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SOLUTIONS & COLLIGATIVE PROPERTIES
IIT-JEE
CONCENTRATION
1) Match the following
A) Gas in solid 1) Soda water
B) Solid in liquid 2) Brine solution
C) Solid in solid 3) Air
D) Gas in liquid 4) H2 occluded in Pd
5) Magnalium
Correct matching
m
A B C D
ail N
1) 4 2 5 3
gm DHA
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2) 4 5 2 1
3) 4 2 3 5
4) 4 2 5 1
Hint : Soda water = CO 2 in water
Brine i@ R= NaCl in Water
Air = O 2 (and other gases) in N 2
ad VA
Magnalium = Mg (1-15%) in Al (99-85%)
2) Not a homogeneous mixture
1) Soda water 2) aqueous sugar solution
3) Sodium amalgam 4) Milk
em TYA
Note : In case of milk, fine liquid fat particles are dispersed in water. It is not a true solution.
3) The molarity of 500 cc of solution containing 0.2 moles of NaCl.
1) 0.2 mole L-1 2) 0.4 mole L-1 3) 0.1 mole L-1 4) 0.8 mole L-1
Hint : Molarity is no. of moles of solute per litre of solution.
ich DI
4) The molarity of H2SO4 solution is 2 M at 27oC. What will be its molarity at 100oC ?
1) = 2 M 2) < 2 M 3) > 2 M 4) All
ad V. A
m
ail N
14) The weight of NaOH in 10 mL of 2 m NaOH solution of specific gravity 1.08 is
1) 0.8g 2) 1.6 g 3) 2 g 4) 1.08 g
gm DHA
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w
15) The molality of 20% w NaOH solution is.
1) 20 m 2) 2 m 3) 6.25 m 4) 2.65 m
Hint: weight of solvent = weight of solution - weight of solute
16) What is the molality of 9.8% H2SO4 solution of specific gravity 1.098
1) 1 m 2) 1.098 m i@ R
3) 9.8 m 4) 2 m
ad VA
Hint : First calculate weight of the solution
weight = density X volume
17) 120 g of NaOH is added with one litre of water. The molarity of the solution formed is
em TYA
22) 4.9 g of H2SO4 is present in 250 mL of solution. The molarity and normality of the solution are ,
respectively.
1) 0.1 M & 0.2N 2) 0.2M & 0.4N 3) 0.2 M & 0.2N 4) 0.1 M & 0.1N
23) The weight of H3PO4 in 500 mL of 0.3N H3PO4 solution is.
1) 0.3 g 2) 9.8 g 3) 0.98 g 4) 4.9 g
Hint : Basicity of H PO = 3
3 4
24) The normality of 5.7% Al2(SO4)3 solution is
1) 5.7 N 2) 2 N 3) 1 N 4) None
FW
Hint: EW of Al 2 (SO 4 ) 3
6
25) The specific gravity of 31.6% w/w KMnO4 solution is 1.5. The normality of the solution in the
acidic medium is
1) 15 2) 1.5 3) 31.6 4) 3.16
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w
% X d X 10
w
Formula : N
G .E .W
7+ 2
Hint : Mn Mn (in acidic medium)
m
1) 5.26N 2) 1N 3) 3.16N 4) 2N
ail N
7+ 4
Hint : Mn Mn (in basic medium)
gm DHA
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29) The number of H+ ions in 100 mL of 0.1M H2SO4
1) 6.023 X 1021 2) 1.2046 X 1022 3) 3.10 X 1021 4) All
30) The solution with least molarity is
1) 1N HCl 2) 1N H2SO4 3) 1N Na3PO4 4) None
i@ R
31) The amount of HNO3 to be added to double the concentration of 500mL of 1M HNO3.
ad VA
1) 63 gr 2) 6.3 gr 3) 31.5 gr 4) 12.6 gr
32) The ratio of volumes of 2 M and 4M solutions to be mixed to get 500mL of 3M solutions.
1) 1 : 2 2) 1 : 1 3) 2 : 1 4) 2 : 4
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33) 500 ml of 0.4M Na3PO4 solution is diluted to 0.1M solution. The volume of solvent
required is.
1) 2000 mL 2) 1500mL 3) 1000mL 4) All
H in t : U se M V M V
1 1 2 2
ich DI
N N
35) 10 mL of HCl solution is mixed with 125 mL of H 2 SO4 and the resultant solution is
2 5
made up to 1 Litre. The normality of the final solution is
1) 0.03 N 2)0.01 N 3) 0.3 N 4) 0.5 N
36) What are the volumes of 3M HCl and 5M HCl solutions, respectively, to be mixed to get 2
litres of 3.5M HCl solution?
