Professional Documents
Culture Documents
Trend
Atomic Radius
Ionisation Energy
Melting Points
Reactivity With
Water
Reasons
Mg<Ca<Sr<Ba
(Increases as you go down
group)
Mg>Ca>Sr>Ba
(Decreases as you go down
group)
Mg>Ca<Sr>Ba
(Decreases as you go down
group but Sr has a higher
melting point than Ca)
Mg<Ca<Sr<Ba
(Increases as you go down
group)
Compared to group 1, metals are less reactive as ions get smaller across a period.
Metal
Reaction with Cold Water
Mg
Reaction too slow to notice
Ca
Reaction quick but not violent
Sr/Ba
Reaction increasingly exothermic
Example:
Ca(s) + 2H2O(l) H2(g) + Ca(OH)2
Ca(s) + 2H2O(l) H2(g) + Ca2+(aq) + 2OH-(aq)
Group 2 Sulphates
Solubility
MgSO4>CaSO4>SrSO4>BaSO4
Decreases as you go down group.
They are all ions and therefore
aqueous.
Why
Haloalkanes
The following is called a Free Radical Substitution.
When an alkane reacts with a halogen under conditions of: 1) Ultraviolet Light
2) Heat
3) Other forms of energy
Then the U.V. Light provides the energy needed to break the covalent bond in the halogen or
haloalkane molecule homolytically. Homolytic bond breaking creates radicals.
There are three stages: 1) Initiation: makes the radicals
2) Propagation: a) Take one atom
b) Pairs of Reaction
c) 2nd Reaction produces Radical of 1st Reaction
d) Makes the real products
e) Further steps occur if excess reactant
3) Termination: Destroys Radicals
Ozone is O3. It is formed by either: 1) Ultraviolet light on Oxygen light in the atmosphere
2) Electrical sparks at ground level
Polluting Ozone is a very toxic gas. The ozone layer in the atmosphere absorbs U.V. light
limiting the amount reaching the surface of the Earth. At present, there are large holes in the
North and South Pole.
Chlorine and chlorine compounds, which are found in the poles, destroy Ozone.
First, U.V. light hits chlorine or chlorine based compounds:
Cl2 2Cl
Then Cl reacts with Ozone (O3) in a pair of propagation steps. The Chlorine free radical is
called the reactive intermediate.
Cl + O3 OCl + O2
OCl + O3 Cl + 2O2
This makes the overall equation:
2O3 3O2
Therefore, as you can see, Chlorine is a catalyst in turning Ozone (O3) into Oxygen (O2).
This is because the termination step Cl + Cl Cl2 = makes Chlorine, which would once
again get hit by U.V. light. Therefore Chlorine provides an alternative route of lower
activation energy.
Chlorine atoms are also formed from chlorine-containing organic compounds in the upper
atmosphere due to the carbon-chlorine bond breakage in a homolytic way.
Therefore a C-Cl bond is not considered environmentally acceptable or friendly.
The IUPAC name of CF3Cl is Chlorotrifluoromethane
Also remember that when a metal chloride reacts with Sulphuric Acid, it makes Hydrochloric
Acid (HCl) and one other product.
Nomenclature
Functional Group
Word Endings
Connection with
Carbon Chain
Alcohol
Anol
Aldehyde
Anal
Ketones
Anone
Carboxylic Acid
Anoic
Amines
Conditions
1) The isomer
will end with ol
if there is a
number in the
middle.
1) It is always
at the rear end
of a chain.
2) Numbers
begin from
butanal
1) Isomer will
be in the
middle of a
chain
1) It is always
at the rear end
of a chain.
NO
CONDITIONS
Nitriles
Cyanide
NO
CONDITIONS
In a test for Alkanes and Alkenes, we use bromine water, it remains orange with Alkane, but
turns colourless with an Alkene.
IMPORTANT: If it asks you for the displayed formula of any of the above, you must show the
bonds. So instead of writing OH, you must O-H.
