WORKSHEET-7 1

1. Write the structural formulas for each of the following. a) 3-methyl-1-pentyne b) 1-hexyne c) 2,5-dimethyl-3-heptyne d) 2- methyl-3-hexyne e) 4-chloro-2-pentyne 2. Name each of the following alkynes by the IUPAC system. a) CH3 CC 2 3 b) HCC CH CH CH 3 CH CH3 3. 4. Write the all alkyne isomers of C4H6 and also name them. How many liters of oxygen at STP are required to burn a sample of acetylene which is obtained from 6,4 g of calcium carbide? Write the reactions of 1-butyne with excess hydrogen, chlorine, hydrobromic acid. Also, show necessary conditions and catalysts. And, name products. Write the reactions of acetylene and propyne with water in the presence of sulphuric acid solution of mercuric sulphate. Starting with calcium carbonate, obtain a) acetylene, ethylene, ethane b) acetaldehyde, benzene c) *e) 8. 1,1-dichloro ethane vinyl acetylene d) 1,1,2,2-tetrachloro ethane

ALKYNES*11. When an alkyne is burned, the mass of water produced is the same as the mass of alkyne used up. What is the molecular formula of alkyne? 12. A 10 mL sample of hydrogen adds to a 20 mL mixture of ethane and acetylene. What is the volume percentage of ethane in the mixture? 13. When a 112 cm3 mixture of ethylene and acetylene at STP is passed through an excess amount of aqueous ammoniacal cuprous chloride solution, 0,3775 g of precipitate forms. What is the volume percentage of ethylene in the mixture? *14.The carbon dioxide gas produced by the combustion of 10 g of propyne, can be absorbed by a 3 liter solution of sodium hydroxide. What is the molar concentration of sodium hydroxide solution? 15. What is the molecular formula of an alkyne,a 1,7 g sample of which is saturated with 200 g of 4 % aqueous solution of bromine?

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Suppose you were given three jars, each contains methane, ethylene, and acetylene. How can you identify the gases? 10 % of the molecular weight of an alkyne is hydrogen. What is the molecular formula of the alkyne?

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*10. A 13,6 gram sample of an alkyne requires 31,36 liters of oxygen at STP to be burned completely. What is the molecular formula of the alkyne?