Some exams questions and answers

Which of the following does not represent-1 ?a chemical change A)iron rusting B)reaction of sodium metal with water C)dissolving sugar in water D) souring of milk F)leaves changing color

C) dissolving sugar in water Which of the following does not represent-2 :a physical property A) boiling point C) density oxygen. B) odor D) reaction with F) solubility in water

Indicate the numbers of protons, neutrons :and electrons in the following atoms
64 30

Zn

109 47

Ag

14 6

243 95

Am

-A-1

Am: 95 protons, neutrons C : 6 protons neutrons Ag: 47 protons neutrons Zn: 30 protons neutrons

95 electrons, 6 electrons 47 electrons 30 electrons

148 8 62 34

Calculate the molecular mass of each of the following: Li2O, C3H7Br, (CH3CH2CH2)2O, KHSO3, N2O5, KNO2
(a) (b) (c) (d) (e) (f)

-Li2O= (7x2) + 16 = 30 g -C3H7Br = (3x16) + (7x1) + 80= 123 g -(CH3CH2CH2)2O = 102 g -KHSO3 = 39 + 1 + 32 + ( 3x16) = 120 g -N2O5 = ( 2x14) + (sx16) = 108 g -KNO2= 39 + 14 + (2x16) = 85 g moles of CO

-Calculate the number of present in a 125 g sample of (the gas. ) (6 marks

number of moles = mass in grams/molar mass number of moles of CO = 125/28 = 4.464 mol

Answer whether each of statement is true or false:

the

following

(Answer 5 only) (15 marks)

a. Bases react with many metals to produce ionic compounds and hydrogen gas. ( false) b. The molarity (M) so called molar concentration.( true ) c. Within a group, electronegativity increases from bottom to top.( true) d. Dilution increases the volume of a solution.( true) e. Acids turn the color of the indicator litmus from red to blue.( false) f. Matter is anything that has mass and occupies a size of space.( true)

5. The metal indium melts at 156C. The boiling point of the organic liquid cyclohexanol is 321 F. Will indium melt in boiling cyclohexanol? ) (6 marks) F = ( C x 1.8 ) + 32 F = ( 156 x 1.8 ) + 32 = 280.8 F yes Indium will melt in boiling point of cyclohexanol 6. Determine which of the following represent elements and which do not. C, CO, Cl, CaCl2, Na, KI C , Cl , Na : are elements , , KI : are not CO , CaCl

Which of the following pairs of symbols represent isotopes? (marks 4)

7.

and

186 74

66 28

and

57 28

E
70 33

,
E

186 74 70 34

and

44 22

and

22 11

8 4

and
70 34

7 3

E
70 33

and

are isotops

8. What are the names and symbols of the SI base units for length, ?mass and time mass = kg , time = second 9. Write: (10 marks) a) The molecular formula of Phosphorus Pentachloride .b) The name of SF6 a) - phosphorus pentachloride PCl) b) sulphur hexafluoride SF) Which of the following does not .10 ?represent a physical property A) color B) clarity C) hardness D) melting point E) flammability E) flammability does not represent a physical property

In the metric system, the prefix micro .11 represents the multiple A) 10-1. B) 10-2. C) 10-3. D) 10-6. E) 10-9. D)- 10-6. ?How many g in 580.4 mg-4

g 0.5804 Which metric prefix would replace the-5 ?power of ten in 3.68x10 m

mm 3.68

.Convert

184F to Celsius-6

C = F - 32/1.8 C = 184-32/1.8 = 48.44 During the course of a day, the .12 difference between the highest and the lowest temperature for the day was 9C. What was the ?temperature variation in F A) 5 B) 9.3 C) 16.6

D) 25.7 E) 34 F) 48.2 F = (C x 1.8 ) + 32 F = ( 9 x 1.8 ) + 32 = 48.2 7-What is the volume in L of 64.0 fluid ounce bottle? (1L=1.o6qt) and (1qt=32fl.oz). Number of Which of the following does not vary .13 ?with temperature A) volume B) mass C) density D) Kelvin E) C B) mass Aqueous HI is known as .14 .A) hydroiodic acid .B) hydrogen iodide .C) helium iodide .D) hydrogen monoidide .E) hyperiodous acid .A) hydroiodic acid What the PH of 0.001 M solution of -15 ?hydrochloric acid [ PH= - log [ H [ PH= - log [ 10 PH= 3 Calculate the PH value of a solution of -16 sulphoric acid containing 4.9 g per liter ?of the acid

the molar concentration of the acid= 4.9/98=0.05

the molar concentration of hydrogen ions [ H ]=0.05 x 2 = 0.1 mol/lit

[PH = - log [10 PH= 1 Calculate the PH value of 0.004 -17 solution of acetic acid, where the ionization ratio .constant () is 25% H ] = M x ] H ] = 0.004 x 0.25 = 10 ] [ PH= - log [ H [ PH = - log [ 10 PH = 3 Calculate the PH value of 0.001 M -18 ?solution of sodium hydroxide OH ] = 10 ] [ POH = - log [ OH [ POH = - log [ 10 POH = 3 We know that : PH + POH = 14 :So we write PH + 3 = 14

PH = 11

Q1-Answer only 15
1)-Which of the following is the correct formula of copper(1) oxide? a)CuO e) CuO b)CuO c) Cu(OH) d)CuO

