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Note: For the following problems the variable kelvin is used for the SI
unit of absolute temperature so as not to conflict with the variable K
used for the equilibrium constant
13.4
i = 1 1 + 1 + 1 = 0
n0 = 1 + 1 = 2
By Eq. (13.5).
yH = yCO =
2
1
2
yH2O = yCO =
2 2
2
2
G ( ) :=
e := 0.5
Guess:
d
Given
d e
( )
G e = 0
( )
J
mol
e := Find e
e = 0.45308
G ( )
2.084
10
2.086
2.088
0.2
0.3
0.4
0.5
483
0.6
13.5
i = 1 1 + 1 + 1 = 0
n0 = 1 + 1 = 2
By Eq. (13.5).
yH = yCO =
2
1
2
yH2O = yCO =
+ 2 ln
+ R T 2
ln
2 2
2
2
G ( ) :=
e := 0.5
Guess:
d
Given
d e
( )
G e = 0
J
mol
( )
e := Find e
e = 0.502
Ans.
2.103
G ( )
2.104
10
2.105
2.106
2.107
0.3
0.35
0.4
0.45
0.5
484
0.55
0.6
0.65
(b)
=
i = 1 1 + 1 + 1 = 0
n0 = 1 + 1 = 2
By Eq. (13.5),
yH = yCO =
2
2
1
2
yH2O = yCO =
+ 2 ln
+ R T 2
ln
2 2
2
2
G ( ) :=
e := 0.1
Guess:
d
Given
d e
( )
G e = 0
J
mol
( )
e = 0.53988
0.55
0.6
e := Find e
Ans.
2.122
2.123
G ( )
5 2.124
10
2.125
2.126
2.127
0.35
0.4
0.45
0.5
485
0.65
0.7
(c)
=
i = 1 1 + 1 + 1 = 0
n0 = 1 + 1 = 2
By Eq, (13.5),
yH = yCO =
2
1
2
yH2O = yCO =
2 2
2
2
G ( ) :=
e := 0.6
Guess:
d
Given
d e
( )
G e = 0
( )
J
mol
e := Find e
e = 0.57088
Ans.
2.142
G ( )
5
2.144
10
2.146
2.148
0.35
0.4
0.45
0.5
0.55
486
0.6
0.65
0.7
13.6
i = 1 1 + 1 + 1 = 0
n0 = 1 + 1 = 2
By Eq, (13.5),
yH = yCO =
2
1
2
yH2O = yCO =
With data from Example 13.13, the following vectors represent values for
Parts (a) through (d):
1000
1100
T :=
kelvin
1200
1300
3130
150 J
G :=
3190 mol
6170
G
2 2
=
= K = exp
1 1 ( 1 ) 2
R T
2 2
G
:= exp
R T
:=
0.4531
0.5021
=
0.5399
0.5709
1+
Ans.
n0 = 6
H298 := 114408
J
mol
T := 773.15 kelvin
G298 := 75948
487
J
mol
T0 := 298.15 kelvin
The following vectors represent the species of the reaction in the order in
which they appear:
1
:=
2
3.156
3.639
A :=
3.470
4.442
end := rows ( A)
A :=
0.623
0.506 3
B :=
10
D :=
1.450
0.089
0.151
0.227 105
0.121
0.344
i := 1 .. end
( i A i)
B :=
( i B i)
D :=
i
5
A = 0.439
( i D i)
B = 8 10
C := 0
D = 8.23 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
4 J
G = 1.267 10
mol
G
R T
K := exp
K = 7.18041
By Eq. (13.5)
yO2 =
yHCl =
yH2O =
5 4
6
2
6
:= 0.5
yHCl :=
2 6 = 2 K
5 4 1
5 4
6
yHCl = 0.3508
yO2 :=
yO2 = 0.0397
2
6
(guess)
Given
yCl2 =
1
6
:= Find ( )
yH2O :=
yH2O = 0.3048
488
2
6
= 0.793
yCl2 :=
yCl2 = 0.3048
2
6
Ans.
= 0
n0 = 2
This is the reaction of Pb. 4.21(x). From the answers for Pbs. 4.21(x),
4.22(x), and 13.7(x), find the following values:
H298 := 42720
J
mol
A := 0.060
B := 0.173 10
G298 := 39430
3
T := 923.15 kelvin
J
mol
5
C := 0
D := 0.191 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 3.242 10
G
R T
4 J
K := exp
mol
K = 0.01464
By Eq. (13.5),
yN2 =
1
2
yC2H4 =
By Eq. (13.28),
1
2
:= 0.5
2
yN2 :=
1
2
yN2 = 0.4715
yC2H4 :=
2e
=
2
(guess)
2 = K
Given
yHCN =
:= Find ( )
1
2
yC2H4 = 0.4715
= 0.057
yHCN :=
yHCN = 0.057 Ans.
489
13.13
= 1
n0 = 2.5
This is the reaction of Pb. 4.21(r). From the answers for Pbs. 4.21(r),
4.22(r), and 13.7(r), find the following values:
J
mol
H298 := 68910
G298 := 39630
3
A := 1.424 B := 1.601 10
T := 623.15 kelvin
J
mol
C := 0.156 10
D := 0.083 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
3 J
G = 6.787 10
K := exp
mol
1
2.5
( 2.5 )
( 1 ) ( 1.5 )
yCH3CHO :=
yH2 =
:= 0.5
By Eq. (13.28),
Given
1
2.5
yCH3CHO = 0.108
2.5
yC2H5OH =
2.5
(guess)
= 3 K
yH2 :=
1.5
K = 3.7064
1.5
2.5
yH2 = 0.4053
:= Find ( )
yC2H5OH :=
= 0.818
2.5
( 2.5 )
( 1 ) ( 1.5 )
yCH3CHO :=
1
2.5
yCH3CHO = 0.1968
= 1 K
yH2 :=
1.5
2.5
yH2 = 0.4645
490
:= Find ( )
yC2H5OH :=
= 0.633
2.5
= 1
n0 = 2.5
This is the REVERSE reaction of Pb. 4.21(y). From the answers for Pbs.
