C

CCR
RRP
PP-
--P
PPA
AAP
PPE
EER
RR-
--1
11


P
PPA
AAR
RRT
TT -
-- I
III
II:
:: C
CCH
HHE
EEM
MMI
IIS
SST
TTR
RRY
YY

SECTION 1 : Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. Arrange the following species according to increasing oxidation no. of carbon.
(I) CH
4
(II) CH
3
OH (III) HCHO (IV) HCOOH.
(A) I > II > III >IV (B) I < II < III < IV
(C) IV < III < I < II (D) IV < II < III < I

2. The equivalent wt. of KMnO
4
(M.W = 158) in acidic, neutral and alkaline medium are.
(A)
158 158 158
, ,
1 5 3
(B)
158 158 158
, ,
5 3 1
(C)
158 158
158/ 3, ,
1 5
(D) All of these

3. For the 4
th
energy level of an atom, the maximum number of sub-shells, orbitals and electrons are
(A) 4, 8, 16 (B) 4, 4, 32 (C) 4, 16, 32 (D) 4, 4, 16

4. Considering atomic numbers 2, 4, 24 and 42, identify the INCORRECT statement.
(A) Maximum first ionisation potential belongs to Z = 2.
(B) Z = 24 and Z = 42 belong to the same group of the periodic table.
(C) All elements with the above atomic numbers form oxides that are basic.
(D) None of the above atomic numbers belong to the f-block.

5. Two separate bulbs containing ideal gases A and B are taken. Density of A is twice that of B. Molecular
weight of A is half that of B. If the two gases are at the same temperature, the ratio of the pressure of A to that
of B is?
(A) 1:2 (B) 2:1 (C) 4:1 (D) 1:4

6. The polarisablity of halide ion increasing in order
(A) F

< I

< Br

< Cl

(B) F

< Cl

< Br

< I


(C) I

< Br

< Cl

< F

(D) Br

< Cl

< F

< I

7. Elements X and Y have valence shell electron configuration as X = ns
2
np
5
; Y = ns
2
np
3

Which compound is likely formed form X and Y?
(A) X
3
Y
5
(B) Y3X5

(C) XY (D) YX
5


8. A diatomic molecule has a dipole moment of 1.92 D and bong length of 2.0 . What is the percentage ionic
character of the molecules?
(A) 33% (B) 20% (C) 70% (D) 50%

9. Which of the following is wrong statement?
(A) H
2
and D
2
posses same physical properties
(B) H
2
and D
2
can be separated by using their rate of reactivity towards Cl
2

(C) H
2
O is stronger acid than D
2
O
(D) When water (H
2
O + D
2
O) is electrolysed, H
2
is liberated much faster than D
2

10. Which of the following are isoelectronic?
(A)
2
3 3 3
NO , CO , ClO

(B)
2
3 3 2
NO , CO , SO

(C)
2
3 3 2
CO , ClO , SO

(D) None of these

SECTION 2 : Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE are correct.
11. 5 moles of H
2
SO
4
will exactly neutralise:
(A) 5 moles of NaOH (B) 10 equivalents of KOH
(C) 10 equivalents of Ca(OH)
2
(D) 5 moles of Ca(OH)
2


12. A molar volume of a van der Waals gas can be liquefied:
(A) at Boyles temperature under high pressure
(B) at critical temperature, under a pressure more than critical pressure
(C) at critical pressure when it is cooled below the critical temperature
(D) at very high pressure and above critical temperature

13. Be and Al show diagonal relationship and thus
(A) their oxides are soluble in alkali solution forming
( ) ( )
3 2
4 6
Be OH and Al OH

( (


(B) they form complex anion
2 3
4 6
BeF and AlF


(C) BeCl
2
and AlCl
3
are Lewis acids
(D) oxides are basic

14. Which of the following has tetrahedral structure?
(A) PCl
3
(B)
4
BF

(C) CCl
4
(D)
4
NH
+


15. Which of the following is amphoteric?
(A) Zn(OH)
2
(B) CO (C) Al(OH)
3
(D) Be(OH)
2


SECTION 3 : Integer Answer Type


This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).
16. Find the quantum number n corresponding to the excited state of He
+
ion if on transition to the ground state
that ion emits two photons in secession with the wavelengths 108.5 and 30.4 nm respectively.

