Gas Condensate
PE 543
Spring 2013
HW # 1
Deadline Due To March,25,2013
Group No.1
Muhommed AlGhanemi
Submitted By:
Nasser Hadi AlAzmi
Supervised By:
Dr. Osama AlOmair
Problem# 1:
Pure Butane is contained in a closed vessel at 120 F. Both gas and Liguid phases are
present. Calculate the density of the gas and Liquid phases, by using:

P
T
Input Data
Psia
14.7
F
120
Bure Butane
Solution:
1. Van Der Waals EOS.
Where:
R = 10.73
2. RedlichKwong EOS.
Where:
R = 10.73
Pv
Output Data
Van Der Waals EOS
70(using cox
Psia
chart)
Pv
Tc
305.62
Tc
305.62
Pc
a
b
A
B
Psia
Fraction
Fraction
Fraction
Fraction
550.8
51691.11
1.864357
0.093424
0.02097
Pc
a
b
A
B
Psia
Fraction
Fraction
Fraction
Fraction
550.8
1449253.401
1.292223111
0.108760937
0.014534759
Zv
Fraction
0.9219
Zv
Fraction
0.897192854
ZL
Mw
Fraction
IB/Ibmole
0.0314
58.123
ZL
Mw
Fraction
IB/Ibmole
0.0217
58.123
IB/ft3
0.709144
IB/ft3
0.728672771
IB/ft3
20.82038
IB/ft3
30.12718906
So Van Der Waals and Redlich Kwong EOSs have the same value of gas density
but different liquid density.
Problem #2:
Calculate the mixture Density of eight gascondensate samples (see attached table).
The composition and other properties are mentioned in the table, by using:

Mixture
Aa
Bb
Cc
Dd
Ee
Ff
Gg
Hh
CO2
0.6954
0.6
0.44
0.61
2.44
2.26
0.3
N2
5.3159
5.56
5.47
0.46
0.08
5.67
0.72
Ch4
86.0031
85.19
85.48
91.35
68.64
82.1
45.74
79.17
C2H6
3.4912
3.57
3.5
4.03
13.9
5.78
11.47
7.48
C3H8
1.4032
1.54
1.46
1.53
6.89
2.87
7.59
3.29
iC4H10
0.3573
0.37
0.37
0.66
0.56
0.52
nC4H10
0.5237
0.57
0.58
0.82
2.66
1.23
6.38
1.25
iC5H12
0.2812
0.27
0.28
0.62
0.52
0.36
nC5H12
0.1842
0.23
0.23
0.34
0.94
0.6
4.31
0.55
nC6H14
0.4004
0.39
1.14
0.72
5.92
0.62
nC7H16
0.3272
nC8H18
0.2877
0.71
nC9H20
0.1577
0.47
nC10H22
0.1478
0.31
nC11H24
C7+
0.1048

2.1
2.14
1.54
3.48
3.1
10.66
C12+
0.31
2.25
Type Of
Sampel
Description
+
SG(60/60)
MW
Tb(K)
0.8314
213
554.7
SAI mixture,C12
SAI mixture,C7+
0.7734
129.81
428.3
SAI mixture,C7
0.7861
143.6
451.74
[11]C7+
0.7961
138.78
444.7
[12]C7+
0.7763
152.3
461.25
[13]C7+
0.774
132
430.96
[14]C7+
0.8044
148
462.89
[1]C7+
0.8438
231
579.6
Solution:
In this problem, we will make two different solutions. The first one by assuming the
Binary Interaction equal zero and the other one is by taking account the Binary
Interaction. These two solutions will be solved by Using SRK and PR EOSs under
the same Pressure and Temperature ( P = 3500 psia, T = 180 F) in order to compare
between these two methods. Then, the problem will be solved again but this time by
taking account the Binary Interaction under pressure and temperature of 4200 psia
and 220 F respectively.
SRK EOS:
(
))
R = 10.73
For gases:
(
PR EOS:
(
))
R = 10.73
For gases:
(
Notes:
Properties
Tc
Pc
K
w
C7+
By Chart 3.10, McCain Book
By Chart 3.10, McCain Book
Wilsons Correlation
Using Edmisters Correlation
Where:
Edmisters Correlation:
(
C12+
By RiaziDaubert Correlation
By RiaziDaubert Correlation
Wilsons Correlation
Using Edmisters Correlation
Wilsons Correlation:
(
Where:
)(
Solution #1:
Assume Binary Interaction Equal Zero Under ( P = 3500 Psi, T = 180 F).

SRK EOS.
Component
A
B
C
D
E
F
G
H
Liquid Density(ibf/ft3)
33.095114
32.28809822
32.31289
31.31722
26.69003
29.71608
30.12558
36.91125812
10.151163
10.12674986
10.06368
9.786115
10.8329
10.4608
11.10716
10.04717025
Liquid Density(ibf/ft3)
36.914214
36.06045214
36.09999
34.12399
29.55941
33.07055
33.53245
41.2136076
10.68062
10.65026324
10.17652
9.95524
11.43184
11.02048
11.69047
10.57471499
PR EOS.
Component
A
B
C
D
E
F
G
H
SRK and PR EOSs have approximately the same values of gas density but different
values of liquid density.
Solution #2:
Part A: Taking account Binary Interaction under ( P = 3500 Psia, T = 180 F).

SRK EOS.
Component
A
B
C
D
E
F
G
H
Liquid Density(ibf/ft3)
32.990943
31.74563219
32.28835
31.28223
26.62511
29.64107
30.04791
36.82214424
10.123429
9.696420363
10.04033
9.776373
10.80652
10.41603
11.05026
10.03032702
Liquid Density(ibf/ft3)
36.814972
35.35988166
36.07308
34.07195
29.47839
32.99596
33.46749
41.11310895
10.648443
10.14136278
10.55821
10.99952
11.40105
10.96841
11.62361
10.55523279
PR EOS.
Component
A
B
C
D
E
F
G
H
SRK and PR EOSs have approximately the same values of gas density but different
values of liquid density.
Part B: Taking account Binary Interaction under ( P = 4200 Psia, T = 220 F).

SRK EOS.
Component
A
B
C
D
E
F
G
H
Liquid Density(ibf/ft3)
33.237415
31.88581055
32.37103
31.4352
26.71882
29.71631
29.86112
36.95653523
10.868891
10.46128983
10.77115
10.4676
11.66259
11.19791
11.99521
10.79549262
Liquid Density(ibf/ft3)
37.045763
35.43966615
36.0628
34.22984
29.61331
33.01777
33.20437
41.16342617
11.482186
10.98042483
11.35427
10.71678
12.33213
11.90174
12.65538
11.39356412
PR EOS.
Component
A
B
C
D
E
F
G
H
SRK and PR EOSs have approximately the same values of gas density but different
values of liquid density.
Notes: All Work Done By Microsoft Excel and it is Attached By CDs Attachment.