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''Cooling means transfer thermal froma place the of heat where is unwanted a plae it to if where doesnot disturb"
,|903 Willis Havilnd carrier,
of This is howthefther modern and ir.onditioning refrigeration defined ooIing the systems proess'But in orderto transfer heatfromone p|ae to thermal medium is another, trnsport that the required bsorbs hetat whereit is notwnted the p|ae it anddelivers to the plaewhere his it doesnotdisturb. is the maintskof any refrigerant, of and irrespetive type,thermI properties or hemial No no omposition' more, less. hedrivingforethtmakesthe movearound the in refrigerant systemis the refrigeration with heat ompressor' thetuI plaein the tking transfer (instIled the pIe evaportor at the where hetis unwanted)nd (instalIed the theondenser at the lewhere hetdoes not So tht disturb)' it beomes Ier medi refrigerants essentia] are for thefuntionIity any of refrigeration systemandshould be treated suh. s of hepurpose this Refrigernt Guideis to assistyou Handling protet bothyourinvestment to and andtheenvironment, to pro!n mote sfetonbord.addition, a Iog it ontains refrigernt that improved helpsyouto hieve overyourrefrigera. ontrol Iogging tionosts.continuous onsumption is of refrigerant by required someauthorities (refer thetableon page't5in to thisguide).
Disclaimerof epressedand impliedwarranties: lthoughreasonablecarehasbeentakeninthpreparationofthisbooklet,nowarrantiesorrepresntationsastotheaccuracorcompletenessoftheinfo begiven;norcanUnitorAsassumeanrsponsibilitregardingthesuitabilitofthisinformationfortheuser'sintendedpurposesorforthecon as shouldmakea determination to the suitabilitof the informationfor thirpafticular prpose(s)'
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with when Sfehand|ing woking refrigerants of and Charging rovery efrigerants Inspetion nvironmenta| System
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Compressor oil - tehnia| environmental tab|e data and Refrigerants overview p^,gJo'br (as,pgr 2003) ru|es Refrigeration ndregulations Glossary log Refrigerant Referenes
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odour. gas. Slight Liquefied Colourless. ethereal frostbite. may with Contat |iquid ause or anaesthetiother as as and headahe dizziness, wel| ausing may eposure ause or pro|onged High onentrations disordrs. system nervous entral disturbanes. heat rhythm may of amounts vapour ause of |arge InhaIation layr. ' tothe potentia| it maybfl'angous ozone and waming type, on Depending refrigernt it hasa g|oba| guide)' 14 on (Please totab|e page inthis efer l
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oC.Store a ompressed Keepin a we|l.venti|ated Keep p|ae. gas' as in unde transported pressure gas he soures ignition. gas is norma|ly of and hot openflames, surfaes other awayfrom fIames. and sparks open heat, gas wiII out. ln ontainers.seofa |eak, or|iquid flow Avoid cylinders/pressuized above to ylinders temperatures 45 Do notexpose persons to Measures protet Sfety |othing Protetive the gloves against o|d. insu|ated protetive gloves other or and War protetion |eather eye A|ways Never a |ift y|inders. whenhand|ing boots Wearsafety or ontat sp|ashes' of is if be shouId won there a possibi|itydiret system and the Consider refrigeration the ap keepthey|inder on whenmoving y|inder. A|ways by y|inder theva|ve. risk. without Wearse|f-ontained you Stopgas |eakif possib|e unti| knowit is empty. to ontainers be fi|led refrigerant are and eating drinking Smoking, goodventilation' Provide are if appratus highgs onentrations possible. breathing area in forbiddenthework the to Measures protet environment Safety to mustbe returned th y|inders mpty equipment. Use into refrigerants the environment. reovery Do notdisharge information. for supplier dispos| Contt supp|ler.
