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110.
CH2COOC 2H5 OH
CH3 CH2COOC 2H5
CH3
(A)
(B)
CH2COOC2H5
CH3
CH3
(C)
CHCOOC2H5
(D)
CH2COOH
Ans.
C
COOH Ph Ph
H product will be
+
171.
Ph
O
CO Ph Ph
(A)
Ph
(B)
Ph
Ph
COPh Ph
(C)
Ph
(D) None
Ans.
B
NO2 Cl O
i ) CH2N 2 A ii) Ag2 O, H2O
179.
QB-CAD-2
NO2 , Carbene
(A)
O NO2
COOH
(B)
, Carbanion COOH
NO2
(C)
NO2
(D)
Ans.
83*.
the, one or more than one undergoing decarboxylation readily is (are) (A) Only a (B) Both a and b (C) a, b and d (D) a, b and c Ans. 90. C Acetamide is treated separately with the following reagents. Which one of these would give methylamine? (A) PCl5 (B) Sodalime (C) NaOH + Br2 (D) None of these C Hofmann's bromamide reaction In the following reaction,
i) DIBALH hydroxy carboxylic acid + ii) H
QB-CAD-3
O
O
(A)
H OH
O O
(B)
HO HO O
(C)
HO OH
(D)
O HO OH
Ans. 78.
D
O
3 Product is ii) KOH, Br , H O 2 2 i) ND ,
OH NH2 ND2
(A)
O NH2
(B)
O ND2
(D)
(A) I >II > III > IV (C) I < III < II < IV Ans. 65. A
(B) I < II < III < IV (D) IV < I < III < II
Cl, RCOO, RO, NH2 are replaced, weaker the conjugate base, better the leaving group hence greater the reactivity, leaving nature is in order NH2 < RO < RCOO < Cl Compound X has molecular formula C4H8O3. It evolves CO2 with aq. NaHCO3 X reacts with LiAlH4 to given an achiral product. The structure of X is:
OH MeO
66.
(A)
H3C HO COOH
(B) (D )
H3C H3C
COOH
(C)
H3C COOH
COOH HO
Ans. 70.
B
O
P4O10 CH3MgBr Ca(OH) 2, I 2 A B C D ( yellow pt) H O+
3
NH2
QB-CAD-4
O
(A)
CH3 O
(B)
COOH
(C)
(D )
Ans. 70.
A
COOH ii) H3 O+
iii) i) HCN
(A)
COOH
(B)
O O
NH2
(C)
COOH
(D )
HOOC
COOH
Ans. 75.
OMe
Cl IV
OMe
towards hydrolysis is: (A) I > II > III > IV (C) IV > III > II > I Ans. 75. C
(B) II > I > III >IV (D) IV > III > I > II
Due to the presence of two electronegative Cl atoms, at the carbonyl carbon, the electron density decreases and facilitates the hydrolysis, In (I) due to bulky benzene ring, if is difficult to hydrolyse the ester. In the reaction sequence CH3
[ x] O II NH2 CH3CH2 NH2 C
74.
[x] will be (1) LiAl H4, (2) Na/C2H5OH (3) BH3 /THF (4) NaBH4 Select the correct answer from following codes given below (A) 1, 2 and 3 (B) 1, 2 and 4 (C) 2, 3 and 4 (D) Only 4 Ans. A
QB-CAD-5
79.
Which among the following compound will give HVZ reaction? (A) Benzoic acid (B) Phenyl acetic acid (C) Formic acid (D) 2,2 - dimethyl propanoic acid B Consider the following reaction C6H5COOH
( ii ) CH2N 2 ( excess) ( iii ) H 2 O / Ag2 O ( i ) SOCl 2 C6H5 CH2 COOH
Ans. 82.
OH
O
(B)
,
OH
OH Mg Br OH OH , Mg Br
(A)
H3C OH , OCH3 , OH Mg Br
O
(C) Ans. 74. D
O
(D)
H3C HO
CH3
NH2 O
(A)
CH3 O
(B)
COOH
(C)
(D)
Ans. 80.
C Match List I (name of reaction) and List II (Product) and select the correct answer from the code given below the list. List I List II a) Perkin reaction 1. CH3 CH2 COOC2H5
QB-CAD-6
C 3 1 3 1
Identify X in the following sequence of reactions: NH Br2 / KOH C4H7OCl 3 C4H9ON CH3CH2CH2NH2
H3C
CO Cl
(A) H C 3
H3C
(B)
H3C
CO Cl
(C)
Cl
OH
(D) Cl
CHO
84.
COBr
Br
(A)
(B)
Br
Br
COOPh
(D)
61. 61.
Which of the following reagent/solution can be used to distinguish between methanoic acid and ethanoic acid? (A) Tollens reagent (B) FeCl3 solution (C) NaOH solution (D) Na2CO3 solution (A)
O
QB-CAD-7
Which gives only glucose by hydrolysis? (A) Sucrose (C) Maltose (C)
90. 68.
Amylose is a polymer of (A) -D-glucose (B) -D-glucose (C) -D-fructose (D) -D-fructose (A) There is desorpiton of physical adsorption when (A) temperature is increased (B) temperature is decreased (C) pressure is increased (D) concentration is increased (A) Al certain value of pH, the Zwitter ion of amino acid does not migrate towards any of the electrode under the influence of electric field. This pH value is called (A) isoelectric point (B) neutralization point (C) intectic point (D) end point (A)
electrolysis K+OOC(CH2)4COOK+ X + CO2 + H2 + KOH, X is: (A) n-butane (B) n-octane (C) cyclobutane (D) butane
68. 68.
C
H2C H2C CH2 COO K CH2 COO K
- + - +
H2C H2C
CH2 CH2
67.
Which statement is true about the relationship between Brnsted-Lowry (B-L) bases and Lewis bases? (A) A Lewis base must be a B-L base but a B-L base need not be a Lewis base. (B) A B-L base must be a Lewis base but a Lewis base need not be a B-L base. (C) B-L bases and Lewis bases are interchangeable. (D) There is no relationship between Lewis and B-L bases.
67.
Objective 6.
O O
3 A. A is
CH OH
(A) (C) 7.
CH2CH2 OH COOCH3
both are correct
10.
None is correct P2O5 A 4H The end product of the sequence Acetamide B is (A) CH3NH2 (B) C2H5NH2 (C) CH3CN (D) CH3COONH4 Select the suitable reagent [X] for
QB-CAD-8 CH=CHCH3 [ X]
(A) KMnO4/ (C) O3H2O A 7. b10.c
6.
4.
On standing in dilute aqueous acid the given compound is smoothly converted to CH3
O O CH3 , the compound A is CH2CO2H O
O (B) O CH2OH
(A) O
CH3
CH3 (C) O
9.
OH
COOCH3
COOCH3 (B)
Cl COOCH3
(D) OCH3
14.
4.
CH3CHO + H2NOH CH3CH = NOH. The above reaction occurs at (A) pH = 1 (B) pH = 4.5 (C) Any value of pH (D) pH = 12 A9. A14. B