4.21(y), 4.22(y), and 13.7(y) WITH OPPOSITE SIGNS, find the following
values:
H298 := 117440
J
mol
A := 4.175 B := 4.766 10
T := 923.15 kelvin
J
mol
G298 := 83010
C := 1.814 10
D := 0.083 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
3 J
G = 2.398 10
mol
By Eq. (13.5),
yH2 =
1.5
G
R T
K := exp
yC6H5C2H5 =
2.5
:= 0.5
( 2.5 )
( 1 ) ( 1.5 )
yC6H5CHCH2 :=
yC6H5CHCH2 =
By Eq. (13.28),
Given
1
2.5
yC6H5CHCH2 = 0.2794
1.5
2.5
yH2 = 0.5196
491
1
2.5
2.5
(guess)
= 1.0133 K
yH2 :=
K = 1.36672
:= Find ( )
yC6H5C2H5 :=
= 0.418
2.5
yC6H5C2H5 = 0.201
Ans.
13.15 Basis: 1 mole of gas entering, containing 0.15 mol SO2, 0.20 mol O2,
and 0.65 mol N2.
= 0.5
n0 = 1
By Eq. (13.5),
ySO2 =
0.15
0.20 0.5
yO2 =
1 0.5
ySO3 =
1 0.5
1 0.5
H298 := 98890
G298 := 70866
J
mol
The following vectors represent the species of the reaction in the order
in which they appear:
1
:= 0.5
1
5.699
A := 3.639
8.060
end := rows ( A)
A :=
0.801
3
B := 0.506 10
D :=
1.056
1.015
5
0.227 10
2.028
i := 1 .. end
( i A i)
B :=
( i B i)
D :=
i
6
A = 0.5415
B = 2 10
T := 753.15 kelvin
( i D i)
C := 0
D = 8.995 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
4 J
G = 2.804 10
By Eq. (13.28),
Given
mol
G
R T
K := exp
:= 0.1
( 1 0.5 )
(guess)
0.5
K = 88.03675
= K
:= Find ( )
= 0.1455
By Eq. (13.4),
nSO3 = = 0.1455
By Eq. (4.18),
H753 = 98353
13.16
J
mol
Q := H753
nC3H8 = 1
n0 nC3H8
n0
yC3H8 =
J
Ans.
mol
= 1
By Eq. (13.5),
Q = 14314
yC2H4 =
1+
1 ( 1 )
=
1
yCH4 =
1+
1+
J
mol
G298 := 42290
J
mol
The following vectors represent the species of the reaction in the order
in which they appear:
1
:= 1
1
1.213
A := 1.424
1.702
end := rows ( A)
A :=
8.824
6
4.392 10
2.164
i := 1 .. end
( i A i)
B :=
A = 1.913
28.785
3
B := 14.394 10
C :=
9.081
( i B i)
C :=
( i C i)
i
3
B = 5.31 10
T0 := 298.15 kelvin
493
C = 2.268 10
D := 0
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 2187.9
J
mol
G
R T
K := exp
:= 0.5
By Eq. (13.28),
Given
= 0.777
K = 1.52356
(guess)
( 1 + ) ( 1 )
:= Find ( )
= K
(b) := 0.85
K :=
G := R T ln ( K)
K = 2.604
( 1 + ) ( 1 )
G = 4972.3
J
mol
Ans.
By Eq. (13.5),
1
yH =
1.5 +
1.5 +
yC2H4 =
1.5 +
J
mol
G298 := 100315
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
494
1
:= 1
1
1.131
A := 3.249
1.424
19.225
3
B := 0.422 10
14.394
5.561
6
C := 0.0 10
4.392
0.0
5
D := 0.083 10
0.0
end := rows ( A)
A :=
i := 1 .. end
( i Ai)B := ( iBi)
i
C :=
D :=
i
3
( i D i)
i
A = 3.542 B = 4.409 10
T := 1100 kelvin
( i C i)
C = 1.169 10
D = 8.3 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
3 J
G = 5.429 10
By Eq. (13.28),
Given
K := exp
mol
:= 0.5
( 1.5 + ) ( 1 )
1
1+
yC2H6 = 0.0899
K = 1.81048
(guess)
:= Find ( )
= K
= 0.83505
nH2 = nC2H4 =
yH2 :=
1+
yC2H4 = 0.4551
495
yC2H4 :=
n= 1+
1+
yH2 = 0.4551
Ans.
= 1
(2)
(3)
y1 =
y2 = y3 =
1+x+
1+x+
= 0.10
J
mol
G298 := 79455
J
mol
1
:= 1
1
1.967
A := 2.734
3.249
31.630
3
B := 26.786 10
0.422
9.873
6
C := 8.882 10
0.0
0.0
5
D := 0.0 10
0.083
end := rows ( A)
A :=
i := 1 .. end
( i Ai)B := ( iBi)
i
A = 4.016
C :=
i
3
C = 9.91 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
496
D :=
( i D i)
i
B = 4.422 10
T := 950 kelvin
( i C i)
D = 8.3 10
G = 4.896 10
G
R T
3 J
K := exp
mol
K = 0.53802
( 0.1) ( 0.1) ( 1 + x + )
By Eq. (13.28),
1
Since
0.10 ( 1 + x + ) =
x :=
(a)
:=
1
0.10
y1 :=
13.19
6.5894
7.5894
yH2O = 0.7814
Ans.
ysteam = 0.8682
Ans.