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the wi|| endanger surroundings' the to air risk. the without Move ylinde(s)open where |eak not if |eak possib|e Stop the by |iquid out Prevent |eaking ofthey|inder turning gassideup. Contro| xposure oxygen by sufoation reduing and aumulate theground mayause a|ong gases than Rfrigerant areheavier air,andwi|| aras. apparatus onfined in brathing Wea for avai|ab|e breathing. se|f-ontained
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under refrigerants beombustib|e pressure. an based oi|, mixed airnd/or F|uorine with When
Equipment Fire Proper Fighting from distane. of with amountswater a safe the Cool ylinder |arge
Hazards FireandxpIosion heated. when may Cylindrs explode formHCIin of:0, formation toxigases/vapours/fumes HF andCoFz. HCFC,swi|l of auses ireor hightemperatures form also CoCIz. and ddition, may whenFirefighting Protetion PersonaI breathing use apparatus. in are |frefrigerants invo|vedfire, self-ontained l otherInformation gas from Remove ylinders fireare. down. invo|vedfireunti| is oo|ed in it whih been has any Donotmove y|inder . .l'' ' vlit,, .l
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use is throughput required nd hosess shortapossible wheninresed of 5. Keepthelengths reovery hoses. Irger diameter first. the refrigerant is 6' Thekeyto quikreovery to reover |iquid
on is opertions shown the shemati as for set-up bothreovery we|ls harging reovery reommended The Unitor for Customer Sevie ssistane. Unitor please the arrangements, ontat nearest on drawing page11.Forother
RFBIGRAI0N'sRvl
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Larqe56 ltr.Gvl. 48 kq/ 105lbs 45 ko/ 99 Ibs 45 kq/ 99 Ibs 45 ko/ 99lbs 36ko/ 79lbs 41 ko/ 90 lbs 44 k/ 97|bs Ibs 47ko/ 103 36 ko/ 79 lbs 47 kq/ 103lbs 43 ko/ 94lbs 44 kq/ 97 lbs 36 kq/ 79lbs
R-22
R-502
R-507
21 SmII ltr.Tank 17ko/ 37lbs 17kq/ 37 lbs 17ko/ 37lbs 17kq/ 37lbs 13ko/ 29lbs 15kq/ 33lbs 16kq/ 35lbs 17kq/ 37lbs 13kq/ 29 lbs 17ko/ 37Ibs 17kq/ 37lbs 16ko/ 35 lbs
13ks/ 29lbs
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aid Hydrofluori withthe moisture aggressive forming at that very hygrosopi) may deompose hightemperatures
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entes lf exerise.themoisture an systems bea ost|y inside refigertion moisture prob|ems by aused toomuh To retify the but the that ost|y it wi|| with thesystem therefrigerant leadto ontinuous repairs retify onsequenes do noteltninate ause. puity. to qua|ity with standards regards their with omp|y appropriate that important refrigerants Itis therefore by supp|ied Unitor a|l.refrigerants mhinery, refrigeration onboard of and toub|e-fre saveoperation your to Inorder ensure of the and that standard defines benhmrks purity thes AR| with omp|y thestringent 700-1999 the throughout wold .l0ppm. than ontent be |ess to the e.g. he substanes. standard demands moistue 7). (P|ase page see operation as reovery we|l harging for as set-up both, reovery reommended TheUnitor
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tht but for not is system ritia| on|y theompressor alsoto ensure theoi|doesnot for se|etion a efrigeation Lubriant gas of from separate therefigeant in anypat thep|ant. an poormisibitity the p|ant ause within and inompatibi|ityhene is hanged, manuftue |f theoi|typeor supp|y problems. it is tehnology, vita||y additive with oup|ed differnt produts themrket, on and of Withthewiderange minera| syntheti from the is to grade Thea|ternative drain oi|omp|etely a oiI. prior with oi| to importnthek misibility totop-up a different proedures, waranty, During strenuous without or whihan be very diffiu|t even impossib|e system, refrigeation oi|s. refrigeration the oftn designers prohibit useof non-approved system and/or omprssor
0ilTesting
has if the the inspeting oi|ndusean oilaidtestkitto determine system been by test A field of oi|anbe done visua||y '} 1-\1l]: ],, to eoosed moisture. and bottIes is usedforsystems samp|e |ean requires this for be an Oi|samp|es a|so sentto a |aboratory ana|ysis; routine ofoi|. large ontaining quantities
Proedures 0iIChanging