1) 1.5 L & 5 L 2) 2 L & 3 L 3) l L & l L 4) 1.5 L & 0.5 L
-
37) Equal volumes of lM KNO3 and lM Al (NO3)3 solutions are mixed. The concentration of NO3
ions in the final solution is
1) 2M 2) 1M 3) 4M 4) 0.5M
-
Note : 1M Al(NO 3)3 contains 3M NO ions.
3
38) 10 mL of 1M Na2 CO3 solution is made upto 1 litre by adding water. The normality of the final
solution is
1) 0.01 N 2) 0.1 N 3) 0.2 N 4) 0.02 N
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-
39) 20 mL of 1M NaCl is added to 10 mL of 2 M AgNO3 . The concentration of Cl ions in the final
solution is
1) 0.5M 2) 0. 4M 3) 1.5M 4) None
- -
Note : All the Cl ions are precipitated out as AgCl. Hence the final concentration of Cl will be almost zero.
40) Which of the following solutions contains more number of ions?
1) 9M KNO3 2) 8M NaCl 3) 4M Al2 (SO4 )3 4) 6M Na2 SO4
41) A 0.02N NaCl solution is diluted by 100 times. The number of moles of NaCl will be
1) increased 2) decreased 3) unchanged 4) Cannot say
Hint : There is no change in the number of moles of solute during dilution. Only the concentration is changed.
42) Which of the following graph represents the variation of molality (m) with temperature (T)
1) 2)
m
ail N Molality (m)
Molality (m)
gm DHA
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T emperature (T) T emperature (T)
i@ R
3) 4)
ad VA
Molality (m)
Molality (m)
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m
46) 300 mL of 0.1M BaCl2 is added to 100 mL of 0.1M Na3 PO4 . The amount of Ba3 (PO4 )2
ail N
precipitate formed is
gm DHA
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1) 10-3 moles 2) 2 x 10-3 moles 3) 5 x 10-3 moles 4) 5 x 10-2 moles
Hint : 3 BaCl2 + 2 Na3PO 4 Ba3 (PO 4 )2 + 6 NaCl
3 moles 2 moles 1 mole
47) Choose the incorrect statement.
1) One equivalent weight of an acid is completely neutralised by one equivalent weight of a
i@ R
base
ad VA
2) One mole of an acid is always completely neutralised by one mole of a base.
3) One equivalent weight of an oxidising agent oxidises one equivalent weight of a reducing
agent
4) All are incorrect.
em TYA
48) The volume of 0.1N KOH required to neutralise completely a 20mL of 0.2N H2SO4 is
1) 10mL 2) 40mL 3) 10mL 4) 20mL
Hint : Use the formula N V =N bV b
a a
49) 25 mL of 0.2 M Na2CO3 is completely neutralised by 12.5 mL of HCl solution. What is the
ich DI
50) 100mL of 0.2 M KMnO4 oxidises 50mL of oxalic acid solution in acidic medium completely. The
molarity of oxalic acid is
1) 1M 2) 0.2M 3) 0.4M 4) 2M
-2 2+
Hint : KM n O 4 + C 2O 4 Mn + CO 2
oxidant reductant
Formula : N V = N r Vr
o o
N o = M o x no. of e- gained by KMnO 4
N r = M r x no. of e- lost by C 2 O 4 2-
51) 20 mL of H2SO4 is required to completely neutralise 10 mL of 0.2M NaOH solution. The weight
of H2SO4 in 500 mL of H2SO4 solution is
1) 4.9g 2) 2.45g 3) 9.8g 4) None
52) 0.18gr of a metal (Atomic weight = 54g) reacts completely with 100mL of 1M HCl. The valency
of the metal is
1) 1 2) 2 3) 4 4) 3
weight w
Hint : no. of equivalents (n )=
e equivalent weight(EW)
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A to m ic w e ig h t A .W
E .W
v a len c y
53) 'x' g of a metal 'M' is completely reacted with 100 ml of 0.2N HCl. If the atomic weight of metal
is ‘100x’ g, then the formula of its sulfate salt is
1) M2 SO4 2) MSO4 3) M2 (SO4 )3 4) M(SO4 )2
54) 20g of a bivalent metal liberates 11.2 litres of H2 gas at STP by reacting with excess of acid
solution . The metal is
1) Mg 2)Al 3) Ca 4) Ba
55) 10mL of 0.2M KMnO4 solution is required to oxidise 20mL of 0.3M KI solution completely.
