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a
Research Institute of Mechanical Technology, Pusan National University, San 30, Jangjeon-dong, Keumjeong-ku, Busan 609-735, Republic of Korea
b
Department of Mechanical Engineering, Pusan National University, San 30, Jangjeon-dong,
Keumjeong-ku, Busan 609-735, Republic of Korea
Abstract
Electrospinning is a fabrication process that uses an electric field to control the deposition of polymer fibers onto a target sub-
strate. This electrostatic processing strategy can be used to fabricate fibrous polymer mats composed of fiber diameters ranging from
several microns down to 100 nm or less. In this study, optimized conditions to produce nanofibers using Nylon 6 are investigated
and the Nylon 6 nanofilters using nanofibers of 80–200 nm in diameter are designed and evaluated the filtration efficiency and pres-
sure drop across the filter. When the Nylon 6 concentration is 15 wt.%, electrospun fibers have an average diameter of 80 nm, but
there are many beads, and the concentration increases to 24 wt.%, the fiber diameter gradually thickens to 200 nm, but there are not
any beads. When the spinning distance is small, the thinner nanofibers are produced and the more fibers are collected on the
grounded electrode. The filtration efficiency of Nylon 6 nanofilters is 99.993% superior to the commercialized HEPA filter at the
face velocity of 5 cm/s using 0.3 lm test particles. Even though the high pressure drops across the nanofilter, they show the potential
to have the application of HEPA and ULPA grade high efficiency filter.
Ó 2005 Elsevier B.V. All rights reserved.
PACS: 81.05.L
1567-1739/$ - see front matter Ó 2005 Elsevier B.V. All rights reserved.
doi:10.1016/j.cap.2005.07.013
Y.C. Ahn et al. / Current Applied Physics 6 (2006) 1030–1035 1031
Table 1
Experimental conditions to produce Nylon 6 nanofibers by
electrospinning
Parameters Values
Polymer Nylon 6
Solvent Formic acid
Concentration (wt.%) 15–24
Electric voltage (kV) 25
Tip to collector distance (cm) 5–14
Collector Steel mesh
Capillary diameter (mm) 0.7
Fiber diameter range (nm) 80–200
Temperature (°C) 25
Relative humidity (%) 40
Compressed
Air Excess
Aerosol
HEPA HEPA Filter ΔP
Diffusion Flow
Filter Flow HEPA
Dryer meter meter
Filter
Test Filte
Atomizer Kr-85
HEPA Neutralizer
Filter
Vacuum
Dilution Air
Pump
Condensation
Particle Counter
Fig. 4. Scanning electron micrographs of Nylon 6 nanofibers as a function of concentration (applied voltage = 25 kV, spinning distance = 5 cm).
Fig. 5. Scanning electron micrographs of Nylon 6 nanofibers as a function of spinning distance (applied voltage = 25 kV, Nylon 6
concentration = 24%).
the stretch ability of a droplet. During the travel of strength has the opportunity to stretch the fibers
the fibers towards the target, the higher electric field more and results in thin fibers. The morphology of the
1034 Y.C. Ahn et al. / Current Applied Physics 6 (2006) 1030–1035
99.90
2 3 4 5 6 7 8 9 10 11
Three samples of filters are used in this study. The Face Velocity (cm/s)
one is HEPA(High Efficiency Particulate Air) filter to Fig. 7. Filtration efficiency of the HEPA filter and the Nylon 6
measure reference values and others are Nylon 6 nano- nanofilters as a function of face velocity.
filters to evaluate the performances such as filtration effi-
ciency and pressure drop. The HEPA filter is used as a
commercialized one (Hollingsworth & Vose, HB5443), Fig. 7 shows the filtration efficiency of the HEPA filter
and Nylon 6 nanofilters are prepared by electrospinning. and the Nylon 6 nanofilters as a function of face velocity.
The homogeneity of the Nylon 6 nanofilters are con- The filtration efficiency of test particle can be calculated
firmed as following methods. Several sample filters with by comparing with the particle number concentration be-
the same nominal base weight and dimensions are pre- tween upstream and downstream of the test filter medium
pared and the pressure drop across each filter is mea- for the size range of each particle. The nanofilter sample 1
sured as a function of face velocity. The results show shows a good filtration efficiency to satisfy the criterion of
that the filters are the same. HEPA filter for the filtration efficiency of 99.97% at
Fig. 6 shows the pressure drop of the HEPA filter and 0.3 lm particle size. At the condition of 10 cm/s of face
the Nylon 6 nanofilters as a function of face velocity. velocity, the filtration efficiency of nanofilter sample 1 is
The normal criteria of the HEPA filter media show decreased to 99.96% while the other filters still satisfy
that the filtration efficiency is over 99.97% at 0.3 lm the criterion of HEPA filter. As the velocity is increased,
particles and the pressure drop is lower than 40 mmAq collection by diffusion is reduced, but collection by
at 5 cm/s face velocity [10]. The test results show the impaction rises. In the high velocity conditions, some
pressure drop of the HEPA filter is in the normal particles, acquired more momentum, pass through the fil-
range, however, the pressure drops of the Nylon 6 nano- ters because of extremely thin thickness of the nanofilter
filters are higher than that of HEPA filter. The pore sample 1. On the other hand, the nanofilter sample 2,
size of the HEPA filter is 1.7 lm and the Nylon 6 nano- which has double thickness to the sample 1, shows better
filters are 0.24 lm and the thickness of the HEPA filter filtration efficiency than commercialized HEPA filter and
is 500 lm and the Nylon 6 nanofilters are 50 lm 99.993% at 5 cm/s using 0.3 lm particle.
(base weight: 5.75 g/m2) and 100 lm (base weight:
10.75 g/m2). When it is considered that the base weight
of HEPA filter is 78.2 g/m2 and the Nylon 6 nanofilters 4. Conclusions
are 5.75 and 10.75 g/m2, the Nylon 6 nanofilters are
formed just like a thin film with very fine sized pores. Electrospinning is a process of electrostatic fiber
formation by which uses electrical forces to produce
polymer fibers from polymer solution, with nanometer-
300
scale diameters. Nanofibers have a large specific surface
HEPA Filter
250
2
Nano Filter, Sample 1 (Base Weight: 5.75 g/m )
area and a small pore size in comparison with conven-
2
Nano Filter, Sample 2 (Base Weight: 10.75 g/m ) tional commercial textiles. Therefore, polymer nanofi-
Pressure Drop (mmAq)
200 bers are being used or finding uses in the industrial and
the biomedical fields. Especially, in this study, the appli-
150
cation for the filtration medium is evaluated using nano-
100 filters made by electrospun Nylon 6 nanofibers.
The concentration of the polymer solution has shown
50 a great influence on the fiber diameter as well as on
bead. When the Nylon 6 concentration is 15 wt.%, elec-
0
2 3 4 5 6 7 8 9 10 11 trospun fibers have an average diameter of 80 nm, but
Face Velocity (cm/s) there are many beads, and the concentration of Nylon
Fig. 6. Pressure drop measurements across the HEPA filter and the 6 increases to 24 wt.%, the fiber diameter gradually
Nylon 6 nanofilters as a function of face velocity. thickens to 200 nm, but there are not any beads. When
Y.C. Ahn et al. / Current Applied Physics 6 (2006) 1030–1035 1035