Course Plan: Chemistry Course code : CHEM 103 No.

of credits: 4 Course Plan 2010-2011

Format No QSP/7.1/01.F.02(b) Issue No 01, Rev.03, Dated July 2009

University of Petroleum & Energy Studies College of Engineering Studies Energy Acres P.O. & Vill: Bidholi Dehradun
http://upesindia.ac.in TEL: +911352776091/93/95, FAX: +911352776094/89

Program: B. Tech (ADE, ASE, CS, EE, IFE, PSE, MECHATRONICS ) (2010-2011)

Faculty: Chemistry Group Email: kmastan@ddn.upes.ac.in

Approved by:

HOD

Dean

COURSE PLAN
PREREQUISITE Basic knowledge of chemistry OBJECTIVES OF THE COURSE

The objectives of this course are: a) The prime objective of this course is to make students familiar with the fundamental
concepts of chemistry. b) This course provides the students with a strong background of the chemistry of engineering materials and shows how these concepts are applied to petroleum and petrochemical industries. c) This course helps in creating quality human resources to enhance the productivity of the existing petroleum and petrochemical industries which provide cost effective substitute of natural products, which not only help conserving our natural resources but also spur economic growth d) The entire module will enable our students as a future petroleum/gas engineer or technologist for solving problems faced by the petroleum industries and giving new dimensions to the petroleum products.

THE SYLLABUS
The syllabus consists of the following major sections: Unit 1- Fuels and Thermochemistry Unit 2- Solid State Unit 3- Electrochemistry Unit 4- Corrosion Unit 5- Polymers Unit6- Organic Chemistry Unit 7- Chemical Kinetics Unit 8 - Nanochemistry

PEDAGOGY Presentations (Individual/Group) Class Test Quiz Assignments Video presentations

EVALUATION & GRADING Students will be evaluated based on the following three components. Internal assessment Mid term examination End term examination

Internal assessment: weightage 30% Internal assessment shall be done based on the following: Quizzes Three quizzes to be held during the semester. The schedule for quizzes is given in the detailed session plan. Students who miss out on a quiz will lose the marks for the quiz. Any two out of three quizzes shall be considered for evaluation. Presentations- Presentations shall be held towards the end of the semester. Presentations will be group assignments. Each member of the group shall be awarded the same grade. Announcements of groups shall be made by the faculty. No group shall have more than five members. Presentations shall be of 20 minutes length which will be followed by a question and answer session by students as well as faculty. Each member of the group is supposed to present. Presentations shall be assessed on contents, presentation style and ability to answer queries related to the subject. Assignment(s)- Assignment(s) could be numerical problems or case studies or both. Students are supposed to submit assignments on a particular date. Those who do not submit the assignment by the due date shall be penalized through deduction of marks. This deduction shall be at the discretion of the faculty.

Mid term examination: Weightage 20% Mid term examination shall be of two hours duration and shall be a combination of short theory questions and numerical problems. End term examination : Weightage 50% End term examination shall be of three hours duration. The examination shall have short theory questions and/ or objective type questions, short numerical problems and a caselet.

Grading The overall marks obtained at the end of the semester comprising all the three components mentioned above shall be converted to a grade by the faculty. The grades awarded by the faculty shall be finalized by an examination committee. Attendance Students are required to have a minimum attendance of 75% in each subject. Students with less than the stipulated percentage shall not be allowed to appear in the end semester examination. DETAILED SESSION PLAN Unit No. Topics Lecture Sub-topics to be covered No. 1 Introduction Classification Characteristics 2 Distillation of crude oil and petroleum composition Calorific value 3 Determination of calorific value, Combustion and its calculations 4 5 6 7 Analysis of coal- proximate Ultimate analysis, Flash point Octane number, cetane number Enthalpy of formation Enthalpy of neutralization Enthalpy of combustion Hesss law of constant heat summation and its application, bond energy Introduction Types of solids Types of crystals Elements of symmetry No. of atoms per unit cell Bravice lattice Different crystal structure Structures- AB, AB2, A2B type Braggs equation, diamond, graphite Fullurene References

FUELS AND THERMOCHEMISTRY

3-7

II

SOLID STATE

10

1,2, 10

11

12

III

ELECTROCHEMISTRY 13 14 15 16 17 18 19 20 21

IV

CORROSION

POLYMERS 22

23

24

25 VI ORGANIC CHEMISTRY 26

27 28

29 30 31 32

Conductance and its types Variation of conductance with dilution Theoritical aspect of electrolysis Galvanic cell, Single electrode potential, Nernst equation ECS and its applications, types of instrumental titrations Conductometry and applications, pHmetry, potentiometry Introduction, dry theory Wet theory, acid theory, types Factors, prevention Introduction, classification Physical properties Types of polymerization Copolymers, vulcanization, PVC, polyurethane, PAN, PET, polyamides Polyethylene, polypropylene, Resins (phenol-formaldehyde), polymethylmethacrylate, Inductive effect Electromeric effect Resonance Hyperconjugation Types of fission Reactive intermediates Carbonium ion Carbanions Free radicals Types of organic reactions Aliphatic nucleophilic substitution-SN1 and SN2, stereochemistry Electrophilic substitution with energy profile- Halogenation Nitration, sulphonation Friedel craft reaction (comparison also) Addition reactions electrophilic and nucleophilic Elimination- E1 and E2 Elimination vs. substitution Baeyer Villiger oxidation Pinacol- pinacolone rearrangement

1-7,10

3-7

3-7,11

8,9,13,14

33

34 VII CHEMICAL KINETICS 35

36 37 38 39 VIII NANOCHEMISTRY 40 Total Sessions = 40 One Session = 1 Hrs Suggested references: BOOKS: S.No. Title 1 Principles of Physical Chemistry

Rate of reaction and rate constant Factors affecting rate of a reaction Order and molecularity of a reaction Rate expression for first order, second order and third order reaction Methods of determining order of a 1-7, 10 reaction Steady state approximation Concept of activation energy and energy barrier Limdemann theory of unimolecular reaction Kinetics of complex reactions Introduction Methods of preparation 12 Application areas

2 3 4 5 6 7 8 9 10. 11.

Essentials of Physical Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry A Text Book of Organic Chemistry Organic chemistry Physical Chemistry Vol I, III & IV Polymer Chemistry

Author B.R .Puri, L.R. Sharma and M.S. Pathania B.S. Bahl, G.D. Tuli and Arun Bahl Jain & Jain Gurtu and Singhal Shashi Chawla

Publisher Vishal Publishing Co.

S. Chand & Co. Ltd. Dhanpat Rai Pragati Prakashan Dhanpat Rai & Company Katson Cengage Learning

Sunita Rattan Mani, Mishra & Singhal Arun Bahl & B.S. Bahl S. Chand & Co. Ltd. Morrison & Boyd Pearson Education K.L.Kapoor MacMillon Gwariker, Viswanathan & Sreedhar Sulbha K. Kulkarni New Age International Ltd. Capital

12.

Nanotechnology: Principles and Practices

13. 14.

Reaction Mechanism Pharmaceutical Chemistry- II

O.P.Agarwal Singhal & Singhal

Dhanpat Rai Pragati

Evaluation Scheme Component Internal Assesment Activity Class test I Class test II Assignment I Assignment II Assignment III Class Discipline Weightage(%) 5 5 5 5 5 5 20 50

Mid term exam End-term exam