y1 =
1
1 + x + 2
J
mol
= 2
n0 = 1 + x
y2 =
1 + x + 2
= 0.12
y3 = 2 y2 = 0.24
= 0.843
yH2O := 1 0.2 y1
1+x+
ysteam :=
K
K + 0.10
x = 6.5894
y1 = 0.0186
(b)
= K
G298 := 166365
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
1
:= 1
2
1.935
A := 2.734
3.249
36.915
3
B := 26.786 10
0.422
497
11.402
6
C := 8.882 10
0.0
end := rows ( A)
A :=
( i A i)
0.0
5
D := 0.0 10
0.083
i := 1 .. end
B :=
( i B i)
C :=
( i C i)
A = 7.297
( i D i)
i
3
B = 9.285 10
T := 925 kelvin
D :=
i
6
C = 2.52 10
D = 1.66 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 9.242 10
3 J
mol
G
R T
K := exp
K = 0.30066
( 0.12) ( 0.24) ( 1 + x + 2 )
2
By Eq. (13.28),
0.12 ( 1 + x + 2 ) =
Because
= K
K
:=
K + ( 0.24)
x :=
1 2
0.12
(a) y1 :=
1
1 + x + 2
y1 = 0.023
(b) ysteam :=
4.3151
5.3151
x = 4.3151
= 0.839
yH2O := 1 0.36 y1
yH2O = 0.617
Ans.
ysteam = 0.812
Ans.
498
13.20
= 1
n0 = 2
This is the reaction of Pb. 4.21(a) with all stoichiometric coefficients divided
by two. From the answers to Pbs. 4.21(a), 4.22(a), and 13.7(a) ALL
DIVIDED BY 2, find the following values:
J
mol
H298 := 46110
A := 2.9355
(a)
G298 := 16450
B := 2.0905 10
T := 300 kelvin
J
mol
C := 0
D := 0.3305 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 1.627 10
P := 1
K := exp
mol
K = 679.57
P0 := 1
yNH3 :=
(b) For
:=
2
3
2
yNH3 = 0.5
0.5
= 0.9664
yNH3 = 0.9349
Ans.
1 1
1
K :=
1.299
K = 6.1586
499
Find by trial the value of T for which this is correct. It turns out to be
T = 399.5 kelvin
Ans.
1 1
1
K :=
K = 0.06159
129.9
T := 583kelvin
P := 100bar
T
Tc1
Pc1 := 112.8bar
Tr1 = 1.437
Tc2 := 126.2kelvin
Tr2 :=
583
126.2
Pr1 :=
1 := 0.253
P
Pc1
Pc2 := 34.0bar
Tr2 = 4.62
Pr2 :=
Pr1 = 0.887
2 := 0.038
100
34.0
Pr2 = 2.941
For H2(3), estimate critical constants using Eqns. (3.58) and (3.59)
Tc3 :=
43.6
21.8
kelvin
1 +
T
2.016
kelvin
Pc3 :=
1+
20.5
44.2
Tc3 = 42.806 K
Tr3 :=
bar
T
Tc3
Tr3 = 13.62
T
2.016
kelvin
3 := 0
500
P
Pc3
Pr3 = 5.061
i := 1 .. 3
Therefore,
( i)
0.924
= 1.034
1.029
= 1.184
1 1
1
K :=
129.9
1.184
K = 0.07292
Ans.
Of course, the INITIAL assumption made for T was not so close to the
final T as is shown here, and several trials were in fact made, but not
shown here. The trials are made by simply changing numbers in the
given expressions, without reproducing them.
= 2
n0 = 3
H298 := 90135
J
mol
G298 := 24791
J
mol
B := 10.815 10
T0 := 298.15 kelvin
501
C := 3.45 10
D := 0.135 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 2.439 10
P := 1
K := exp
mol
K = 1.762 10
P0 := 1
By Eq. (13.5), with the species numbered in the order in which they appear
in the reaction,
y1 =
y2 =
3 2
( 3 2 )
Given
(b)
4 ( 1 )
3 2
(guess)
2
P
=
K
P0
:= Find ( )
= 0.9752
y3 = 0.9291 Ans.
3 2
y3 := 0.5
:=
y3 =
3 2
:= 0.8
By Eq. (13.28),
y3 :=
2 2
3 y3
= 0.75
2 y3 + 1
( 3 2 )
4 ( 1 )
K = 27
Find by trial the value of T for which this is correct. It turns out to be:
T = 364.47 kelvin Ans.
502
( 3 2 )
4 ( 1 )
100
K = 2.7 10
P := 100bar
Tr1 :=
For CH3OH(3):
Tr :=
T
Tc3
Pc1 := 34.99bar
P
Pc1
Pr1 = 2.858
Pc3 := 80.97bar
3 := 0.564
Tr1 = 3.973
Tc3 := 512.6kelvin
Tr = 1.03
Pr :=
1 := 0.048
Pr1 :=
P
Pc3
Pr = 1.235
3 := 0.6206 0.9763
3 = 0.612
i := 1 .. 3
:=
1.0
0.612
1
:= 2
1
( i)
1.032
= 1
0.612
= 0.5933
i
503
( 3 2 )
4 ( 1 )
100
0.593
K = 1.6011 10
J
mol
G298 := 130401
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
1
:= 1
1
i := 1 .. 3
12.572
A := 6.104
5.457
A :=
( i A i)
2.637
3
B := 0.443 10
1.045
B :=
A = 1.011
( i B i)
i
C := 0
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
504
D :=
( i D i)
i
B = 1.149 10
T := 1151.83 kelvin
3.120
5
D := 1.047 10
1.157
D = 9.16 10
G = 126.324
G
R T
J
mol
K := exp
K = 1.0133
Thus
Although a number of trials were required to reach this result, only the
final trial is shown. A handbook value for this temperature is 1171 K.
13.23 NH4Cl(s) = NH3(g) + HCl(g)
The NH4Cl exists PURE as a solid phase, for which the activity is f/f0.
Since f and f0 are for practical purposes the same, the activity is unity. If
the equimolar mixture of NH3 and HCl is assumed an ideal gas mixture at
1.5 bar, then with f0 = 1 bar the activity of each gas species is its partial
pressure, (0.5)(1.5) = 0.75. As a result, Eq. (13.10) becomes K =
(0.75)(0.75) = 0.5625 , and we must find the T for which K has this value.