Geometrical Isomers take place at sights of restricted rotation.
If the both of the above connected chain are different to the bottom connected chain, then
there will be E/Z isomerism.
Double bonded isomers and Rings isomers have restricted rotation.
The E isomer looks like a Z shape.
The Z isomer looks like an E shape.
Type of isomer
What Happens
Priority
Functional Group
Isomer
Ending changes
e.g. goes from ANE to ENE, etc.
1st
Chain Isomer
2nd
3rd
Position Isomer
Numbers change
e.g. goes from 1-methylpentane to 2-methylpentane
Geometrical
Isomer
4th
Alcohols
Primary Alcohols (Alcohols in which the Carbon connected to the OH is connected to 1 other
Carbon) are oxidised (they are made to gain Oxygen or lose Hydrogen) first to Aldehyde,
then to Carboxylic Acids.
The Reagent that will be the oxidising agent for the alcohol: Acidified Potassium Dichromate
(H+/Cr2O72-/ [O])
EXAMPLE: Ethanol (primary alcohol)
CH3CH2OH + [O] CH3CHO + [O] CH3CO2H
Ethanol
Ethanal
Ethanoic Acid
(Lost 2 Hydrogens) (Gained 1 Oxygen)
Aldehyde boils at a lower temperature than alcohols. Therefore we carry out the oxidation at
a temperature greater than the boiling point of the Aldehyde so that the Aldehyde is
separated from the [O] and the alcohol.
By using Reflux, we can make the carboxylic acid.
Secondary Alcohols (Alcohols in which the Carbon connected to the OH is connected to 2
other Carbons) are oxidised (they are made to gain Oxygen or lose Hydrogen) to Ketones.
EXAMPLE: Propan-2-ol (secondary alcohol)
CH3CHOHCH3 + [O] CH3COCH3
Propan-2-ol
Propanone
(Lost 2 Hydrogens)
Tertiary Alcohols (Alcohols in which the Carbon is connected to 2 other Carbons) cant be
oxidised easily as the double bond cant be made without breaking a C-C bond. Therefore, if
it hints towards an alcohol that doesnt react with Acidified Dichromate, then this alcohol is
tertiary. Alcohols are a Homologous Series. In hydration, we use concentrated H2SO4
How each reagent helps
distinguish between
Aldehydes (Anal) &
Ketones (Anone)
Aldehyde
Ketone
Acidified Dichromate
Orange to Green
Orange to Orange
Tollens Reagent
Colourless to Colourless
Benedicts or Feheiling
Industrial
Raw Material
Glucose
Ethene
Renewable
Yes
No
Other Requirements
Temperature
37oC
Level of Technology
Low
High
Rate of Production
Slow
Very Fast
Purity
Very impure
Very pure
Purification Process
Distillation V.Expensive
Not needed
We use the industry method. We dont use fermentation because it is a slow reaction and is
very expensive. The industry method involves Hydration/ Electrophilic Addition of ethene to
from ethanol.
Brazil runs cars on alcohol through fermentation as it has lots of land; the sugar grows
quickly and due to cheap labour.
Bio Fuels
Fuel produced from biological or renewable sources
Fermentation is not Carbon Neutral: 1) Fuel used to distil impure ethanol releases CO2
2) Harvesting/planting sugar involved using fuel that
releases CO2
For a complete combustion of a fuel to take place in air, you must have sufficient supply of
oxygen.
Fermentation:
1) Yeast
2) Sugar
3) Water
4) 37oC
Essential Conditions:
1) Yeast
2) 30oC T 42oC
3) No Air
It is an Oxidation reaction as respiration is Anaerobic.
