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AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

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1




ANSWERS, HINTS & SOLUTIONS
CRT(Set-V)
(Paper 2)



ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1. A A D
2. A A B
3. D D B
4. D B A
5. C A A
6. B B B
7. C B C
8. C B D
9. A A B
10. C B C
11. A A C
12. D A D
13.
B

B B
14. C

A C
15. A, D B, D A, B, C, D
16. B, C A, C, D B, C, D
17. A, B, C A, B, D A, B, D
18. B, C A, B A, B, C
19. B, D A, B, C A, B
20. A, B A, B, C B, D
A
L
L

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N
D
I
A

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AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
P Ph hy ys si ic cs s PART I


3. ( )
A o
P P g a h = + +


B o
P P =

( )
o o
2T
P g a h P
d
2
+ + = +
A
B
h


5.
o
v 2ga =


2 2
a h

By conserving angular momentum about vertical axis OP
( )
2 2
o
mv a mv a h 1 =
a
h

By conserving mechanical energy
( )
2 2
0
1 1
mv mv mgh ........... 2
2 2
= +
From equation (1) and (2)
( )
a 5 1
h
2

=
11. when it crosses mean position then it is having velocity = A

( ) d d D d D A
dt dt d d dt d
| |
= = =
|
\ .


K mg m
g
d m k d K

= =


12. The x-coordinate of the 2
nd
maxima on the plate are =
2

y
d

13. (Amp.)
1
( ) 3.14ms

=
and
2 =
where
5Hz =


14. Equation of standing wave is

| | (0.1 ) sin sin(10 )
2
y m x t


( | |
=
| (
\ .

Putting
0.5 x m =
and
0.15sec t =
we get
1
10 2
y m =
.

AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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C Ch he em mi is st tr ry y PART II


SECTION A

1.
2
2
2
H O
H
H O
H O
P.P.
R 100
V.P.
W
P.P. V RT
m
W 821 gm=0.82 kg
=
=
=



4.
C H
2
C
H
2
C
O
C
AlCl
3
O
C
H
2
C
C H
2
C O
O AlCl
3
C CH
2
O
C
OH
CH
2
COCH
2
COCH
3
tauto

EAS
+
+
_
_

7. Moles of FeS
2
=
2
15

Moles of S =
4
15

Moles of H
2
SO
4
=
4
15

Required moles of NaOH =
8
15


8. 3 = 13.6 + E
photon

E
photon
= 16.6 eV
Energy of electron in first excited state =
2
13.6
2
= 3.4 eV
When photon striked this electron, its energy becomes 3.4 + 16.6
So, K.E. of electron = 13.2 eV

11. Follow structure.

12. Since (I) contains 8 and (II) has 7.

13.
( ) ( )
( ) ( ) ( )
3 3 2
2 2
3 3 2
2 2 2
Ca HCO Ca OH 2CaCO H O
Mg HCO 2Ca OH Mg OH CaCO H O
+ +
+ + +


AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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14.
( )
( ) ( )
3 3 2 2
2
3 2
2 2
Ca HCO CaCO H O CO
Mg HCO Mg OH 2CO

+ +
+


17. Borazine has same structure as benzene.
Boron nitride has graphite like structure.

18.
ether
2 2 7 2 4 2 2 2 4 5 2
K Cr O H SO 4H O K SO 2CrO 5H O + + + +

3
5 2
CrO Cr O
+
+

19. ( )
2NaOH
2 2 2 2
2
ZnCl 2NaOH Zn OH Na ZnO 2H O + +

2 2 2
Na ZnO H S ZnS 2NaOH + +
( )
2 2 3 3 3 2
2
Na ZnO 4CH COOH CH COO Zn 2CH COONa 2H O + + +
( ) ( ) ( )
3 4 2 3
2 6 6
2 CH COO Zn K Fe CN Zn Fe CN 4CH COOK ( ( + +



( ) ( ) ( )
2 4 3 2
6 6 6
2
3Zn Fe CN K Fe CN 2Zn K Fe CN white ( ( ( +


AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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5
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. Image of the centre C
2
(1, 3) in the line
3x + 4y 16 = 0 is P(7, 5).
Now for C
1
C
2
+ C
2
C
3
+ C
3
C
1
to be
minimum C
1
, C
3
and P should be on
same line so C
3
= (0, 4)
distance between C
3
and C
1