The change in oxidation state of ‘Mn’ in this reaction is.
1) Mn7+ Mn2+ 2) Mn7+ Mn3+
m
3) Mn4+ Mn7+ 4) Mn7+ Mn4+
ail N
H.W : Write the balanced equation for the reaction
gm DHA
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KMnO4 6 KI 4 H 2 O 2 MnO2 3 I 2 8 KOH
56) 18g of glucose is dissolved in 1800 g of water. The mole fraction of glucose is
1) 0.1 2) 0.01 3) 0.001 4) 1
n glucose
Formula : X =
i@ R
glucose n glucose+ n water
57) The mole fraction of urea in its aqueous solution is 0.23. The mole fraction of water is
ad VA
w
59) The mass percentage of ethyl alcohol in water is 23% . The mole fraction of alcohol is
w
1) 0.208 2) 0.104 3) 1.04 4) 3.26
Hint : solution contains 23 g ethyl alcohol + 77g water
ich DI
-1
60) 10 mL of a liquid (density = 4.9 g. mL ) is dissolved in 0.18Kg of water. If the mole fraction of the
liquid is 0.01, then its molecular weight will be
ad V. A
1) 98 g 2) 49 g 3) 4.9 g 4) 490 g
Hint : For very dilute solutions
nsolute
X
solute nsolvent
61) The molality of an aqueous solution of urea is 3 m. What will be its mole fraction?
1) 0.3 2) 0.18 3) 0.054 4) 0.003
Hint : For dilute solutions
molality x MWsolvent
X solute
1000
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VAPOUR PRESSURE
m
ail N
1) 2)
A C B
gm DHA
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vapour pressure
vapour pressure
A
C
i@ R
T emper ature T emper ature
ad VA
3) 4)
A B C A B C
em TYA
vapour pressure
vapour pressure
ich DI
6) Which of the following represents graph of logP against 1/T according to Clausius-clapeyron
equation (where P = vapour pressure and T = temperature)
1) 2)
log P
log P
1/ T 1/T
3) 4)
log P
log P
1/ T 1/ T
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Hint : Clausius - clapeyron’s equation is
H va p
ln P C
RT
H.W : What is the slope of the curve in the given graph ?
H vap
Ans :
2 .3 0 3 R
7) Which characterizes the weak inter molecular forces of attraction in a liquid ?
1) High boiling point 2) High vapour pressure
3) High critical temperature 4) High heat of vapourisation
8) At equIlibrium, the kinetic energies of vapour and liquid are
1) Equal 2) Not equal 3) Equal only at boiling point 4) All
9) According to Raoult’s law, the partial vapour pressure of a liquid in a solution is
1) inversly proportional to its mole fraction 2) directly proportional to its mole fraction
m
ail N
3) equal to its mole fraction 4) greater than the vapour pressure of pure liquid.
10) According to Raoult’s law, the vapour pressure (P) of an ideal solution containing two miscible
gm DHA
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liquids i.e., A and B, is
1) P PAo X A PBo X B 2) P PAo X A PBo X B
3) P PAo X A PBo X B i@ R 4) All
11) A solution of two liquids behaves ideally when
1) Hmixture 0 2) Smixture 0 3) Vmixture 0 4) Hmixture 0
ad VA
13) Which, among the following solutions, shows positive deviation from Raoult’s law
1) Ethanol + Water 2) Ether + Acetone
3) Carbontetrachloride + acetone 4) All
14) The partial vapour pressure of liquid ‘A’ in a solution showing positive deviation from Raoult’s law
ich DI
is given by
1) PA = P0A XA 2) PA > P0A XA
ad V. A
3) PA < P0AXA 4) PA = XA
15) The vapour pressure (P) of a solution showing negative deviation from Raoult’s law is given by
(solution contains two liquids i.e, A and B)
1) P = P0A XA+ P0BXB 2) P = P0A XA - P0B XB
1) P
total 0
2) 0
P P P
A total A
vapour pressure
vapour pressure
0 0
P P
B B
0 X 1 0 X 1
A A
1 XB 0 1 XB 0
m
ail N
3) 0
4) P
P total 0
A P
A
gm DHA
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P
vapour pressure
vapour pressure
P total 0
B P
B
i@ R
0 X 1 X 1
A 0 A
ad VA
1 XB 0 XB
1 0
19) The forces of attraction in the following solution are greater than those of in their component pure
liquids
1) Benzene + Toluene 2) Ethanol + Water 3) Acetone + Chloroform 4) Acetone + Ether
20) 50 mL of ethanol is mixed with 50 mL of water. The volume of the solution formed will be
ich DI
21) The vapour pressure of water at 300K in a closed container is 0.4 atm. If the volumeof the con-
tainer is doubled its vapour pressure at 300K will be
1) 0.8 atm 2) 0.2 atm 3) 0.4 atm 4) 0.6 atm
22) The vapour pressure of deliquescent substance is
1) Equal to the atmospheric pressure 2) Equal to the pressure of water vapour in air
3) Greater than the pressure of water vapour in air
4) Less than the pressure of water vapour in air
Note : Deliquescent substance absorbs water from air and becomes liquid (by dissolving in water).