C6H12O6
Sugar (glucose)
2C2H5OH
Ethanol
+ 2CO2
Carbon Dioxide
Mechanisms
What Happens
Nucleophilic Substitution
Base Elimination
Electrophilic Addition
Acid Elimination
1) A Bonding Pair
Effect
Makes a Saturated (single
bond) reactant into a
Saturated (single bond)
product
Makes a Saturated (single
bond) reactant into a
Unsaturated (double bond)
product
Makes a Unsaturated
(double bond) reactant into a
Saturated (single bond)
product
Makes a Saturated (single
bond) reactant into a
Unsaturated (double bond)
product
2) A Lone Pair
Nucleophile: Electron pair donor.
Electrophile: Electron pair acceptor.
Reagent: Chemical/chemicals that react with an organic molecule.
Substrate: The organic molecule that undergoes the reaction.
RULES:
1) First curly arrow goes to something positive
2) If curly arrow departs, it makes +1 charge
3) If curly arrow arrives, it makes -1 charge
4) Atoms have a max of 4 pairs, except Hydrogen which has a max of 1 pair
Electrophilic Addition:
The substrate is an Alkene. It is the only mechanism that begins with an Alkene. It makes a
Haloalkane.
Reagents:
1) Bromine (Br-Br) or Chlorine (Cl-Cl) : How: the double bond in the substrate is a
centre of high electron density. This induces a DIPOLE in the Br-Br or Cl-Cl bond.
2) HCl or HBr: How: H-Cl and H-Br are polar bonds.
3) Sulphuric Acid (H-OSO3H): HOW: The H-O bond in Sulphuric Acid is highly polar.
IMPORTANT: The most stable intermediate connects to the Halogen forming more often and
therefore giving the major product.
Types of Carbon
What is it
Stability
Tertiary
Most Stable
Secondary
Less Stable
Primary
Least Stable
When an alkene becomes an alkane, but it does not involve curly arrows, then it is simply
called Addition or Reduction or Hydrogenation.
Nucleophilic Substitution:
The substrate is a haloalkane. It can make an Alcohol, Nitrile or Amine.
Reagents:
1) Aqueous Sodium/Potassium Hydroxide (HO-) Remember: We dont use the Sodium
Ion. This reagent makes an alcohol.
2) Alcoholic Potassium Cyanide (N C-) Remember: we dont use the Potassium. This
reagent makes a Nitrile.
3) Ammonia (H3N); more ammonia will be added because this makes an unstable
intermediate. This reagent makes an Amine.
If we have an excess of haloalkane, further reactions take place.
As we go down the Halogen group, the Haloalkane in the Nucleophilic Substitution increases
the rate of the Nucleophilic Substitution (R-I reacts fastest with Reagent, R-Cl reacts slowest
with Reagent). As we go down the group, the bond strength of the halogen with the alkane
decreases even though polarity decreases (the more polar a bond, the weaker it is). Hence,
the reason the rate of Nucleophilic reaction increases as you down the halogen group is due
to polarisibility (the R-I bond is EASILY polarised).
The characteristic of the haloalkane that enables it to undergo the Nucleophilic Substitution
is the fact that it has a polar bond between a Carbon and Halogen.
Base Elimination:
The substrate is a haloalkane. It makes an Alkene.
Reagents (Base):
1) Alcoholic Potassium/Sodium Hydroxide (HO-) Remember: We dont use the Sodium.
Acid Elimination:
The substrate is saturated. It makes an alkene.
Reagents:
1) H+ How: There is a lone pair in the substrate that goes to the positive H+
Polymerisation
It is a reaction which turns many small molecules into long chain molecules.
Hence:
MONOMER POLYMER
Addition Polymers: (Alkenes undergo Addition)
Made from alkenes or similar compounds
EXAMPLE: Ethene to Poly(ethene)
Others:
Poly(propene)
= plastic bottles
Poly(chloroethene)
(P.V.C) =
drainpipes
Poly(phenylethene) (Polystyrene) = bubble wraps/packaging
If you are shown a polymer and asked what it was before, then count the number of
Carbons, then this shall give you the alkene chain, then you need to work out where the
double bond was.
