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Introduction:
An appropriate amount of sun bath promotes the circulation of blood, invigorates the metabolism and improves resistance to various pathogens. Penetration of UVR into the top layer of the skin leads to damage in the lower layer and produces premature ageing of skin and other effects including roughening, blotches, sagging, wrinkles, squamous cells and basal cell cancer. Many people love sunbathing, thereby extending the long term risk to their health. Persons working in the open atmosphere are also prone to keratose, the precursor of skin cancer. Australia has high levels of solar UV radiation, mainly because of its geographical position; New Zealand, USA, Switzerland, Norway, Scotland, Britain and Scandinavian countries also have high melanoma rates. The principal role of ultraviolet (UV) protective clothing is to protect the skin against the harmful effects of the sun, notably skin cancer. This is one of the most prevalent forms of cancer but, fortunately, it is also one of the most preventable. Public awareness about the dangers of excessive exposure to the sun has grown considerably in recent years. However, large sections of the public remain unaware that UV protective clothing exists or that UV resistance in conventional clothing can be increased. Consequently, they rely on sunscreen for UV protection. The slow and limited adoption of UV protection in clothing by mainstream consumers may be partly due to the fact that it can not be seen or felt unlike other performance features such as moisture management and stretch.
2. UV radiation:
Ultraviolet radiation is electromagnetic radiation or light having a wavelength greater than 10 nm but less than 400 nm. Ultraviolet radiation has a wavelength longer than that of x-rays but shorter than that of visible light. Ultraviolet is energetic enough to break some chemical bonds. Unravelling the mysteries related to ultraviolet rays, their properties, and their effects on various living creatures has been a gradual process spanning to the duration of almost three centuries starting from the seventeenth century. Terms such as near UV (290 400 nm), far UV (180 290 nm) and vacuum UV (below 180 nm) have been coined by physicists based on the properties of the radiation. The term UVA represents the region 320 400 nm, the term UVB represents the region between UVC and UVA, i.e. 290 320 nm, and UVC region represents the region below 290 m . The order of potency has been decided as UVC > UVB >UVA >. The proportion of the UV region is about 5 6 % of the total incident radiation, and the quantum energy of UVR is similar to the bond energies of organic molecules.
Light comparison:
Electromagnetic radiation as well as the light can be classified in to different sections according to their wavelength. In that classification only visible light (wavelength 380nm-750nm) we can observe in open eyes. Except visible light other light are invisible, to see those light or observe their presence we need to follow some special procedure.
Wavelength less than 0.01 nm 0.01 nm to 10 nm 10 nm - 400 nm 380 nm - 750 nm 750 nm - 1 mm 1 mm - 1 meter 1 mm - 100,000 km
Frequency (Hz) more than 10 EHz 30 EHz - 30 PHz 30 PHz - 790 THz 790 THz - 405 THz 405 THz - 300 GHz 300 GHz - 300 MHz 300 GHz - 3 Hz
Photon Energy (eV) 124 keV - 300+ GeV 124 eV to 124 keV 3.3 eV to 124 eV 1.7 eV - 3.3 eV 1.24 meV - 1.7 eV 1.24 eV - 1.24 meV 12.4 feV - 1.24 meV
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Visible light:
Visible light waves are the only electromagnetic waves we can see. We see these waves as the colors of the rainbow. Each color has a different wavelength. Red has the longest wavelength and violet has the shortest wavelength. When all the waves are seen together, they make white light.
When white light shines through a prism, the white light is broken apart into the colors of the visible light spectrum. Water vapor in the atmosphere can also break apart wavelengths creating a rainbow. Each color in a rainbow corresponds to a different wavelength of electromagnetic spectrum.
Infared light:
Infrared (IR) light is electromagnetic radiation with longer wavelengths than those of visible light, extending from the nominal red edge of the visible spectrum at 0.74 micrometres (m) to Page | 3
300 m. This range of wavelengths corresponds to a frequency range of approximately 1 to 400 THz,and includes most of the thermal radiation emitted by objects near room temperature. Infrared light is emitted or absorbed by molecules when they change their rotational-vibrational movements. The existence of infrared radiation was first discovered in 1800 by astronomer William Herschel.
Fig(5): An image of two people in mid-infrared thermal light (false-color). Much of the energy from the Sun arrives on Earth in the form of infrared radiation. Sunlight at zenith provides an irradiance of just over 1 kilowatt per square meter at sea level. Of this energy, 527 watts is infrared radiation, 445 watts is visible light, and 32 watts is ultraviolet radiation. The balance between absorbed and emitted infrared radiation has a critical effect on the Earth's climate. Infrared light is used in industrial, scientific, and medical applications. Night-vision devices using infrared illumination allow people or animals to be observed without the observer being detected. In astronomy, imaging at infrared wavelengths allows observation of objects obscured by interstellar dust. Infrared imaging cameras are used to detect heat loss in insulated systems, to observe changing blood flow in the skin, and to detect overheating of electrical apparatus.
a small fraction actually reaches the surface, contrary to most of UVA. In the face of global efforts to diminish ozone-depleting substances, it can be said that, given the recent measures of increasing ozone levels worldwide, the Montreal Protocol on Substances That Deplete the Ozone Layer is really working.
Fig (6): Year-round (2009) solar UVA (blue) and UVB (red) doses measured in So PauloSP (2332'S, 4638'W), Brazil.