COLLIGATIVE PROPERTIES
1) The property which depends only on the number of particles and not on the nature of particles is
1) Relative lowering of vapour pressure 2) Elevation in boiling point
3) Depression in freezing point 4) All
2) Choose the incorrect statement
1) The vapour pressure of a solution containing a non volatile solute is inversely proportional to the
mole fraction of solute.
2) The lowering of vapour pressure of a solution containing a non volatile solute is proportional to
the mole fraction of solute.
3) The vapour pressure of a solution containing a non volatile solute is proportional to the mole
fraction of volatile solvent.
4) None.
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3) The vapour pressure of a dilute solution (P) containing a non volatile solute is ( Let P01 = vapour
pressure of pure solvent, X1 & X2 = molefractions of solvent and solute respectively)
1) P = P01 X1 2) P = P01 (1-X2) 3) both 1 & 2 4) None
4) The relative lowering of vapour pressure of a dilute solution containing a non volatile solute is
1) equal to mole fraction of solute 2) equal to mole fraction of solvent
3) equal to mole fraction of solution 4) greater than mole fraction of solvent
5) 6 g of Urea is dissolved in 90g of water. The relative lowering of vapour pressure is equal to
1) 0.01 2) 0.06 3) 1.1 4) 0.02
Hint: Urea (NH 2 CONH 2 ) is a non volatile and non electrolytic substance.
P
Formula : Relative lowering of vapour presure X2
P0
m
ail N
X 2 = mole fraction of solute
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6) Calculate the amount of glucose present in 90g of water when the relative lowering of vapour
pressure is 0.02.
1) 9g 2) 12g 3) 18g 4) 24g
Hint: The molecular formula of Glucose is C 6 H 12 O 6
7) The lowering of vapour pressure of a solution containing 15g of non electrolyte in 90g of water at
i@ R
373K is 1.013 X 103N.m-2. The molecular weight of the solute is
1) 300g.mole-1 2) 90g.mole-1 3) 150g.mole-1 4) 135g.mole-1
ad VA
p0 100
10) The vapour pressure of an a aqueous solution of sucrose is 0.99 atm at 373 K. The molality (m) of
the solution is
1) 0.99m 2) 0.55m 3) 5.5m 4) 37.3m
P molality x MWsolvent
Hint: p0 =X solute
1000
11) The lowering of vapour pressure of 1% (w/w) aqueous solution of a non volatile and non electro-
lytic solute is 1.52 mm of Hg at 373K. The molecular weight of the solute is
1) 91g 2) 180g 3) 30g 4) 909g
12) The vapour pressure of a solvent is decreased by 10mm of Hg by adding a non volatile solute. The
mole fraction of solute is 0.14. What would be the molefraction of solvent if decrease in vapour
pressure is 20 mm of Hg
1) 0.28 2) 0.14 3) 0.72 4) 0.86
13) A 6 % glucose solution and 2 % solution of 'x' show same relative lowering of vapour pressure.
Assuming 'x' to be a non-electrolyte, the molecular weight of 'x' is
1) 30g.mole-1 2) 60g.mole-1 3) 90g.mole-1 4) 180g.mole-1
Hint : Molefractions and hence the number of moles of glucose and ‘x’ are equal.