17. 1 mole of Cu
2
S is oxidised to Cu
2+
and S. What is the n-factor of Cu
2
S?

18. What is the Bond order of
2
2
O
+
?

19. Two grams of hydrogen diffuse from a container in 10 minutes. How many grams of oxygen would diffuse
through the same container in the same time under similar conditions?

20. How many of the following relations are correct regarding the given property?
(1) C < N > O < F: First ionization enthalpy
(2) Cl > F > Br: First electronaffinity
(3) O > S > Se: Electronegativity
(4) Li > Be > B: Second ionization enthalpy
(5) F
-
> O > Mg
2+
: Electronegativity
(6) B > Be > Li: Covalent radii
(CHEMISTRY)

1. B 2. B 3. C 4. C
5. C 6. B 7. D 8. B
9. A 10. B 11. B, C, D 12. B, C
13. A, B, C 14. B, C, D 15. A, C, D 16. 5
17. 4 18. 3 19. 8 20. 3

C
CCR
RRP
PP-
--P
PPA
AAP
PPE
EER
RR 2
22
P
PPA
AAR
RRT
TT -
-- I
III
II:
:: C
CCH
HHE
EEM
MMI
IIS
SST
TTR
RRY
YY

SECTION 1 : Single Correct Answer Type
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1. The frequency of first line of Balmer series in hydrogen atom is v
o
. The frequency of corresponding line
emitted by single ionised helium atom is
(A) 2v
o
(B) 4v
o
(C) v
o
/2 (D) v
o
/4

2. Chlorine gas can be produced by reaction of sulphuric acid with a mixture of MnO
2
and NaCl. The reaction
follows the equation:
2 2 4 4 4 2 2
2NaCl MnO 3H SO 2NaHSO MnSO Cl 2H O + + + + + . What volume of chlorine
can be produced from 1 g of sodium chloride under standard conditions of temperature and pressure?
(A) 1.915 L (B) 19.15 L (C) 20.22 L (D) 0.191 L

3. At 400 K, the root mean square speed of a gas X (molecular weight = 40) is equal to the most probable speed
of a gas Y at 60 K. The molecular weight of the gas Y is
(A) 20 (B) 16 (C) 4 (D) 32

4. 4 grams of SO
2
gas diffuses from a container in 8 min. Mass of helium gas diffusing from the same container
over the same time interval under similar condition is
(A) 0.5 gram (B) 1 gram (C) 2 gram (D) 16 gram

5. The ionisation potential for the electron in the ground state of hydrogen atom is 13.6 eVatom
-1
. What is
ionisation potential for the electron in the first excited state of Li
2+
?
(A) 3.4 eV (B) 10.2 eV (C) 30.6 eV (D) 6.8 eV
6. Among LiCl, BeCl
2
, BCl
3
and CCl
4
, the covalent character follows the order
(A) LiCl < BeCl
2
> BCl
3
> CCl
4
(B) LiCl > BeCl
2
< BCl
3
< CCl
4

(C) LiCl < BeCl
2
< BCl
3
< CCl
4
(D) LiCl > BeCl
2
> BCl
3
> CCl
4

7. The shapes of
4 4 3
PCl , PCl and AsCl
+
are respectively
(A) square planar, tetrahedral, see-saw
(B) tetrahedral, see saw and pyramidal
(C) tetrahedral, square planar and pentagonal bipyramidal
(D) trigonal bipyramidal, tetrahedral and square pyramidal

