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Volta potential
Volta potential (also called Volta potential difference, or contact potential difference, or outer potential difference, , delta psi) in electrochemistry, is the electrostatic potential difference between two points ("1" and "2") in the vacuum: point "1" close to the surface of metal M1; point "2" close to the surface of metal M2 (or electrolyte); where M1 and M2 are two metals that are in contact and in thermodynamic equilibrium.[1] The Volta potential is named after Alessandro Volta.
Volta potential
Kelvin probe energy diagram at flat vacuum configuration, used for measuring Volta potential between sample and probe.
where
is the Volta potential. It follows therefore that the value of the potential can be measured by varying the capacitance between the materials by a known amount (e.g., by moving the objects further from each other), and measuring the displaced charge that flows through the wire that connects them. The Volta potential difference between a metal and an electrolyte can be measured in a similar fashion.[2] The Volta potential of a metal surface can be mapped on very small scales by use of a Kelvin probe force microscope. In this case the capacitance change is not knowninstead, a compensating DC voltage is added to cancel the Volta potential so that no current is induced by the change in capacitance. This compensating voltage is the negative of the Volta potential.
References
[1] IUPAC Gold Book, definition of contact (Volta) potential difference. (http:/ / goldbook. iupac. org/ C01293. html) [2] V.S. Bagotsky, "Fundamentals of Electrochemistry", Willey Interscience, 2006.
License
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