From the given data and the data of Table C.4,
H298 := 176013
J
mol
G298 := 91121
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
1
:= 1
1
i := 1 .. 3
5.939
A := 3.578
3.156
A :=
16.105
3
B := 3.020 10
0.623
( i A i)
B :=
( i B i)
A = 0.795
B = 0.012462
T := 623.97 kelvin
C := 0
T0 := 298.15 kelvin
505
D :=
( i D i)
i
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
0.0
5
D := 0.186 10
0.151
D = 3.5 10
G = 2.986 10
G
R T
3 J
K := exp
mol
T = 623.97 K
Thus
K = 0.5624
Ans.
Although a number of trials were required to reach this result, only the
final trial is shown.
13.25
= 0.5
0.5
yNO2
yNO ( 0.21)
T := 298.15 kelvin
= K
0.5
G298 := 35240
G298
K := exp
K = 1.493 10
R T
12
yNO := 10
Given
yNO2 := 10
yNO2 = ( 0.21)
0.5
7 10
K yNO
ppm
(guesses)
yNO2 + yNO = 5 10
yNO
:= Find ( yNO , yNO2)
y
NO2
This is about
12
yNO = 7.307 10
= 0.5
J
mol
G298 := 81470
J
mol
J
mol
nN2 := nO2
506
79
21
n0 := 1 + nO2 + nN2
n0 = 3.976
Index the product species with the numbers:
1 = ethylene
2 = oxygen
3 = ethylene oxide
4 = nitrogen
The numbers of moles in the product stream are given by Eq. (13.5).
:= 0.8
nO2 0.5
n ( ) :=
nN2
1.424
3.639
A :=
0.385
3.280
4.392
0.0 10 6
C :=
9.296 kelvin2
0.0
0.0
0.227 5
2
D :=
10 kelvin
0.0
0.040
i := 1 .. 4
A ( ) :=
14.394
0.506 10 3
B :=
23.463 kelvin
0.593
( n ( ) i A i)
0.5
:=
1
B ( ) :=
( n ( ) i B i)
C ( ) :=
y ( ) :=
n( )
n0 0.5
( n ( ) i C i)
D ( ) :=
( n ( ) i D i)
i
K ( ) :=
( y ( ) i)
K ( ) = 15.947
507
A := 3.629
5
D := 0.114 10 kelvin
Guess:
10
B := 8.816
kelvin
C := 4.904
:= 3
2 2
idcph := A T0 ( 1) +
T0 1 ...
2
C 3 3
D 1
+ T0 1 +
T0
3
+ 1 ( 1)
2
idcps := A ln ( ) + B T0 + C T0 ...
+ D
T 2
0
idcps = 0.417
Given
H298 = R A ( ) T0 ( 1) +
B ( )
T0 1 ...
2
C ( ) 3 3
D ( ) 1
T0 1 +
3
T
H298 G298
K ( ) = exp
:= Find ( , )
R T0
H298
R T 0
0.88244
=
3.18374
508
kelvin
T0 := 298.15 kelvin
10
+ idcps
1
T 0
idcph
0.0333
0.052
y ( 0.88244) =
0.2496
0.6651
T := T0
13.27
Ans.
(gases only)
The carbon exists PURE as an individual phase, for which the activity is
unity. Thus we leave it out of consideration.
From the data of Table C.4,
H298 := 74520
J
mol
G298 := 50460
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
1
:= 1
2
1.702
A := 1.771
3.249
9.081
3
B := 0.771 10
0.422
i := 1 .. 3
2.164
6
C := 0.0 10
0.0
0.0
5
D := 0.867 10
0.083
A :=
( i A i)
B :=
A = 6.567
( i B i)
C :=
i
3
B = 7.466 10
T := 923.15 kelvin
( i C i)
6
509
( i D i)
i
C = 2.164 10
T0 := 298.15 kelvin
D :=
D = 7.01 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 1.109 10
(a)
:=
K := exp
mol
By Eq. (13.5),
n0 = 1
yCH4 =
yCH4 :=
= 0.7173
yH2 :=
1+
K = 4.2392
yH2 =
1+
( 2 ) 2
( 1 + ) ( 1 )
By Eq. (13.28),
K
4+K
= 0.7893
yCH4 :=
1
2+
yH2 = 0.5659
= K
(fraction decomposed)
2
yCH4 = 0.1646
1+
yH2 = 0.8354
Ans.
n0 = 2
:= .8
By Eq. (13.28),
Given
1+
( 2 ) 2
( 2 + ) ( 1 )
(guess)
:= Find ( )
= K
(fraction decomposed)
yH2 :=
2
2+
yCH4 = 0.0756
510
Ans.
= 0
(1)
H298 := 90250
G298 := 86550
3
A := 0.0725
B := 0.0795 10
T := 2000 kelvin
J
mol
C := 0
D := 0.1075 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 6.501 10
K1 := exp
mol
K1 = 0.02004
= 0.5
(2)
J
mol
G298 := 51310
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
0.5
:= 1
1
i := 1 .. 3
3.280
A := 3.639
4.982
A :=
( i A i)
0.593
3
B := 0.506 10
1.195
B :=
( i B i)
A = 0.297
T := 2000 kelvin
i
4
B = 3.925 10
T0 := 298.15 kelvin
511
0.040
5
D := 0.227 10
0.792
D :=
( i D i)
i
C := 0
D = 5.85 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 1.592 10
G
R T
5 J
K2 := exp
mol
K2 = 6.9373 10
(1)
( yN2) ( yO2)
0.5
0.5
0.5
0.5
yNO := K1 ( 0.7)
(2)
P0 := 1
yNO2
( 0.05)
yNO
=
( 0.7)
0.5
( 0.05)
0.5
= K1
yNO = 3.74962 10
Ans.