= 50 = 5 2
radius of C
1
= 3 2
C
1

(7, 3)
C
2

(1, 3)
C
3
P
3x + 4y 16 = 0
(7, 5)
so radius of C
3
= 2 2
Equation of C
3
(x 0)
2
+ (y 4)
2
= 8
x
2
+ y
2
8y + 8 = 0, a = 0, b = 8, c = 8
2. Let the number be b d, b, b + d
3b = 15
b = 5
a < 5, b = 5, c > 5
x(2 cos + 3 sin ) y(3 cos + sin ) + 7(cos sin ) = 0
cos (2x 3y + 7) + sin (3x y 7) = 0
So family of lines passing through the point of intersection of
lines 2x 3y + 7 = 0 and
3x y 7 = 0 which is (4, 5)
So at a distance 5 one line so q = 1
(4, 5)
D = 5
(1, 1)
at a distance a < 5 two lines p = 2
at a distance c > 5 no line r = 0
3. We know
x
x 0
lim x 1

=

( )
x
x 0
lim x 1 0

=

( )
( ) ( )
x
x 1 x
2
x 0
x
2
e x
lim
x 1

=
( )
( ) ( )
( )
( ) ( )
2 3
x x
x x
2
x 0
2
x
x 1 x 1
1 x 1 ..... 1 x 1
2! 3!
lim
x 1

| |

|
+ + + +
|
\ .


=
( ) ( )
( ) ( )
2 3
x x
2 2
x 0
x x
x 1 x 1
.....
2! 3!
lim
x 1 x 1


+ +
+
=
1 1 1
2 4 8
=

4. ( )
4
8 4
det A adj B 2 3 ( =



( )
4
2
8 4
A B 2 3 =

2
2
A B 2 3 =
A x y z = + +
B =pqr
(x + y + z)(pqr)
2
= 2
2
3
So either x + y + z = 3 and (pqr) = 2 or x + y + z = 12 and pqr = 1
=
5
C
2
3 +
14
C
2
1 = 30 + 91 = 121


AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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5. k
1
, k
2
, k
3
, k
4
{1, 2, 3, 4, 5, 6} and they should be of the form of 4k
1
, 4k + 1, 4k + 2 and 4k + 3
So required probability =
4
4! 1 2 2 1 2
27
6

=

6.
2 2 2 2
3 3 1 1
x y 1 x y 1
x y 1 (n 1) x y 1 0
x y 1 x y 1
+ =

( ) ( ) ( )
2 2 2 2
3 3 1 1
x y 1 x y 1
x y 1 x y 1 0
x y 1 n 1 x n 1 y n 1
+ =



( ) ( )
2 2
1 3 1 3
x y 1
x y 1 0
n 1 x x n 1 y y n
=
+ +


( ) ( )
2 2
1 3 1 3
x y 1
x y 1 0
n 1 x x n 1 y y
1
n n
=
+ +

This is line passing through B and dividing AC in a ratio of 1 : (n 1)

7. Given f(3) = 2
f(3) = 0

n 0
f(3 2h) f(3)
2 lim 5
2h
+
=
2f(3) = 5
( )
5
f ' 3
2
=

( ) ( )
4
2
I II
3
x 4 f "' x dx 9 =



( ) ( ) ( ) ( )
4
4
2
3
I II
3
x 4 f " x 2 x 4 f " x dx 9 =



( )
4
4
3
3
2 x 4 f '(x) 1.f '(x)dx 9
(
( =
(



( ) ( ) ( ) | | 2 f ' 3 f 4 f 3 9 + =
2f(3) + 2f(4) 2f(3) = 9
5 + 2f(4) 4 = 9
2f(4) = 18
f(4) = 9







AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
7
8.
( ) ( )
/ 2
2013 2013
L
0
I sinx cosx dx

=

=
( ) ( )
/ 2
2013
2013
0
1
sin 2x dx
2

=
( )
2013
2014
0
2 sinx dx



( )
/ 2
2013
2013
L
0
I 2 sinx dx

=



( )
/ 2
2013
2013
L
0
I 2 cosx dx

=



( ) ( ) ( )
/ 2
2013 2013
2013
L
0
2I 2 sinx cosx dx

= +



2014
L R
I 2 I

=

1007
L R
I 4 I

=
k = 1007
9. Equation of BC 7x y = 25
Equation of line perpendicular to BC is
x + 7y =
Now for the third reflection at D.
Equation of incident ray is x + 7y = 25
`
A
D
B
C

10. Equation of circle is x
2
+ y
2
=
25
2

Total 22 integral points lies inside the circle.
11. for P(x) to lie below and above the xaxis D > 0
4 4(a
2
5a + 5) > 0
a
2
5a + 4 < 0
(a 4) (a 1) < 0
1 < a < 4 so a {2, 3}
for Q(x) to lie completely above the xaxis D < 0
(b 3)
2
4b < 0
b
2
10b + 9 < 0 (b 9)(b 1) < 0 1 < b < 9
b {2, 3, .. 8}







Since a {2, 3}
b {2, 3, 4, 5, 6, 7, 8}
total 14 integral ordered pairs of (a, b) are possible.