if frequenttheoil be or maybeannua||you|d more hese interva|s. onoi| reommendations hange to Refr mnufaturers dark beomes orloudy. or to don theompessorthesystem has or servie epair been the ruIe A good is torenew oi|if a majo |t nkase.is in the to unit, ondensing it is normal rep|e oi|harge theompresso the Fohanging oi|in a standrd time. at drier ors thesame (if and the fi|ter appliab|e) therefrigeant fi|ter or toIean hange oiI alsoeommended
12
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oi| are off that 3. Ensure anyrnkase heaters swithd 4' rankase fom Drain areful|y theompressor oil pressure against of apb|e working with to attah instuctions, pump ompressor a to aording manufturers to 6. FittheoiIpump theoi|ontainer it hose oi| the |oose. Pump into harging unti| is fi|led to the hose harging and|eve hoseonnetionompessor pump proper when funtioning and entering thesystem tonsue into to air Thisis nessary e|iminate from system a working against pressurised pump with prssurised, oiInbeharjd anoi|-fi||ing new out the drained with ompressor 5. |ftheoi|hasbeen
13
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usedrefrigerants. data and of tab|e of Theintentionthebe|ow is togivea summary theenvironment| tehnia| forthemost Refrigerant ODP ASHRAno
R.'11
GWP 4000
Repl. For
Group
Oils *
Min,AB Min,AB Min,AB Min,AB, PAO Min,AB, PAO Min,AB
Boiling Poit"G
+23' -29.8
Trihlorof|uoromethane DihIorodif|uoromethne Mix R-22l115 (48.8/51.2) if ChIorodIuoromthane R-12 |li R-22|152a|124 (53/3/34) 1 CFC HCF HF
ended** and Prodution trade nd ended** Prodution trade and ended** Prodution trde Iimited and Prodution tde Phase 2030** out Zeotrop' rep|aement. Interim 4,9 Glide K ost|y usedforfirefighting Prodution and systems' endd trade refrigerant Single NoGIide wiih Nea.Azeotrop 0,7 GIide K GIide Zeotrop, 7,4K Zeotrop. 6 K GIide with Ner-Azeotrop GIide <0,2K. 60% Pressure approx than hiqhe R-22 GIide Zeotrop. 5 K Azeotrop GIide Zeotrop, 5,6K / Toxi FIammbIe emp./ high LowCrit. nressure Veryflammable
'82
(\ '?.
8500
5590
.45.3
-40.8 .4'4
0 049 0,031
4a IL
1700
970
-5 '
-zo. I
-4b.b
0 0 0 0,048 0 0 0 0 0 0 0
R-502 R-22
Po Po
A.. |\ih, POE
i R-32|125|14a (23125152\
iR.22|R124lR142b (60/25l1 5)
R-4104
R-4134 R-507 R4174 R-717
R-22
MixR-32/125 (50/50)
MixR218/R1344/R6004 (9.0/88.0/3.0)
P0
AB, Min, PAO'Po
-35.0
-47.1
HF HF
POE AB, Min, PAO'P0 Min,PAO AB, Min, PAO.P0 AB, Min, PAo' 0
'r950
-42.0 -33.
-78.4
R.7'14
R.290
-10
-42.1
* Min=inea| AB =Alkyl oiI Po = PAo benzene, =Po|y|phao|efins, Polyo|ester oil, ** Appliable None-AtiIe-S on|y Protoo| Montrea| to ountries the1987 to
14
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Reguttory Body
Validfor
F
and Prodution trade CFC'sis i||gal with (exept essentiaI fo use). nd Podution trade leqal Jan1't2010 until Notpermitted
HF
on gradually redued fina| until phase-out Jan.]2030' Prodution & trde
't9s7
lotrel Prot,ool
Jan. 2004: lst 30% to and ontainers, tovent tmosphere. Jan. 2008: in in l||ega|newsystems, disposable 1st 25% paty ,1st hek approved iftotaI by Annually prod' Virgin Jn. 2010: > harge 3kg. refrigerant disontinued phased-out Jan. 2015: 1st
for VIid
Vl Parties Annex to
F
emissions Deliberate pohibited' Not new allowed'in systems
HF
Deliberte emissions prohibited. in Allowed new systems until vear2020
HF
NA
Servie
(|APP ert.) surveys Regu|ar system y|inders & Reovery to Used mandatory. refrigerants waste to bedelivered appropriate faiIities, reeption
lek [Vlax
[trpo| 7l78
USA {AA608}
to lllegal vent to atmosphere. and lllegal import, to Phse in new out to tovent atmosphere systems from 201 0. |llegl new for systems with power shaft >50kw, in existing to OK year 5. lllegal 201 to vent to tmosohere Illegal reharge to andtoventto atmosphere. Permitted until vear2020. Notl|owed Permitted until ear2020. Notpermitted Permifted until year 2020. GWP <= 2000 Permifted until ear2020'
NA
|f /Csystems: refr' y|inders. reovery have Shall > harge 50lbs15%' not y|inders a||owed. Disposab|e to ordingARI740. Reovery 35% Provision svstem: of Pump apable 500mirons. EPA ship US flagged only: (%oftota| harge in refr' engineer. servie etified oneyear) and system y|inders Reovery Vauum onboard. mandatory 730 pump of apabIe reahing mandatory' Log mirons' book to engineer beSTK Servie inspetion' AnnuaI ertified' is Logbook survey. Annual mandatory. with Fixed systems |-motor > 100kW.Detetionleakage, of figures reorded onsumption units' andreovery
Netherlands
ts,EK).