8. The solubility (in water) order of the following MgCO
3
, CaCO
3
, BaCO
3
, SrCO
3
is
(A) MgCO
3
> CaCO
3
> BaCO
3
> SrCO
3
(B) CaCO
3
> MgCO
3
> BaCO
3
> SrCO
3

(C) SrCO
3
> CaCO
3
> BaCO
3
> MgCO
3
(D) MgCO
3
> CaCO
3
> SrCO
3
> BaCO
3


SECTION 2 : Paragraph Type
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 9 and 10

1 L of 1 M NaOH is mixed with 1 L of 1 M NaHCO
3
in a vessel. This mixture is titrated with 1 M HCl. In another
experiment, 3 L of 1 M NaOH and 1 L of 1 M NaHCO
3
are mixed and titrated with 1 M HCl.

9. The volumes of HCl required for the end points for the two mixtures using phenolphthalein as indicator are
(A) 2 L and 3 L (B) 1 L and 2.5 L (C) 1 L and 2 L (D) 1 L and 3 L

10. The volumes of HCl required for the end points for the two mixtures using methyl orange as indicator are
(A) 2 L and 4 L (B) 2 L and 3 L (C) 1 L and 4 L (D) 2 L and 2 L

Paragraph for Questions 11 and 12

The observed wavelengths in the line spectrum of hydrogen atom sample were first expressed in terms of a series by
Jakob Balmer, a Swiss teacher
Balmers empirical formula is
H 2 2
1 1 1
R
2 n
(
=
(

n = 3, 4, 5.
R
H
= 109678 cm
1
is the Rydbergs constant
Neils Bohr derived this expression theoretically in 1913. The formula is generalized to any one electron atom/ion.

11. Calculate the longest wavelength in in the Balmer series of singly ionized helium He
+
.
(A) 2651 (B) 1641.1 (C) 6569 (D) 3249

12. How many lines in the spectrum will be observed when electrons return form 7
th
shell to 2
nd
shell?
(A) 13 (B) 14 (C) 15 (D) 16

Paragraph for Questions 13 and 14

Johannes van der Waals suggested a somewhat corrected version of the ideal gas law. It is one of the simpler
equations of state for real gases and is referred to as van der Waals equation:
( )
2
2
an
P V nb nRT
V
| |
+ =
|
\ .

where 'n is number of moles of gas and a and b are van der Waals constant.

13. Select the INCORRECT statement:
(A) The value of b is given by
3
A
4
N r 4
3
| |
t
|
\ .
where r is radius of gas molecule
(B) At low pressure the van der Waals equation is reduced to
m
PV a
1
RT V RT
=
where V
m
is molar volume of gas
(C) At high pressure the van der Waals equation is reduced to
m
PV Pb
1
RT RT
= +
(D) Higher is the value of compressibility factor, more easily can the gas be liquefied

14. Which of the following gases will have highest value of van der Waals constant a?
(A) NH
3
(g) (B) H
2
(g) (C) He(g) (D) F
2
(g)


SECTION 3 : Multiple Correct Answer(s) Type

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE are correct.
15. Rate of diffusion and effusion is
(A) directly proportional to pressure difference of the gas diffusing or effusing
(B) directly proportional to area of cross section of aperture
(C) inversely proportional to square root of molar mass or density
(D) independent of temperature

16. van der Waals constant a and b for hydrogen gas are 0.246 l
2
atm mol
-2
and 0.0267 l mol
-1
respectively
then identify the correct statement (s) among the following:
(A) critical temperature of H
2
gas is 33.25 K
(B) Boyle temperature of H
2
gas is 112.2 K
(C) critical compressibility factor is 0.375
(D) critical volume of H
2
gas is 0.080 l/mol.