12. Equation of the circle with ends of diameter as (x
1
, y
1
) and (x
2
, y
2
) is
x
2
+ y
2
2x (b 3)y + a
2
5a + 5 + b = 0
Centre lies on the line 2x + y = 0

b 3
2 0
2
| |
+ =
|
\ .

4 + b 3 = 0
b = 1

2 2
r g f c 1 = + = =
( )
2
1 4 a 5a 4 1 + + = =
2
a 5a 1 1 + + =
a
2
+ 5a + 1 = 1
a
2
5a = 0
a = 0, 5
a
max
= 5

AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
8
1314. Given lines are

1
x 6 y 7 z 4
L :
3 1 1

= = =


and
2
x y 9 z 2
L :
3 2 4
+
= = =


So P (3 + 6, + 7, + 4)
and Q (3, 2 9, 4 + 2)
So drs of PQ are (3 3 6, 2 + 16, 4 2)
Since P and Q are nearest to each other means they lie on the line along the shortest distance
between the skew lines.
3(3 3 6) 1(2 + 16) + 1(4 2) = 0
7 + 11 + 4 = 0 .. (1)
and 3(3 3 6) + 2(2 + 16) + 4(4 2) = 0
29 + 7 22 = 0 .. (2)
on solving (1) and (2) = 1 and = 1
So P (3, 8, 3) and Q (3, 7, 6)
Equation of the plane OPQ is
x y z
3 8 3 0
3 7 6
=


23x 9y + z = 0
Volume of the parallelopiped formed by OP
JJJG
, OQ
JJJJG
and OR
JJJG
is
= OP OQ OR
(

=
3 8 3
3 7 6 96
1 1 0
=

unit
3
.

15. Let 768 32cos =
16 3 32cos =

3
cos
2
=
6

=
So 4 8 32 32cos
6

+ + = 4 8 8cos
12

+ = 4 4sin
24

+ =
11
4 4cos
24

+
=
11
4 1 cos
24
| |
+
|
\ .
=
2
11
4 2cos
48

=
11
2 2 cos
48


So a = 2, b = 11, c = 48
(a + b + c) = 61

16. N
2
ends in 4 if N ends in 2 or 8
2 1
P(B)
10 5
= =
N
4
ends in 1 if N ends in 1, 3, 7, 9
4 2
P(C)
10 5
= =
N
2
can never end with 3 or 7

17. Equation of the required plane is ( ) ( )
1 1 2 2
r n q r n q 0 + = ( ) ( )
1 2 1 2
r n n q q + = +
Now since is perpendicular to
3 4
n n
( ) ( )
1 2 3 4
n n n n 0 + =
AITS-CRT(Set-V)-Paper-2-PCM(S)-JEE(Advance)/13

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website: www.fiitjee.com
9

| |
| |
1 3 4
2 3 4
n n n
n n n
=
So independent on q
3
and q
4
only

18. Given
2 2
dy 2x 3x
y
dx
1 x 1 x
| | | |
+ =
| |
\ + . \ + .

I.F. =
( )
2
ln 1 x
e
+

So general solution is
( ) ( )
2 2
2
3x
y 1 x 1 x dx c
1 x
| |
+ = + +
|
\ + .



( )
2
2
3x
y 1 x c
2
+ = +
at x = 0, y = 2, c = 2

( )
2
2
3x
y 1 x 2
2
+ = +

( )
2
2
3x 4
y
2 x 1
+
=
+
=
( )
2
3 1
2
2 x 1
+
+

Range of f(x) =
3
, 2
2
| (
(
\


19. We have 2xy dy = (x
2
+ y
2
+ 1)dx

2
2 2
2xydy y dx 1
1 dx
x x
| |
= +
|
\ .


2
y 1
d d x
x x
| |
| |
=
| |
\ . \ .


2
y 1
x c
x x
= +
y(1) = 0 c = 0
y
2
= x
2
1
y() = 3

2
1 3 =

2
4 =
= 2

20. z = x + iy
(x 2)
2
= (x 7)
2
+ (y + 2)
2

(x 2)
2
(x 7)
2
= (y + 2)
2

(y + 2)
2
= 5(2x 9)
(y + 2)
2
= 10
9
x
2
| |

|
\ .

y
2
= 49x a =
5
2


min
PQ L(LR) 10 = =
(2,)
x = 2
P
Q
x
Directrix

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