Furthermore, apart from the ozone-depleting gases policy, continuous efforts are under way to monitor the yearly incidence of surface UV radiation. Our research group has been dedicating special attention to the measurement of solar-UV rays in the city of So Paulo (2332'S; 4638'W), the largest in Brazil, and one of the most populous in the World. The incidence of solar UVB and UVA radiation has been measured throughout the day, over the last two years. In the year-round graph presented in Figure 1, the winter (June to August) reduction in UV levels (although lower than in higher latitudes) is more pronounced in UVB daily doses, mainly due to the solar-angle effect at this latitude, as UVB is more absorbed by the atmospheric air mass, whereas UVA practically freely passes through. Data of UVA and UVB doses for an entire day, at different latitudes in Brazil are presented in Figure 2 for comparison. The results show that the daily flow of UVA, besides being remarkably greater than UVB, is comparably more constant and detectable earlier in the day. Nevertheless, and as expected, at a lower latitude (Natal) UVB incidence is higher and can be detected earlier in the morning (around 6:00 a.m.), when compared to the other mid-latitudes (around 7:00 a.m.). Ozone concentration, although important, is not the only factor exerting an influence on the incidence of UV radiation. The solar zenith angle, which varies according to the time of day, day of the year and latitude, also contributes enormously.
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Fig (7): Solar UVA (blue) and UVB (red) irradiation profiles at (a) So Martinho da SerraRS (2944'S, 5382'W), (b) So PauloSP (2332'S, 4638'W), and (c) NatalRN (547'S, 3512'W), Brazil.
levels, possibly inversely correlated to the increase in the incidence of melanoma. Mechanistically, UV irradiance is the cause of many deleterious effects, such as the induction of DNA damage, inseparable from those beneficial. Furthermore, various UV wavelengths exhibit different skin-penetration capabilities, with diversification in carcinogenesis as the outcome. Obviously, both ecosystems and the human population are always much more exposed to UVA than UVB irradiance, in absolute flow terms. Nevertheless, these values require weighting, using action spectra involving the relative biological effectiveness for various endpoints. With this in mind, knowledge on the UV pattern at different sites is of vital interest for determining the potential risks arising from local UV radiation worldwide. Thus, the development of appropriate biological sensors assumes an important role in a scenario of increasing UV incidence.
Fig(8): UV rays effect on skin. Factors that affect solar UVR include cloud cover, the suns altitude, geographical position, altitude, ozone layer, scattering in the atmosphere, environmental and related conditions. Much research has been carried out to assess the impact of the UV rays on various living organisms, especially humans and the relationship between skin cancer and UV dosage is well correlated. Changes in leisure behaviour, which has led to more frequent sun exposure, are one of the major reasons for malignant cutaneous melanoma. Skin cells that receive sunlight absorb harmful UV radiation, and slough off to excrete harmful UV from the body. But the absorption of too much UVR leads to scars that can induce diseases like skin cancer. Excessive UV radiation leads to cell damage and causes inflammation of human skin, the obvious consequences of which are erythema or sunburn. The reciprocal value of these cuticle radiation doses is called erythema effectiveness whose maximum occurs at 308 nm. The total UVR dose reaching the skin is an important factor in the occurrence of both erythema and skin cancer, although there is no proven link between erythema and skin cancer. In terms of sensitivity to light and tendency to pigmentation, there are 6 basic types of skin that demand different levels of UV protection as shown in Table 2.
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Risk level
25 35 30 50 45 60 60 100
8 - 12 10 - 15 15 - 20 20 - 35
100 200
35 - 70
Burns easily, has the highest risk of premature skin ageing and greatest risk of developing skin cancer Burn and only rarely tan Tan and occasionally burn Tan and occasionally burn Sufficient levels of melanin and rarely burns, easily tan Sufficient levels of melanin pigment provide protection. Very rarely burns, easily tan
The minimal erithemal dose (MED) is apparently consistent with a fair complexion, but shows variations among people of types III and IV. For practical purposes, the population could be classified into two main groups, sensitive and less sensitive individuals.
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Fig (9): The absorption spectrum for the DNA molecule. A sample of purified plasmid DNA (pCMUT vector), diluted in a TE buffer (10 mMTris-HCl [pH 8.0], 1 mM EDTA [pH 8.0]) at the indicated concentration, was used to obtain this spectrum, with an Evolution 300 UV-Vis Spectrophotometer (ThermoFisher Scientific, USA). The different wavelengths of UV light induce different types of DNA damage. The direct excitation of the DNA molecule by UV sunlight (mainly by UVB wavelengths) results in wellknown modifications that trigger off dimerization reactions between adjacent pyrimidines. The main products resulting from these photochemical reactions are cyclobutanepyrimidine dimers (CPDs) and pyrimidine (6-4) pyrimidone photoproducts (6-4PPs). In addition, upon further irradiation with UVA wavelengths (around 320 nm), the normal isomers of 6-4 PPs can be converted to their Dewar valence isomers. However, in certain dormant life-forms produced by bacteria, such as Bacillus subtilis, the only DNA photoproduct produced upon exposure to UV light corresponds to two thymines linked by the methyl group of one of the bases. The formation of this specific lesion, viz., 5-thyminyl-5,6-dihydrothymine (spore photoproduct, SP), is possibly due to specific features of the spores, these including DNA conformation (A form), dehydration, the presence of dipicolinicacid in the core, and the binding of small acidsoluble proteins to DNA . Apart from direct induction of DNA lesions, UV radiation can also cause DNA damage indirectly, following photon absorption by chromophores other than DNA itself, thereby generating reactive oxygen species. Oxidatively generated DNA damage, mostly in the form of 7, 8-dihydro-8-oxoguanine (considered a marker for this type of damage), and which occurs more effectively with UVA than UVB, has often been proposed as a pre-mutagenic lesion in UVA mutagenesis. Another type of UV-induced DNA lesion, although rather inefficiently so, is the single-strand break. It has also been suggested that this is probably an innocuous lesion with little involvement in the formation of mutations.