P := 200
0.5
P
=
=
K2
0.5
P0
( 0.7) ( 0.05)
yNO2
0.5
K2 ( 0.7)
0.5
( 0.05)
yNO2 = 4.104 10
Ans.
J
mol
G298 := 89830
512
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
1
:=
3
2
i := 1 .. 4
3.931
5.699
A :=
4.114
3.470
1.490
0.801 3
B :=
10
D :=
1.728
1.450
( i Ai) B := ( iBi)
A :=
D :=
B = 6.065 10
T := 723.15 kelvin
( i D i)
i
A = 5.721
0.232
1.015 105
0.783
0.121
C := 0
D = 6.28 10
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 1.538 10
K := exp
mol
2 2
3
n0 = 3
ySO2 =
1
3
:= 0.5
By Eq. (13.28),
Given
( 2 ) 2 ( 3 )
( 2 2 ) 2 ( 1 )
(basis)
yH2O =
ni0 ni
ni0
100 =
i
ni0
100
513
2
3
(guess)
:= Find ( )
= 8 K
K = 12.9169
= 0.767
Since the reactants are present in the stoichiometric proportions, for each
reactant,
ni0 = i
PC := 100
Whence
PC = 76.667
Ans.
= 1
Data from Tables C.4 and C.1 provide the following values:
H298 := 57200
J
mol
G298 := 5080
T0 := 298.15 kelvin
A := 1.696
J
mol
T := 350 kelvin
3
B := 0.133 10
C := 0
D := 1.203 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
3 J
G = 3.968 10
K := exp
mol
K = 3.911
ya =
(a)
P := 5
ya :=
(b)
yb =
1+
1+
P0 := 1
:=
P0 := 1
:=
514
P
=
K
P0
K
4 P + K
ya = 0.4241
1+
P := 1
( 2 ) 2
( 1 ) ( 1 + )
= 0.4044
Ans.
K
4 P + K
= 0.7031
H := H298 + R IDCPH T0 , T , A , B , C , D
H = 56984
J
mol
= 0.299
Q := H
Whence
( )
Q = 17021
xB B
K=
xA A
( )
ln a = 0.1 xB
J
mol
( 1 xA) B
xA A
2
ln b = 0.1 xA
(
(
Ans.
)
)
Whence
2
1 xA
1 xA exp 0.1 xA
2
2
K=
=
exp 0.1 xA xB
2
xA
xA exp 0.1 xB
K=
1 xA
xA
exp 0.1 ( 2 xA 1)
G := 1000
xA := .5
Given
J
mol
G
R T
K = exp
T := 298.15 kelvin
(guess)
1 xA
xA
G
R T
xA = 0.3955
xA := Find ( xA)
Ans.
1 xA
xA
G
R T
xA := Find ( xA)
= exp
515
xA = 0.4005
= 0
H298 := 41166
T0 := 298.15 kelvin
A := 1.860
G298 := 28618
J
mol
T := 800 kelvin
3
B := 0.540 10
C := 0
D := 1.164 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
3 J
G = 9.668 10
mol
= 0
G
R T
K := exp
K = 4.27837
= 0.02
By Eq. (13.4),
1
1+1++
1
2+
nCO = 1
nH2 = 1 +
= 0.02
:=
NCO2 =
0.96
1.02
= 0.941
w
2 z
=
2+w
2 + 2 z
yCO =
516
1
2 + 2 z
yH2 =
1+
2 + 2 z
yCO2 =
z := 2
By Eq. (13.28)
( 1 + )
Given
(d)
2 + 2 z
( 2 z ) ( 1 )
z := Find ( z)
= K
(guess)
z = 4.1
Ans.
= 1 (gases)
J
mol
G298 := 120021
3
A := 0.476
B := 0.702 10
J
mol
5
C := 0
D := 1.962 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
4 J
G = 3.074 10
mol
G
R T
K := exp
K = 101.7
( yCO)
= K = 101.7
If the ACTUAL value of this ratio is GREATER than this value, the
reaction tries to shift left to reduce the ratio. But if no carbon is present, no
reaction is possible, and certainly no carbon is formed. The actual value of
the ratio in the equilibrium mixture of Part (c) is
yCO2 :=
2 + 2 z
yCO2 = 0.092
RATIO :=
yCO2
( yCO) 2
yCO :=
1
2 + 2 z
3
yCO = 5.767 10
RATIO = 2.775 10
= 2
(1)
This is the reaction of Pb. 13.21, where the following parameter values are
given:
J
mol
H298 := 90135
J
mol
G298 := 24791
T := 550 kelvin
T0 := 298.15 kelvin
3
A := 7.663 B := 10.815 10
C := 3.45 10
D := 0.135 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
4 J
G = 3.339 10
)
4
K1 := exp
mol
K1 = 6.749 10
= 0
(2)
J
mol
G298 := 28618
T := 550 kelvin
J
mol
T0 := 298.15 kelvin
The following vectors represent the species of the reaction in the order in
which they appear:
1
:=
1
1
i := 1 .. 4
3.249
5.457
A :=
3.376
3.470
A :=
0.422
1.045 3
B :=
10
D :=
0.557
1.450
( i A i)
B :=
A = 1.86
( i B i)
i
B = 5.4 10
518
C := 0
0.083
1.157 105
0.031
0.121
D :=
( i D i)
i
D = 1.164 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 1.856 10
G
R T
4 J
K2 := exp
mol
K2 = 0.01726
Stoichiometric numbers,
i=
H2
CO
CO2
CH3OH
H2O
_______________________________________________
j
1
2
-2
-1
-1
1
0
-1
1
0
0
1
By Eq. (13.7)
yH2 =
0.75 2 1 2
yCO2 =
1 2 1
0.05 2
yCO =
0.15 1 + 2
1 2 1
yCH3OH =
1 2 1
P := 100
P0 := 1
By Eq. (13.40),
1 := 0.1
yH2O =
1 2 1
2 := 0.1
2
1 2 1
(guesses)
Given
)2
1 1 2 1
( 0.75 2 1 2) 2 ( 0.15 1 + 2)
( 0.15 1 + 2) 2
( 0.75 2 1 2) ( 0.05 2)
= K2
519
P
=
K1
P0
1
:= Find ( 1 , 2)
2
1 = 0.1186
yH2 :=
2 = 8.8812 10
0.75 2 1 2
yCO2 :=
yCO :=
1 2 1
0.05 2
0.15 1 + 2
1 2 1
yCH3OH :=
1 2 1
yH2O :=
1 2 1
1 2 1
13.34
yH2 = 0.6606
yCO = 0.0528
yCO2 = 0.0539
yCH3OH = 0.1555
yH2O = 0.0116
yN2 = 0.0655
= 2
Ans.
