e

p ndice

Magnitudes termodinmicas de una

seleccin de sustancias a 298.15 K(25C)
Sustancia

Aluminio
Al(s)

AICl3(s)
A1 20 3 (s)

Azufre
5(s, rmbico)

Sg(g)
S02(~)

S03(g)
S042-(ac)

SOCl2(l)

H 2S(g)
H 2S0 4(ac)
H 2S0 4(l)

tiRJ
(kJ/moJ)

-705.6
-1669.8

Berilio
Be(s)
BeO(s)

Be(OHh(s)
Bromo
Br(g)
/:3r-(ac)
Bfl(g)

Brz(l)

HBr(g)

(J/mol-K)

Sustancia

C(5, grafito)
CCl 4(g)
CCl 4(1)
CF4(\,,)

49.7
-300.4
-370.4
-744.5

31.88
430.9
248.5
256.2
20.1

C2H 1(g)
C2H 4(g)
C1 H 6(g)
C3H s(g)
C4H lO (\,,)
C4H lO (l)

-33.01
-744.5
-689.9

205.6
20.1
156.1

o
-630.0
-1576.5

CH4(~)

o
102.3
-296.9
-395.2
-909.3
-245.6
-20.17
-909.3
-814.0

o
-1216.3
-553.5

C6H6(~)

o
-1137.6
-525.1

63.2
112.1
70.42

C6H 6(1)

CHpH(g)
CH 30H(I)
C2H sOH(g)
C2H 50H(l)
C6H 1z6(S)
CO(g)
CO 2(g)
HC 2H 30 2(1)

o
-608.4
-905.8

m.8
-120.9
30.71
O
-36.23

Calcio
179.3
Ca(g)
Ca(s)
O
CaC0 3 (s, calcita) -1207.1
CaCl2(s)
-795.8
CaF2(s)
-1219.6
CaO(s)
-635.5
Ca(OHh(s)
-986.2
-1434.0
Ca50 4(5)

Carbono
C(g)
C(5, diamante)

so

28.32
109.3
51.00

Bario
Ba(s)
BaC0 3(1')
8aO(5)

tiC?
(k]/mol)

718.4
1.88

o
-579.1
-817.9

9.44
13.77
50.21

82.38
-102.8
3.14
O
-53.22

174.9
80.71
245.3
152.3
198.49

145.5
O
-1128.76
-748.1
-1167.3
-604.17
-898.5
-1321.8

154.8
41.4
92.88
104.6
68.87
39.75
83.4
106.7

672.9
2.84

158.0
2.43

so

tiRJ
(kJ/mol)

tiC?
(k]mol)

O
-106.7
-139.3
-679.9
-74.8
226.7
52.30
-84.68
-103.85
-124.73
-147.6
82.9
49.0
-201.2
-238.6
-235.1
-277.7
-1273.02
-110.5
-393.5
-487.0

-64.0
-68.6
-635.1
-50.8
209.2
68.11
-32.89
-23.47
-15.71
-15.0
129.7
124.5
-161.9
-166.23
-168.5
-174.76
-910.4
-137.2
-394.4
-392.4

5.69
309.4
214.4
262.3
186.3
200.8
219.4
229.5
269.9
310.0
231.0
269.2
172.8
237.6
126.8
282.7
160.7
212.1
197.9
213.6
159.8

76.50
2.09
O
-442.8

49.53
0.03
O
-414.4

175.6
92.07
85.15
101.2

121.7
-167.2
O
-167.2
-92.30

105.7
-131.2
O
-131.2
-95.27

165.2
56.5
222.96
56.5
186.69

439
O

393
O

179
28.4

338.4
O
-205.9
-156.1
-170.7

298.6
O
-161.7
-128.3
-147.9

166.3
33.30
108.1
42.59
92.36

(J/mol-K)

Cesio
Cs(~)

Cs(l)

Cs(s)
CsCl(s)
Cloro
Cl(g)

Cnac)
Cl 2(g)
HCl(ac)
HCl(g)
Cobalto
Co(g)

Co(s)
Cobre
ClI(g)
ClI(S)

CuCl 2(s)
CuO(s)
CU20(S)

--e --.---- -

Sustancia
Cromo
Cr(g)
Cr(s)
CrZ03(;)
Escandio
Sc(g)
5(:(5)
E:;;troneio
Sf(S)
Sr(g)
Flor
F(g)
P-(ac)

F2(g)
HF(g)

-.-..