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Fig (10): The main DNA lesions induced by UV light: CPD-cyclobutane pyrimidine dimer; 6-4PPpyrimidine (6-4) pyrimidone photoproduct; DewarPP-Dewar valence isomer; Single strand breaks; 8-oxoG-7, 8-dihydro-8-oxoguanine; Spore photoproduct.
It is well-known that solar UV radiation can generate chemical modifications in the DNA structure, leading to several biological consequences. Thus, in the evolution of life on Earth, cells have developed specific DNA repair mechanisms capable of dealing with different types of lesions. In both prokaryotes and eukaryotes, these biochemical pathways are indispensable for maintaining genomic integrity by removing damaged DNA bases or short fragments of nucleotides containing UV photoproducts. However, through inadequate repair, unremoved UV-induced DNA damage possibly interferes with basic cellular processes, such as transcription and DNA replication, thereby leading to mutations and/or cell-death.
( )(
where I ( , t) is the irradiance at wavelength , t is time and () is the cross -section for eliciting this response at wavelengths . The changes in the spectrum have been covered by including time as an argument of the irradiance function and as a variable of integration. Page | 10
The UV index is designed to provide the public with a numerical indication of the maximum potential solar UVR level during the day; the higher the number, the higher the solar UVR hazard. The global solar UV Index is a measure of the highest level of UVR every day, and the UVI is calculated using various input parameters such as the ozone level, potential cloud cover, water vapour and aerosols. The UV index is reported as the maximum biologically effective solar average UVR (UVReff) for the day, and is an average taken over either 10 or 30 minutes. The UVR is usually highest around midday but the temperature is often highest later in the afternoon. UVR index values are grouped into five exposure categories, from low to extreme with different colour codes.
6. UV protection factor:
The protection extended by the textile materials, accessories and sun screen lotions are denoted by different terminologies known as UPF and SPF. Risk estimates of unprotected skin, protected skin and UPF are given by the following formulae: risk unprotected = SA risk protected = SAT UPF = risk unprotected / risk protected Where S is the source spectrum (Wm2 nm-1), T is the transmittance, A is the action spectrum for measured response and is the bandwidth in nm. Since the relative erythemal spectral effectiveness is higher in the UVB region compared to the UVA region, the UPF values depend primarily on the transmission in the UV B region. UV rays falling on textiles are partly reflected, absorbed and partly transmitted through the fibres& interstices, and the optical porosity of a fabric limits its potential to provide protection against UVR.The solar protection factor (SPF) is defined as a quotient from a harmful dose without, and a harmful dose with, sun protection. This can be calculated from erythemal effectiveness (EW ()), (P()) and from the wavelength dependent transmission of the sun protection agent. The difference between the values of UPS and SPF arises mainly because of the hole effect i n the fabrics.
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8. UV absorbers:
UV absorbers are organic or inorganic colourless compounds with strong absorption in the UV range of 290 360 nm. UV absorbers incorporated into the fibres convert electronic excitation energy into thermal energy, function as radical scavengers and ?singlet oxygen quenchers. The high-energy, short-wave UVR excites the UV absorber to a higher energy state; the energy absorbed may then be dissipated as longer-wave radiation. Alternately,isomerisation can occur and the UV absorber may then fragment into non-absorbing isomers. Sunscreen lotions contain UV absorbers that physically block UVR. The most widely used UVB screens, 2-ethyl hexyl-4methoxy cinnamate with high RI, make a substantial contribution to the RI matching of skin, i.e. refractive index matching. An effective UV absorber must be able to absorb throughout the spectrum, to remain stable against UVR, and to dissipate the absorbed energy to avoid degradation orloss in colour. Organic UV absorbers are mainly derivatives of o-hydroxybenzophenones, o-hydroxy phenyl triazines, o-hydroxy phenyl hydrazines. The orthohydroxyl group is considered essential for absorption and to make the compound soluble in alkaline solution. Some of the substituted benzophenones penetrate into synthetic fibres much like disperse dyes. Commonly-used UV absorbers are 2-hydroxy benzophenones, 2-hydroxy phenyl benzotriazoles, 2-hydroxy phenylStriazinesand chemicals such as benzoic acid esters, and hindered amines. The strong absorptionin the near UV of 2, 4 dihydroxybenzophenone is attributed to conjugating chelation between theorthohydroxyl and carbonyl groups. Organic products like benzotriazole, hydro benzophenone and phenyl triazine are primarilyused for coating and padding processes in order to achieve broad protection against UV rays. Suitable combinations of UV absorbers and antioxidants can yield synergistic effects. Benzophenone derivatives have low energy levels, easy diffusibility and a low sublimation fastness. Orthohydroxy phenyl and diphenyltriazine derivatives have an excellent sublimation fastness, and a self-dispersing formulation can be used in high temperature dyeing in padbathsand also in print pastes. UV absorbers incorporated into the spinning dope prior to the fibre extrusion and dye bath in bath dyeing improve the light fastness of certain pastel shades and the weatherability of spundyed fibres. UV absorbers to the extent of 0.6 2.5% are sufficient enough to provide UVR protection fabrics. The presence of UV absorbers in PET, nylon, silk and wool protects the fibres against sunlight-induced photo degradation. On wool, UV absorbers can retard the photoyellowing that occurs upon exposure to sunlight. Triazine class-hindered amine light stabilisers are used in PP to improve the UV stability. The addition of HALS to 0.15% weight is sufficient to improve stability substantially. Even pigmented PP requires UV stabilisers if the fibres are exposed to UV during their services [43]. High-energy UV absorbers suitable for PET include derivatives of o-hydroxyphenyldiphenyltriazine, suitable for dye baths, pad liquor or print paste. UV absorbers have refractive indices of about > 2.55, by means of which maximum covering capacity and opacity is achieved. The presence of inorganic pigments in thefibres results in more diffuse reflection of light from the substrate, and provides better protection. TiO2 added in the spinning dope for matt effects in the fibres also acts as a UV absorber. Titanium dioxide and ceramic materials have an absorption capacity in the UV region between 280 and 400 nm, and reflects visible and IR rays; these absorbers are also added as dope additives [53]. For maximum effect, the particles have to be monomolecularly distributed, and are often applied Page | 12