17. Which of the following statement is/are correct?
(A) Number of radial nodes for 3d orbital is zero
(B) Number of angular nodes for 3d orbital is 2
(C) Number of nodal planes for 2p orbital is 1
(D) Total number of nodes in 3s orbital is 2

18. Which of the following represents the correct order of increasing bond order?
(A)
2 2 2
O O O
+
< < (B)
2
2 2 2
N N N
+
< <
(C) BN < NO < CN
-
(D) CO < NO < CN
-


19. Which of the following set(s) of ions, represent the correct order of ionic radii?
(A) S
2
> K
+
> Ca
2+
(B) Na
+
< Al
3+
< Mg
2+

(C) Ca
2+
> K
+
> S
2
(D) Na
+
> Mg
2+
> Al
3+


20. The set of quantum numbers which are impossible for an electron are
(A)
s
1
n 1, 0, m 1, m
2
= = = = + (B)
s
1
n 2, 2, m 1, m
2
= = = =
(C)
s
1
n 1, 0, m 0, m
2
= = = = + (D)
s
1
n 2, 1, m 2, m
2
= = = =

Chemistry [PART-II]

1. B 2. D 3. C 4. B
5. C 6. C 7. B 8. A
9. D 10. A 11. B 12. C
13. D 14. A 15. A, B, C 16.A, B, C, D
17. A, B, C, D 18. B, C 19. A, D 20. A, B, D


ITY
Chemistry PAPER-1
Part II

Single Answer Question.
1. Total no of electrons in
2
Cu
+
for which the summation of azimuthal quantum number and
magnetic Quantum number is zero
(a) 4 or 8 (b) 11 or 12 (c) 5 or 6 (d) 10 or 11

2. Proton having energy equivalent to binding energy 4
th
state of He
+
ion is used on the
metal surface having work function of 1.4 eV. The electrons ejected are further
accelerated through the potential difference of 4V then the minimum value of de-Broglie
wave length associated with the electron is _____
(a) 1.1
0
A (b) 9.15
0
A (c) 5
0
A (d) 11
0
A

3. How many moles are there in 1 m
3
of any gas at STP ?
(a) 44.6 mole (b) 4.46 mole (c) 0.0224 moles (d) 22.4 mole

4. Identify the correct order of the size of the following
(a)
2 2
Ca K Ar Cl S
+ +
< < < < (b)
2 2
Ar Ca K Cl S
+ +
< < < <
(c)
2 2
Ca Ar K Cl S
+ +
< < < < (d)
2 2
Ca K Ar S Cl
+ +
< < < <

5. The weight of sulphuric acid needed for dissolving 3g magnesium carbonate is
(a) 3.5 g (b) 7.0 g (c) 1.7 g (d) 17.0 g

More than one correct option questions
6. Which of the following have same mass ?
(a) 1.0 mole of O
2
(b) 310
23
molecules of SO
2

(c) 0.5 moles of CO
2
(d) 1 g atom of sulphur

7. 100 ml of 0.06 M Ca(NO
3
)
2
is added to 50 ml of 0.06 M Na
2
C
2
O
4
. After the reaction is
complete
(a) 0.003 moles of calcium oxalate will get precipitated (b) 0.003 M of excess
of Ca
2+
will remain in excess
(c) Na
2
C
2
O
4
is limiting reagent. (d) Ca(NO
3
)
2
is excess reagent.

8. Which of the following ion leads to hardness of water?
(a)
2
Mg
+
(b)
2
3
CO

(c)
2
Ca
+
(d) OH

9. The relationship between mole fraction ( ( )
A
X of the solute & molality m of its solution in
ammonia would be
(a)
( ) 1
58.82
A
A
X
m
X

= (b)
( ) 58.82
1
A
A
X
m
X
=

(c)
55.56
1
A
A
X
m
X
=

(d)
( ) 55.56 1
A
A
X
X

Comprehension 1
In a reaction vessel 100g of H
2
and 100g of Cl
2
are mixed and suitable conditions are
provided for the following reaction, ( ) ( ) ( ) +
2 2
H g Cl g 2HCl g
Based on the above information answer the following questions (Q. 10- Q.12)