2)-which of the following is not a physical property? (a)solid sulphur is yellow (b)diamond is highly hard (c)solid iron(Fe) melts at 1533C (d)carbon reacts with oxygen to form carbon dioxde (CO)

What is the right name of the following -(3 :compound

BaCl a)Bromuim Chloride , b)Barium Chloride , c)Barium Dichloride d)Barium(11)Chloride

Which of the following compounds are-(4 : insoluble in water a) CaCl b) NaCl e)Pb(NO) f) AgSO Regarding the following reaction, which-(5 ?statement is incorrect Cu + 2Ag Cu + 2Ag c)Fe(OH) d)FeCl

a)copper is oxidized b)copper is reduced c)Ag is reducing agent d) silver is oxidized

Which of the following has the highest-(6 :ionization energy value a) Cu e)O , b) F , c)Na , d) C ,

:Which of the following orbitals fills first-(7 a) 3d b)3p c)4f d)3s e)4d

Which of the following is the best -(8 :electrical conductor a) 0.6 M HNO b)0.4 M CHCOOH , c) 1.0 M CHCHOH d)0.14 M HCl e)0.8 M HSO f) 0.80 M NHOH

Predict which of the following bond is the -(9 :shortest

Which of the following is the correct-(10 :Lewis symbol for an atom of Cl

11)Which of the following bonds is the most polar bond: a)C-O b)NaBr c)N-O d)Cl-Cl e)S-O

12)- Indicate the oxidation number of the underined atom in each of the following: a)KMnO b)Mg(ClO) C)KCrO

13)- Which of the following diagrams is not allowed:

14)-Given the following equation: 2H(g) + O(g) 2HO(l) 571.6kJ/mol Which statement is incorrect?
a) H for the reverse reaction is + 571.6 kJ/mol b) H for the forming one mole of liquid water is -285.8 kJ/mol c) H for the reaction of one-half mole of oxygeb is -285.8kJ/mol d) The equation forming gaseous water would have different H e) The standard heat of formation of liquid water is -571.6 kJ/mol.

H =-

15)-How many protons, electrons and neutrons are there in the following atoms:

16)- The emperical fornula of dichloro butane is CHCl and its molecular mass is 127 u , what is the molecular formula?

17- calculate the formal charge of the nitrogen atom in the compond:

Q2- Identify if the following statements are

correct or wrong. 1-( ) the chemical property displayed by the matter as it does not undergo any change in the composition. 2-( ) kandela is a SI unit

3-( ) electron affinity is the energy required to remove one electron from an isolated atom at the gas state and ground state. 4-( ) work is the transfer of energy between the system and its serroundings. 5-( ) the isotopes are atoms of different atoms having the same mass number and different atomic number.

Q2- Follow the instruction given for each

question and answer the following : Calculate the consumed amount and the remaining amount of oxygen during the reaction of 14.4 g of CH in 100 g of oxygen :
a-

CH +

CO

HO

Answer: 1- we have to balance the equation: CH + 18O 5CO + 6HO

to solve the problem, we write: CH + 8O 5CO + 6HO

72 g 14.4g

8x32g x

3- The consumed amount of oxygen= X= 14.4g x 256 g/72 g = 51.2 g 4the remainin amount of oxygen=

100 51.2 = 48.8 g

b-when 0.20 mol of magnisum Mg is reacted with excess of nitrogen, how many moles of nitrogen are consumed? 3Mg + N MgN

c- what mass of NaOH, in grams is required to prepare 120 ml of 0.20 M of NaOH solution?

d- Calcium oxide reacts with carbon dioxide to form calcium carbonate : CaO(s) + CO(g) CaCO(s) H= - 178.4 kJ What is the heat evolved in the formation of 500 g of CaCO ?

e-use the following equations: N(g) + 2O(g) NO(g) H=9.2 kJ N(g) + 2O(g) 2NO(g) H=33.2 kJ to calculate the enthalpy change for the reaction: 2NO(g) NO(g) H=?

f-write the electron configuration for copper Cu (Z=29) using both : spdf notation and orbital diagram, then the noble gas abbreviation.

g- use the lewis theory to show the ionic bond of Ca & Cl .

h- write the resonance structures of SO accourding to Lewis's theory, the show the formal charge of each atom.

i- how would you prepare 500 ml of an aqueous solution that is 3.0 % KOH by mass.

j- what is the concentration in ppm of 0.40 g of NO in one litter of water. Answer: 1 ppm = 1 mg/liter The number of ppm ( miligrams ) per liter= 0.40x1000= 400 ppm

k-what is the molality of sodium chloride NaCl in a solution containing 117 g of this salt in 360 ml of water. Answer : Molality = the number of moles of the solute/the mass of the solvent in Kg 1- the molar mass of NaCl = 23 + 35.5 = 58.5 g 2- the number 117/58.5 =2 mol
3-

of

moles

NaCl)

the mass of the solvent( HO)=360g = 0.360 Kg 4- the molality= 2/0.360=

l-Arrange the following in order of increasing the first ionization energy: C, N, F, O, Be

m-Arrange the following in order of increasing the electronegativity: O, AS , P

Q4- Define the following terms:(answer only

four) (a) Nonmetals (b) Ionic Bond (c) Molecule (d) Electron Affinity (e) Standard Enthalpy of Formation

GOOD LUCK