in one bath. Nanoscale titanium gel particles strongly bound to the cotton fabrics can give a UPF 50 without impairing the tensile properties. Brighter viscose yarns provide the highest UV transmittance compared to the dull pigmented viscose yarns, modal yarns. Zinc oxide nanoparticles, which have a very narrow size distribution (20-40 nm) and minimal aggregation, can result in higher levels of UV blocking [51]. Use of TiO2, ZnO alone produces less absorption of UVR than a mixture of (67/33) titanium dioxide and zinc oxide on cotton and nylon fabrics [32]. Microfine nylon fabrics with a porosity of 0.1% are capable of giving UPF > 50 with 1.5% TiO2. Incorporating UV absorber in dyeing decreases the dye uptake slightly, except in posttreatment application. Many commercial products and processes have been developed to produce fabrics with a high level of UPF using various dope additions and topical applications for almost all types of fabrics produced from cellulosic fibres, wool, silk and synthetic fibres. Most of the commercial products are compatible with the dyes and other finishing agents applied to the textile materials, and these agents can be applied using simple padding, the exhaust method, the padthermofix and the pad-dry-cure methods.
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scattered waves that have interacted with the fabrics. Another part is absorbed when it penetrates the sample, and is converted into a different energy form. The portion of radiation that travels through the fabric and reaches the skin is appropriately referred to as the transmission component. The UPF increases with fabric density and thickness for similar construction, and is dependent on porosity (UPF = 100 / porosity). A high correlation exists between the UPF and the fabric porosity but is also influenced by the type of fibres. The relative order of importance for the UV protection is given by % cover >fibre type > fabric thickness. Cloth cover does not consider the flatness of the yarns, which might result in a higher cloth cover than the calculated value. A UPF with fabric weight and thickness shows better correlation than cloth cover. Therefore fabrics with themaximum number of yarns in warp and weft give high UPFs. UPF values of 200, 40, 20 and 10 can be achieved with the percentage cover factors of 99.5, 97.5, 95 and 90 respectively. The percentage UVR transmission of a fabric is related to the fabric cover factor by (100 cover factor) and the UPF is given by UPF = 100 / (100-CF). To achieve a minimum UPF rating of 15, the cover factor of the textile must be greater than 93%, and a very small increase in CF leads to substantial improvements in the UPF of the textiles above 95% cover factor. In the case of terry cloth, a high variability in UPF exists due to irregularities in the fabric construction. Woven fabrics usually have a higher cover factor than knits due to the type of construction. Thick rib structures of hemp and linen can allow 10.52 12.70% and 9.03 11.47% of UV A and UV B respectively . However, knitted structure made from a blend of synthetic fibres with Lycra offers the best protection against solar radiation, and warp-knitted blinds are capable of screening up to 80% of the solar radiation and bright glares. Stretching reduces the UPF rating of the fabric during wear, as the effective cover factor is reduced. However, the cover factor can be modified through many dry finishing processes through overfeed on the stenter, compressive shrinkage processes such as compacting and sanforising, whichare normally used to obtain dimensional stability, incidentally increasing the cover factor and hencethe UPF. Gentle milling employed in the case of lightweight wool fabrics can also enhance the cover factor and the UPF.
which is not sufficient to satisfy the minimum requirements. Some of the vinyl sulphone dyes and monochlorotriazine dyes possess UVR absorption characteristics, which also increase with theconcentration. Cellulosic fabrics dyed with these dyes show reduced UVR transmission from 24.6% to 10-20% and 27.8% to 8-22% for UV A and UV B respectively. When mixtures of these dyes are used, the UPF increases synergistically. Some combinations of disperse reactive mix can give prolonged UV protection with a UPF of 50+ for P/C blends. Optical brightening agents or fabric whitening agents are used at the finishing operations, as well as in the wash cycles, and their effect on UPFs has been demonstrated extensively in the past. Optical brightening agents are often applied to enhance the whiteness of textiles by UV excitation and visible blue emission. The phenomenon of excitation and emission is caused by the transition of electrons involving p-orbitals from either conjugated or aromatic compounds. Most optical brighteners have excitation maxima within the range of 340 400 nm. OBA can improvethe UPF of cotton and cotton blends, but not of fabrics that are 100% polyester or nylon. The presence of OBA in the P/C blends (67/33) to the extent of 0.5% can improve the UPF from 16.3 to 32.2, which is more or less closer to that obtained using the UV absorbers with 0.2% (UPF 35.5). Washing the fabrics leads to a loss of UPF in the case of OBA-treated fabrics, and the UPF reaches the level of that in untreated fabric after 10 washes, which shows the semi-permanent nature of the finish and protection. Another limitation of many OBAs is that they mostly absorb in the UVA part of the day light spectrum (93%) but have a weak absorption in UV absorption around 308 nm (92%), which plays an important role in skin disease.