(?.--_._._~

.-.--.--...

--.-----.~

-~-

-_.- ----.-- . ..

~HJ

~Gr

(kJ/mol)

(kJmol)

O/mol-K)

352.6
O
-1058.1

174.2
23.6
81.2

397.5
O

-1139.7
377.8

336.1

174.7
34.6

-592.0
164.4

-561.9
110.0

54.9
164.6

80.0
-332.6
O
-268.61

61.9
-278.8
O
-270.70

158.7
-13.8
202.7
173.51

316.4
144.3
58.9
-17.46

280.0
103.7
24.4
-12.03

163.2
218.1
280
22.85
41.08
311.7
217
300.8
210.2

Fsforo

P(g)
Pz(g)
P4 (g)
P4(s, roj.o)
P4(5, blanco)
PCI 3(g)
PCI 3(l)

Pf5(g)
PH 3 (g)

P40 6(S)
P40 1O(s)
POC1 3(g)
POCJ 3(l)
H 3P0 4(ac)

-288.07
-319.6
-1594.4
5.4
-1640.1
-2940.1
--542.2
-597.0
-1288.3

-269.6
-272.4
-1520.7
13.4

-2675.2
-502.5
-520.9
-1142.6

228.9
325
222
158.2

Hidrgeno

H(g)
H+(ac)
H+(g)
H 2 (g)
Hierro
Fe(g)
Fe(s)
Fe 2+ (ac)

Fe3+(ac)
FeCl 2(s)
FeC13(s)
FeO(s)
Fe203(S)
Fe304(S)
FeS2(S)
Litio
Li(g)
Li(s)
Li+(ac)

217.94
O
1536.2
O

203.26
O
1517.0
O

114.60
O
108.9
130.58

~-

-- .....----.-- - -- .... - ... _. ,-

Sustancia
U+(g)
LiCl(s)
Magnesio
Mg(g)
Mg(s)
MgCl 2(s)
MgO(s)
Mg(OH)z(s)

-87.86
-47.69
-341.8
..,.400
-271.9
-822.16
-1117.1
-171.5

159.3
O
-278.5

369.8
O
-84.93
-10.54
-302.3
-334
-255.2
-740.98
-1014.2
-160.1

180.5
27.15
113.4
293.3
117.9
142.3
60.75
89.96
146.4
52.92

126.6

138.8
29.09
12.2

-273.4

~GJ

(kJlmol)

O/mol-K)

685.7
-408.3

648.5
-384.0

133.0
59.30

147.1

112.5
O
-592.1
-569.6
-833.7

148.6
32.51
89.6
26.8
63.24

173.6
32.0
59.7
53.14
191.2

-641.6
-601.8
'-924.7

Manganel'o
Mn(g)
Mn(s)
MnO(s)
Mn02(S)
Mn04'(ac)

280.7
O
-385.2
-519.6
-54104

238.5
O
-362.9
-464.8
-447.2

Mercurio
Hg(g)
Hg(l)
HgCl2(s)
Hg 2C1 2(s)

60.83
O
-230.1
-264.9

31.76
O
-184.0
-210.5

174.89
77.40
144.5
192.5

429.7

384.5
O
-259.0
-211.7

182.1
29.9
97.65
37.99

Nquel
Ni(g)
Ni(s)
NiCl2(s)
NiO(s)
Nitrgeno
N(g)
N 2(g)
NH 3(ac)
NH 3(g)
NH 4 +(ac)
N zH 4(g)
NH 4CN(s)
NH 4Cl(s)
NH 4 N0 3 (s)
NO(~)

415.5

~Hr

(kJ/mol)

N02(~)

Nz(g)
N 20 4(g)
NOCl(g)
HN0 3(ac)
HN0 3(g)
Oxgeno
O(g)
2(g)
3(g)
OH-(ac)
H 2(g)
H 2(l)
HP2(g)
Hpz(l)