10. The limiting reagent in this reaction is
(a) H
2
(b) Cl
2
(c) both (d) can not be
predicted

11. The actual amount of HCl formed in this reaction is
(a) 102.8 g (b) 73 g (c) 36.5 g (d) 142 g

12. The amount of excess reactant remaining
(a) 50 g (b) 97.2 g (c) 46 g (d) 64 g


Comprehension 2
In the titration of Alkali mixture eg.
2 3
Na CO ,
3 2 3
& NaHCO Na CO two indicators phenolphthalein
and methyl orange are used. For the titration of
2 3
Na CO with acid using phenolphthalein
as indicator the miliequavelents of acid are utilized only for the end point upto
3
NaHCO
state. How ever in the titration with methyl orange as indicator the miliequavelents of
acid corresponds to total miliequavelents of alkali present at that time in mixture.
With this information one student stated the titration of 50 ml of a solution containing 23
gm of mixture of
3 2 3
, & NaOH NaHCO Na CO with 1M
2 4
H SO and found the following
observations
(a) When titrated using phenolphthalein indicator 100 ml of
2 4
H SO is used
(b) When titrated using methyl orange indicator 200ml of
2 4
H SO is used
Based on the above information answer the following questions (Q. 13- Q.15)

13. Amount of
2 3
Na CO in 50 ml of solution
(a) 5.3 gms (b) 10.6 gms (c) 8.4 gms (d) 4.2 gms

14. Amount of
3
NaHCO in 50 ml of solution
(a) 16.8 gms (b) 4.2 gms (c) 8.4 gms (d) 2.1 gms

15. Amount of NaOH in 50ml of solution
(a) 4 gms (b) 2 gms (c) 8 gms (d) 11 gms

Assertion and Reasoning
Directions: The questions (16 - 18) given below consists of an Assertion (A) and Reason
(R). Use the following key to chose the appropriate answer.
(a) Both A and R are true and R is correct explanation of A
(b) Both A and R are true but R is not correct explanation of A.
(c) A is true, R is false .
(d) A is false, R is true.

16. A: Boron has relative atomic mass 10.81
R: Boron has two isotopes B and B
10 11
5 5
and their relative abundance is 19% and
81%.

17. A: First ionization energy of nitrogen is lower than oxygen
R: Across the period effective nuclear change increases

18. A: Equivalent of oxalic acid ( )
2 2 4
H C O is molecular wt/2 when completely
neutralized by base
R: Change in oxidation no of oxalic acid is 2 when treated with
4
KMnO

Numerical
N1. What hydrogen like ion has the wave length difference between the first line of
Balmer and Lyman series equal to 59.3 nm.
( )
5 1
1.1 10
H
R cm

=

N2. Calculate the volume strength of
2 2
H O having concentration 60.7 gm /litre (Write
your answer in nearest integer value)

Match the following.
M1. Match the electronic transactions of hydrogen atom column I with spectrial properties
column II
COLUMN I COLUMN II
A
6 3 n n = =
P 10 lines in the spectrum
B
7 3 n n = =
Q Spectral lines in visible region
C
5 2 n n = =
R 6 lines in the spectrum
D
6 2 n n = =
S Spectral lines in infrared region

M2. Match the compound of column I with correct coefficient in the balanced equation
given below
2 5 2 3
C H OH I CHI H COO I

+ + + (Basic medium)
COLUMN I COLUMN II
A 3
CHI
P 6
B HCOO

Q 1
C OH

R 2
D 2
H O
S 5
M3.
COLUMN I COLUMN II
A s block element P
| |
14 6 2
4 5 6 Xe f d s
B p block elements Q
| |
2
6 Xe s
C d block elements R
| |
14 10 2 2
4 5 6 6 Xe f d s p
D f block elements S
| |
11 0 2
4 5 6 Xe f d s
M4.
COLUMN I COLUMN II
A
10 volume
2 2
H O
P m = 2.79 moles /kg
B
3M NaCl Solution with
( )
3
1.25 / d gm cm =
Q M = 5 moles /lit
C
Mole fraction of ethanol in
3
2
0.1( 1.04 / ) H O d gm cm = =
R M = 0.892 mol/lit
D
20% ( ) / wt vol of NaOH (aq) solution
S m = 6.17 moles/kg