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Construction: Dense, tight construction (either weaves or knits) minimizes the spaces
between yarns, which in turn minimizes the amount of UV light that can pass through. Some tightly constructed UPF-rated garments use vents to boost air circulation and help the wearer stay cool. Thicker fabrics also help reduce UV transmission. Dyes: It is the specific type of dye (and the concentration in which it is used) that impacts a fabric's UV transmission, not its color. Some dyes deflect more UV radiation than others, and some absorb none at allincluding black dyes. How can one know what kind of dyes are used in individual garments? The only tip-off is if the garment carries a UPF rating. Clothing engineered for UV protection may use high concentrations of premium dyes that disrupt UV light. Such dyes include "conjugated" molecules that disrupt UV radiation. The higher the concentration of such dyes, the darker the garment becomes. But ultimately color has no influence on UV rays. Note: Pigment-dyed fabrics, which include a resin that creates a powdery look and feel, get high marks for UV protection. Treatments: Chemicals effective at absorbing UV light may be added during processing. Specialized laundry additives, which include optical brightening agents and newly developed UV-disrupting compounds, can boost a garment's UPF rating. Fiber type: Polyester does an excellent job at disrupting UV light (due to hydrogenand carbon-based benzene rings within the polymer). Nylon is good. Wool and silk are moderately effective. Cotton, rayon, flax and hemp fabrics (natural fibers composed of cellulose polymers) often score low without added treatments. However, unbleached or naturally colored cotton performs better at interacting with UV light than bleached cotton. Stretch: If a garment is stretched 10% or more beyond its normal dimensions, spaces between yarns are widened and its effectiveness against UV light may be reduced up to 40%. Wetness: A fabric's ability to disrupt UV radiation is usually reduced when wet, though the reasons why are not completely understood. Wetness may cause a 30% to 50% reduction in a fabric's UPF rating. Condition: Worn or faded fabrics are less effective against UV light.
11.
There are several reasons or factors available which effects the protection factor of UV protective textile. Those factors are so important for the better performance to that textile. Those factors are Effects of yarn structure on UV protection Effects of fabric geometry on UV protection Effect of cover factor or open porosity Effect of fabric tightness Effect of volume porosity Effects of colour on UV protection Effects of maintenance and usage on UV protection Effects of additives on UV protection Page | 17
Effects of yarn structure on UV protection: Woven fabrics are made from different types of yarns. Raw material of yarn or fibre composition is the initial yarn parameter which has an effect on UVR protection. Fibres have different ability to absorb UV radiation and to block most of the incident radiant energy and those prevent it from reaching the skin. There is a lack of studies dealing with the effect of fibre composition only. The reason is that yarn colour, additives and coatings have much more significant impact on UV transmission properties rather than fibre composition itself. Never less, Crews et al. (Hatch &Osterwalder, 2006) conducted a comparison of undyed woven fabrics and determined how fibre composition ranked relative in regard to UV absorbance. They established three distinct groups regarding the decreasing ability of fibre UVR absorbance: 1.group includes polyester, 2. group includes wool, silk and nylon and 3. group includes cotton and rayon fibres. Natural fibres have lower UV blocking properties regarding the synthetic ones, but from the thermo-physiology point of view there are more suitable in hot wearing conditions. Hustvedt et al. (2005) found that naturally-pigmented cotton fabrics have excellent sun protective properties, which are far superior to conventional, bleached or unbleached cotton fabrics. Stankovic et al. (2009) conducted a study of yarn twist effect on UPF of cotton knitted fabric and found that yarn twist to a great extent influenced the UV protection properties through the influence on yarn compactness and surface properties, which in turn influenced the open porosity of the fabric.
AS/NZ standard. This is possible only by higher thread densities and definitely not by plain weaves in our case. Even if the plain fabric would have the 0highest cover factor it would not reach the UPF 15. The results of mentioned study refer to the theoretical values of open porosity and cover factor. In real fabric open porosity is much lower, especially in the case of fabrics made from the staple-fibre yarns, where the phenomenon of latticed pores, the phenomenon of changing the position of warp threads according to the longitudinal axis and the phenomenon of thread spacing irregularity occur. In this case the correlation between the measured open porosity/cover factor (image analysis) and UPF is not so good and should be treated regarding the type of weave (Fig. 6).
Fig (13): The influence of theoretical values of open porosity or cover factor on UV protectionof cotton fabrics in a grey state. The plain-weave fabric includes the maximum percentage of weave passages (67%) and it is reasonable to assume that all the threads are more or less equidistant and that the effect of fully latticed pores is reduced to its minimum, whereas by satin weave the effect of fully latticed pores is very high those reducing open area for UV transmission. If we observe measured values of open porosity, the limit values to reach good UV protection of fabrics is 12% or lower without taking into account the type of weave. Further observation regarding the type of weave shows that by plain and twill weave it is not possible to reach UPF 15 neither by 12% of open porosity, while by satin weaves this is possible. The results clearly indicate that theoretically defined open porosity/cover factor is not satisfactory parameter toasses its influence on UPF because of the absence of weave influence. In real fabrics, especially in fabrics with staple-fibre yarns, different types of pores regarding the type of weave and other phenomenon are involved, which all reduce the fabric open area in comparison with theoretically calculated values of open porosity. On the other hand, open porosity/cover factor could be a good parameter showing the influence on UPF if the set of fabrics with the same type of weave, raw material and yarn fineness is observed. In our previous research (Dubrovski&Brezocnik, 2002) we also proposed the predictive model of open porosity which is in better correlation with measured values than theoretical ones. Page | 19
Fig (14): The influence of measured values of open porosity and cover factor on UV protection of cotton fabrics in a grey state (a without weave influence, b with the weave influence).