(1)
J
mol
G298 := 141863
J
mol
The following vectors represent the species of the reaction in the order in
which they appear:
A :=
1
:=
1
1.702
3.470
A :=
3.376
3.249
9.081
1.450 3
B :=
10
0.557
0.422
2.164
0.0 6
C :=
10
0.0
0.0
0.0
0.121 5
D :=
10
0.031
0.083
i := 1 .. 4
( i A i)
i
A = 7.951
B :=
( i B i)
C :=
( i C i)
i
B = 8.708 10
( i D i)
i
C = 2.164 10
520
D :=
D = 9.7 10
T := 1300 kelvin
T0 := 298.15 kelvin
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G
R T
5 J
G = 1.031 10
K1 := exp
mol
K1 = 13845
J
mol
G298 := 28618
3
B := 0.540 10
C := 0.0
J
mol
5
D := 1.164 10
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
G = 5.892 10
3 J
mol
G
R T
K2 := exp
K2 = 0.5798
521
1
5
( 3 + )
( 1 )
Ratio =
yH2
Ratio :=
yCO
(guess)
:= Find ( )
= K2
3+
5
yH2 =
:= 0.5
By Eq. (13.28),
Given
yCO2 =
3+
= 0.1375
Ratio = 3.638
Ans.
(e) One practical way is to add CO2 to the feed. Some H2 then reacts
with the CO2 by reaction (2) to form additional CO and to lower the
H2/CO ratio.
(f) 2CO(g) = CO2(g) + C(s)
= 1 (gases)
This reaction is considered in the preceding problem, Part (d), from
which we get the necessary parameter values:
H298 := 172459
J
mol
G298 := 120021
For T = 1300 K,
T := 1300 kelvin
A := 0.476
B := 0.702 10
C := 0.0
T
H298 G298 ...
T0
+ R IDCPH T0 , T , A , B , C , D ...
+ R T IDCPS T0 , T , A , B , C , D
G := H298
522
J
mol
T0 := 298.15 kelvin
5
D := 1.962 10
G = 5.673 10
G
R T
4 J
K := exp
mol
K = 5.255685 10
yCO2
( yCO) 2
When for ACTUAL compositions the value of this ratio is greater than the
equilibrium value as given by K, there can be no carbon deposition. Thus
in Part (c), where the CO2 mole fraction approaches zero, there is danger
of carbon deposition. However, in Part (d) there can be no carbon
deposition, because Ratio > K:
Ratio :=
( 1 )
Ratio = 0.924
(1)
CO + H2O = CO2 + H2
(2)
CH4
H2O
CO
CO2
H2
_________________________________________________
j
1
2
-1
0
-1
-1
1
-1
0
1
523
3
1
2
0
For initial amounts: 2 mol CH4 and 3 mol H2O, n0 = 5, and by Eq. (13.7):
yCH4 =
yCO2 =
2 1
5 + 2 1
2
5 + 2 1
3 1 2
yH2O =
yH2 =
yCO =
5 + 2 1
1 2
5 + 2 1
3 1 + 2
5 + 2 1
yCH4 yH2O
yCO2 yH2
= k1
= k2
yCO yH2O
J
mol
G2 := 3130
G1
K2 := exp
K1 = 27.453
K2 = 1.457
R T
Given
R T
2 := 1
(guesses)
( 1 2) ( 3 1 + 2) 3
= K1
2
( 2 1) ( 3 1 2) ( 5 + 2 1)
(
)
( 1 2) ( 3 1 2)
2 3 1 + 2
1
:= Find ( 1 , 2)
2
yCH4 :=
T := 1000 kelvin
G2
K1 := exp
1 := 1.5
J
mol
2 1
5 + 2 1
= K2
1 = 1.8304
yH2O :=
3 1 2
5 + 2 1
524
2 = 0.3211
yCO :=
1 2
5 + 2 1
yCO2 :=
yH2 :=
5 + 2 1
3 1 + 2
5 + 2 1
yCH4 = 0.0196
yH2O = 0.098
yCO2 = 0.0371
yH2 = 0.6711
yCO = 0.1743
Water(2):
x1 =
x2 =
y1 P
415 kPa
y2 P
Psat2
(steam tables)
Ethylene glycol(3):
Psat3 = 0.0
Therefore, y2 = 1 y1
y3 = 0.0
x3 = 1 x2 x3
and
3 x3
y P x
( 2 2)
1
P0
x3
T := 298.15 kelvin
y1 x2
G298 := 72941
G298
12
k := exp
k = 6.018 10
R T
525
J
mol
Ans.