Sweden
Notpermifted
NA
{sWA}
DnV
and Sweden Swedish ships flagged DnV|assed ships ClssNotation CIean ships LRS |assed
NA GWP <3500 GWP< 1890 NA GWP <1950 2000 GWP <= 3800 GWP <=
LRS'
R - Chracter
+ system Reovery & y|inders mandatory logbook + & systemy|inders Reovery logbook mandatory
+ & system ylinders Reovery Fixed mandatory. leak logbook req' svstem detetion
,!0% harge oftota| annu||y' harge 10% oftota| annually. 10% oftota| harge annually.
As
GL
s nottion
GreenPasspot
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9. GLOSSARY
with working refrtgerants. used and terms abbreviations when used the tab|e hebe|ow explains most Institute inoandRefriqeration Air U.S. andAirRefr of Soiety Amerian 0r in hange omposttlon appreiably oesnot refrigerant like pessure' Behaves a sing|e onstant under or as tempeatu itevaporatesondenses 34 byANSliASHRA destgnations number seies R-500 assigned b|ends andhasno glide'Refiigeant volatilities different ntswith of Mixture 2 or moreref R502 R500' R12, e.g. hbfluoroarbon, y itabgenated GWP High 0DP,high nvironmenta|burdn: Fluoroarbons ated off is while e inrease vapour boiled at theevapoation used Usual|y todesribe oit pressure. most (The vo|atile omponnt offfirst) onstant bIend ofa zeotropi orondensation Protool GWP.TheKyoto a ertain Pef|uoroarbon ; FIuoroabons,
offievI
Ful|yhalognateot^.yoroafe.fightingagent'Regulatedandin GWP. buden: oDP..igh nvironmental High Protool. qenral b bjnned iheMontea| lowGWP' burden: nejlrtane.nt/tronmelrtd No0DP,
e.g"R-22andR-401A
R.125 e.g. droarbon, R-134, not Gases ontrol|ed n ofGreenhouse of to tibute thedepletiontheozone
(i.e. R12,R22' 0DP).g' a laver have ertain has whih oDP=,1 is Iue R.11, or hlorine bomIne. ontain oiI rfriqeration aolefin
ontainer,e.g.areOVerylinder.NB:Never re!-gglxy in reoverused refrigerants to empty Reuseofareoveredeig@sssuhasfiIteinganddryingfor the1e.!! and of removal oil,moistue aidfrom to the restore substan a speified ARI700 1999 e.o. and Omponent e.q.R-22 R-1344 ofonesinqle vanhetKoe|tehnish stbh@efening for toset (Dutrr organizatton standards ndmonitor Insta|laiebediif non-profit Areditation Swedish toaountthediretGWPandtheenergyonsumtI0n butrather infomation, is system' retrigeration TheTWI not refrigeanlspeifi th 1ui".jtorun
" - - " ' - . . . J - .
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as it rtemperatue omposition
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kg 12.5 57kg
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12.5 kg 57kg
592905620 592905557
blue blue
jt
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Temperatur =Vap0rating
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