Circus Charlie: Charles Law!

A Strategic Intervention Material in Chemistry

Presented by:
DON KING EVANGELISTA CHRISTOPHER LOUIS ORQUIZA

TABLE OF CONTENTS
I. Cover page II. Table of Contents III. Guide Card IV. Introduction V. Activity Card1 VI. Activity Card 2 VII. Assessment Card VIII. Enrichment Card IX. Answer Card 1 X. Answer Card 2 XI. Reference Card

GUIDE CARD

Understanding the different concepts governing the behavior of gasses (i.e. Ideal Gas) has always been focused by chemistry as it plays a very important role in our society, in the industry and in the different fields of our lives. In this Strategic Intervention Material, the student is subjected to a deeper understanding of Charles Law. After completing this SIM the learner is expected to: State and Define the Charles Law. Recognize the key concepts regarding the behavior of ideal gasses at constant pressure. Identify the applicability and limitations of Charles Law and its association with other physical concepts (e.g. Ideal Gas Law, Kinetic Theory & Absolute Zero). Solve practical problems involving Charles Law.

Now you are ready to learn! Let us have the basics of Charles Law!

INTRODUCTION
Charles' law (also known as the law of volumes) is an experimental gas law which describes how gases tend to expand when heated. It was first published by French natural philosopher Joseph Louis Gay-Lussac in 1802, although he credited the discovery to unpublished work from the 1780s by Jacques Charles. The law was independently discovered by British natural philosopher John Dalton by 1801, although Dalton's description was less thorough than GayLussac's.[2] The basic principles had already been described a century earlier by Guillaume Amontons. Whatever the priority of the discovery, Gay-Lussac was the first to demonstrate that the law applied generally to all gases, and also to the vapours of volatile liquids if the temperature was more than a few degrees above the boiling point. His statement of the law can be expressed mathematically as: where V100 is the volume occupied by a given sample of gas at 100 C; V0 is the volume occupied by the same sample of gas at 0 C; and k is a constant which is the same for all gases at constant pressure. Gay-Lussac's value for k was 1 2.6666, remarkably close to the present-day value of 12.7315. A modern statement of Charles's law is: At constant pressure, the volume of a given mass of an ideal gas increases or decreases by the same factor as its temperature on the absolute temperature scale (i.e. the gas expands as the temperature increases). which can be written as: where V is the volume of the gas; and T is the absolute temperature. The law can also be usefully expressed as follows:

The equation shows that, as absolute temperature increases, the volume of the gas also increases in proportion.

ACTIVITY CARD
Activity 1 Read and analyze each item. Write your answers on the corresponding boxes. Complete the Cipher Code by filling in the number for the corresponding English Alphabet Letter. Decode the mystery phrase.

Silly CIPHER
1.
6 5 24 17 17 16 5 24

2.
3 19 8 16 20 24

At constant (1)_______, the (2)______ of a given mass of an ideal (3)_____ increases or decreases by the same factor as its temperature on the absolute temperature scale(i.e. the gas expands as the temperature increases). So at constant pressure, if the temperature (K) is doubled, the volume of gas is also (4)_______. A hypothetical gas which obeys Charles' Law at all temperatures and pressures is called an (5)_____ gas.

3
23 26 17

4.
12 19 16 13 8 24 12

5.
22 12 24 26 8

CIPHER CODE
A B C D E = = = = = 25 F G H I J = = = = = 11 10 9 K L M N O = = = = = 21 P Q R S T = = = = = 18 U V W X Y = = = = = Z 15 2 14 = 1

Decode me! C 25 K 21 H 10 26 5 8 24 17 N W N 7 19 15 7 26 17 W 8 26 15 T H 4 10 24

22 17 L A 8 26 15

26

8 19

17 F 11

19

3 19 8 16 20 24 17

The Cipher Text says that ____________________________________.

ACTIVITY CARD
Activity 2 In the following items, assume that the gas is hold at constant pressure.

CROSS NUMBER
A B C E F I J L M K D G H

Down A. V1=20L, T1=10C, V2=__L, T2=52C B. The volume of a gas at a certain temperature is 224L. If a drop of 12C will reduce the volume by 24L, what is the original temperature? D. V1=____mL, T1=10C, V2=70L, T2=20C E. Find the increase in temperature of a gas whose original volume and temperature is 150L and 100C respectively, if the new volume is equal to 412.5L? F. If after the temperature is tripled the new volume of a gas is 1107L, find the original volume. G. V1=46mL, T1=C, V2=____mL, T2=9C H. V1=___mL, T1=10C, V2=10mL, T2=C L. 147 An ideal gas has a volume of 100L under the temperature of 100C. If the temperature grows by 47C, what is the new volume?