(Dubrovski&Golob, 2009), the following decreasing rate of UPF values could be seen within the same fabric tightness: satin twill plain
Fig(15): The influence of fabric tightness on UV protection of cotton fabrics in a grey state.
The macropores in plain fabrics have very stable and uniform form as a consequence of more thread passages. On the other hand, the pores in satin fabrics are not as stable due to few thread passages, and tend to group together which further reduces the free space area. By fabrics made from staple-fibre yarns macropores are further reduced because of the phenomenon of latticed pores. Nerveless higher actual warp/weft density by each weave means higher fabric tightness and consequently higher UV protection. Results for fabrics in a grey state show that none of the plain fabrics offered minimum UV protection, even if they were tightly woven. Twill fabrics had good UV protection if they were woven with tightness above 70%, while satin fabrics offered good UV protection already by 60% tightness.
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Fig(16):The influence of fabric volume porosity on UV protection of cotton fabrics in a grey State.
(red, blue marine and black), bleached fabrics (white) and naturally pigmented abrics (dirty white). The comparison of UPF of fabrics with the same construction but different colour was made for fabrics in plain, twill and satin weave and by three different levels of fabric tightness (55-65%, 65%-75%, 75%-85%). By satin and twill fabrics at third level of fabric tightness, where higher densities can be achieved and those the influence of open porosity is set to its minimum, the results show that all dyed fabrics posses excellent UV protection (UPF=1000), while naturally pigmented twill and satin fabric had UPF 25 and 50, respectively. UPF of bleached twill and satin fabric was 10 and 15, respectively. The L* component of fabric colour was around 93, 86, 44, 31 and 17 for white, dirty white, red, blue marine and black fabric, respectively. The previous mentioned recommendation that L* value of the dyed fabrics should be less than 38 to develop fabric with good UV protection, could not be generalized, while in our case also white satin fabric with L* of 93 showed good UV protection at third level of fabric tightness. Our results show that there were no big differences between red, blue and black coloured fabrics UPF at higher thread densities by twill and satin fabrics, but there was a huge difference between uncoloured and bleached fabrics UPF on one side and coloured fabrics UPF on another. The general conclusion of mentioned research was that UPF of cotton fabrics dyed with direct dyestuffs is influenced by the colour components (L*, a*, b*), fabric tightness and type of weave so we proposed a prediction model of UPF based on CIELAB colour components, weave factor, and warp/weft density. Riva et al. (2009) analyzed the influence of the shade and colour intensity of the dyeing as well as their interaction with the initial UPF of the uncoloured cotton fabrics. They proposed UPF prediction model for cotton fabrics dyed with direct dyestuffs (yellow 98, blue 77, red89) on the basis of the initial UPF of fabrics before dyeing, standard depth of colour, the corrected standard depth of colour and two categorical qualitative variables that define colour hue of dyestuffs.
2003). Varga et al. (2009) introduced a nanoparticle coating on yarns. They applied anoZnOfinish on undyed and reactive dyed cotton yarns with the aim of studying the effect of the knitting operation on the durability of the coated nanoparticles and found that such yarns withstand the knitting process. They also performed sol-gel finishing of cotton fabrics, coated with TiO2 nanoparticles and found that such fabrics are durable to domestic washing, and even there was a reduction in the load of nanoparticles on the fabric surface after washing, the UPF values were not affected. Abidi et al. (2009) reported that titania or titania-silicianonosol treatment in the form of thin film at cotton fabric surface offer excellent UV protection.Gorensek et al. (2007) treated cotton fabrics with nanosilver, which was in the form of nano powder added in the dyebathat two concentration (5 mg/L and 20 mg/L) and found that a noticeable increase of UPF was recorded by the 5% mock dyed sample with 20 mg/L nanosilver as well as by pale dyed fabrics in comparison with bleached and dyed cotton fabrics, respectively. Grancaric et al. (2009) treated PET fabrics for summer clothing with ultrasound (US), ethylene-diamine (EDA), fluorescent whitening agents Uvitex ERN based on benzoxazolederivate (FWAs) and Tinofast PES UV absorbers based ontriazine derivate and compared their UPF values. Untreated PET fabrics did not have any UV protection (UPF=5), while all other treatments lead to very good UV protection. EDA treated fabric resulted in better UV protection than US treated fabrics.
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In the early 1990s UV protective clothing was considered to be a niche market as it comprised mainly swimwear for children and babywear. Its lack of popularity among adults was due to its relatively high cost, and the perception that it was heavy, hot and uncomfortable to wear. However, in the past decade, a number of companies have introduced UV protective fabrics and garments which do not sacrifice comfort, breathability or other desirable characteristics commonly associated with good performance apparel. Furthermore, high quality UV protective clothing today is both functional and fashionable. It is typically made from lightweight, breathable fabrics, and can provide as much protection from UV radiation as heavyweight denim. Looking ahead, it has been projected by some authorities that consumers will come to expect their outdoor apparel to offer UV protectionin the same way as they expect it to be waterproof or insulating today. Others in the industry are less optimistic, and believe that it will take some time before garment manufacturers and consumers fully understand the benefits of UV protective clothing. Although clothing has been used for protection against solar exposure for thousands of years, in modern times sun protective clothing was popularized (but not exclusively used) in Australia as an option or adjunct to sunscreen lotions and sunblock creams. Sun protective clothing and UV protective fabrics in Australia now follow a lab-testing procedure regulated by a federal agency: ARPANSA. This standard was established in 1996 after work by Australian swimwear companies. The British standard was established in 1998. The NRPB (National Radiological Protection Board) forms the basis of the British Standards Institute standard. Using the Australian method as a model, the USA standard was formally established in 2001, and now employs a more stringent testing protocol: This method includes fabric longevity, abrasion/wear and washability. (To date, the focus for sun protection is swimwear, appropriate hats, shade devices and sunglasses for children.) UPF testing is now very widely used on clothing used for outdoor activities. The original UPF rating system was enhanced in the United States by the ASTM (American Standards and Testing Methods) Committee D13:65 at the behest of the U.S. Federal Trade Commission (FTC) to qualify and standardize the emerging sun protective clothing and textile industry. The FDA had reviewed clothing making sun protection claims (SPF, % UV blockage, or skin cancer prevention claims) in 1992. Only one brand of sun protective clothing, Solumbra , was reviewed and cleared under medical device regulations. The FDA initially regulated sun protective clothing as a medical device, but latter transferred oversight for general sun protective clothing to the FTC. The UPF rating system may eventually be adopted by interested apparel and domestic textile/fabric manufacturers in the industry at large as a "value added" program strategic to complement consumer safety and consumer awareness.