Chemistry
1.B 2. C 3. A 4. A 5. A
6. A,B,D 7.A,C,D 8. A,C 9. B
10. B 11. A 12. B
13. B 14.C 15.A
16. A 17. D 18.B
N1.0003 N2. 0020
M1. A R,S B P,S C Q,R D P,Q
M2. A Q B Q C P D S
M3. A Q B R C P D S
M4 A R B P C Q,S D Q

ITY
Chemistry PAPER-2 Part
II

Single Answer Question
1. 50 mL of 0.03M H
3
PO
4
and 25 mL of 0.1 M Ba (OH)
2
are mixed to give a ppt of
Ba
3
(PO
4
)
2
. Molarity of the excess reactant is
(a) 0.03 (b) 0.0033 (c) 0.0133 (d) 0.15

2. Weight of MnO
2
(M.W. = 87) and volume of 12 M HCl needed for the preparation of 1.5
mole of Cl
2
are respectively (other products are MnCl
2
and H
2
O)
(a) 130 g ; 5000 mL (b) 5000 g ; 1300 (c) 130 g ; 500 mL
(d) 500g ; 130 mL

3. The momentum of a particle associated with deBroglies wavelength of 6 A is
(a)
24 1
1 1 10 . kg ms

(b)
34 1
1 1 10 . kg ms


(c)
34 1
39 6 10 . kg ms

(d)
24 1
39 6 10 . kg ms



4. Number of moles of KMnO
4
required to oxidize one mole of FeC
2
O
4
in acid medium is
(a) 0.6 (b) 1.67 (c) 0.2 (d) 0.4

5. In which of the following reaction H
2
O
2
is a reducing agent.
(a)
2 2 2 3 2
2FeCl +2HCl +H O 2FeCl +2H O (b)
2 2 2 2
Cl + H O 2HCl +O
(c)
2 2 2 2
2HI +H O 2H O+I (d)
2 3 2 2 2 4 2
H SO +H O H SO +H O


More than one correct option questions
6. Which of the following give out 11.2 L of O
2
at STP per mole of the compound ?
(a)
2
HgO Hg O +
A
(b)
3 2
KClO KCl O +
A

(c)
2 2 2
N O N O +
A
(d)
2 2
Ag O Ag O +
A


7. 11.2L of a gas at STP weighs 14g. The gas could be
(a) N
2
O (b) NO
2
(c) N
2
(d) CO

8. 1 gm
3
O contains.
(a) same no of O atom as in 1 gm
2
O (b)
1
2
mole of e

(c) 0.466 lits at 1 atm, 25
0
C (d)
48
A
N
molecules
9. K having atomic no 19 contains.
(a) 12 e

having azimuthal 1 Quantum Number l =

(b) 4e

having magnetic Quantum Number m = + 1

(c) 11 e

having magnetic 0 Quantum Number m=

(d) 8e

having principle 3 Quantum Number n =

Comprehension 1
The observed wavelengths in the line spectrum of hydrogen atom were first expressed in
terms of a series by Johann Jakob Balmer a Swiss teacher. Balmers emphrical formula is.
2 2
1 1 1
3, 4, 5.....
2
H
R n
n

| |
= =
|
\ .