16) The lowering of vapour pressure of solution containing 'X' is twice of solution
containing 'Y', then (both 'X' & 'Y' are non electrolytes)
1) The MW of 'X' is twice of 'Y' 2) The MW of 'Y' is twice of 'X'
3) The mole fraction of 'X' is twice of 'Y' 4) The mole fraction of 'Y' is twice of 'X'
17) An aqueous solution of Ca(HCO3)2 is heated strongly and filtered. The vapour pressure of clear
filtrate is
1) Greater than that of pure water 2) less than that of pure water
3) Equal to that of pure water 4) Can not say
m
2+
ail N
Hint : Ca aq 2 HCO3 aq CaCO3 s CO2 g H 2 O( l )
gm DHA
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1) = 76 cm Hg 2) > 76 cm Hg 3) < 76 cm Hg 4) = 100 cm Hg
19) Which of the following aqueous solutions has the minimum boiling point ?
1) 0.1M NaCl 2) 0.2M urea 3) 0.1M sucrose 4) 0.05M CaCl2
20) The vapour pressure of an aqueous solution of 0.2m glucose is 1atm at 100.360C. What is the
i@ R
molal boiling point elevation constant of the solvent ?
ad VA
1) 1.8 2) 1.8 K.mole-1 3) 1.8 K.Kg.mole-1 4) 1.8 Kg-1.mole-1
Hint : Elevation in boiling point = Tb K b . m
m Molality
-1
Note : The unit of K b is Kelvin.Kg.mole
21) 0.2g of a non volatile and non electrolytic solute is dissolved in 20g of a liquid to elevate the boiling
ich DI
point of the liquid by 0.180C. The ebbulioscopic constant of the liquid is 4.212 K.Kg. mole-1 .
What is the molecular weight of solute ?
ad V. A
Hint : K b
M
R Tb
0
1
ΔH vap 1000
m
ail N
W1 = Weight of solvent
26) The latent heat of fusion of water is 3.35 X 105J.Kg-1. Calculate the depression in freezing point of
gm DHA
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1m aqueous solution of glucose.
1) 0.00185 K 2) 1.85 K 3) 0.0185 K 4) None
2 2
R Tf M
0
1
0
R Tf
Hfusion = lf .M1
Hint : K f
i@ R
ΔHfusion 1000 lf .1000
2
ad VA
0
R Tf
T f .m
lf .1000
0
Tf Freezing point of pure liquid (solvent)
m = Molality
ad V. A
27) The freezing point of acetamide in glacial acetic acid is 298K. At this temperature, the crystals of
1) acetamide appear first 2) acetic acid appear first
3) both appear together 4) None
Hint : Always crystals of pure solvent seperate out first at the freezing point of solution.
28) How many grams of glucose should be dissolved in 100g of water in order to produce a solution
with a 1050C difference between the freezing point and the boiling point. (Kf = 1.86K.Kg.mol-1
and Kb = 0.51K.Kg.mole-1).
1) 18.2g 2) 37.9g 3) 180g 4) 72g
Hint : T f Tb
Tf T f0 Tb0 Tb
0
ΔTf +ΔTb + Tb0 -Tf0 =105 C
0
or ΔTf +ΔTb + 1000C-00C =105 C
ΔTf +ΔTb =50 C
But ΔTf = K f m
and ΔTb = K b m
0
Kf m + Kbm = 5 C
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29) Ethylene glycol is used as an anti freeze in radiators to
1) increase the boiling point of water 2) decrease the freezing point of water
3) decrease the boiling point of water 4) freeze the water above 00C.
30) The depression in freezing point of an aqueous solution is 0.670C. What is its relative lowering of
vapour pressure?(Kf= 1.8 K.Kg.mole-1)
1) 0.0067 2) 0.042 3) 0.21 4) 0.42
31) Choose the correct statement
1) Spontaneous flow of solvent from dilute solution to concentrated solution through a semi
permeable membrance is called osmosis.
2) According to van’t Hoff, the solute behaves as a gas and the osmotic pressure of solution is
equal to the pressure exerted by solute if it were a gas at the same temperature and occupying the
same volume as that of solution.