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Solumbra:
Solumbra is a line of sun protection clothing and a patented fabric. Introduced in 1992, Solumbra was reviewed under medical device regulations by the U.S. (FDA) and by Health Canada. This was revolutionary; no sun protective clothing had previously been reviewed as a medical device in the U.S. or Canada.] Solumbra offered improved and superior (UV) protection when compared to a conventional 30 SPF sunscreen and typical summer clothing. Solumbra sun protective clothinghats, shirts, pants and accessoriesis now rated at 100+ SPF. Solumbra was developed as a personal sun protection clothing solution by Shaun Hughes, who was diagnosed and treated for malignant melanoma, a potentially deadly form of skin cancer, at age 26 during a visit to Memorial Sloan-Kettering Cancer Center in 1983. After two surgeries, he found that traditional UV protection was not sufficient: he would sun tan through his sunscreen and sunburn through his summer clothing. Based upon medical research and involvement of UV and medical experts, Hughes developed the Solumbra line of fabric and clothing. Solumbra was reviewed under medical device regulations. Solumbra entered the U.S. marketplace soon after May 13, 1992. The Solumbra logo is a depiction of the suns rays eclipsed by effective sun protection that, in turn, provides an area of safe shade. Solumbra has been used by highly sun sensitive patients as well as by world-class athletes participating in international competition. Sun protection clothing can offer superior photoprotection because of typical sunscreen shortcomings: not equally broad spectrum, misapplication, low durability, allergic reaction, poor reapplication behavior, and poor cosmetic elegance. Sun protection clothing has become a choice of patients with skin cancer, lupus, vitiligo, porphyria, XP, and sun allergies.
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Technology: Solumbra sun protection fabrics rely on four methods to achieve sun protection: fiber content, weaving methods, fabric dyeing process and finishing process. The key concept is to prevent UV from transmitting through the fibers and apertures (holes between the fibers). Solumbra I fabric is protected by U.S. and international design and process patents.Hughes developed the technology without treatments or coatings that could lose their effectiveness and photoprotection after use, laundering and exposure to environmental factors. Solumbra clothing designs are based upon published medical guidelines.] Designs are typically long sleeved, long legged and wide brimmed, all to provide maximum UV protection against both direct and indirect UV exposure. Research: Solumbra fabrics were at the forefront of in vitro and in vivo research into UV protection offered by fabrics. This research revealed that traditional summer clothing in North America offered less than 15 SPF protection, the minimum level recommended by doctors. R Sayre was the lead researcher of in vitro SPF testing for regular summer fabrics, which tested between SPF 5 to 9 when dry and SPF 3-9 when wet. Nicholas Lowe and R Sayre followed this up with in vivo research. They found that Solumbra offered over 50 SPF when dry or wet. In vivo research spearheaded by J Menter and Sayre, published in the Journal of the American Academy of Dermatology, showed that most mice contracted squamous cell carcinoma (scc) skin cancers through typical summer fabrics and mice protected by Solumbra fabrics did not incur skin cancers. Subsequent research by Menter and Sayre found that specific Solumbra fabrics provided photoprotection for mice against injury from visible light when sensitized with the photosensitizer, ALA, compared to insufficient protection by typical summer fabric. Research was just presented by an independent researcher in March 2012 that showed that Solumbra fabrics now offer 100+ SPF even after 500 durability cycles. Innovation: The New York Times declared Sun Precautions was the innovator, with its Solumbra line, which blocks more than 97 percent of UVA and UVB. Solumbra has been featured in other leading publications and national media, including Time, U.S. News and World Report, People, MSNBC, The Today Show, The Los Angeles Times, Vogue, and Health. In October 2011, Travel and Leisure magazine found that Solumbra was one of the 'The Game Changers'--Worlds Most Important Travel Innovations. The American Academy of Dermatology recognized Solumbra and Sun Precautions with a Gold Triangle Award for assisting with skin cancer awareness and prevention.
engineering researcher Chris Oldham said.The fabric coating resists the sun's UV rays, which can prevent fading of outdoor materials such as flags. It might also be used on clothing to reduce the risk of skin cancer.UV-resistant fabrics already on the market can be expensive."They are looking for a more affordable product that will protect them in the sunlight," Oldham said rather than dipping fabrics in an oil-based liquid solution, NCSU researchers heated chemicals into gas form that deposits a coating 1,000 times thinner a human hair. The process might work on a wide range of lightweight, summer-time fabrics. "What we're trying to do is use greener materials like cotton and recycled polyesters and make those feel the same and also act the same as some of these high-end, UV-resistant fabrics," NCSU textile engineering researcher Jesse Jur said. In addition to protecting people from the sun, the clothing could be used as a sensor to track heart rate and body temperature in real time.The NCSU Chancellor's Innovation Fund recently awarded a $75,000 grant to get the technology into the market more quickly.