Polymers are now recycled because:
1) It preserves raw materials
2) Prevents pollution
3) Saves energy
Polymers are non-biodegradable materials.
The Mass Spectrometer
Molecules can also be analysed by a mass spectrometer (not just elements).
Cl2 + e- Cl2+ + 2eThe mass spectrometer can measure to at least 4 decimal places of an a.m.u.
Mr
Mass Spectrometer Mr
CO
28
28.0104
N2
28
28.0134
C2H4
28
28.0536
Therefore, the mass spectrometer can distinguish between compounds of similar Mr.
Propane and Carbon Dioxide have the same Mr when it is to one decimal place.
Carbon has Mr 12.00000 by definition.
Some Chemicals have the same Mr EVEN TO 5 DECIMAL PLACES: Why:
They contain the same number of atoms of the same element, or another way of saying it is
that they have the same molecular formula.
Some Chemicals have a different Mr when made to 5 DECIMAL PLACES: Why:
They contain different number of elements of different elements.
Halogens
Trend
Melting Point
Electronegativity
Oxidising Ability
(The ability to attract
electrons to itself and
take away electrons from
others)
Order of Reactivity
Reducing Ability
(The ability to give away
electrons to others)
F2<Cl2<Br2<I2
(Increases as you go down
group)
F2>Cl2>Br2>I2
(Decreases as you go
down group)
F2>Cl2>Br2>I2
(Decreases as you go
down group)
F2>Cl2>Br2>I2
(Decreases as you go
down group)
F2>Cl2>Br2>I2
(Decreases as you go
down the group)
Reasons
Halogens may or may not displace with halide ions. The colour given off is of the element of
the displaced ion
Halides: F-, Cl-, Br-, I-} colourless
Halogens:
F2 an aqueous solution of F2 cannot be made as it reacts with water
Cl2 an aqueous solution of Cl2 has the colour (pale) green
Br2 an aqueous solution of Br2 has the colour Orange/Brown
I2 an aqueous solution of l2 has the colour Purple/Black
It takes less energy to break the weaker C-halogen bond; therefore the precipitate would
form quicker.
Chlorine reacts slowly with water: It is used in swimming pools but as small doses as it is
toxic. A Universal Indicator would turn pink in chlorine
water.
Cl2(aq) + H2O
HCl (oxidation number of Cl here is -1) + HOCl (oxidation number of Cl here is +1) (aq)
This is an example of disproportionation. When the same chemical is oxidised and reduced.
Over time the HOCl (Chloric Acid) decomposes: 2HOCl(aq) 2HCl(aq) + O2(g)
When Chlorine reacts with Sodium Hydroxide, Sodium Chloride and Sodium Chlorate
(NaClO) is formed. When it says give the formula you must not write the name of the
substance, you should write the actual chemical formula of it, even if it may be an element.
Cl-
Br-
I-
Halide Ions
Add dilute HNO3
(Destroys
Carbonate ions
that could make
Ag2CO3 which is
white and would
give a false result
HOW does it
destroy it:
2H+ + CO32-
CO2 + H2O
Add Silver Nitrate
(Forms The
Precipitates)
Add Dilute
Ammonia
(Dissolves AgCl(s))
Add
Concentrated
Ammonia
(Dissolves
AgBr(s))
Colourless Solution
Colourless Solution
Colourless Solution
Colourless Solution
Colourless Solution
Colourless Solution
White Precipitate
Ag+(aq) + Cl-(aq) AgCl(s)
Cream Precipitate
Ag+(aq) + Br-(aq) AgBr(s)
Yellow Precipitate
Ag+(aq) + I-(aq) AgI(s)
Colourless Solution
AgCl + 2NH3 [Ag(NH3)2]+ + Cl-
Cream Precipitate
Yellow Precipitate
Colourless Solution
Colourless Solution
AgCl + 2NH3 [Ag(NH3)2]+ + Cl-
Yellow precipitate
Fluoride ions are not tested for in the test for Halide ions, this is because when we add the
Silver Nitrate, it makes AgF, which is soluble and therefore forms no precipitates.