-305.3
-239.7

153.3
191.50

472.7
O
-80.29
-46.19
-132.5
95.40
0.0
-314.4
-365.6
90.37
33.84
81.6
9.66
52.6
-206.6
-134.3

-203.0
-184.0
86.71
51.84
103.59
98.28
66.3
-110.5
-73.94

94.6
151
210.62
240.45
220.0
304.3
264
146
266.4

247.5

230.1

161.0
205.0
237.6
-10.7
188.83
69.91
232.9
109.6

142.3
-230.0
-241.82
-285.83
-136.10
-187.8

455.5
O
-26.50
-16.66
-79.31
159.4

163.4
-1573
-228.57
-237.13
-105.48
-120.4

111.3
192.5
113.4
238.5

Apndice C Magnitudes termodinmicas de una seccin de sustancias a 298.15 K (25C)

6.GJ
(kJ/mol)

Sustancia

6.HJ
(kJ/mol)

Plata
Ag(s)
Ag"'(ac)
AgCl(s)
AgzO(s)
AgN0 3(s)

O
105.90
-127.0
-31.05
-124.4

Plomo
Pb(s)
PbBrz(s)
PbC03 (s)
Pb(N0 3)z(l1c)
r'b(NOJ)z(s)
PbO(s)

O
-277.4
-699.1
-421.3
-451.9
-217.3

O
-260.7
-625.5
-246.9
-187.9

68.70

89.99
O
-435.9
-391.2
-349.5
-1150.18
-492.70
-363.2
-284.5
-495.8
-424.7
-482.4

61.17
O
-408.3
-289.9
-284.9
-1064.58
-393.13
-322.1
-240.6
-429.8
-378.9
-440.5

160.2
64.67
82.7
143.0
265.7
155.44
288.1
94.14
122.5
113.0
78.91
91.6

Potasio
K(g)
K(s)
KCl(s)
KClOJ(s)
KClO 3(tIC)
K ZC0 3(s)
KN0 3(s)
KP(s)
KOz(s)
K 2O Z(s)
KOH(s)
KOH(ac)
Rubidio
Rb(g)
Rb(s)
RbCl(s)
RbClO 3(s)

77.11
-109.70
. -11.20
-33.41

85.8
O
-430.5
-392.4

55.8
O
-412.0
-292.0

29.7

15.9

O/mol-K)

SiCl4 (l)
SiOz(s, cuarzo)

42.55
73.93
96.11
. 121.3
140.9

Silicio
Si(g)

Na(g)
Na(s)
Na+(ac)
Na+(g)
NaBr(ac)
NaBr(s)
Na ZC03(s)
NaCl(ac)
NaCl(g)
NaCl(s)
NaHC03(s)
NaN0 3(ac)
NaN0 3(s)
NaOH(ac)
NaOH(s)

68.85
161
131.0
303.3

Titanio
Ti(g)
Ti(s)
TiCl#)
TiCl4 (1)
TiOz(s)
Vanadio
V(g)
V(s)

170.0
76.78
92
152

Yodo
1(g)
nac)
1z(g)
1z(5)

Si(s)

SiC(s)

HI(g)

368.2
O
-73.22

323.9
O
-70.85

6. Hl
(kJ/mol)

6.GJ
(kJ/mol)

-640.1
-910.9

-572.8
-856.5

239.3
41.84

107.7
-240.1
609.3
-360.6
-361.4
-1130.9
-407.1
-181.4
-410.9
-947.7
-446.2
-467.9
-469.6
-425.6

. 77.3
O
-261.9
574.3
-364.7
-349.3
-1047.7
-393.0
-201.3
-384.0
-851.8
-372.4
-367.0
'-419.2
-379.5

153.7
51.45
59.0
148.0
141.00
86.82
136.0
115.5
229.8
72.33
102.1
207
116.5
49.8
64.46

468
O
-763.2
-804.2
-944.7

422
O
-726.8
-728.1
-889.4

180.3
30.76
354.9
221.9
50.29

514.2

453.1

182.2
28.9

106.60
-55.19
62.25
O
25.94

70.16
-51.57
19.37
O
1.30

180.66
111.3
260.57
116.73
206.3

S
O/mol-K)

Sodio

Selenio
Hze(~)

Sustancia

1043

219.0
Zinc
Zn(g)
Zn(s)
ZnClz(s)
ZnO(5)

167.8
18.7
16.61

~.

130.7
O

-415.1
-348.0

95.2
O
-369.4
-318.2

160.9
41.63
111.5
43.9