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Appropriate precaution which were applied while carrying out the measurement should be sufficient to collect all the scattered and transmitted lights through an integrating sphere, to include all the erythemal active wavelengths (UVA & UVB) spectral measurements without any influence of fluorescence from FWA, if it is present in the fabric. There are currently 12 sites in Australia and Antarctica installed with broadband UVR detectors to measure the total energy received over a range of wavelength in UVR region in both direct and diffuse radiation. Polysulphone films have been widely used in the construction of personal dosimeters, which absorb strongly in the UV B region. The instrument for measuring fabric transmission includes broadband radiometers, spectroradiometers, or spectrophotometers, and Xenon lamps. Filters are placed next to the test specimen to prevent the effects of fluorescence reaching the integrating sphere. The spectral response of the detector is also important in determining system performance, and it must be capable of detecting UVR accurately and linearly over a very large rangeof intensities and discriminating the signal from the detector dark current. Many commercial systems have difficulty in measuring UPFs above 100 due to dynamic range, dark current discrimination at lower wavelengths of <300 nm, and fluorescence at wavelengths of >380 nm. Low light levels in the UVR source used for measurement can also lead to difficulty in distinguishing between the transmitted UVR and the natural dark current of the detector.The measurement of UPF on a clothing material can be carried out by measuring the diffuse spectraltransmittance in vitro or by measuring the increase in exposure time required to induce erythema or sun burn in vivo. The preparation of the fabric prior to the UV transmission test includes the exposure of specimen to laundering, simulated sunlight and chlorinated pool water, and to present in a state that simulate the conditions at the end of two years of normal seasonal use, so that the UV protection level finally stated on the label estimates the maximum transmittance of the garment fabric during a two-year life cycle.
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Initiatives for developing standards related to UV protection started in the 1990s, and standards related to the preparation of fabrics, testing and guidance for UV protection labelling have been formulated by different agencies. Care labelling similar to fabric andgarment care labels has been developed for UV protection, and standard procedures have been established for the measurement, calculation, labelling methods and comparison of label values of textile products. Since 1981, the Skin Cancer Foundation, an international body, has offered a Seal of Recommendation for the photo-protective products which includes sunscreens, sunglasses, window films and laundry detergent additives, in accordance with AATCC TM 183 or AS/NZS 4399; the products recommended are reviewed annually.
Grade III II I
Table(3): Grades and classification of UPF UV labelling is an additional requirement besides other labelling requirements of garments including Permanent Care Labels and Fibre Content labels. Apart from the UPF label, block numbers can also be used based on the UV transmittance value in their respective UVR range. Table 2 shows the various grades and the related protection factors for the textile materials. The UPF value to be placed on the label is that of the sample, reduced by its standard error of UPF values, and then rounded down to the nearest multiple of 5 but not greater than 50. A UPF of 20 means that 1/20th, i.e. 5%, of the biologically effective UV radiation striking the surface of the fabric actually passes through it.
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Conclusion:
The best technique for reducing UV exposure is to avoid sun exposure, but this is an unacceptable solution to all. Recreational exposure accounts for most of the significant UVR exposures of the population, and occupational exposure is also significant. However, there is growing interest in reducing the UVR exposure of outdoor workers. This necessitates the development of stronger UV absorbers which will be especially suitable for low UPF fibres, which are highly preferred by the consumers. UVR exposure can be reduced by implementing by behavioural changes such as avoiding sunlight at its maximum, using protection such as hats, sunscreens, sun glasses, and clothing.
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Woven fabrics can provide simple and convenient protection against harmful effects of UV radiation if the necessary attention is paid to their engineering in the phase of a new product development. There are several factors influencing UV protection properties of woven fabrics like yarn construction (fibre type, twist, yarn packing factor), fabric construction with its primary (type of weave, yarn fineness, warp/weft density, relative fabric density or fabric tightness) and secondary (cover factor, open porosity, mass, thickness, volume porosity) parameters of fabric geometry, additives (dye, pigment, delusterant, optical brighteners, UV absorbers), laundering and wearing conditions (stretch, wetness). The proper combination of mention factors allows production of passive woven fabrics with high UV protection properties, which may reduce risk associated with UV overexposure. For subject wearing garment made from UV protected fabrics the information about how long he/she could be exposed to the harmful UV rays before the serious skin damage occur, will be more useful, instead of knowing UPF value of garment. UV exposure time is affected by several factors like subject skin type, geographic position of subject, daily time or the sun position, the presence of clouds, altitude, portion of skin covered by fabric, etc. However, nowadays, there is a trend to develop smart textiles or active intelligent fabrics which, for example, could change their own colour in dependence on external stimulus like UV light (Vikova, 2004). Soon such smart textiles will be developed which will warn the subject how long he/she could be on the sun, what is the average UV index in a particular position, what is the UPF of wearing fabric in a particular moment, when subject should use the shadow, etc.
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1. 2. 3. 4. 5. 6. 7. 8. 9.
References:
D. Saravanan, UV PROTECTION TEXTILE MATERIALS Perkin S.W., Functional Finishes and High Performance Textiles Mallik S.K., Arora T., UV Radiations: Problems and Remedies Hatch K.L., Making a Claim that a Garment Fabric is UV Protective Anon, UPF Analysis of Textile Achwal W.B., UV Protection by Textiles Polona Dobnik Dubrovski Woven Fabrics and Ultraviolet Protection http://en.wikipedia.org/wiki/Space_suit http://www.rei.com/learn/expert-advice/sun-protection.html
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