Hence
4
1
2 3
0
109678
8
H
me e
R cm
h C c

= = is the Rydbarg constant.
10. Longest wavelength in
0
A in Balmer series of singly ionized
helium ( ) He
+
____________
(a) 1641 (b) 164 (c) 912 (d) 91
11. Shortest wavelength in
0
A in Balmer series of hydrogen
____________
(a) 6564 (b) 656 (c) 3647 (d) 364

12. Wave length in
0
A in Balmer series if any transition takes
place from n = 4 for Li
2+

(a) 5403 (b) 540.3 (c) 54 (d) 1641

Comprehension 2
Carbon reacts with oxygen to yield carbon monoxide or carbon dioxide, depending on the
quantity of oxygen available per mole of carbon. If excess of O
2
is available after initial
formation of carbon monoxide, then carbon dioxide is produced.
C+O
2
CO
CO + O
2

CO
2

100 g of oxygen is reacting with different amounts of carbon as given in the following
questions. Find out the number of moles of CO and CO
2
in each of the following cases.
13. 10 g of carbon
(a) O,

3.125 (b)3.125, 3.125 (c) O, 0.833 (d)0.833, 3.125
14. 100 g of carbon
(a) 6.25,0 (b) 3.125, 6.25 (c) 6.25, 3.125 (d) 0, 6.25
15. 60 g of carbon
(a) 1.25, 3.75 (b) 3.75, 1.25 (c) 1.3, 3.7 (d) 4,2

Assertion and Reasoning
Directions: The questions (16 - 18) given below consists of an Assertion (A) and Reason
(R). Use the following key to choose the appropriate answer.
(a) Both A and R are true and R is correct explanation of A
(b) Both A and R are true but R is not correct explanation of A.
(c) A is true, R is false .
(d) A is false, R is true.
16.
A:
The angular momentum of d-orbital is 6
2
h
t


R:
d-orbital have double dumb-bell shaped except
2
z
d

17. A: The kinetic energy of photoelectrons increases with increase in frequency
of incident light.
R: The no of photoelectron ejected increases with increase in intensity of light.

18. A: The first ionization energy of N is more than that of O.
R: Oxygen after losing one electrons gets a stable configuration.

Numerical
N1.
The wavelength of a certain line in Balmer series for Hydrogen atom is
observed to be 4341 A
-
. To what value of n
2
does this correspond ? (R
H
= 1.1
10
5
cm
-1
)
N2. P and Q are two elements which forms
2 3
P Q and
2
PQ . If 0.15 mole of
2 3
P Q
weighs 15.9 gm and 0.15 mole of
2
PQ weighs 9.3 gm what is the sum of atomic
weights of P and Q.

Match the following
M1.
COLUMN I COLUMN II
A Lyman series P Visible region
B Balmer series Q UV region
C Pfund series R IR region
D Light emitted by sodium lamp S None of the above region

M2.
COLUMN I COLUMN II
A 52g of He P
13 atoms
B 52 moles of He Q 44.8 L
C 34 g of NH
3
R 313.196 10
23
atoms
D 52 u of He S 78.299 10
23
atoms

M3.
COLUMN I COLUMN II
A
2 2 2
2 2
1 1
H O H O
g g
+

P 0.56 g of CaO
B
2 2 3
3 2
1 1
N H NH O
g g
+

Q 1.333 g
C
3 2
1
CaCO CaO CO
g
+

R 1.125 g
D
2 4
2
1 1
H C CH
g g
+

S 1.214 g
M4.
COLUMN I COLUMN II
Reaction

n factor of the underlined compound
A 3 2 2
SO SO O +
P
2
B 3 2 2
NH N H +
Q
7
C
2
4 2
( ) Mg MnO Mn
+

R
3
D 2 2 2 2
H O H O O +
S
10

Chemistry
1. B 2.C 3.A 4.A 5.B
6. A,C,D 7. C,D 8. A,B,D 9. A,B,C,D
10. A 11. C 12. B
13. C 14. A 15. B
16. B 17. B 18.A
N1. 0044 N2. 0005
M1. A Q B P C R D P
M2 A S B R C Q D P
M3. A R B S C P D Q
M4. A P B R C S D P