Add Concentrate Sulphuric Acid (H2SO4)
Equation
NaCl
(bleach)
(kills
bacteria
)
NaBr
Acidic fumes (SO2)
Misty Acidic Fumes (HI)
NaI
Infrared Spectroscopy
Infrared waves do not break bonds but makes them vibrate.
The frequency of the vibration depends on: 1) strength of the bond- single, double or triple
2) Masses of the bonded atoms (C, N, O=heavy.
H=light)
More absorption (higher wave number) of an infrared wave makes that chemical a more
effective greenhouse gas.
Bonding Type
Frequency
Bonds to Hydrogen
2500-3500
Triple Bond
2220-2260
Double Bond
1620-1680
Single Bond
750-1300
Bonds to Hydrogen
2500-3500
Triple Bond
2220-2260
Double Bond
1620-1680
Alcohol
Aldehyde
and
Ketone
Carboxyli
c Acid
Nitrile
Alkene
Single Bond
750-1300
Metal
W (Tungsten)
Oxide
WO3
How
Tungsten is made by
reducing (given
electrons) WO3
with Hydrogen Gas.
Reaction
WO3 + 3H2 W + 3H2O
Extras
Hydrogen is explosive;
therefore Water should
be used to put out a fir
which a metal is burnin
Ti (Titanium)
Aluminium (Al)
TiO2
Al2O3
Titanium is made in
a 2 stage process.
First it is made into
TiCl4, and then the
TiCl4 is then reduced
with a more reactive
metal, either Na
(Sodium) or Mg
(Magnesium) and
made into Titanium.
An inert (no oxygen)
atmosphere is
required as Titanium
can react with
oxygen.
Stage 1:
Purified Bauxite
used in extraction
(Very high melting
point- this is
dissolved in molten
CRYOLITE-lowers
melting point). The
melting point of
mixture is much
lower than pure
Al2O3 much cheaper
Copper present in
Cu2+(aq) + Fe(s) Cu(s) + Fe2+(aq)
Copper (Cu)
ground water (any
dilute aqueous
Or
solution-low grade
ore) can be captured CuO + C Cu + CO
by using scrap iron.
Every time a metal is given and in the middle of its name there is a bracket with a symbol in
it, then that symbol represents the positive charge on that metal ion.
FOR EXAMPLE: If you see Copper (II), it means Cu2+. Also the atom economy must be high
when extracting.
Remember that Aluminium is expensive. Sometimes the cost of extracting a metal is high
because of the energy required when heating it with another metal. Using enthalpy, we can
find this high amount of energy. Al = Al3+, Zn = Zn2+. Also Aluminium is recycled to save
electricity, energy and conserve bauxite. Also, Titanium is stronger than Aluminium. When
metal reacts with water, it makes an Oxide and Hydrogen.
1)
2)
3)
4)
Recycling
Preserves resources (Economic)
Reduces pollution (Environmental)
Saves energy (Economic)
Scrap Iron/Steel has higher iron content (Economic)
Equilibrium
2NH3
Pressure: If we increase the pressure, the reaction will attempt to decrease the pressure by
converting the reactant (which is 4 moles) into the product (which is 2 moles).
Therefore if we increase the pressure, the equilibrium moves to the side of fewest
gaseous molecules. However if there are the same number of moles on each side,
then the pressure shall have no effect.
Pressure increases Ammonia yield: There are more moles of reactant therefore an increase
in pressure is opposed.
-92
N2 + 3H2
2NH3
+92
Temperature: The sign + means that it is endothermic, the sign - means that the reaction is
exothermic. Therefore, if we increase the temperature, the reaction will
attempt to decrease the temperature (try to cool down) by moving towards the
endothermic reaction, therefore making the N2 and 3H2.