Across A. V1=74mL, T1=____C, V2=200mL, T2=300C C. The volume of a given mass of gas, at 288K is 400 ml. At what temperature, will it occupy a volume of 600 ml? I. What is the new volume of a gas after the temperature is tripled if the original volume is 21667mL? J. The temperature is reduced by 2/3. If the original volume is 1737mL, what is the new volume? K. The temperature is squared. If the original volume is 20, find the new volume. L. The volume of a gas is 9L under a temperature of 90C, if after applying heat the volume changes to 10.6L, find the new temperature? N. V1=1080mL, T1=300C, V2=__mL, T2=200C

M.V1=600L, T1=300C, V2=__L, T2=315C

ASSESSMENT CARD
PROBLEM SOLVING

Activity 1 Read and analyze each Problem. Show your solution.

1. A sample of gas at 101.3kPa had a volume of 1.2L at 100oC.

What would its volume be at 0oC at the same pressure? Vi = 1.2L Vf = ? Ti = 100oC = 100 + 273 = 373K Tf = 0oC = 0 + 273 =273K

2. A balloon had a volume of 75L at 25oC. To what does the temperature need to raised in order for the balloon to have a volume of 100L at the same pressure? Vi = 75L Vf = 100L Ti = 25oC = 25 + 273 = 298K Tf = ? (K)

ENRICHMENT CARD
Charles Law and its effect on Real Gasses
A Real Gas is one which approaches Charles' Law as the temperature is raised or the pressure lowered. As a Real Gas is cooled at constant pressure from a point well above its condensation point, its volume begins to increase linearly. As the temperature approaches the gases condensation point, the line begins to curve (usually downward) so there is a marked deviation from Ideal Gas behaviour close to the condensation point. Once the gas condenses to a liquid it is no longer a gas and so does not obey Charles' Law at all. Absolute zero (0K, -273oC approximately) is the temperature at which the volume of a gas would become zero if it did not condense and if it behaved ideally down to that temperature.

ANSWER CARD
Activity 1
1.
P R E S S U R E 6 5 24 17 17 16 5 24

2.
V O L 3 19 8 U M E 16 20 24

At constant (1)_______, the (2)______ of a given mass of an ideal (3)_____ increases or decreases by the same factor as its temperature on the absolute temperature scale(i.e. the gas expands as the temperature increases). So at constant pressure, if the temperature (K) is doubled, the volume of gas is also (4)_______. A hypothetical gas which obeys Charles' Law at all temperatures and pressures is called an (5)_____ gas.

3
G A S 23 26 17

4.
D O U B L E D 12 19 16 13 8 24 12

5.
I D E A L 22 12 24 26 8

The Cipher Text states that Charles Law is also known as the Law of Volumes. Activity 2
A B

1 0
C D

1 1

4
E F

3 5

2
G H

1
I

3 6 7 9
L

4 0
K M

1 0 0 0

7
J

0 0

1 4

1 4
N

6 3

ANSWER CARD
Assessment 1
a. A sample of gas at 101.3kPa had a volume of 1.2L at 100oC. What would its volume be at 0oC at the same pressure? Vi = 1.2L Ti = 100oC = 100 + 273 = 373K =273K 1.2/373 =
V f/273 V f/273

Vf = ? Tf = 0oC = 0 + 273

3.22 x 10-3 =

Vf = 3.22 x 10-3 x 273 = 0.88L (880mL) b. A balloon had a volume of 75L at 25 oC. To what does the temperature need to raised in order for the balloon to have a volume of 100L at the same pressure? Vi = 75L Ti = 25oC = 25 + 273 = 298K
V i/Ti

Vf = 100L Tf = ? (K)

f/Tf

75/298 = 100/Tf 0.2517 = 100/Tf Tf = 100/0.2517 = 397K (397-273 = 124oC)

REFERENCE CARD
1. Gay-Lussac, J. L. (L'An X 1802), "Recherches sur la dilatation des gaz et des vapeurs", Annales de chimie XLIII: 137. English translation. 2. http://www.chemistryexplained.com/Fe-Ge/Gay-Lussac-JosephLouis.html 3. Fullick, P. (1994), ISBN 0435570781. Physics, Heinemann, pp. 14142,

4. Clapeyron, E. (1834), "Mmoire sur la puissance motrice de la chaleur", Journal de l'cole Polytechnique XIV: 15390. Facsimile at the Bibliothque nationale de France (pp. 15390). 5. Thomson, William (1848), "On an Absolute Thermometric Scale founded on Carnot's Theory of the Motive Power of Heat, and calculated from Regnault's Observations", Philosophical Magazine: 1006, http://zapatopi.net/kelvin/papers/on_an_absolute_thermomet ric_scale.html. 6. Thomson, William (1852), "On the Dynamical Theory of Heat, with numerical results deduced from Mr Joule's equivalent of a Thermal Unit, and M. Regnault's Observations on Steam", Philosophical Magazine 4. 7. http://www.ausetute.com.au/charslaw.html