1 1
13.41
1 0
a) Stoichiometric coefficients: :=
1 1
Number of components: i := 1 .. 4
v j :=
i , j
Number of reactions:
1
1
v=
50
Initial
50 kmol
numbers of n0 :=
0 hr
moles
0
n0 :=
Given values:
yA := 0.05
yB := 0.10
Guess:
yC := 0.4
yD := 0.4
n0i
j := 1 .. 2
n0 = 100
kmol
hr
2 := 1
kmol
hr
1 := 1
kmol
hr
Given
yA =
yC =
n01 1 2
n0 1 2
n03 + 1 2
n0 1 2
n02 1
yB =
n0 1 2
yD =
yC
yD
:= Find ( yC , yD , 1 , 2)
1
Eqn. (13.7)
n04 + 2
n0 1 2
1 = 44.737
526
kmol
hr
2 = 2.632
kmol
hr
kmol
hr
kmol
nB = 5.263
hr
(i) nA := n01 1 2
nA = 2.632
nB := n02 1
kmol
hr
kmol
nD = 2.632
hr
kmol
Ans.
n = 52.632
hr
nC := n03 + 1 2
nC = 42.105
nD := n04 + 2
n := nA + nB + nC + nD
yC = 0.8
(ii)
yD = 0.05
1
b) Stoichiometric coefficients: :=
1
0
Number of components:
v j :=
i , j
i
i := 1 .. 4
1
2
0
1
Ans.
40
Initial
40 kmol
numbers of n0 :=
0 hr
moles
Number of reactions:
1
2
v=
n0 :=
Given values:
yC := 0.52
yD := 0.04
Guess:
yA := 0.4
yB := 0.4
n0i
j := 1 .. 2
n0 = 80
1 := 1
kmol
hr
2 := 1
Given
yA =
yC =
n01 1 2
n0 1 2 2
n03 + 1
n0 1 2 2
yB =
yD =
n02 1 2 2
n0 1 2 2
n04 + 2
n0 1 2 2
527
kmol
hr
Eqn. (13.7)
kmol
hr
yA
yB
:= Find ( yA , yB , 1 , 2)
1
1 = 26
nC := n03 + 1
nD := n04 + 2
1
c) Stoichiometric coefficients: :=
1
0
Number of components:
yB = 0.2
i := 1 .. 4
1
1
0
1
Ans.
100
Initial
0 kmol
numbers of n0 :=
0 hr
moles
Number of reactions:
1
1
v=
n0 :=
n0i
Given values:
yC := 0.3
yD := 0.1
Guess:
yA := 0.4
yB := 0.4
1 := 1
kmol
hr
j := 1 .. 2
n0 = 100
kmol
hr
2 := 1
kmol
hr
Given
yA =
yC =
n01 1 2
n0 + 1 2
n03 + 1
n0 + 1 2
kmol
hr
nA = 12
nB := n02 1 2 2
i , j
2 = 2
yA = 0.24
kmol
hr
kmol
nB = 10
hr
kmol
nC = 26
hr
kmol
nD = 2
hr
nA := n01 1 2
v j :=
kmol
hr
=0
yB =
yD =
n02 + 1 2
n0 + 1 2
n04 + 2
n0 + 1 2
528
Eqn. (13.7)
yA
yB
:= Find ( yA , yB , 1 , 2)
1
1 = 37.5
yA = 0.4
nA = 50
nB := n02 + 1 2
nC := n03 + 1
nD := n04 + 2
1
1
d) Stoichiometric coefficients: := 1
0
0
Number of components:
i , j
yA := 0.2
0
1
1
i := 1 .. 5
Ans.
40
60
Initial
kmol
n0
:=
numbers of
0
moles
0 hr
Number of reactions:
1
0
v=
kmol
hr
2 = 12.5
yB = 0.2
kmol
hr
kmol
nB = 25
hr
kmol
nC = 37.5
hr
kmol
nD = 12.5
hr
nA := n01 1 2
v j :=
kmol
hr
n0 :=
n0i
j := 1 .. 2
n0 = 100
kmol
hr
yD := 0.20
yB := 0.4
529
yE := 0.1
1 := 1
kmol
kmol
2 := 1
hr
hr
Given
yA =
yC =
n01 1 2
yB =
n0 1
n03 + 1
yD =
n0 1
yA
yB
yE := Find ( y , y , y , , )
A B E 1 2
1
n02 1 2
n04 + 2
yE =
n0 1
1 = 20
kmol
hr
(i)
13.45
Eqn. (13.7)
n0 1
n05 + 2
n0 1
2 = 16
kmol
hr
(ii)
kmol
hr
kmol
24
hr
kmol
20
hr
kmol
16
hr
kmol
16
hr
nA := n01 1 2
nA = 4
yA = 0.05
nB := n02 1 2
nB =
yB = 0.3
nC := n03 + 1
nC =
nD := n04 + 2
nD =
nE := n05 + 2
nE =
Ans.
yC = 0.25
yD = 0.2
yE = 0.2
P0 := 1bar
H0f1 := 52500
T := 400kelvin
J
mol
J
mol
J
3 = C2H5OH(g) H0f3 := 235100
mol
2 = H2O(g)
H0f2 := 241818
530
P := 2bar
G0f1 := 68460
J
mol
J
mol
J
G0f3 := 168490
mol
G0f2 := 228572
kJ
mol
kJ
G0 = 8.378
mol
H0 = 45.782
A = 1.376
3
B = 4.157 10
C := [ ( 4.392) ( 0) + ( 6.002) ] 10
D := [ ( 0) ( 0.121) + ( 0) ] 10
G0
R T0
a) K0 := exp
C = 1.61 10
D = 1.21 10
H0
T0
1
T
R T0
b) K1 := exp
K298 = 29.366
3
K1 = 9.07 10
Eqn. (13.22)
+
IDCPS ( T0 , T , A , B , C , D)
K2 := exp
K400 := K0 K1 K2
Ans.
Eqn. (13.23)
K400 = 0.263
Eqn. (13.20)
Ans.
1 e
2 e
y2 =
1 e
y3 =
2 e
y3
y1 y2
= K
P
P0
531
e
2 e
e
2 e
1 e 1 e
2 e 2 e
= K400
P
P0
e := 0.5
Guess:
Given
y1 :=
2 e
= K400
1 e 1 e
2 e 2 e
1 e
y2 :=
2 e
y1 = 0.447
P
P0
1 e
2 e
y2 = 0.447
( )
e := Find e
y3 :=
e = 0.191
e
2 e
y3 = 0.105
Ans.
kJ
mol
J
mol kelvin
S0H2O2 := 232.95
T := 298.15kelvin P := 1bar
S0O2 := 205.152
J
mol kelvin
J
mol kelvin
S0fH2O2 = 102.882
G0f = 105.432
532
kJ
mol
J
mol kelvin
Ans.