Temperature decreases Ammonia yield: The forward reaction is exothermic; therefore if we
provide heat, the equilibrium will move to cool down by moving towards the
endothermic reaction, therefore less Ammonia is formed.
N2 + 3H2
2NH3
Concentration: If we increase the amount of concentration of the product, the reaction will
attempt to decrease the concentration by moving towards the reactants.
Therefore, if we want a high yield of ammonia, the temperature must be kept low, and the
pressure must be kept high:
Increase pressure
N2 + 3H2
2NH3
Increase temperature
If we increased it further
Temperature (450oC)
Pressure (200atms)
If we lowered it further
explosion
Less ammonia and slow reaction
A catalyst increases the rate of attainment of equilibrium and speeds up forward and
backward reactions. But it does not have an effect on the equilibrium amounts. The catalyst
in ammonia manufacture is Iron.
Why does the catalyst have no effect on the position of equilibrium:
A catalyst increases the rate of the forward and backward reaction, and this increase in rate
of forward and backward reaction is equal.
Equilibrium may also shift to oppose the loss of a substance.
Also, it is of paramount importance to remember that a negative H (enthalpy has
decreased) is always an exothermic reaction. The actual sign - means exothermic reaction.
Therefore the overall enthalpy of an exothermic reaction must have a - before it. FOR
EXAMPLE: The following is an exothermic reaction:
If the enthalpy has decreased as shown above, it means the sum of the bond enthalpies of
the product is lower than the sum of the bond enthalpies of the reactants.
Collision Theory
For particles to react chemically, they must: 1) Collide
2) With at least the activation energy
Only reactions with at least the activation energy can pass from reactants to products.
Reacting particles have different activation energies; some high, some low.
Maxwell Boltzmann Distribution:
1) Increase temperature: The curve of the graph becomes flatter and distributes to the
right.
2) Add a catalyst: The Ea on the graph moves to the left, however the distribution of the
graph is not affected, and the catalyst is usually hot: WHY: To provide the activation
energy. If a catalyst remains hot during a reaction, it is because the reaction is
exothermic.
3) If we double the pressure, the volume halves, therefore the concentration also
doubles. Increasing Concentration/Pressure: The hump of the graph grows higher,
but does not move right or left.
4) What does the area under the graph represent: Total number of molecules. The
graph start at the origin because all molecules have some energy, therefore no
molecules have no energy. However very few molecules have the Ea.
5) The Y axis is labelled Number Of Molecules and the X axis is labelled Energy.
If we decrease the temperature: There is a decrease in the number of particles which have
the minimum energy to react, therefore there are fewer
successful collisions.
If we increase the temperature: There is an increase in the number of particles which have
the minimum energy to react, therefore there are many
more successful collisions. Also the Emp (the place where
the hump on the graph is) increases. This is more effective
in increasing the rate than increasing the pressure
because increasing the pressure by a small amount
increases the frequency of collisions by a small amount.
If we increase the concentration: The number of particles reacting is doubled (many more),
therefore there is a greater collision frequency (higher
chance of a successful collision).
If we decrease the concentration: The number of particles reacting is much fewer, therefore
there is a lower collision frequency.
If we add a catalyst: There is an increase in the number of particles which have the minimum
energy to react, therefore there are many more successful collisions.
Also the graph distribution remains the same. Sometimes a metal
catalyst is often used in the form of gauze or a powder to increase the
surface area of the catalyst.
If we increase the surface area of reactants: There is a greater collision frequency.
Enthalpy
Once condition necessary for enthalpies of formation to be quoted as standard values at a
specific temperature of 298K: All reactants and products are in their standard states.
There is a difference between the value calculated through mean bond enthalpies and the
value given in a book because:
1) Mean bond enthalpies are not specific for this reaction
2) They are average values from many different compounds
An incomplete combustion can lead to a reaction being less exothermic.
Questions about q = m c T
Q = m c T
(You must write this in the exam)