41. A solution is prepared by dissolving 24.5 g of sodium hydroxide in distilled water to give 1 L solution. The molarity of NaOH in the solution is (Given, molar mass of NaOH = 40.0 g mol”) (@) 0.2450M —(b) 0.6125 M (© 0.9800M —(d) 1.6326 M 42, An electron with values 4, 3,—2.and+ 3 forthe set of four quantum numbers n, l,m; and m,, respectively, belongs to (@) Asorbital (>) 4p-orbital © 4¢-orbital @) 4f-orbital 43. The electronic configuration (ols)? (@1s)"(02s)(62s)"(o2p, (x2p,F (2p, PE 2p, PCH 2p,F can be assigned to @) 0, (b) 03 © 0; @ oF }. What is the number of tetrahedral voids per atom in a crystal? @1 (b) 2 @6 @s In an osmotic pressure measurement experiment, a 5% solution of compound ‘X" is found to be isotonic with a 2% acetic acid solution, The gram molecular mass of ‘X" is (@ 24 @) 60 © 150 @ 300 . On pasting 0.5 faraday of electricity through molten sodium chloride,sodium deposited at cathode will be (a) 29.253 © 58.503 () 11.508 (@ 0.008 47. The rate constant of a reaction is 3.00x10° L mols". The order of this reaction will be (@) zero (b) first (© second @) third48. The value of 4 £ for combustion of 16 g of CH, is -885389 J at 298 K. The AH combustion for CH, in J mol” at this temperature will be (Given that R = 8.314 JK“'mol”) (a) - 55337 () - 880430 (© ~ 885389 (d) ~ 890344 When two moles of hydrogen expands isothermally against a constant pressure of 1 atm, at 25°C from 15 L to 50 L, the work done Gin L atm) will be @ 175 () 35 © 515 (@) 70 50. The enthalpy change for the transition of liquid ‘water to steam is 40.8 kJ per mol at 100°C. The entropy change for the process will be (@) 0.408 JK" mot"! (b) 408 JK* mol (©) 109.4 JK molt (@) 0.1094 JK mol" 51. The entropy change for the reaction H,(g)+ Cl) —> 2HCIGg), will be [Given, $° (HC) = 187 JK mol", S°(H,)=131 JK7 mo, and $°(Cl,)= 223K" mol] (@) 20JK* mol (b) -20JK™ mol" (© 167 JK* mol" (d) -167 JK mol 52, If the temperature of 500 mL of air increases from 27°C to 42°C under constant pressure, then the increase in volume shall be (a) 15 mL () 20 mt. (©) 25 mL @ 30m. 53. Which of the following pair of structures is an example of diastereomers? COOH (oa and KB ro and ZO a Ne eee News @ i o. f (b) a HL pBr v7 © en Now, 54, 55. 56. 37. 58. o: H ih @ and H oO 0 A: HO 6H Which of the following pair of compounds is not an example of structural isomers? - : @ ~AA and eee oy AL ant 2 © Zim ang S278 @ Ne and DX ‘The systematic (IUPAC) name of the compound with the following structural formula will be Pa Oo (@) T-ethy!-2-methyl cyclohexene (b) 2-methyl-t-ethyl cyclohexene © 3-ethyl-2-methyl cyclohexene @ 4-ethyl-3-methyl cyclohexene Which of the following compounds will form alcohol on treatment with NaNO,, HCI/ 1,0 at oc? (@) (CH3),CHNH, (©) CyHNH, © SS In the nucleophilic substitution reactions (S,20rS,1), the reactivity of alkyl halides follows the sequence (@) R—I>R—Br > R—Cl> R—F (b) R—Cl> R—F>R—Br>R—1 (© R—F>R—Cl>R—Br>R—I @ R—I>R—F > R—Cl> R—Br Compound ‘A’ reacts with alcoholic KOH to yield compound ‘B’, which on ozonolysis59. 