poss oo NAL SS Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page I Substance key: 000000060961 Revision Date: 11/10/2004 Version : 1 -2/USA Date of printing :11/19/2004 Section 01 - Product informati Tdentification of the Clariant Corporation ‘company: +4000 Monroe Road Charlotte, 28205 Telephone No.: +1 704 931 7000 Information of the substance/preparation: Product Safety 1-704-381-7710 Emergency tel. number: +1 800-424-9300 CHEMTREC. Trade name: NIPACIDE BK 4719-04-4 5: Product Has No Synonyms Primary productuse: _Microbiocide: Usa EPA FIFRA Registration #49403-16. It Is A Violation Of Federal Law To Use This Product In A Manner Inconsistent With Its Labeling Chemical family: 1,3,S4tris(2-hydroxyethyi)hexahydrotriazine ion information on hazardous ingredients Section 02 - Composit Hazardous ingredients: Component TCAS=no. (Trade secret Concentration no) HewanyaoT SST TASOEE TES% (2-Hydroxyethyl)}-S-Triazine ‘Section 03 - Hazards identification Expected Route of entry: Inhalation: yes Skin contact yes Eye contact: yes Ingestion: 0 Skin absorptior no Health effects of exposure: Nipacide 8k ‘Causes severe eye and skin damage. Harmful if swallowed. Known effects on other illnesses: No known effects on other illnesses for this product Listed carcinogen: IARC: No NTP: No OSHA: No Other: Nox Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page 2 Substance key: 000000060961 Revision Date: 11/10/2004 Version: 1-2/ USA Date of printing 11/19/2004 Ms: Health: 3 Flammability: 1 Reactivity: 0 Personal protection: Section 04 - First aid measures After inhalation: Get victim to fresh air. Give artificial respiration or oxygen if breathing has stopped. Get prompt medical attention. Do not give fluids if victim is unconscious. After contact with ski Remove contaminated ciothing. Flush all affected areas with large amounts of water for at least 15 minutes. Seok medical attention immediately. After contact with eyes: Immediately flush eyes with large amounts of water for atleast 15 minutes, holding lids apart to ensure flushing of the entire surface. Washing eyes within 1 minute is essential to achieve maximum effectiveness. Seek medical attention immediately. After ingestion: Ifingested, drink promplly a large quantity of mik, egg whites, gelatin solution, or if these are not available, drink large quantities of water. Seek immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconcious person, ‘Advice to doctor / Treatment: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsion may be needed. Section 05 - Fire fighting measures } Hazardous combustion products: {In case of fires, hazardous combustion gases are formed: Nitrogen oxides (NOx) Carbon monoxide (CO) Extinguishing me: water spray jet ry powder sand. alcohol-resistant foam Special fire fighting procedure: Exercise caution when fighting any chemical fire. Use NIOSH approved self-contained breathing apparatus and full protective clothing, Unusual fire and explosion _ Emits toxic and corrosive fumes under fire conditions. hazards: Section 06 - Accidental release measures ‘Stops to be taken in case of spill or leak: ‘Wearing appropriate personal protective equipment, contain spill, colect into suitable container. For large spills, contain spills with dikes of soil or commercially available diking ‘material and collect into suitable containers for disposal. Avoid washing spills into sewers andx Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page 3 ‘Substance key: 000000060961 Revision Date: 11/10/2004 Version: 1 -2/ USA Date of printing :11/19/2008 waterways. This product is toxic to fish, See special precautions section of msds for further information, [Section 07 - Handling and storage ‘Advice on sate handling: ‘Store in original container, tightly closed and in a safe place, Do not use or store near heat or open time, Do not contaminate water, food or feed by storage or disposal Further info on storage conditions: ‘Store in original container. Keep containers closed. ‘Section 08 - Exposure controls / personal protection Respiratory protection: It airborne concentrations pose a health hazard, become irritaling ‘or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29 CFR 1910.134 Hand protection: Rubber. Eye protection: ‘As requited, a niosh approved respirator with a full facepioce wil give eye protection, or chemical splash proof goggles and a faceshield, Other protective equipment: Protective clothing to minimize skin contact should be wor. Chemically resistant safety shoes. Wash contaminated clothing with soap and water and dry before reuse. Safety showers and ‘eyewash stations should be provided in all areas where this, ‘material is handled, ‘Advice on system design: —_Local ventilation recommended - mechanical ventilation may be used, IDLH: Not Determined [Section 09 - Physical and chemical properties Form: Liquid, viscous Color: colourless to pale colour Odor: amine-ike pH: 9.8 - 108 (100 gf) Solubility in water: completely soluble Density: approx. 