You are on page 1of 8

QB-CAD-1 Carboxylic acid

110.

What is the major product for the following reaction?


CH3
H Product
+

CH2COOC 2H5 OH
CH3 CH2COOC 2H5

CH3

(A)

(B)
CH2COOC2H5

CH3

CH3

(C)
CHCOOC2H5

(D)
CH2COOH

Ans.

C
COOH Ph Ph
H product will be
+

171.

Ph
O
CO Ph Ph

(A)
Ph

(B)

Ph

Ph
COPh Ph

(C)
Ph

(D) None

Ans.

B
NO2 Cl O
i ) CH2N 2 A ii) Ag2 O, H2O

179.

The product A and the intermediate of this reaction is

QB-CAD-2
NO2 , Carbene

(A)
O NO2

COOH

(B)

, Carbanion COOH

NO2

(C)

, Carbanion and carbene both COOH

NO2

(D)

, Carbene only COOH

Ans.

83*.

Among the carboxylic acids:


O O CH3 (a) OH (b) O H OH (c) OH O O and N (d) OH O

the, one or more than one undergoing decarboxylation readily is (are) (A) Only a (B) Both a and b (C) a, b and d (D) a, b and c Ans. 90. C Acetamide is treated separately with the following reagents. Which one of these would give methylamine? (A) PCl5 (B) Sodalime (C) NaOH + Br2 (D) None of these C Hofmann's bromamide reaction In the following reaction,
i) DIBALH hydroxy carboxylic acid + ii) H

Ans. 90. 71.

A is (A) hactone (C) a hemiacetal Ans. 75. C

(B) Lactide (D) , - unsaturated acid

Which of the following can form an anhydride on heating?

QB-CAD-3
O
O

(A)

H OH
O O

(B)

HO HO O

(C)
HO OH

(D)

O HO OH

Ans. 78.

D
O
3 Product is ii) KOH, Br , H O 2 2 i) ND ,

OH NH2 ND2

(A)
O NH2

(B)
O ND2

(C) Ans. 65. A

(D)

Reactivity of carboxylic acid derivatives towards nucleophilic acyl substitution is


RCOCl , (RCO) 2 O, RCOOR , RCONH2
(I) (II) (III) (IV)

(A) I >II > III > IV (C) I < III < II < IV Ans. 65. A

(B) I < II < III < IV (D) IV < I < III < II

Cl, RCOO, RO, NH2 are replaced, weaker the conjugate base, better the leaving group hence greater the reactivity, leaving nature is in order NH2 < RO < RCOO < Cl Compound X has molecular formula C4H8O3. It evolves CO2 with aq. NaHCO3 X reacts with LiAlH4 to given an achiral product. The structure of X is:
OH MeO

66.

(A)
H3C HO COOH

(B) (D )
H3C H3C

COOH

(C)
H3C COOH

COOH HO

Ans. 70.

B
O
P4O10 CH3MgBr Ca(OH) 2, I 2 A B C D ( yellow pt) H O+
3

NH2

QB-CAD-4
O

(A)
CH3 O

(B)

COOH

(C)

(D )

Ans. 70.

A
COOH ii) H3 O+
iii) i) HCN

(A)

COOH

(B)

O O

NH2

(C)

COOH

(D )
HOOC

COOH

Ans. 75.

B The order of reactivity of the following esters


O H3C OMe I II CH3 O Cl III O Cl O

OMe

Cl IV

OMe

towards hydrolysis is: (A) I > II > III > IV (C) IV > III > II > I Ans. 75. C

(B) II > I > III >IV (D) IV > III > I > II

Due to the presence of two electronegative Cl atoms, at the carbonyl carbon, the electron density decreases and facilitates the hydrolysis, In (I) due to bulky benzene ring, if is difficult to hydrolyse the ester. In the reaction sequence CH3
[ x] O II NH2 CH3CH2 NH2 C

74.

[x] will be (1) LiAl H4, (2) Na/C2H5OH (3) BH3 /THF (4) NaBH4 Select the correct answer from following codes given below (A) 1, 2 and 3 (B) 1, 2 and 4 (C) 2, 3 and 4 (D) Only 4 Ans. A

QB-CAD-5

79.

Which among the following compound will give HVZ reaction? (A) Benzoic acid (B) Phenyl acetic acid (C) Formic acid (D) 2,2 - dimethyl propanoic acid B Consider the following reaction C6H5COOH
( ii ) CH2N 2 ( excess) ( iii ) H 2 O / Ag2 O ( i ) SOCl 2 C6H5 CH2 COOH

Ans. 82.

