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IITJEE CHEMISTRY SAMPLE PAPER III

SOLUTIONS
SECTION I
Straight Objective Type

1.

(a)

2.

(b)

N
NaOH (excess)
H3O+

CH2Br

pOH = pKb

COOH

CH2OH

CH2

[Salt ]
[acid ]
NH4Cl
0.03
0.04

+ log

NH3 + HCl
Mole initially 0.020
0.01
Moles finally 0.01

0.04
pOH = 4.74 + log
= 4.74 + log(4) = 4.74 + 0.60 = 5.34
0.01
pH = 14 pOH = 8.66
3.

(c)

xA = 0.2 ; xB = 0.8
PTotal = (60 0.2) + (15

0.8) = 24

Mole fraction of A in vapour phase = yA =

4.

(b)

12
24

0.5

Rate law = r = k1 [O] [O3]

[O 2 ][O]
K
[O 3 ]
r

[O 3 ] 2
k 1K
[O 2 ]

Since it is given r

k[O 3 ] 2
[O 2 ]

k = k1K
, P2 O 5

5.

(b)

HOOCCH2COOH

6.

(c)

Cu+2 form insoluble blue coloured ppt of Cu(OH)2 whereas Zn+2 forms soluble
complex, [Zn(OH)4]2.

7.

(d)

8.

(a)

2 H 2O

O=C=C=C=O

Li, Mg and Al when burn in air produces nitrides whose hydrolysis will liberate NH3.
NH3 gives white fumes with HCl.

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SECTION II
Reasoning Type
9.

(a)

10.

(b)

11.

(b)

12.

(d)

Under the conditions of high pressure it is the size effect which dominates.
SECTION III
Linked Comprehension Type
PassageI

13.

(a)

14.

(b)

15.

(c)

E.Wt

71
nf

71 3
5

42.6

PassageII
16.

(b)
O

17.

(a)

HCH + OD

HCH + HCH

HCOD + HCH

OD

18.

(b)

HCOO + CH3OD

In the given compound, the lone pair on nitrogen decreases the electrophilicity of
carbonyl carbon and as a result Cannizzaro reaction does not occur.
SECTION IV
Matrix Match Type

1.

(A) 2, 4 ; (B) 1, 2 ; (C) 3, 4 ; (D) 1, 3

2.

(A) 2, 4 ; (B) 3 ; (C) 1 ; (D) 4

OH

CH3CHCH3
(P)

conc.H2SO4

CH3CH=CH2
(Q)

O
(i) Br2
(ii) NaNH2
(excess)

KMnO4 + H2SO4

CH3CH CH
(R)

H2SO4 /
HgSO4

CH3CCH3
(Q)

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SECTION V
Subjective or Numerical Type
1.

C6H14(g)
1
1x

Initial pressure
Pressure at equilib

Kp =

1
4
3
4

1
3

3(4 )

= 5.2 103

log 5.2 103 = 23.45

13941
= 25.74
T
T = 541.60 K

2.

6C(s) 3H 2 (g)

C6H6(l) + 4H2(g)
0
4x = 1
1
x = atm
4

13941
13941
; 2.29 = 23.45
T
T

C6 H 6

Hexp = 358.5 kJ

Htheor = 6(716.8) + 3 (436.9) 3(340) 3(620) 6

490

= 4300.8 + 1310.7 1020 1860 2940 = 208.5

Resonance energy = Hexp Htheor = 358.5 (208.5) = 150 kJ mol1.