1.16 gicms (20 *C) Boiling point : from 212 °Fs Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page 4 ‘Substance key: 000000060961 Revision Date: 11/10/2004 Version : 1 -2/USA Date of printing °11/19/2004 Section 10 - Stability and reactivity ‘Thermal decomposition: No decomposition if used as prescribed. Chemical stability: Stable Hazardous Polymerization: Will not occur. Conditions to avoid: None known, Conditions to avoid: ‘None known, ‘Section 11 - Toxicological information Product information: Acute oral toxicity: LD50 <2,000 mg/kg (rat) Skin irritation: Not available Not available [Section 12 - Ecological information Product information: Biodegradation: 96% Method: OECD 301D * 1981 closed bottle test (ready) Source: literature The product is biodegradable. Bacteria toxicity: C5029 mg/l (0.25 h, Photobacterium phosphoreum) Method: Microtox test Source: literature 360 mgf Method: respiration inhibition method Source: literature Posticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture or rinsate is a violation of federal law. If these wastes cannot be disposed of by use according to label instructions, contact your state pesticide or environmental control agency, or the hazardous waste representative at the nearest EPA regional office for guidance. Do not contaminate water, food or feed by storage or disposal Container disposal: tripie rinse(or equivalent), Then otfer for recycling or reconditioning, (or puncture and dispose of in a sanitary landfil, or incineration, or it allowed by state and local authorities, by burning. If bumed, stay out of smoke. RCRA hazardous waste: No Not as sold. CRA number: NONE< S Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page $ ‘Substance key: 000000060961 Revision Date: 11/10/2004 Version ; 1- 2/ USA Date of printing :1 1/19/2004 ‘Section 14 - Transport information oT not restricted IATA not restricted imoG not restricted [Section 15 - Regulatory information TSCA Status: ‘All components of this product are listed on the TSCA Inventory SARA (section 311/312): Reactive hazard: no. Pressure hazard: no. Fire hazard: no. Immediate/acute: yes Delayediehronic: lo. SARA 313 information: ‘This product does not contain any toxic cherrical listed under Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986. Clean Water Act: Contains no known priority pollutants at concentrations greater than 0.1%. Volatile organic compounds VOC: Remarks’ Not Available FDs ‘This product is not registered with the FDA. ‘Section 16 - Other information Other precaution: Environmental Hazard: This pesticide is towic to fish. Do not discharge effluent containing this, product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent Containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your state water board or regional office of the EPA. Avoid breathing fumes or vapors and avoid contact with skin and eyes. Wear proper protective equipment. Keep container closed when notin use. Label information: WARNING! ‘When shipping this product use pre-printed tabels supplied through Product Safety, Functional Chemicals Division, Labels must comply with the Federal insecticide, Fungicide and Rodentacide Act (FIFRA)& Clariant MATERIAL SAFETY DATA SHEET NIPACIDE BK Page 6 ‘Substance key: 000000060961 Revision Date: 11/10/2004 Version: 1-2/USA Date of printing "11/19/2004 This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygione and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are ‘appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof, We assume no responsibilty for damage or injury from the use of the product described herein, Data provided here are typical and not intended for use as product specifications. (R) and TM indicate trademarks of Clariant AG, its business partners or suppliers.