61. followed by reaction with Zn/H,0_ gives methanal and propanal. Compound ‘A’ is (@) 1-propanol —_(b) 1-butanol (©) L-chlorobutane (4) 1-chloropentane In the reaction sequence cl, Cl, x, yo, FeCl» 1,50, Oo jin O a 1H- , compound ‘X" is (a) chlorobenzene (b) benzene (©) toluene (d) biphenyl methane In the sequence of reactions, HBr AgCN, =— ct, 2S x ta ¥——>z, HA/Ni compound ‘2"is (@) N-methyl ethanamine (b) N-propylamine (© N,N-dimethylamine @ ethyl cyanide In the reaction sequence, H0® 4 SHH AM EBS CoHt,0 compound ‘A’ is (@) L-propancl —(b) propanal © ethanal (@) 2-propanol Which of the following compounds is weakest acid? 63. 67. Acetophenone can be ‘ethylbenzene by reaction with (@) LAI, (b) H,NOH (©) Pa/BaSO,—Hy (@) Zn-Hg/HCl Which of the following hydroxides is amphoteric in nature? converted to (@) Be(OH), (b) Mg(OH), (© Ca(OH), (@) Ba(OH), Number of electrons in 3d-orbital of v*,cr*, Mn and Fe” are 3, 4, 5 and 6, respectively. Which of the following ions will have largest value of magnetic moment (11)? @ v* ®) cr (© Mn? @ Fe* ). The coordination compounds [Co(NH, )g]** [Cr(CN),]** and [Cr(NH,)g]** [Co(CN),]* are the examples of (@) linkage isomerism (©) coordination isomerism (©) ionisation isomerism (@) geometrical isomerism ‘The spontaneous disintegration of 3$°U by loss ‘of eight a-particles and six -particles terminates at (@) “Ra &) BiPo © th @ Pb ‘The relative Lewis acid character of boron trihalides follows the sequence (a) BF, > BCl, > BBr, > BI, () Bl, > BBr, > BCL, > BF, (©) BCL, > BF, > Bl; > BBr, (@) Bl, > BBr, > BF, > BCL, The tendency for catenation in group 14 clements varies in the order (a) C>>Si>Ge=Sn> Pb (b) C<>Si>Si=Ge=Sn> Pb ‘The thermal stability of CF, is {@) less than SiF, (b) more than Sif, (©) less than CCl, (@) less than Sicl,mn. 72. 73. 74. Which of the following enzymes hydrolyses starch to glucose? @ Amylase (b) Invertase (©) Lactase (d) Maltase Which of the following reactions is an example of heterogeneous catalysis? (@) 0, +0 -4s 20,as phase) () 2€06)+ 0,2) 8% 260,46) 1 (© cH, —C—0CH,(0 + Hoa) 2895 ci, —C—on) + 6,8,080) Cu,2n0—Cr,03 CH;OH() If one strand of DNA has the sequence ‘TATGACTG, the sequence in the complimentary’ strand would be (@) ATACACTC (b) ACGTTGAC (© ATACTGAC (@ ATACTGCA Which of the following hormones is secreted from adrenal cortex? @ COCg) + 2H,(g) 75. 78. (a) Cortisone (b) Estrogen (©) Progesterone (4) Testosterone ‘Which of the following compounds is an azo dye? (a) Martius yellow (b) Malachite green (©) Methyl orange (@) Mercurochrome . Which of the following is a thermosetting polymer? (a) Bakelite (b) Polystyrene (©) Polyethene (4) Terylene 7. The carbohydrate that will yield glucose and fructose on homogeneous catalytic hydrolysis in presence of dilute sulphuric acid, is (a) cellulose (b) maltose (©) starch (@) sucrose The gas that is not considered as a “green house gas” is (a) CO, ©o, (b) CH, @) 05 The enzyme that is used to dissolve blood clot is (a) trypsin () renin (©) streptokinase (d) tyrosinase ). Which of the following compounds is known as the antisterility factor? (a) a-tocopherol (b) Retinol © Calciferol (qd) Pyridoxine Answer — Key