3) Reverse osmosis occurs, when a pressure greater than the osmotic pressure of solution is
m
applied over it
ail N
4) All
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32) The osmotic pressure of 0.2 molar solution of urea at 270C is
1) 4.92 atm 2) 1 atm 3) 2.7 atm 4) 8.2 atm
Hint : Osmotic pressure ( ) = CRT
n
where C = = molar concentration
i@ R
V
-1 1
R = Gas constant (0.0821 L.atm.mole .K )
ad VA
T = Absolute temperature
33) 20g of a non electrolytic solute is present in 500 mL of solution at 270C. The osmotic pressure of
this solution is 1.8 atm. What is the molecular weight of the solute (in g.mole-1) ?
em TYA
36) Insulin is dissolved in a suitable solvent and the osmotic pressures ( in atm.) of solutions of
various concentrations (C) in g/cc are measured at 270C. The slope of a plot of against C is
calculated to be 5 X 10-3. The approximate molecular weight of insulin is
1) 4.51 X 106 g 2) 4.926 X 106 g 3) 6.32 X 105g 4) 9.12 X 107g
n W 1000
Hint : π = RT= X X RT
V M.W V
where C = W in grams
π 1000 RT
Slope = =
C M.W
V in cc
1000 RT W
note : π = . is in y = mx form
MW V
37) The correct order of osmotic pressure of equimolar solutions of BaCl2, NaCl and C6H12O6 is
1) NaCl > C6 H12 O6 > BaCl2 2) BaCl2 > NaCl > C6 H12 O 6
3) C6 H12O6 > NaCl > BaCl2 4) All are equal
38) The osmotic pressure of 0.1M NaCl is greater than that of 0.1M CH3COOH. It is due to
1) NaCl is a weak electrolyte 2) CH3COOH is acid
3) CH3COOH is a weak electrolyte 4) All
39) When mercuric iodide is added to an aqueous solution of KI, the
1) Osmotic pressure is decreased 2) Vapour pressure is increased
3) Freezing point is raised 4) All
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m
Hint : Value of colligative property
ail N
Molecular weight
41) The relation between van’t Hoff factor (i) and degree of dissociation ( ) of a weak electrolyte ‘A’’
gm DHA
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which dissociates by giving ‘n’ number of ions ( A nB ) is
i 1 i 1 i
1) 2) 3) 4) None
n 1 n 1 n
Hint : A nB
i@ R
initia l 1 mole 0
(1 - )
ad VA
equilibrium n
Total no.of particles in the solution = (1- ) + n
= 1+n -
= 1+ (n-1)
em TYA
= n-1
42) The relation between van’t Hoff factor (i) and degree of association ( ) of ‘A’ which associates
ad V. A
as follows nA An .
i 1 i 1 i 1 i 1
1) 2) 3) 4)
n 1 1 n 1 1
1 1
n n
Hint : A An
initial 1 mole 0
at equilibrium (1- )
n
1
Total no.of particles in the solution = (1- ) + = 1+ = 1+ ( -1)
n n n
no.of particles in the solution
van't Hoff factor (i) =
no.of particles taken
1
1+ ( -1)
n
1
1 1
i .e., i = 1+ ( -1) i-1= ( -1)
n n
i-1
= 1
1
n
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43) Choose the incorrect statement.
1) Van’t Hoff factor (i) for aqueous solution of sucrose is one.
2) Van’t Hoff factor (i) for aqueous solution of acetic acid is greater than one
3) Van’t Hoff factor (i) for a solution of acetic acid in benzene is less than one
4) None
Hint : Van’t Hoff factor ‘i’ = 1 when there is no dissociation or association
i > 1 when there is dissociation
i < 1 when there is association
Acetic acid dimerizes in benzene (a solvent with low dielectric constant)
44) The degree of dissociation ( ) of a weak electrolyte AX BY is related to van’t Hoff factor (i) by
the expression.
i 1 i 1 i 1 x y 1
1) 2) 3) 4)
x y 1 x y 1 x y 1 i 1
m
45) If van’t Hoff factor of Ca(NO3)2 is 2.3, then its percentage of dissociation is
ail N
1) 22% 2) 65% 3) 60% 4) 44%
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46) The molecular weight of acetic acid dissolved in benzene is calculated as 90g.mole-1 by using
osmotic pressure method. What is the percentage of association of acetic acid.
1) 0.33% 2) 0.66% 3) 90% 4) 66.6%
0
47) 0.01m aqueous solution of K3[Fe (CN)6] freezes at -0.062 C. Its % of dissociation is
(Kf =1.86K.Kg. mole-1)
i@ R
1) 72% 2) 88% 3) 78% 4) 56%
-1
48) A solution containing 0.8716 mole.L of sucrose is iso-osmotic with a 0.5M NaCl solution. What
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51) At 25 C, a solution containing 0.2g of poly ethene in 100 mL of toluene shows a rise of 4.8mm at
osmotic equilibrium. The molecular weight of polyethene will be (density of the solution =
0.44g.mL-1)
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