In the reaction intermediate is (A) Carbocation (C) Carbene Ans. 69*. B O


O

(B) Ketene (D) Nitrene

1. CH3 MgBr ( excess ) A + B. A and B are 2. H2 O

OH

O
(B)
,

OH

OH Mg Br OH OH , Mg Br

(A)
H3C OH , OCH3 , OH Mg Br

O
(C) Ans. 74. D
O

(D)

H3C HO

CH3

P4 O10 CH MgBr , Ca OH )2 ,I A 3 H3O B ( 2 C D. D is

NH2 O

(A)
CH3 O

(B)

COOH

(C)

(D)

Ans. 80.

C Match List I (name of reaction) and List II (Product) and select the correct answer from the code given below the list. List I List II a) Perkin reaction 1. CH3 CH2 COOC2H5

QB-CAD-6

b) Claissen condensation c) Aldol condensation d) Tischenko reaction Cordes A B a) 4 2 b) 4 2 c) 2 4 d) 2 4 Ans. 82. A

2. CH3 || CH2 || CH3


C C

C 3 1 3 1

3. C6H5 CH = CH CHO 4. C6H5 CH = CH COOH D 1 3 1 3

Identify X in the following sequence of reactions: NH Br2 / KOH C4H7OCl 3 C4H9ON CH3CH2CH2NH2
H3C
CO Cl

(A) H C 3
H3C

(B)
H3C

CO Cl

(C)
Cl

OH

(D) Cl

CHO

84.

(A) The product (P) of the reaction:


COOH
i ) Ag2 O P, is ii ) Br2 ,

COBr

Br

(A)

(B)
Br

Br

COOPh

(C) 84. 61. (C)

(D)

61. 61.

Which of the following reagent/solution can be used to distinguish between methanoic acid and ethanoic acid? (A) Tollens reagent (B) FeCl3 solution (C) NaOH solution (D) Na2CO3 solution (A)
O

Since methanoic acid contains H


OH

aldehydic group and as well as carboxylic acid group.

Since it contains aldehydic group, so it gives positive iodoform test.

QB-CAD-7

87. 87. 88.

Which gives only glucose by hydrolysis? (A) Sucrose (C) Maltose (C)

(B) Starch (D) Galactose

88. 89. 89. 90.

90. 68.

Amylose is a polymer of (A) -D-glucose (B) -D-glucose (C) -D-fructose (D) -D-fructose (A) There is desorpiton of physical adsorption when (A) temperature is increased (B) temperature is decreased (C) pressure is increased (D) concentration is increased (A) Al certain value of pH, the Zwitter ion of amino acid does not migrate towards any of the electrode under the influence of electric field. This pH value is called (A) isoelectric point (B) neutralization point (C) intectic point (D) end point (A)
electrolysis K+OOC(CH2)4COOK+ X + CO2 + H2 + KOH, X is: (A) n-butane (B) n-octane (C) cyclobutane (D) butane

68. 68.

C
H2C H2C CH2 COO K CH2 COO K

- + - +

H2C H2C

CH2 CH2

67.

Which statement is true about the relationship between Brnsted-Lowry (B-L) bases and Lewis bases? (A) A Lewis base must be a B-L base but a B-L base need not be a Lewis base. (B) A B-L base must be a Lewis base but a Lewis base need not be a B-L base. (C) B-L bases and Lewis bases are interchangeable. (D) There is no relationship between Lewis and B-L bases.

67.

Objective 6.

O O
3 A. A is

CH OH

(A) (C) 7.

CH2CH2 OH COOCH3
both are correct

CH2CH2 COOH OCH3

10.

None is correct P2O5 A 4H The end product of the sequence Acetamide B is (A) CH3NH2 (B) C2H5NH2 (C) CH3CN (D) CH3COONH4 Select the suitable reagent [X] for

QB-CAD-8 CH=CHCH3 [ X]
(A) KMnO4/ (C) O3H2O A 7. b10.c

COOH COOH COOH


(B) O3AcOH + Zn (D) O3(CH3)2S

6.

4.

On standing in dilute aqueous acid the given compound is smoothly converted to CH3
O O CH3 , the compound A is CH2CO2H O

O (B) O CH2OH

(A) O

CH3

CH3 (C) O
9.

OH

O CH3 CH3 (D) O O CH3 CH3

The ease of alkaline hydrolysis is more for

COOCH3

COOCH3 (B)

(A) NO2 COOCH3


(C)

Cl COOCH3
(D) OCH3

14.

4.

CH3CHO + H2NOH CH3CH = NOH. The above reaction occurs at (A) pH = 1 (B) pH = 4.5 (C) Any value of pH (D) pH = 12 A9. A14. B

You might also like