QUINTERO, Ramon Paolo T.

2011-11368

ChE 123 WFU

November 27, 2013

1. Prepare a P-xy diagram and a y-x diagram for n-pentane and n-heptane at 50oC, assuming Raoults
Law applies.
x1
0.000
0.010
0.020
0.030
0.040
0.050
0.060
0.070
0.080
0.090
0.100
0.110
0.120
0.130
0.140
0.150
0.160
0.170
0.180
0.190
0.200
0.210
0.220
0.230
0.240
0.250

y1
0.000
0.079
0.148
0.209
0.262
0.310
0.352
0.391
0.426
0.458
0.487
0.513
0.538
0.560
0.581
0.601
0.619
0.636
0.652
0.667
0.681
0.694
0.706
0.718
0.729
0.740

P (kPa)
18.8991
20.3219
21.7447
23.1675
24.5903
26.0131
27.4359
28.8587
30.2815
31.7044
33.1272
34.5500
35.9728
37.3956
38.8184
40.2412
41.6640
43.0868
44.5096
45.9324
47.3553
48.7781
50.2009
51.6237
53.0465
54.4693

x1
0.260
0.270
0.280
0.290
0.300
0.310
0.320
0.330
0.340
0.350
0.360
0.370
0.380
0.390
0.400
0.410
0.420
0.430
0.440
0.450
0.460
0.470
0.480
0.490
0.500

y1
0.750
0.759
0.768
0.777
0.785
0.793
0.801
0.808
0.815
0.821
0.828
0.834
0.839
0.845
0.850
0.856
0.861
0.865
0.870
0.875
0.879
0.883
0.887
0.891
0.895

P (kPa)
55.8921
57.3149
58.7377
60.1605
61.5833
63.0062
64.4290
65.8518
67.2746
68.6974
70.1202
71.5430
72.9658
74.3886
75.8114
77.2342
78.6571
80.0799
81.5027
82.9255
84.3483
85.7711
87.1939
88.6167
90.0395

x1
0.510
0.520
0.530
0.540
0.550
0.560
0.570
0.580
0.590
0.600
0.610
0.620
0.630
0.640
0.650
0.660
0.670
0.680
0.690
0.700
0.710
0.720
0.730
0.740
0.750

y1
0.899
0.902
0.906
0.909
0.912
0.916
0.919
0.922
0.925
0.927
0.930
0.933
0.936
0.938
0.941
0.943
0.945
0.948
0.950
0.952
0.954
0.956
0.958
0.960
0.962

P (kPa)
91.4623
92.8851
94.3080
95.7308
97.1536
98.5764
99.9992
101.4220
102.8448
104.2676
105.6904
107.1132
108.5360
109.9589
111.3817
112.8045
114.2273
115.6501
117.0729
118.4957
119.9185
121.3413
122.7641
124.1870
125.6098

x1
0.760
0.770
0.780
0.790
0.800
0.810
0.820
0.830
0.840
0.850
0.860
0.870
0.880
0.890
0.900
0.910
0.920
0.930
0.940
0.950
0.960
0.970
0.980
0.990
1.000

y1
0.964
0.966
0.968
0.970
0.972
0.973
0.975
0.977
0.978
0.980
0.981
0.983
0.984
0.986
0.987
0.989
0.990
0.991
0.993
0.994
0.995
0.996
0.998
0.999
1.000

P (kPa)
127.0326
128.4554
129.8782
131.3010
132.7238
134.1466
135.5694
136.9922
138.4150
139.8379
141.2607
142.6835
144.1063
145.5291
146.9519
148.3747
149.7975
151.2203
152.6431
154.0659
155.4888
156.9116
158.3344
159.7572
161.1800

P-xy and yx diagrams for n-pentane

(1)/n-heptane (2) system at 50oC

2. Prepare a T-xy diagram and a y-x diagram for n-pentane and n-heptane at 101.3 kPa, assuming
Raoults Law applies.
x1
0.000
0.010
0.020
0.030
0.040
0.050
0.060
0.070
0.080
0.090
0.100
0.110
0.120
0.130
0.140
0.150
0.160
0.170
0.180
0.190
0.200
0.210
0.220
0.230
0.240
0.250

y1
0.000
0.055
0.106
0.154
0.198
0.240
0.279
0.315
0.349
0.381
0.411
0.439
0.466
0.491
0.515
0.537
0.558
0.578
0.596
0.614
0.631
0.647
0.662
0.676
0.690
0.703

T ( C)
98.3910
96.8194
95.2944
93.8141
92.3771
90.9816
89.6261
88.3091
87.0291
85.7847
84.5745
83.3972
82.2515
81.1363
80.0504
78.9925
77.9618
76.9571
75.9775
75.0221
74.0898
73.1800
72.2917
71.4242
70.5767
69.7485

x1
0.260
0.270
0.280
0.290
0.300
0.310
0.320
0.330
0.340
0.350
0.360
0.370
0.380
0.390
0.400
0.410
0.420
0.430
0.440
0.450
0.460
0.470
0.480
0.490
0.500

y1
0.715
0.727
0.738
0.748
0.759
0.768
0.778
0.786
0.795
0.803
0.811
0.818
0.825
0.832
0.839
0.845
0.851
0.857
0.862
0.868
0.873
0.878
0.882
0.887
0.891

T ( C)
68.9389
68.1473
67.3730
66.6155
65.8741
65.1483
64.4377
63.7416
63.0596
62.3913
61.7361
61.0937
60.4638
59.8457
59.2393
58.6442
58.0599
57.4863
56.9229
56.3694
55.8256
55.2912
54.7660
54.2495
53.7417

x1
0.510
0.520
0.530
0.540
0.550
0.560
0.570
0.580
0.590
0.600
0.610
0.620
0.630
0.640
0.650
0.660
0.670
0.680
0.690
0.700
0.710
0.720
0.730
0.740
0.750

y1
0.896
0.900
0.904
0.908
0.911
0.915
0.918
0.922
0.925
0.928
0.931
0.934
0.937
0.940
0.942
0.945
0.947
0.950
0.952
0.954
0.957
0.959
0.961
0.963
0.965

T ( C)
53.2423
52.7510
52.2676
51.7918
51.3236
50.8627
50.4089
49.9620
49.5218
49.0882
48.6609
48.2400
47.8251
47.4161
47.0129
46.6154
46.2233
45.8367
45.4553
45.0790
44.7078
44.3414
43.9799
43.6230
43.2707

x1
0.760
0.770
0.780
0.790
0.800
0.810
0.820
0.830
0.840
0.850
0.860
0.870
0.880
0.890
0.900
0.910
0.920
0.930
0.940
0.950
0.960
0.970
0.980
0.990
1.000

y1
0.967
0.969
0.970
0.972
0.974
0.976
0.977
0.979
0.980
0.982
0.983
0.985
0.986
0.987
0.989
0.990
0.991
0.992
0.994
0.995
0.996
0.997
0.998
0.999
1.000

T ( C)
42.9228
42.5794
42.2402
41.9052
41.5742
41.2473
40.9244
40.6052
40.2899
39.9782
39.6701
39.3656
39.0645
38.7669
38.4726
38.1815
37.8936
37.6089
37.3273
37.0487
36.7730
36.5003
36.2304
35.9634
35.6990

T-xy and yx diagrams for npentane (1)/n-heptane (2)

system at 101.3 kPa