Cl2 is added to a 1.0-L container and the temperature is elevated to
375 K. If the decomposition has not yet occurred, what is the initial pressure in this container?
As the system attains equilibrium at 375 K, the total pressure in the container is 1.43 atm.
Calculate the partial pressures of SO2, Cl2 and SO2Cl2. <0.798> <0.632, 0.166>
Jan 00
Jul 00
6. At a certain temperature, the equilibrium constant Kc for the following reaction is 7.5:
2NO2(g) N2O4(g)
If 2.0 mol of NO2 is placed in a 2.0-L container and let the reaction to occurs; calculate the
concentrations of NO2 and N2O4 at equilibrium. <0.228, 0.386>
If the size of the container is increased, predict the changes in concentrations of the above
species.
30
SK017
Past Year Examination Questions Unit 6
Aug 01
Aug 02
Sept 03
11. The value of Kc at 45 °C for the reaction P(g) + Q(g) R(g) + S(g) is 0.84.
A mixture of these gases which is not in equilibrium has the following concentrations of the
reactants and products:
[P] = 0.04 M; [Q] = 0.50 M; [R] = 0.40 M and [S] = 0.04 M.
In which direction must the reaction proceed to reach equilibrium?
12. A system was charged with NOCl gas until its concentration reached 0.400 mol L −1. The
temperature of the system was then increased to 245°C and it was allowed to reach
equilibrium according to equation
2NOCl(g) Cl2 (g) + 2NO(g)
At equilibrium, the concentration of Cl2 was 0.0225 mol L−1. Calculate the value of Kc at this
temperature. <3.62x10−4 M>
Oct 04
31
SK017
Past Year Examination Questions Unit 6
Oct 05
15. (a) A 2.50-L flask contains 0.525 mol of CO2, 1.250 mol of CF4 and 0.750 mol of COF2 at
1000°C. Explain in which direction will a net reaction occur to reach the equilibrium shown
below.
CO2(g) + CF4(g) 2COF2(g) Kc = 0.50 at 1000°C
<0.857>
(b) Sodium hydrogen carbonate decomposes at 100°C according to the equation below:
2NaHCO3(s) Na2CO3(s) + H2O(g) + CO2(g)
If the value of Kp is 0.231, calculate the total gas pressure (atm) at equilibrium. <0.96>
Oct 06
At 100oC , the value of Kc is 5.0. Calculate Kp for the above reaction. Explain how the product
could be increased.
If initially 1 mole of NO2 is filled into a 1 L vessel, determine the concentration of N2O4 at
equilibrium.
Oct 07
17. (a) Two moles of hydrogen bromide, HBr, is placed in a 4 L container. At high temperature, it
decomposes according to the following equation:
(b) Carbon monoxide reacts with oxygen to produce carbon dioxide as follows:
Oct 08
18. Sulphuryl chloride, SO2Cl2, gas dissociates reversibly into sulphur dioxide gas, SO2, and
chlorine gas, Cl2. The reaction is endothermic. Suggest all the possible ways to increase the
chlorine production.
An amount of 0.20 mol of SO2Cl2 was placed into a 2-L vessel and allowed to reach
equilibrium. Calculate the equilibrium constant for the reaction if the final concentration of Cl2
is 0.08 M.
The system in equilibrium is disturbed by adding 0.14 mol of SO2Cl2 at the same temperature.
Calculate the concentrations of sulphuryl chloride and chlorine at the new equilibrium.
32