13.48
P0 := 1bar
T := 750kelvin
1 = C3H8 (g)
H0f1 := 104680
2 = C3H6 (g)
H0f2 := 19710
3 = H2 (g)
H0f3 := 0
4 = C2H4 (g)
H0f4 := 52510
5 = CH4 (g)
J
mol
P := 1.2bar
G0f1 := 24290
J
mol
G0f2 := 62205
J
mol
G0f3 := 0
J
mol
H0f5 := 74520
J
mol
J
mol
G0f4 := 68460
J
mol
J
mol
J
mol
G0f5 := 50460
J
mol
H0I = 124.39
AI = 3.673
3
CI := [ ( 8.824) + ( 6.915) + ( 0) ] 10
DI := [ ( 0) + ( 0) + ( 0.083) ] 10
G0I
R T0
KI0 := exp
CI = 1.909 10
DI = 8.3 10
Eqn. (13.21)
H0I 1 T0
T
R T0
KI1 := exp
BI = 5.657 10
Eqn. (13.22)
KI0 = 0
+
IDCPS ( T0 , T , AI , BI , CI , DI)
Eqn. (13.23)
KI2 := exp
533
13
KI1 = 1.348 10
KI = 0.016
Eqn. (13.20)
H0II = 82.67
AII = 1.913
3
BII = 5.31 10
CII = 2.268 10
DII := [ ( 0) + ( 0) + ( 0) ] 10
G0II
R T0
KII0 := exp
DII = 0
8
KII0 = 3.897 10
Eqn. (13.21)
T
R T0
KII1 := exp
KII1 = 5.322 10
+
IDCPS ( T0 , T , AII , BII , CII , DII)
Eqn. (13.23)
KII2 := exp
KII = 21.328
y4 =
1 I II
1 + I + II
II
1 + I + II
y2 =
I
1 + I + II
y5 =
II
1 + I + II
y3 =
I
1 + I + II
Eqn. (13.7)
P0
P
= KI
y4 y5
y1
P0
P
= KII
534
Eqn. (13.28)
1 + I + II 1 + I + II = KI P0
1 I II
P
1 + I + II
II
II
1 + I + II 1 + I + II = KII P0
1 I II
P
1 + I + II
Use a Mathcad solve block to solve these two equations for I and II. Note
that the equations have been rearranged to facilitate the numerical
solution.
Guess:
I := 0.5
II := 0.5
Given
I
1 + I + II 1 + I + II
II
II
1 + I + II 1 + I + II
P0 1 I II
P 1 + I + II
= KI
y4 :=
1 I II
1 + I + II
II
1 + I + II
y1 = 0.01298
P0 1 I II
P 1 + I + II
= KII
I
:= Find ( I , II)
II
y1 :=
I = 0.026
y2 :=
I
1 + I + II
y5 :=
y2 = 0.0132
II = 0.948
y3 :=
I
1 + I + II
II
1 + I + II
y3 = 0.0132
535
y4 = 0.4803
y5 = 0.4803
A summary of the values for the other temperatures is given in the table below.
T=
y1
y2
y3
y4
y5
13.49
750 K
0.0130
0.0132
0.0132
0.4803
0.4803
1000 K 1250 K
0.00047 0.00006
0.034
0.0593
0.034
0.0593
0.4658 0.4407
0.4658 0.4407
P0 := 1bar
1 = n-C4H10(g)
H0f1 := 125790
2 = iso-C4H10(g)
T := 425kelvin
J
mol
J
H0f2 := 134180
mol
H0 = 8.39
G0 := G0f1 + G0f2
A := ( 1.935) + ( 1.677)
A = 0.258
3
B = 9.38 10
C = 5.43 10
B := [ ( 36.915) + ( 37.853) ] 10
C := [ ( 11.402) + ( 11.945) ] 10
D = 0
Eqn. (13.21)
K0 = 5.421
H0
T0
1
T
R T0
b) K1 := exp
D := [ ( 0) + ( 0) ] 10
G0
R T0
J
mol
J
G0f2 := 20760
mol
G0f1 := 16570
kJ
mol
kJ
G0 = 4.19
mol
H0 := H0f1 + H0f2
a) K0 := exp
P := 15bar
Eqn. (13.22)
K1 = 0.364
IDCPH ( T0 , T , A , B , C , D) ... K2 = 1
T
+ IDCPS ( T0 , T , A , B , C , D)
K2 := exp
536
Ans.
Eqn. (13.23)
Ke := K0 K1 K2
Ke = 1.974
Eqn. (13.20)
Ans.
y2 = e
y2
= Ke
y1
( 1 e)
= Ke
1
1 + Ke
y1 := 1 e
e = 0.336
y1 = 0.664
y2 := e
y2 = 0.336
Ans.
b) Assume the gas is an ideal solution. In this case Eqn. (13.27) applies.
( yi i) =
K
P0
Eqn. (13.27)
( 1 e) 2 = K
e 1
e =
2
2 + Ke 1
T
Tc1
1 := 0.200
Tc1 := 425.1kelvin
Tr1 = 1
Pr1 :=
T
Tc2
P
Pc1
Pc1 := 37.96bar
Pr1 = 0.395
1 = 0.872
2 := 0.181
Tc2 := 408.1kelvin
Tr2 = 1.041
Pr2 :=
537
P
Pc2
Pc2 := 36.48bar
Pr2 = 0.411
e :=
2 = 0.884
2
2 + Ke 1
y1 = 0.661
y2 := e
e = 0.339
y2 = 0.339
Ans.
The values of y1 and y2 calculated in parts a) and b) differ by less than 1%.
Therefore, the effects of vapor-phase nonidealities is here minimal.
538